Citation: Yue Zhang, Bao Li, Lixin Wu. 氧化石墨烯辅助的超分子骨架膜用于水包油型纳米乳液的高效分离[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230503. doi: 10.3866/PKU.WHXB202305038 shu

氧化石墨烯辅助的超分子骨架膜用于水包油型纳米乳液的高效分离

State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China

Received Date: 18 May 2023
Revised Date: 26 June 2023
Accepted Date: 27 June 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22271117, 22172060).

制备可以同时高效且高通量地处理纳米乳液的超浸润材料仍然具有挑战。为此，本文提出了一种通过在超分子骨架纳米片上修饰氧化石墨烯以增强亲水性的策略。通过将两种具有片状形态的材料连续抽滤于商业基质上，可制备得到氧化石墨烯辅助的超分子骨架复合膜，并用于分离具有纳米尺寸液滴的水包油乳液。骨架一方面通过均匀的纳米孔拦截乳液中分散的微小液滴，另一方面也通过带负电的表面提供静电相互作用来驱动破乳过程发生。具有良好亲水性的氧化石墨烯赋予膜材料改善的亲水能力和水合层。该复合膜具有纳米级的截留尺寸、带负电的表面和水下疏油性，并且还获得了高的水通量和耐油污染性。基于尺寸筛分和破乳效应，该复合膜可有效地去除分散在水包油乳液中由非离子、阴离子和阳离子表面活性剂稳定的纳米油滴。特别是对于离子型乳液，在分离后动态光散射未检测出残留液滴。滤液中总有机碳含量小于10 ppm，对应着大于99.9%的分离效率，优于许多国家和组织的标准。在各种乳液的分离过程中，复合膜表现出较高的分离渗透性，约为原始骨架膜的3.5倍。此外，具有防污效果的复合膜获得了较高的通量回收率，通过简单的水洗处理即可实现5次具有稳定分离性能的循环。该复合膜在重复使用过程中没有组分损失，在150 °C内具有热稳定性，并能抵抗腐蚀性化学环境。在本工作中，我们试图将具有不同结构特性和表面特性的两种组分结合，通过简单的方法制备复合膜，并在功能协同作用下实现水包油型纳米乳液的高性能分离。
- Supramolecular framework,
- Graphene oxide composite membrane,
- Demulsification,
- Nanosized emulsion,
- High-performance separation
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