Citation: ZilinHu, YaoshenNiu, XiaohuiRong, Yongsheng Hu. Ni³⁺抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230600. doi: 10.3866/PKU.WHXB202306005 shu

Ni³⁺抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减

ZilinHu ^1,2 ,
YaoshenNiu ¹ ,
XiaohuiRong ^1,2,3,, ,
Yongsheng Hu ^1,2,3,4,,

1.
Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
2.
College of Materials Science and Optoelectronic Technology, University of Chinese Academy of Sciences, Beijing 100049, China;
3.
Yangtze River Delta Physics Research Center Co. Ltd., Liyang 213300, Jiangsu Province, China;
4.
Huairou Division, Institute of Physics, Chinese Academy of Sciences, Beijing 101400, China

Corresponding author: XiaohuiRong, Yongsheng Hu,
Received Date: 1 June 2023
Revised Date: 29 June 2023
Accepted Date: 17 July 2023

Fund Project: The project was supported by the National Key R&D Program of China (2022YFB2402500), the National Natural Science Foundation of China (51725206, 52122214, 52072403, 52002394), the Youth Innovation Promotion Association of the Chinese Academy of Sciences (2020006), the Beijing Municipal Natural Science Foundation (2212022), the Young Elite Scientists Sponsorship Program by CAST (2022QNRC001).

由于钠资源丰富，钠离子电池在大规模储能方面显示出巨大的潜力。随着近年来研究的深入，在正极材料中引入适量的阴离子氧化还原可以有效地提升钠离子电池的能量密度，同时减少高成本过渡金属元素如V、Co和Ni等的用量。有研究表明，材料循环过程中不可逆的氧损失以及Mn⁴⁺/Mn³⁺氧化还原的激活，导致了层状氧化物正极材料持续的电压衰减。本工作通过在Na_x[Li，Ni，Mn]O₂基钠离子电池正极材料中引入Ni³⁺作为Mn⁴⁺/Mn³⁺氧化还原屏障，利用Ni³⁺/Ni²⁺的氧化还原代替Mn⁴⁺/Mn³⁺的氧化还原，成功抑制了材料的电压衰减。电化学测试结果显示，改性材料在不损失容量的前提下，循环稳定性得到明显提升。X射线光电子能谱结果也验证了Ni³⁺的引入有利于维持材料多周循环后Mn价态的稳定。
- Na-ion battery,
- Anion-redox,
- Voltage decay,
- Single-phase solid solution reaction
1. [1]
  (1) Li, Y.; Lu, Y.; Zhao, C.; Hu, Y.-S.; Titirici, M.-M.; Li, H.; Huang, X.; Chen, L. Energy Stor. Mater. 2017, 7, 130. doi:10.1016/j.ensm.2017.01.002
2. [2]
  (2) Zhao, E.; Nie, K.; Yu, X.; Hu, Y. S.; Wang, F.; Xiao, J.; Li, H.; Huang, X. Adv. Funct. Mater. 2018, 28, 1707543. doi:10.1002/adfm.201707543
3. [3]
  (3) Zhao, C.; Liu, L.; Qi, X.; Lu, Y.; Wu, F.; Zhao, J.; Yu, Y.; Hu, Y.-S.; Chen, L. Adv. Energy Mater. 2018, 8, 1703012. doi:10.1002/aenm.201703012
4. [4]
  (4) Zhao, C.; Lu, Y.; Yue, J.; Pan, D.; Qi, Y.; Hu, Y.-S.; Chen, L. J. Energy Chem. 2018, 27, 1584. doi:10.1016/j.jechem.2018.03.004
5. [5]
  (5) Lu, Z.; Dahn, J. R. J. Electrochem. Soc. 2001, 148, 1225. doi:10.1149/1.1407247
6. [6]
  (6) Lee, D. H.; Xu, J.; Meng, Y. S. Phys. Chem. Chem. Phys. 2013, 15, 3304. doi:10.1039/c2cp44467d
7. [7]
  (7) Kim, D.; Kang, S.-H.; Slater, M.; Rood, S.; Vaughey, J. T.; Karan, N.; Balasubramanian, M.; Johnson, C. S. Adv. Energy Mater. 2011, 1, 333. doi:10.1002/aenm.201000061
8. [8]
  (8) Clément, R. J.; Xu, J.; Middlemiss, D. S.; Alvarado, J.; Ma, C.; Meng, Y. S.; Grey, C. P. J. Mater. Chem. A 2017, 5, 4129. doi:10.1039/c6ta09601h
9. [9]
  (9) Wang, P. F.; You, Y.; Yin, Y. X.; Wang, Y. S.; Wan, L. J.; Gu, L.; Guo, Y. G. Angew. Chem. Int. Ed. 2016, 55, 7445. doi:10.1002/anie.201602202
10. [10]
  (10) Xu, J.; Lee, D. H.; Clément, R. J.; Yu, X.; Leskes, M.; Pell, A. J.; Pintacuda, G.; Yang, X.-Q.; Grey, C. P.; Meng, Y. S. Chem. Mater. 2014, 26, 1260. doi:10.1021/cm403855t
11. [11]
  (11) Yoshida, H.; Yabuuchi, N.; Kubota, K.; Ikeuchi, I.; Garsuch, A.; Schulz-Dobrick, M.; Komaba, S. Chem. Commun. 2014, 50, 3677. doi:10.1039/c3cc49856e
12. [12]
  (12) Wu, X.; Guo, J.; Wang, D.; Zhong, G.; McDonald, M. J.; Yang, Y. J. Power Sources 2015, 281, 18. doi:10.1016/j.jpowsour.2014.12.083
13. [13]
  (13) Kubota, K.; Yoda, Y.; Komaba, S. J. Electrochem. Soc. 2017, 164, A2368. doi:10.1149/2.0311712jes
14. [14]
  (14) Kubota, K.; Kumakura, S.; Yoda, Y.; Kuroki, K.; Komaba, S. Adv. Energy Mater. 2018, 8, 1703415. doi:10.1002/aenm.201703415
15. [15]
  (15) Komaba, S.; Yabuuchi, N.; Nakayama, T.; Ogata, A.; Ishikawa, T.; Nakai, I. Inorg. Chem. 2012, 51, 6211. doi:10.1021/ic300357d
16. [16]
  (16) Qi, X.; Wang, Y.; Jiang, L.; Mu, L.; Zhao, C.; Liu, L.; Hu, Y.-S.; Chen, L.; Huang, X. Part. Part. Syst. Charact. 2016, 33, 538. doi:10.1002/ppsc.201500129
17. [17]
  (17) Wang, P. F.; Yao, H. R.; Liu, X. Y.; Zhang, J. N.; Gu, L.; Yu, X. Q.; Yin, Y. X.; Guo, Y. G. Adv. Mater. 2017, 29, 1700210. doi:10.1002/adma.201700210
18. [18]
  (18) Zheng, L.; Obrovac, M. N. Electrochim. Acta 2017, 233, 284. doi:10.1016/j.electacta.2017.03.033
19. [19]
  (19) Zheng, S.; Zhong, G.; McDonald, M. J.; Gong, Z.; Liu, R.; Wen, W.; Yang, C.; Yang, Y. J. Mater. Chem. A 2016, 4, 9054. doi:10.1039/c6ta02230h
20. [20]
  (20) Yabuuchi, N.; Hara, R.; Kajiyama, M.; Kubota, K.; Ishigaki, T.; Hoshikawa, A.; Komaba, S. Adv. Energy Mater. 2014, 4, 1301453. doi:10.1002/aenm.201301453
21. [21]
  (21) Du, K.; Zhu, J.; Hu, G.; Gao, H.; Li, Y.; Goodenough, J. B. Energy Environ. Sci. 2016, 9, 2575. doi:10.1039/c6ee01367h
22. [22]
  (22) Rong, X.; Liu, J.; Hu, E.; Liu, Y.; Wang, Y.; Wu, J.; Yu, X.; Page, K.; Hu, Y.-S.; Yang, W.; et al. Joule 2018, 2, 125. doi:10.1016/j.joule.2017.10.008
23. [23]
  (23) de la Llave, E.; Talaie, E.; Levi, E.; Nayak, P. K.; Dixit, M.; Rao, P. T.; Hartmann, P.; Chesneau, F.; Major, D. T.; Greenstein, M.; et al. Chem. Mater. 2016, 28, 9064. doi:10.1021/acs.chemmater.6b04078
24. [24]
  (24) Rong, X.; Hu, E.; Lu, Y.; Meng, F.; Zhao, C.; Wang, X.; Zhang, Q.; Yu, X.; Gu, L.; Hu, Y.-S.; et al. Joule 2019, 3, 503. doi:10.1016/j.joule.2018.10.022
25. [25]
  (25) Yabuuchi, N.; Hara, R.; Kubota, K.; Paulsen, J.; Kumakura, S.; Komaba, S. J. Mater. Chem. A 2014, 2, 16851. doi:10.1039/c4ta04351k
26. [26]
  (26) Dai, K.; Wu, J.; Zhuo, Z.; Li, Q.; Sallis, S.; Mao, J.; Ai, G.; Sun, C.; Li, Z.; Gent, W. E.; et al. Joule 2019, 3, 518. doi:10.1016/j.joule.2018.11.014
27. [27]
  (27) Mortemard de Boisse, B.; Nishimura, S.-i.; Watanabe, E.; Lander, L.; Tsuchimoto, A.; Kikkawa, J.; Kobayashi, E.; Asakura, D.; Okubo, M.; Yamada, A. Adv. Energy Mater. 2018, 8, 1800409. doi:10.1002/aenm.201800409
28. [28]
  (28) Li, Y.; Wang, X.; Gao, Y.; Zhang, Q.; Tan, G.; Kong, Q.; Bak, S.; Lu, G.; Yang, X. Q.; Gu, L.; et al. Adv. Energy Mater. 2018, 9, 1803087. doi:10.1002/aenm.201803087
29. [29]
  (29) Song, B.; Tang, M.; Hu, E.; Borkiewicz, O. J.; Wiaderek, K. M.; Zhang, Y.; Phillip, N. D.; Liu, X.; Shadike, Z.; Li, C.; et al. Chem. Mater. 2019, 31, 3756. doi:10.1021/acs.chemmater.9b00772
30. [30]
  (30) Seo, D. H.; Lee, J.; Urban, A.; Malik, R.; Kang, S.; Ceder, G. Nat. Chem. 2016, 8, 692. doi:10.1038/nchem.2524
31. [31]
  (31) Zhao, C.; Wang, Q.; Lu, Y.; Hu, Y.-S.; Li, B.; Chen, L. J. Phys. D 2017, 50, 183001. doi:10.1088/1361-6463/aa646d
32. [32]
  (32) Rong, X.; Gao, F.; Lu, Y.; Yang, K.; Hu, Y. Chin. Chem. Lett. 2018, 29, 1791. doi:10.1016/j.cclet.2018.11.023
33. [33]
  (33) Ku, K.; Hong, J.; Kim, H.; Park, H.; Seong, W. M.; Jung, S.-K.; Yoon, G.; Park, K.-Y.; Kim, H.; Kang, K. Adv. Energy Mater. 2018, 8, 1800606. doi:10.1002/aenm.201800606
34. [34]
  (34) Hong, J.; Seo, D.-H.; Kim, S.-W.; Gwon, H.; Oh, S.-T.; Kang, K. J. Mater. Chem. 2010, 20, 10179. doi:10.1039/c0jm01971b
35. [35]
  (35) Evstigneeva, M. A.; Nalbandyan, V. B.; Petrenko, A. A.; Medvedev, B. S.; Kataev, A. A. Chem. Mater. 2011, 23, 1174. doi:10.1021/cm102629g
36. [36]
  (36) Li, Y.; Deng, Z.; Peng, J.; Chen, E.; Yu, Y.; Li, X.; Luo, J.; Huang, Y.; Zhu, J.; Fang, C.; et al. Chem. Eur. J. 2018, 24, 1057. doi:10.1002/chem.201705466
37. [37]
  (37) Wang, Y.; Yu, X.; Xu, S.; Bai, J.; Xiao, R.; Hu, Y. S.; Li, H.; Yang, X. Q.; Chen, L.; Huang, X. Nat. Commun. 2013, 4, 2365. doi:10.1038/ncomms3365
38. [38]
  (38) Xia, H.; Lu, L.; Ceder, G. J. Power Sources 2006, 159, 1422. doi:10.1016/j.jpowsour.2005.12.01
1. [1]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
2. [2]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
3. [3]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
4. [4]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
5. [5]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
6. [6]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . 层状双金属氢氧化物的层间阴离子对衍生的Ni-Al₂O₃催化剂光热催化CO₂甲烷化反应的影响. Acta Physico-Chimica Sinica, 2025, 41(1): 2309002-. doi: 10.3866/PKU.WHXB202309002
7. [7]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
8. [8]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
9. [9]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
10. [10]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
11. [11]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
12. [12]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
13. [13]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
14. [14]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
15. [15]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
16. [16]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
17. [17]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
18. [18]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
19. [19]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
20. [20]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006

Get Citation

PDF

XML

Metrics

PDF Downloads(2)
Abstract views(536)
HTML views(36)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ni3+抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减

Metrics

通讯作者: 陈斌, bchen63@163.com

Ni³⁺抑制具有阴离子氧化还原活性钠离子电池正极材料的电压衰减