Citation: Yixuan Wang, Canhui Zhang, Xingkun Wang, Jiarui Duan, Kecheng Tong, Shuixing Dai, Lei Chu, Minghua Huang. 构筑高效耐腐蚀的碳铠甲层包覆Co₉Se₈电催化剂用于海水基锌空气电池[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230500. doi: 10.3866/PKU.WHXB202305004 shu

构筑高效耐腐蚀的碳铠甲层包覆Co₉Se₈电催化剂用于海水基锌空气电池

School of Material Science and Engineering, Ocean University of China, Qingdao 266000, Shandong Province, China

Corresponding author: Xingkun Wang, Minghua Huang,
Received Date: 8 May 2023
Revised Date: 26 July 2023
Accepted Date: 27 July 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52261145700, 22279124) and the Natural Science Foundation of Shandong Province (ZR2022ZD30).

得益于较高的理论能量密度、环境友好性和丰富的海水储量，海水基锌-空气电池（S-ZABs）被认为是一种极具应用前景的储能和能源转换装置，是解决能源短缺和环境污染问题的能源装置之一。然而对于S-ZABs而言，构筑在海水中具有高耐氯离子腐蚀性与高性能的阴极氧还原反应电催化剂仍然具有挑战性。因此，我们通过高温硒化策略，在氮掺杂介孔碳材料上设计了超薄碳铠甲层封装的Co₉Se₈纳米颗粒高效ORR电催化剂（命名为NMC-Co₉Se₈）。外部的超薄碳铠甲层不仅可以改善催化过程中的电子转移过程，抑制纳米颗粒的团聚，而且可以作为盔甲保护内部活性位点免受Cl^-吸附和腐蚀。得益于这种独特的结构，NMC-Co₉Se₈在0.1 mol·L^-1 KOH海水电解质中表现出优异的ORR性能，其起始电位为0.904 V，半波电位为0.860 V。更重要的是，基于NMC-Co₉Se₈催化剂的S-ZABs可提供172.4 mW·cm^-2的功率密度和超过150 h的优异长期放电稳定性，均高于基于Pt/C的S-ZABs性能。这项工作为开发用于海水基锌-空气电池和其他能源转换技术具有耐氯离子腐蚀且高效的ORR催化剂提供了新思路。
- Co₉Se₈ nanoparticle,
- Oxygen reduction reaction,
- Ultrathin carbon-chainmail-shell,
- Seawater-based Zn-air battery,
- Cl⁻ corrosion-resistant
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构筑高效耐腐蚀的碳铠甲层包覆Co9Se8电催化剂用于海水基锌空气电池

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构筑高效耐腐蚀的碳铠甲层包覆Co₉Se₈电催化剂用于海水基锌空气电池