Citation: Lei Feng, Ze-Min Zhu, Ying Yang, Zongbin He, Jiafeng Zou, Man-Bo Li, Yan Zhao, Zhikun Wu. 长期探寻的Au₂₃(S-Adm)₁₆结构及未曾预期的掺杂效应[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230502. doi: 10.3866/PKU.WHXB202305029 shu

长期探寻的Au₂₃(S-Adm)₁₆结构及未曾预期的掺杂效应

Lei Feng ^1,2 ,
Ze-Min Zhu ¹ ,
Ying Yang ^1,2 ,
Zongbin He ^1,2 ,
Jiafeng Zou ^1,2 ,
Man-Bo Li ^1,2 ,
Yan Zhao ^1,2 ,
Zhikun Wu ^1,2

1.
Institute of Physical Science and Information Technology, Anhui University, Hefei 230601, China;
2.
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, CAS Center for Excellence in Nanoscience, Institute of Solid State Physics, Hefei Institutes of Physical Science, Chinese Academy of Sciences, Hefei 230031, China

Received Date: 15 May 2023
Revised Date: 10 June 2023
Accepted Date: 12 June 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (21925303, 21771186, 21829501, 21222301, 21528303, 21171170, 92061110), CASHIPS Director’s Fund (BJPY2019A02), Key Program of 13th Five-year Plan, CASHIPS (KP-2017-16), Collaborative Innovation Program of Hefei Science Center, CAS (2020HSC-CIP005, 2022HSC-CIP018), Anhui Provincial Natural Science Foundation (2108085Y05), Hefei National Laboratory for Physical Sciences at the Microscale (KF2020102), and the Startup Fund of Anhui University (S020318006/037).

一锅同时获得单个金属原子掺杂的纳米团簇与母体团簇富有挑战性。这样的合成可排除微量杂质的影响，使得掺杂和未掺杂纳米团簇的性质对比更加合理可靠。在此，我们首次实现了这种合成，得到了长期追寻的纳米团簇Au₂₃(S-Adm)₁₆和其单镉掺杂的Au₂₂Cd₁(S-Adm)₁₆纳米团簇，并通过单晶X射线晶体学解析了其结构。令人惊讶的是，与以前的报道结果相反，Au₂₃(S-Adm)₁₆比Au₂₂Cd₁(S-Adm)₁₆更稳定。另一方面，由于掺入镉原子后，内核Au―Au键长度增加，光激发电子转移阻力增加，导致Au₂₂Cd₁(S-Adm)₁₆吸收和发射强度明显下降。因而，不仅团簇的稳定性，而且团簇的吸收和发射强度也与内核Au―Au键的长度关联。这项工作表明了两种团簇结构上的微小差异就可导致光学、热稳定性等方面的显著区别，也为研究金属纳米团簇的构效关系提供了良好的借鉴。
- Metal nanoclusters,
- Synthesis,
- Au―Au bond length,
- Property,
- Property–structure correlation
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长期探寻的Au₂₃(S-Adm)₁₆结构及未曾预期的掺杂效应