Citation: Zhuoran Lu, Shengkai Li, Yuxuan Lu, Shuangyin Wang, Yuqin Zou. Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts[J]. Acta Physico-Chimica Sinica, ;2024, 40(4): 230600. doi: 10.3866/PKU.WHXB202306003 shu

Cleavage of C―C Bonds for Biomass Upgrading on Transition Metal Electrocatalysts

Zhuoran Lu ¹ ,
Shengkai Li ^1,2 ,
Yuxuan Lu ^1,3 ,
Shuangyin Wang ¹ ,
Yuqin Zou ^1,,

1.
State Key Laboratory of Chemo/Bio-Sensing and Chemometrics, Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China;
2.
Shenzhen Institute of Hunan University, Shenzhen 518057, Guangdong Province, China;
3.
School of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, Hunan Province, China

Corresponding author: Yuqin Zou, yuqin_zou@hnu.edu.cn
Received Date: 1 June 2023
Revised Date: 3 July 2023
Accepted Date: 3 July 2023

Fund Project: The project was supported by the National Key R&D Program of China (2020YFA0710000), the National Natural Science Foundation of China (22122901), the Provincial Natural Science Foundation of Hunan, China (2021JJ0008, 2021JJ20024, 2021RC3054), the Shenzhen Science and Technology Program, China (JCYJ20210324140610028).

Transforming the current structure of energy production and consumption, which currently excessively relies on fossil fuels, into a more efficient utilization of renewable energy, is an effective solution for addressing the energy crisis and achieving carbon neutrality. Biomass represents one of the most promising sources of renewable energy, capable of replacing fossil fuels and yielding valuable organic compounds. In recent years, the vigorous utilization of biomass energy sources has become an inevitable trend. The conventional thermochemical catalysis method used for biomass conversion often requires harsh conditions, such as high temperatures and pressures, and even external sources of hydrogen or oxygen. In comparison, the electrocatalytic conversion of organic molecules derived from biomass offers a greener and more efficient strategy for producing high-value chemicals under relatively mild conditions. Particularly, the cleavage of carbon chains through C―C bond cleavage is crucial in transforming biomass-derived molecules into short-chain chemicals of high value. Numerous studies have demonstrated that transition metal (TM) electrocatalysts play a critical role in the C―C bond cleavage of organic compounds, owing to their rich 3d electron structure and unique e_g orbitals that enhance the covalence of transition metal-oxygen bonds. Moreover, the coordination environments and electronic structures of TM electrocatalysts can influence the selectivity of the products. Undoubtedly, well-defined active sites and reaction pathways facilitate a comprehensive understanding of the structure-activity relationship between catalyst structure and reaction activity. However, the electrocatalytic cleavage of C―C bonds for biomass upgrading on TM electrocatalysts is still in its initial stages, and the reaction mechanism and catalytic processes remain unclear. Therefore, there is a need to systematically comprehend the role of electrocatalysts at the atomic level during the C―C bond cleavage process. This review begins by providing an overview of the extensively studied TM electrocatalysts that mediate C―C bond cleavage reactions of organic molecules derived from biomass, including glycerol, cyclohexanol, lignin, and furfural. Several representative examples and corresponding reaction pathways are presented. Subsequently, we systematically review the reaction mechanisms underlying the catalytic C―C bond cleavage by transition metal compounds, elucidate interfacial behaviors, and establish a structure-activity relationship between the structure of TM electrocatalysts and cleavage reaction activity. Finally, we provide a brief summary of the content covered and highlight the challenges and prospects in exploring C―C bond cleavage on TM electrocatalysts. It is anticipated that this work will serve as a guide for the controlled conversion of biomass and the rational design of TM electrocatalysts for C―C bond cleavage.
- Electrocatalytic biomass upgrading,
- C―C bond cleavage,
- Electrocatalysis,
- Transition metal catalyst
1. [1]
  (1) Araji, N.; Madjinza, D. D.; Chatel, G.; Moores, A.; Jérôme, F.; Vigier, K. D. O. Green Chem. 2017, 19, 98. doi: 10.1039/C6GC02620F
2. [2]
  (2) Li, K.; Sun, Y. Chem-Eur. J. 2018, 24, 18258. doi: 10.1002/chem.201803319
3. [3]
  (3) Du, L.; Shao, Y.; Sun, J.; Yin, G.; Du, C.; Wang, Y. Catal. Sci. Technol. 2018, 8, 3216. doi: 10.1039/c8cy00533h
4. [4]
  (4) Kim, H. J.; Kim, Y.; Lee, D.; Kim, J.-R.; Chae, H.-J.; Jeong, S.-Y.; Kim, B.-S.; Lee, J.; Huber, G. W.; Byun, J.; et al. ACS Sustain. Chem. Eng. 2017, 5, 6626. doi: 10.1021/acssuschemeng.7b00868
5. [5]
  (5) Wang, H.; Thia, L.; Li, N.; Ge, X.; Liu, Z.; Wang, X. ACS Catal. 2015, 5, 3174. doi: 10.1021/acscatal.5b00183
6. [6]
  (6) Dodekatos, G.; Schünemann, S.; Tüysüz, H. ACS Catal. 2018, 8, 6301. doi: 10.1021/acscatal.8b01317
7. [7]
  (7) Si, D.; Xiong, B.; Chen, L.; Shi, J. Chem Catal. 2021, 1, 941. doi: 10.1016/j.checat.2021.08.001
8. [8]
  (8) Li, Y.; Peng, Y.-K.; Hu, L.; Zheng, J.; Prabhakaran, D.; Wu, S.; Puchtler, T. J.; Li, M.; Wong, K.-Y.; Taylor, R. A. Nat. Commun. 2019, 10, 4421. doi: 10.1038/s41467-019-12385-1
9. [9]
  (9) Bambagioni, V.; Bianchini, C.; Marchionni, A.; Filippi, J.; Vizza, F.; Teddy, J.; Serp, P.; Zhiani, M. J. Power Sources 2009, 190, 241. doi: 10.1016/j.jpowsour.2009.01.044
10. [10]
  (10) Caliman, C. C.; Palma, L.; Ribeiro, J. J. Electrochem. Soc. 2013, 160, F853. doi: 10.1149/2.073308jes
11. [11]
  (11) Habibi, B.; Ghaderi, S. Int. J. Hydrog. Energy 2015, 40, 5115. doi: 10.1016/j.ijhydene.2015.02.103
12. [12]
  (12) Fernández, P. S.; Martins, C. A.; Martins, M. E.; Camara, G. A. Electrochim. Acta 2013, 112, 686. doi: 10.1016/j.electacta.2013.09.032
13. [13]
  (13) Lopes, F. S.; Nogueira, T.; Do Lago, C. L.; Gutz, I. G. Electroanalysis 2011, 23, 2516. doi: 10.1002/elan.201100321
14. [14]
  (14) Jeffery, D. Z.; Camara, G. A. Electrochem. Commun. 2010, 12, 1129. doi: 10.1016/j.elecom.2010.06.001
15. [15]
  (15) Kwon, Y.; Birdja, Y.; Spanos, I.; Rodriguez, P.; Koper, M. T. M. ACS Catal. 2012, 2, 759. doi: 10.1021/cs200599g
16. [16]
  (16) Kwon, Y.; Lai, S. C.; Rodriguez, P.; Koper, M. T. J. Am. Chem. Soc. 2011, 133, 6914. doi: 10.1021/ja200976j
17. [17]
  (17) Simões, M.; Baranton, S.; Coutanceau. Appl. Catal. B. Environ. 2010, 93, 354. doi: 10.1016/j.apcatb.2009.10.008
18. [18]
  (18) Yongprapat, S.; Therdthianwong, A.; Therdthianwong, S. J. Appl. Electrochem. 2012, 42, 483. doi: 10.1007/s10800-012-0423-3
19. [19]
  (19) Yongprapat, S.; Therdthianwong, S.; Therdthianwong, A. Electrochim. Acta 2012, 83, 87. doi: 10.1016/j.electacta.2012.08.031
20. [20]
  (20) Zhang, Z.; Xin, L.; Li, W. Int. J. Hydrog. Energy 2012, 37, 9393. doi: 10.1016/j.ijhydene.2012.03.019
21. [21]
  (21) Zhou, H.; Li, Z.; Xu, S. M.; Lu, L.; Xu, M.; Ji, K.; Ge, R.; Yan, Y.; Ma, L.; Kong, X.; et al. Angew. Chem. Int. Ed. 2021, 60, 8976. doi: 10.1002/anie.202015431
22. [22]
  (22) Dash, S.; Munichandraiah, N. J. Electrochem. Soc. 2013, 160, H197. doi: 10.1149/2.007304jes
23. [23]
  (23) Renard, D.; Mccain, C.; Baidoun, B.; Bondy, A.; Bandyopadhyay, K. Colloids Surf. A 2014, 463, 44. doi: 10.1016/j.colsurfa.2014.09.027
24. [24]
  (24) Zhiani, M.; Rostami, H.; Majidi, S.; Karami, K. Int. J. Hydrog. Energy 2013, 38, 5435. doi: 10.1016/j.ijhydene.2012.09.001
25. [25]
  (25) Zalineeva, A.; Baranton, S.; Coutanceau, C. Electrochim. Acta 2015, 176, 705. doi: 10.1016/j.electacta.2015.07.073
26. [26]
  (26) Dai, C.; Sun, L.; Liao, H.; Khezri, B.; Webster, R. D.; Fisher, A. C.; Xu, Z. J. J. Catal. 2017, 356, 14. doi: 10.1016/j.jcat.2017.10.010
27. [27]
  (27) Bender, M. T.; Lam, Y. C.; Hammes-Schiffer, S.; Choi, K.-S. J. Am. Chem. Soc. 2020, 142, 21538. doi: 10.1021/jacs.0c10924
28. [28]
  (28) Bender, M. T.; Warburton, R. E.; Hammes-Schiffer, S.; Choi, K.-S. ACS Catal. 2021, 11, 15110. doi: 10.1021/acscatal.1c04163
29. [29]
  (29) Franceschini, F.; Taurino, I. J. P. I. M. Phys. Med. 2022, 100054. doi: 10.1016/j.phmed.2022.100054
30. [30]
  (30) Li, Y.; Wei, X.; Chen, L.; Shi, J.; He, M. Nat. Commun. 2019, 10, 5335. doi: 10.1038/s41467-019-13375-z
31. [31]
  (31) Wu, J.; Liu, X.; Hao, Y.; Wang, S.; Wang, R.; Du, W.; Cha, S.; Ma, X. Y.; Yang, X.; Gong, M. Angew. Chem. Int. Ed. 2023, 62, e202216083. doi: 10.1002/anie.202216083
32. [32]
  (32) Sun, S.; Sun, L.; Xi, S.; Du, Y.; Prathap, M. A.; Wang, Z.; Zhang, Q.; Fisher, A.; Xu, Z. J. Electrochim. Acta 2017, 228, 183. doi: 10.1016/j.electacta.2017.01.086
33. [33]
  (33) Han, X.; Sheng, H.; Yu, C.; Walker, T. W.; Huber, G. W.; Qiu, J.; Jin, S. ACS Catal. 2020, 10, 6741. doi: 10.1021/acscatal.0c01498
34. [34]
  (34) Li, Y.; Wei, X.; Han, S.; Chen, L.; Shi, J. Angew. Chem. Int. Ed. 2021, 60, 21464. doi: 10.1002/anie.202107510
35. [35]
  (35) Kruyer, N. S.; Peralta-Yahya, P. Curr. Opin. Biotechnol. 2017, 45, 136. doi: 10.1016/j.copbio.2017.03.006
36. [36]
  (36) Yan, W.; Zhang, G.; Wang, J.; Liu, M.; Sun, Y.; Zhou, Z.; Zhang, W.; Zhang, S.; Xu, X.; Shen, J.; et al. Front. Chem. 2020, 8, 185. doi: 10.3389/fchem.2020.00185
37. [37]
  (37) Yang, J.; Liu, J.; Neumann, H.; Franke, R.; Jackstell, R.; Beller, M. Science 2019, 366, 1514. doi: 10.1126/science.aaz1293
38. [38]
  (38) Rios, J.; Lebeau, J.; Yang, T.; Li, S.; Lynch, M. D. Green. Chem. 2021, 23, 3172. doi: 10.1039/d1gc00638j
39. [39]
  (39) Schaub, T. Science 2019, 366, 1447. doi: 10.1126/science.aaz6459
40. [40]
  (40) Van De Vyver, S.; Román-Leshkov, Y. Catal. Sci. Technol. 2013, 3, 1465. doi: 10.1039/c3cy20728e
41. [41]
  (41) Skoog, E.; Shin, J. H.; Saez-Jimenez, V.; Mapelli, V.; Olsson, L. Biotechnol. Adv. 2018, 36, 2248. doi: 10.1016/j.biotechadv.2018.10.012
42. [42]
  (42) Wang, R.; Kang, Y.; Wu, J.; Jiang, T.; Wang, Y.; Gu, L.; Li, Y.; Yang, X.; Liu, Z.; Gong, M. Angew. Chem. Int. Ed. 2022, 61, e202214977. doi: 10.1002/anie.202214977
43. [43]
  (43) Chaenko, N.; Kornienko, G.; Sokolenko, V.; Kornienko, B. Russ. J. Appl. Chem. 2014, 87, 444. doi: 10.1134/s1070427214040089
44. [44]
  (44) Rauen, A. L.; Weinelt, F.; Waldvogel, S. R. Green Chem. 2020, 22, 5956. doi: 10.1039/d0gc02210a
45. [45]
  (45) Zhao, H.; Qu, X.; Qin, M.; Yang, W. J. Solid State Electrochem. 2016, 20, 2773. doi: 10.1007/s10008-016-3286-4
46. [46]
  (46) Li, Z.; Li, X.; Zhou, H.; Xu, Y.; Xu, S. M.; Ren, Y.; Yan, Y.; Yang, J.; Ji, K.; Li, L.; et al. Nat. Commun. 2022, 13, 5009. doi: 10.1038/s41467-022-32769-0
47. [47]
  (47) Lyalin, B.; Petrosyan, V. Russ. Chem. Bull. 2009, 58, 2426. doi: 10.1007/s11172-009-0339-1
48. [48]
  (48) Hasanzadeh, M.; Karim-Nezhad, G.; Mahjani, M. G.; Jafarian, M.; Shadjou, N.; Khalilzadeh, B.; Saghatforoush, L. A. Catal. Commun. 2008, 10, 295. doi: 10.1016/j.catcom.2008.09.010
49. [49]
  (49) Collinson, S.; Thielemans, W. Coord. Chem. Rev. 2010, 254, 1854. doi: 10.1016/j.ccr.2010.04.007
50. [50]
  (50) Vennestrøm, P.; Osmundsen, C. M.; Christensen, C.; Taarning, E. Angew. Chem. Int. Ed. 2011, 50, 10502. doi: 10.1002/anie.201102117
51. [51]
  (51) Shuai, L.; Amiri, M. T.; Questell-Santiago, Y. M.; Héroguel, F.; Li, Y.; Kim, H.; Meilan, R.; Chapple, C.; Ralph, J.; Luterbacher, J. S. Science 2016, 354, 329. doi: 10.1126/science.aaf7810
52. [52]
  (52) Rahimi, A.; Ulbrich, A.; Coon, J. J.; Stahl, S. S. Nature 2014, 515, 249. doi: 10.1038/nature13867
53. [53]
  (53) Jiang, L.; Sheng, L.; Fan, Z. Sci. China Mater. 2018, 61, 133. doi: 10.1007/s40843-017-9169-4
54. [54]
  (54) Wong, S. S.; Shu, R.; Zhang, J.; Liu, H.; Yan, N. Chem. Soc. Rev. 2020, 49, 5510. doi: 10.1039/d0cs00134a
55. [55]
  (55) Tian, H.; Fu, X.; Zheng, M.; Wang, Y.; Li, Y.; Xiang, A.; Zhong, W.-H. Nano Res. 2018, 11, 4265. doi: 10.1007/s12274-018-2013-0
56. [56]
  (56) Constant, S.; Wienk, H. L.; Frissen, A. E.; De Peinder, P.; Boelens, R.; Van Es, D. S.; Grisel, R. J.; Weckhuysen, B. M.; Huijgen, W. J.; Gosselink, R. J. Green Chem. 2016, 18, 2651. doi: 10.1039/C5GC03043A
57. [57]
  (57) Sun, Z.; Fridrich, B.; De Santi, A.; Elangovan, S.; Barta, B. Chem. Rev. 2018, 118, 614. doi: 10.1021/acs.chemrev.7b00588
58. [58]
  (58) Bosque, I.; Magallanes, G.; Rigoulet, M.; KäRkäS, M. D.; Stephenson, C. R. ACS Cent. Sci. 2017, 3, 621. doi: 10.1021/acscentsci.7b00140
59. [59]
  (59) Han, S.; Wang, C.; Wang, Y.; Yu, Y.; Zhang, B. Angew. Chem. Int. Ed. 2021, 133, 4524. doi: 10.1002/anie.202014017
60. [60]
  (60) Möhle, S.; Zirbes, M.; Rodrigo, E.; Gieshoff, T.; Wiebe, A.; Waldvogel, S. R. Angew. Chem. Int. Ed. 2018, 57, 6018. doi: 10.1002/anie.201712732
61. [61]
  (61) Yuan, Y.; Lei, A. Acc. Chem. Res. 2019, 52, 3309. doi: 10.1021/acs.accounts.9b00512
62. [62]
  (62) Xu, C.; Arancon, R. a. D.; Labidi, J.; Luque, R. Chem. Soc. Rev. 2014, 43, 7485. doi: 10.1039/c4cs00235k
63. [63]
  (63) Nichols, J. M.; Bishop, L. M.; Bergman, R. G.; Ellman, J. A. J. Am. Chem. Soc. 2010, 132, 12554. doi: 10.1021/ja109016b
64. [64]
  (64) Wu, A.; Patrick, B. O.; Chung, E.; James, B. R. Dalton Trans. 2012, 41, 11093. doi: 10.1039/C2DT31065A
65. [65]
  (65) Norman, C. Science 2011, 332, 1263. doi: 10.1126/science.332.6035.1263-c
66. [66]
  (66) Lahive, C. W.; Deuss, P. J.; Lancefield, C. S.; Sun, Z.; Cordes, D. B.; Young, C. M.; Tran, F.; Slawin, A. M.; De Vries, J. G.; Kamer, P. C.; et al. J. Am. Chem. Soc. 2016, 138, 8900. doi: 10.1021/jacs.6b04144
67. [67]
  (67) Luo, N.; Wang, M.; Li, H.; Zhang, J.; Hou, T.; Chen, H.; Zhang, X.; Lu, J.; Wang, F. ACS Catal. 2017, 7, 4571. doi: 10.1021/acscatal.7b01043
68. [68]
  (68) Luo, N.; Wang, M.; Li, H.; Zhang, J.; Liu, H.; Wang, F. ACS Catal. 2016, 6, 7716. doi: 10.1021/acscatal.6b02212
69. [69]
  (69) Lancefield, C. S.; Ojo, O. S.; Tran, F.; Westwood, N. Angew. Chem. Int. Ed. 2015, 127, 260. doi: 10.1002/anie.201409408
70. [70]
  (70) Sedai, B.; Baker, R. T. Adv. Synth. Catal. 2014, 356, 3563. doi: 10.1002/adsc.201400463
71. [71]
  (71) Tran, F.; Lancefield, C.; Kamer, P.; Lebl, T.; Westwood, N. Green Chem. 2015, 17, 244. doi: 10.1039/c4gc01012d
72. [72]
  (72) Hanson, S. K.; Wu, R.; Silks, L. A. P. Angew. Chem. Int. Ed. 2012, 124, 3466. doi: 10.1002/anie.201107020
73. [73]
  (73) Cho, D. W.; Parthasarathi, R.; Pimentel, A. S.; Maestas, G. D.; Park, H. J.; Yoon, U. C.; Dunaway-Mariano, D.; Gnanakaran, S.; Langan, P.; Mariano, P. S. J. Org. Chem. 2010, 75, 6549. doi: 10.1021/jo1012509
74. [74]
  (74) Lim, S. H.; Nahm, K.; Ra, C. S.; Cho, D. W.; Yoon, U. C.; Latham, J. A.; Dunaway-Mariano, D.; Mariano, P. S. J. Org. Chem. 2013, 78, 9431. doi: 10.1021/jo401680z
75. [75]
  (75) Hanson, S. K.; Baker, R. T. Acc. Chem. Res. 2015, 48, 2037. doi: 10.1021/acs.accounts.5b00104
76. [76]
  (76) Parthasarathi, R.; Romero, R. A.; Redondo, A.; Gnanakaran, S. J. Phys. Chem. Lett. 2011, 2, 2660. doi: 10.1021/jz201201q
77. [77]
  (77) Kim, S.; Chmely, S. C.; Nimlos, M. R.; Bomble, Y. J.; Foust, T. D.; Paton, R. S.; Beckham, G. T. J. Phys. Chem. Lett. 2011, 2, 2846. doi: 10.1021/jz201182w
78. [78]
  (78) Kleine, T.; Buendia, J.; Bolm, C. Green Chem. 2013, 15, 160. doi: 10.1039/c2gc36456e
79. [79]
  (79) Cui, T.; Ma, L.; Wang, S.; Ye, C.; Liang, X.; Zhang, Z.; Meng, G.; Zheng, L.; Hu, H. S.; Zhang, J.; et al. J. Am. Chem. Soc. 2021, 143, 9429. doi: 10.1021/jacs.1c02328
80. [80]
  (80) Yan, K.; Zhang, Y.; Tu, M.; Sun, Y. Energy Fuels 2020, 34, 12703. doi: 10.1021/acs.energyfuels.0c02284
81. [81]
  (81) Lange, J. P.; Van Der Heide, E.; Van Buijtenen, J.; Price, R. ChemSusChem 2012, 5, 150. doi: 10.1002/cssc.201100648
82. [82]
  (82) Mariscal, R.; Maireles-Torres, P.; Ojeda, M.; Sádaba, I.; Granados, M. L. Energy Environ. Sci. 2016, 9, 1144. doi: 10.1039/C5EE02666K
83. [83]
  (83) Caes, B. R.; Teixeira, R. E.; Knapp, K. G.; Raines, R. T. ACS Sustain. Chem. Eng. 2015, 3, 2591. doi: 10.1021/acssuschemeng.5b00473
84. [84]
  (84) Ye, W.; Yang, Y.; Fang, X.; Arif, M.; Chen, X.; Yan, D. ACS Sustain. Chem Eng. 2019, 7, 18085. doi: 10.1021/acssuschemeng.9b05126
85. [85]
  (85) Li, X.; Ho, B.; Lim, D. S.; Zhang, Y. Green Chem. 2017, 19, 914. doi: 10.1039/C6GC03020C
86. [86]
  (86) Wu, H.; Song, J.; Liu, H.; Xie, Z.; Xie, C.; Hu, Y.; Huang, X.; Hua, M.; Han, B. Chem. Sci. 2019, 10, 4692. doi: 10.1039/c9sc00322c
87. [87]
  (87) Wojcieszak, R.; Santarelli, F.; Paul, S.; Dumeignil, F.; Cavani, F.; Gonçalves, R. V. Sustain. Chem. Proc. 2015, 3, 1. doi: 10.1186/s40508-015-0034-5/
88. [88]
  (88) Centi, G.; Trifiro, F.; Ebner, J. R.; Franchetti, V. M. Chem. Rev. 1988, 88, 55. doi: 10.1021/cr00083a003
89. [89]
  (89) Li, X.; Ko, J.; Zhang, Y. ChemSusChem 2018, 11, 612. doi: 10.1002/cssc.201701866
90. [90]
  (90) Murthy, M.; Rajamani, K. Chem. Eng. Sci. 1974, 29, 601. doi: 10.1016/0009-2509(74)80071-0
91. [91]
  (91) Lan, J.; Chen, Z.; Lin, J.; Yin, G. Green Chem. 2014, 16, 4351. doi: 10.1039/C4GC00829D
92. [92]
  (92) Guo, H.; Yin, G. J. Phys. Chem. C 2011, 115, 17516. doi: 10.1021/jp2054712
93. [93]
  (93) Shi, S.; Guo, H.; Yin, G. Catal. Commun. 2011, 12, 731. doi: 10.1016/j.catcom.2010.12.033
94. [94]
  (94) Li, X.; Lan, X.; Wang, T. Catal. Today 2016, 276, 97. doi: 10.1016/j.cattod.2015.11.036
95. [95]
  (95) Román, A. M.; Hasse, J. C.; Medlin, J. W.; Holewinski, A. ACS Catal. 2019, 9, 10305. doi: 10.1021/acscatal.9b02656
96. [96]
  (96) Kubota, S. R.; Choi, K.-S. ACS Sustain. Chem. Eng. 2018, 6, 9596. doi: 10.1021/acssuschemeng.8b02698
1. [1]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
2. [2]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
3. [3]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
4. [4]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
5. [5]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
6. [6]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
7. [7]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
8. [8]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
9. [9]
  Wei Zhong , Dan Zheng , Yuanxin Ou , Aiyun Meng , Yaorong Su . K原子掺杂高度面间结晶的g-C₃N₄光催化剂及其高效H₂O₂光合成. Acta Physico-Chimica Sinica, 2024, 40(11): 2406005-. doi: 10.3866/PKU.WHXB202406005
10. [10]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
11. [11]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
12. [12]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
13. [13]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
14. [14]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
15. [15]
  Geyang Song , Dong Xue , Gang Li . Recent Advances in Transition Metal-Catalyzed Synthesis of Anilines from Aryl Halides. University Chemistry, 2024, 39(2): 321-329. doi: 10.3866/PKU.DXHX202308030
16. [16]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
17. [17]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
18. [18]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
19. [19]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
20. [20]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005

Get Citation

PDF

XML

Metrics

PDF Downloads(9)
Abstract views(494)
HTML views(57)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142