Citation: Jingshuo Zhang, Yue Zhai, Ziyun Zhao, Jiaxing He, Wei Wei, Jing Xiao, Shichao Wu, Quan-Hong Yang. 锂离子电池硅基负极用功能粘结剂的研究进展[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230600. doi: 10.3866/PKU.WHXB202306006 shu

锂离子电池硅基负极用功能粘结剂的研究进展

Jingshuo Zhang ¹ ,
Yue Zhai ¹ ,
Ziyun Zhao ¹ ,
Jiaxing He ¹ ,
Wei Wei ³ ,
Jing Xiao ^1,3,4 ,
Shichao Wu ^1,2,, ,
Quan-Hong Yang ^1,2,3,4,,

1.
Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), and National Industry-Education Integration Platform of Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China;
2.
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China;
3.
Tianmu Lake Institute of Advanced Energy Storage Technologies, Liyang 213300, Jiangsu Province, China;
4.
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou 350207, China

Corresponding author: Shichao Wu, Quan-Hong Yang,
Received Date: 2 June 2023
Revised Date: 5 July 2023
Accepted Date: 20 July 2023

Fund Project: The project was supported by the National Key Research and Development Program of China (2021YFF0500600) and the National Natural Science Foundation of China (U2001220, 52272231).

硅（Si）具有超高的理论比容量、较低的嵌锂电位及丰富的储量等优势，是发展高比能锂离子电池的关键负极材料。同纳米Si相比，低成本、高振实密度和低界面反应的微米Si应用于高体积能量密度器件独具优势。然而其300%体积形变产生的巨大应力，使得颗粒破碎粉化、电极结构退化以及导电网络失效等问题更为严峻，极大制约了其商业化进程。粘结剂是适应Si体积变化，提供稳定导电网络的重要手段。开发高容量、高稳定微米Si基负极对粘结体系设计提出了更大的挑战。本文首先阐明了粘结剂的基础功能与粘结机制，然后从自愈合、电子导电、离子导电以及参与固态电解质层构建四个方面，总结了Si基负极用功能粘结剂的设计策略和作用原理，最后展望了面向实用化的Si基负极功能粘结剂面临的挑战和未来发展方向。
- Lithium-ion battery,
- Silicon-based anode,
- Functional binder,
- Self-healing polymer,
- Conductive polymer
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沈阳化工大学材料科学与工程学院沈阳 110142