Citation: Xiaojun Liu, Lang Qin, Yanlei Yu. 胆甾相液晶微球光子禁带的动态调控及其应用[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230501. doi: 10.3866/PKU.WHXB202305018 shu

胆甾相液晶微球光子禁带的动态调控及其应用

Xiaojun Liu ¹ ,
Lang Qin ¹ ,
Yanlei Yu ^1,2

1.
Department of Materials Science, State Key Laboratory of Molecular Engineering of Polymers, Fudan University, Shanghai 200433, China;
2.
Yiwu Research Institute of Fudan University, Yiwu 322000, Zhejiang Province, China

Received Date: 8 May 2023
Revised Date: 28 June 2023
Accepted Date: 29 June 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52173110), Natural Science Foundation of Shanghai (21ZR1405900), and Shanghai Rising-Star Program (22QA1401200).

胆甾相液晶微球是空间结构高度对称的三维光子晶体，能够全方位地选择性反射特定波长的圆偏振光，具有无角度依赖性的光子禁带，作为一种新兴的光学材料在全向激光器、反射式显示和微传感器等领域展现出广阔的应用前景。近年来，毛细管微流控技术的蓬勃发展为连续、可控、高通量地制备结构复杂且分子规则取向的单分散胆甾相液晶微球提供了强有力的支持。本综述重点关注利用毛细管微流控技术制备胆甾相液晶微球的相关研究工作，首先分析了毛细管微流控装置在设计微球结构中的决定性作用，阐明了溶液体系的选择与液晶分子取向间的关系以及边界效应对微球尺寸的影响；随后，从胆甾相液晶微球的光学特性切入，介绍了利用温度、溶剂和光等外界刺激调控螺旋结构自组装的原理和策略以及微球之间独有的“光子交叉通讯”现象；最后，总结了现阶段胆甾相液晶微球的潜在应用方向并讨论了该材料体系未来面临的挑战。
- Cholesteric liquid crystal,
- Structural color,
- Microfluidics,
- Microdroplets Optical device,
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