Citation: Ke Qiu,  Fengmei Wang,  Mochou Liao,  Kerun Zhu,  Jiawei Chen,  Wei Zhang,  Yongyao Xia,  Xiaoli Dong,  Fei Wang. A Fumed SiO2-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries[J]. Acta Physico-Chimica Sinica, ;2024, 40(3): 230403. doi: 10.3866/PKU.WHXB202304036 shu

A Fumed SiO2-based Composite Hydrogel Polymer Electrolyte for Near-Neutral Zinc-Air Batteries

  • Corresponding author: Yongyao Xia,  Xiaoli Dong,  Fei Wang, 
  • Received Date: 20 April 2023
    Revised Date: 16 May 2023
    Accepted Date: 17 May 2023

    Fund Project: The project was supported by the National Key R&D Program of China (2021YFA1201900) and the Science and Technology Commission of Shanghai Municipality (21511103300).

  • Near-neutral zinc-air batteries show great promise for long-cycle applications in ambient air owing to their impressive deposition/stripping compatibility with zinc anodes and greater chemical stability towards CO2 in ambient air compared to batteries with traditional alkaline electrolytes. However, the inherent water volatilization of liquid electrolytes and the flexibility of electrolytes required for wearable devices severely limit the practical application of this system. In this study, a fumed SiO2-based composite hydrogel polymer electrolyte (SiO2-HPE) was prepared for application in near-neutral zinc-air batteries. The design of the SiO2-HPE was carried out considering the following three aspects. Firstly, it is widely acknowledged that the polyacrylamide polymer skeleton is beneficial to excellent ionic conductivity and the mechanical strength of the SiO2-HPE. Secondly, fumed SiO2 bearing multiple silicon hydroxyl groups is a suitable option as a water-retaining additive. Thirdly, the near-neutral liquid electrolyte (1 mol·kg-1 Zn(OTf)2) absorbed in the SiO2-HPE is stable towards CO2 in ambient air. In conclusion, these three aspects of the electrolyte design contribute to the practical application of the SiO2-HPE. Raman spectroscopy and scanning electron microscopy revealed that the synthesized SiO2-HPE exhibited a high degree of polymerization, plentiful surface pores, and a uniform distribution of elements. According to the infrared and Raman spectra, the abundant hydroxyl groups located on the surface of the SiO2 particles enhanced water molecule binding by altering the hydrogen bond network within the SiO2-HPE. This conclusion was further confirmed by thermogravimetry and differential scanning calorimetry. After exposure to ambient air (30% relative humidity) for 96 h, the SiO2-HPE exhibited a water retention capacity of 49.52%, which is 6.23% and 1.73% higher than those for 1 mol·kg-1 Zn(OTf)2 and the HPE (hydrogel polymer electrolyte without SiO2). Moreover, owing to the dynamic recombination of the hydrogen bonds between the silicon hydroxyl groups and the gel skeleton, SiO2-HPE exhibited a higher mechanical strength and modulus than HPE under tensile and compressive conditions, respectively. This further rendered it an ideal electrolyte for flexible zinc-air batteries. The near-neutral zinc-air battery assembled with the SiO2-HPE exhibited a cycle life of up to 200 h under 30% relative humidity, far exceeding those of 1 mol·kg-1 Zn(OTf)2 and the HPE. Based on such remarkable performance, the flexible near-neutral zinc-air battery device assembled by the SiO2-HPE has shown a satisfactory performance under special conditions, such as bending and cutting, and can be used as a power supply for different electronic devices, making it a promising next-generation electrochemical energy storage device. Overall, this work provides new insight into the development of flexible zinc-air battery devices with long-term stability in ambient air.
  • 加载中
    1. [1]

      (1) Fu, J.; Cano, Z. P.; Park, M. G.; Yu, A.; Fowler, M.; Chen, Z. Adv. Mater. 2017, 29, 1604685. doi:10.1002/adma.201604685

    2. [2]

      (2) Liu, J. N.; Zhao, C. X.; Wang, J.; Ren, D.; Li, B. Q.; Zhang, Q. Energy Environ. Sci. 2022, 15, 4542. doi:10.1039/d2ee02440c

    3. [3]

    4. [4]

    5. [5]

      (5) Liu, X.; Fan, X.; Liu, B.; Ding, J.; Deng, Y.; Han, X.; Zhong, C.; Hu, W. Adv. Mater. 2021, 33, 2006461. doi:10.1002/adma.202006461

    6. [6]

      (6) Wu, W. F.; Yan, X.; Zhan, Y. Chem. Eng. J. 2023, 451, 138608. doi:10.1016/j.cej.2022.138608

    7. [7]

      (7) Liu, Q.; Liu, R.; He, C.; Xia, C.; Guo, W.; Xu, Z. L.; Xia, B. Y. eScience 2022, 2, 453. doi:10.1016/j.esci.2022.08.004

    8. [8]

      (8) Cheng, H. H.; Tan, C. S. J. Power Sources 2006, 162, 1431. doi:10.1016/j.jpowsour.2006.07.046

    9. [9]

      (9) Li, Y.; Gong, M.; Liang, Y.; Feng, J.; Kim, J. E.; Wang, H.; Hong, G.; Zhang, B.; Dai, H. Nat. Commun. 2013, 4, 1805. doi:10.1038/ncomms2812

    10. [10]

      (10) Sun, W.; Wang, F.; Zhang, B.; Zhang, M.; Küpers, V.; Ji, X.; Theile, C.; Bieker, P.; Xu, K.; Wang, C.; et al. Science 2021, 371, 46. doi:10.1126/science.abb9554

    11. [11]

      (11) Wang, C.; Li, J.; Zhou, Z.; Pan, Y.; Yu, Z.; Pei, Z.; Zhao, S.; Wei, L.; Chen, Y. EnergyChem 2021, 3, 100055. doi:10.1016/j.enchem.2021.100055

    12. [12]

      (12) Li, Y.; Fu, J.; Zhong, C.; Wu, T.; Chen, Z.; Hu, W.; Amine, K.; Lu, J. Adv. Energy Mater. 2019, 9, 1802605. doi:10.1002/aenm.201802605

    13. [13]

      (13) Tan, P.; Chen, B.; Xu, H. R.; Zhang, H. C.; Cai, W. Z.; Ni, M.; Liu, M. L.; Shao, Z. P. Energy Environ. Sci. 2017, 10, 2056. doi:10.1039/c7ee01913k

    14. [14]

    15. [15]

    16. [16]

    17. [17]

      (17) Li, M.; Liu, B.; Fan, X.; Liu, X.; Liu, J.; Ding, J.; Han, X.; Deng, Y.; Hu, W.; Zhong, C. ACS Appl. Energy Mater. 2019, 11, 28909. doi:10.1021/acsami.9b09086

    18. [18]

      (18) Li, H.; Liu, Z.; Liang, G.; Huang, Y.; Huang, Y.; Zhu, M.; Pei, Z.; Xue, Q.; Tang, Z.; Wang, Y.; et al. ACS Nano 2018, 12, 3140. doi:10.1021/acsnano.7b09003

    19. [19]

      (19) Huang, Y.; Liu, J.; Wang, J.; Hu, M.; Mo, F.; Liang, G.; Zhi, C. Angew. Chem. Int. Ed. 2018, 57, 9810. doi:10.1002/anie.201805618

    20. [20]

      (20) Zhong, C.; Deng, Y. D.; Hu, W. B.; Qiao, J. L.; Zhang, L.; Zhang, J. J. Chem. Soc. Rev. 2015, 44, 7484. doi:10.1039/c5cs00303b

    21. [21]

      (21) Fan, X.; Liu, J.; Song, Z.; Han, X.; Deng, Y.; Zhong, C.; Hu, W. Nano Energy 2019, 56, 454. doi:10.1016/j.nanoen.2018.11.057

    22. [22]

      (22) Song, Z.; Ding, J.; Liu, B.; Liu, X.; Han, X.; Deng, Y.; Hu, W.; Zhong, C. Adv. Mater. 2020, 32, 1908127. doi:10.1002/adma.201908127

    23. [23]

      (23) Li, H.; Lv, T.; Li, N.; Yao, Y.; Liu, K.; Chen, T. Nanoscale 2017, 9, 18474. doi:10.1039/C7NR07424G

    24. [24]

      (24) Tan, M. J.; Li, B.; Chee, P.; Ge, X.; Liu, Z.; Zong, Y.; Loh, X. J. J. Power Sources 2018, 400, 566. doi:10.1016/j.jpowsour.2018.08.066

    25. [25]

    26. [26]

      (26) Zhao, Q.; Qiao, K.; Yao, Y. J.; Chen, Z.; Chen, D. C.; Gao, Y. F. J. Inorg. Mater. 2021, 36, 161. doi:10.15541/jim20200376

    27. [27]

      (27) Qin, Y.; Li, H.; Han, C.; Mo, F.; Wang, X. Adv. Mater. 2022, 34, 2207118. doi:10.1002/adma.202207118

    28. [28]

      (28) Yang, Y.; Liang, S.; Lu, B.; Zhou, J. Energy Environ. Sci. 2022, 15, 1192. doi:10.1039/D1EE03268B

    29. [29]

      (29) Zhang, Q.; Ma, Y.; Lu, Y.; Li, L.; Wan, F.; Zhang, K.; Chen, J. Nat. Commun. 2020, 11, 4463. doi:10.1038/s41467-020-18284-0

    30. [30]

      (30) Du, H.; Wang, K.; Sun, T.; Shi, J.; Zhou, X.; Cai, W.; Tao, Z. Chem. Eng. J. 2022, 427, 131705. doi:10.1016/j.cej.2021.131705

    31. [31]

      (31) Huang, S.; He, S.; Li, Y.; Wang, S.; Hou, X. Chem. Eng. J. 2023, 464, 142607. doi:10.1016/j.cej.2023.142607

    32. [32]

      (32) Zhang, Y.; Wu, D.; Huang, F.; Cai, Y.; Li, Y.; Ke, H.; Lv, P.; Wei, Q. Adv. Funct. Mater. 2022, 32, 2203204. doi:10.1002/adfm.202203204

    33. [33]

      (33) Huang, Y.; Zhong, M.; Shi, F.; Liu, X.; Tang, Z.; Wang, Y.; Huang, Y.; Hou, H.; Xie, X.; Zhi, C. Angew. Chem. Int. Ed. 2017, 56, 9141. doi:10.1002/anie.201705212

  • 加载中
    1. [1]

      Mingyang Men Jinghua Wu Gaozhan Liu Jing Zhang Nini Zhang Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019

    2. [2]

      Jiandong Liu Zhijia Zhang Mikhail Kamenskii Filipp Volkov Svetlana Eliseeva Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048

    3. [3]

      Zhongxin YUWei SONGYang LIUYuxue DINGFanhao MENGShuju WANGLixin YOU . Fluorescence sensing on chlortetracycline of a Zn-coordination polymer based on mixed ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2415-2421. doi: 10.11862/CJIC.20240304

    4. [4]

      Tao Jiang Yuting Wang Lüjin Gao Yi Zou Bowen Zhu Li Chen Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057

    5. [5]

      Zunxiang Zeng Yuling Hu Yufei Hu Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO2Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069

    6. [6]

      Qinjin DAIShan FANPengyang FANXiaoying ZHENGWei DONGMengxue WANGYong ZHANG . Performance of oxygen vacancy-rich V-doped MnO2 for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326

    7. [7]

      Pengyang FANShan FANQinjin DAIXiaoying ZHENGWei DONGMengxue WANGXiaoxiao HUANGYong ZHANG . Preparation and performance of rich 1T-MoS2 nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339

    8. [8]

      Haoxiang Zhang Zhihan Zhao Yongchen Jin Zhiqiang Niu Jinlei Tian . Synthesis of an Efficient Absorbent Gel: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(11): 251-258. doi: 10.12461/PKU.DXHX202401084

    9. [9]

      Yifeng TANPing CAOKai MAJingtong LIYuheng WANG . Synthesis of pentaerythritol tetra(2-ethylthylhexoate) catalyzed by h-MoO3/SiO2. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2155-2162. doi: 10.11862/CJIC.20240147

    10. [10]

      Guang-Xu DuanQueting ChenRui-Rui ShaoHui-Huang SunTong YuanDong-Hao Zhang . Encapsulating lipase on the surface of magnetic ZIF-8 nanosphers with mesoporous SiO2 nano-membrane for enhancing catalytic performance. Chinese Chemical Letters, 2025, 36(2): 109751-. doi: 10.1016/j.cclet.2024.109751

    11. [11]

      Chongjing Liu Yujian Xia Pengjun Zhang Shiqiang Wei Dengfeng Cao Beibei Sheng Yongheng Chu Shuangming Chen Li Song Xiaosong Liu . Understanding Solid-Gas and Solid-Liquid Interfaces through Near Ambient Pressure X-Ray Photoelectron Spectroscopy. Acta Physico-Chimica Sinica, 2025, 41(2): 100013-. doi: 10.3866/PKU.WHXB202309036

    12. [12]

      Ziliang KANGJiamin ZHANGHong ANXiaohua LIUYang CHENJinping LILibo LI . Preparation and water adsorption properties of CaCl2@MOF-808 in-situ composite moulded particles. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2133-2140. doi: 10.11862/CJIC.20240282

    13. [13]

      Han ZHANGJianfeng SUNJinsheng LIANG . Hydrothermal synthesis and luminescent properties of broadband near-infrared Na3CrF6 phosphor. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 349-356. doi: 10.11862/CJIC.20240098

    14. [14]

      You Wu Chang Cheng Kezhen Qi Bei Cheng Jianjun Zhang Jiaguo Yu Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H2O2及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027

    15. [15]

      Xiaotian ZHUFangding HUANGWenchang ZHUJianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260

    16. [16]

      Xinpin PanYongjian CuiZhe WangBowen LiHailong WangJian HaoFeng LiJing Li . Robust chemo-mechanical stability of additives-free SiO2 anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567

    17. [17]

      Wenqi Gao Xiaoyan Fan Feixiang Wang Zhuojun Fu Jing Zhang Enlai Hu Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026

    18. [18]

      Xiaowu Zhang Pai Liu Qishen Huang Shufeng Pang Zhiming Gao Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021

    19. [19]

      Doudou Qin Junyang Ding Chu Liang Qian Liu Ligang Feng Yang Luo Guangzhi Hu Jun Luo Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034

    20. [20]

      Min LIUHuapeng RUANZhongtao FENGXue DONGHaiyan CUIXinping WANG . Neutral boron-containing radical dimers. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 123-130. doi: 10.11862/CJIC.20240362

Metrics
  • PDF Downloads(12)
  • Abstract views(703)
  • HTML views(91)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return