Citation: Anbang Du, Yuanfan Wang, Zhihong Wei, Dongxu Zhang, Li Li, Weiqing Yang, Qianlu Sun, Lili Zhao, Weigao Xu, Yuxi Tian. 不同层数石墨烯的光热显微成像[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230402. doi: 10.3866/PKU.WHXB202304027 shu

不同层数石墨烯的光热显微成像

Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory of Vehicle Emissions Control, Nanjing University, Nanjing 210023, China

Received Date: 14 April 2023
Revised Date: 2 June 2023
Accepted Date: 6 June 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22073046, 22173044, 62011530133), the National Key R&D Program of China (2020YFA0406104), the Fundamental Research Funds for the Central Universities (020514380256, 020514380278) and the State Key Laboratory of Analytical Chemistry for Life Science (SKLACL2217), the Natural Science Foundation of Jiangsu Province (BK20220121), Postgraduate Research & Practice Innovation Program of Jiangsu Province (KYCX22_0096).

二维层状材料(石墨烯、二维过渡金属硫族化合物等)因具有独特的物理性质，引起了研究学者们的广泛关注，极大促进了化学、材料科学和凝聚态物理学的发展。开发能够探究层状材料中层数依赖的光学、电学、力学和热学特性的新技术一直是二维材料领域最活跃的研究方向之一。光热显微镜利用光激发后非辐射跃迁产生的热效应，可实现在单个颗粒或单分子水平上成像与检测，并实时捕捉微观尺度热弛豫和热传输过程。本文对比研究了石墨烯薄片在不同光热介质(空气、甘油)中随厚度变化的光热特性，发现了在两种介质中光热信号强度与样品厚度之间均存在非线性依赖关系。相比于空气介质，甘油介质中光热信号强度具有更高的对比度，且随着厚度增加表现出非单调变化。该研究提供了不同介质环境中不同层数石墨烯光吸收和热弛豫特征的细节信息，相关研究结论将为层状材料及其异质结的热学性质研究提供依据。
- Graphene,
- Photothermal microscopy,
- Thickness-dependence,
- Optical absorption,
- Nonradiative relaxation
1. [1]
  (1) Novoselov, K. S.; Geim, A. K.; Morozov, S. V.; Jiang, D. E.; Zhang, Y.; Dubonos, S. V.; Grigorieva, I. V.; Firsov, A. A. Science 2004, 306, 666. doi: 10.1126/science.1102896
2. [2]
  (2) Splendiani, A.; Sun, L.; Zhang, Y.; Li, T.; Kim, J.; Chim, C. Y.; Galli, G.; Wang, F. Nano Lett. 2010, 10, 1271. doi: 10.1021/nl903868w
3. [3]
  (3) Wang, X.; Du, K.; Liu, Y. Y. F.; Hu, P.; Zhang, J.; Zhang, Q.; Owen, M. H. S.; Lu, X.; Gan, C. K.; Sengupta, P.; et al. 2D Mater. 2016, 3, 031009. doi: 10.1088/2053-1583/3/3/031009
4. [4]
  (4) Huang, B.; Clark, G.; Navarro-Moratalla, E.; Klein, D. R.; Cheng, R.; Seyler, K. L.; Zhong, D.; Schmidgall, E.; McGuire, M. A.; Cobden, D. H.; et al. Nature 2017, 546, 270. doi: 10.1038/nature22391
5. [5]
  (5) Li, L. K.; Kim, J.; Jin, C.; Ye, G. J.; Qiu, D. Y.; da Jornada, F. H.; Shi, Z.; Chen, L.; Zhang, Z.; Yang, F.; et al. Nat. Nanotechnol. 2017, 12, 21. doi: 10.1038/nnano.2016.171
6. [6]
  (6) Wang, L.; Xu, X.; Zhang, L.; Qiao, R.; Wu, M.; Wang, Z.; Zhang, S.; Liang, J.; Zhang, Z.; Zhang, Z.; et al. Nature 2019, 570, 91. doi: 10.1038/s41586-019-1226-z
7. [7]
  (7) Fang, S.; Duan, S.; Wang, X.; Chen, S.; Li, L.; Li, H.; Jiang, B.; Liu, C.; Wang, N.; Zhang, L.; et al. Nat. Photon. 2023, 17, 531. doi: 10.1038/s41566-023-01181-5
8. [8]
9. [9]
  (9) Geim, A. K.; Novoselov, K. S. Nat. Mater. 2007, 6, 183. doi: 10.1038/nmat1849
10. [10]
  (10) Zhang, Y.; Tan, Y. W.; Stormer, H. L.; Kim, P. Nature 2005, 438, 201. doi: 10.1038/nature04235
11. [11]
  (11) Zhang, Y.; Tang, T. T.; Girit, C.; Hao, Z.; Martin, M. C.; Zettl, A.; Crommie, M. F.; Shen, Y. R.; Wang, F. Nature 2009, 459, 820. doi: 10.1038/nature08105
12. [12]
  (12) Ju, L.; Wang, L.; Cao, T.; Taniguchi, T.; Watanabe, K.; Louie, S. G.; Rana, F.; Park, J.; Hone, J.; Wang, F.; et al. Science 2017, 358, 907. doi: 10.1126/science.aam9175
13. [13]
  (13) Cai, L.; Yu, G. Adv. Mater. 2021, 33, 2004974. doi: 10.1002/adma.202004974
14. [14]
  (14) Cao, Y.; Rodan-Legrain, D.; Rubies-Bigorda, O.; Park, J. M.; Watanabe, K.; Taniguchi, T.; Jarillo-Herrero, P. Nature 2020, 583, 821. doi: 10.1038/s41586-020-2393-7
15. [15]
  (15) Lin, M.; Feng, M.; Wu, J.; Ran, F.; Chen, T.; Luo, W.; Wu, H.; Han, W.; Zhang, X.; Liu, X.; et al. Research 2022, 2022, 9819373. doi: 10.34133/2022/9819373
16. [16]
  (16) Liu, M.; Wang, L.; Yu, G. Adv. Sci. 2022, 9, 2103170. doi: 10.1002/advs.202103170
17. [17]
  (17) Xiao, Y.; Liu, J.; Fu, L. Matter 2020, 3, 1142. doi: 10.1016/j.matt.2020.07.001
18. [18]
  (18) Haigh, S. J.; Gholinia, A.; Jalil, R.; Romani, S.; Britnell, L.; Elias, D. C.; Novoselov, K. S.; Ponomarenko, L. A.; Geim, A. K.; Gorbachev, R. Nat. Mater. 2012, 11, 764. doi: 10.1038/Nmat3386
19. [19]
  (19) No, Y. S.; Choi, H. K.; Kim, J. S.; Kim, H.; Yu, Y. J.; Choi, C. G.; Choi, J. S. Sci. Rep. 2018, 8, 571. doi: 10.1038/s41598-017-19084-1
20. [20]
  (20) Ohta, T.; Bostwick, A.; McChesney, J. L.; Seyller, T.; Horn, K.; Rotenberg, E. Phys. Rev. Lett. 2007, 98, 206802. doi: 10.1103/PhysRevLett.98.206802
21. [21]
  (21) Lu, X.; Chen, X.; Dubey, S.; Yao, Q.; Li, W.; Wang, X.; Xiong, Q.; Srivastava, A. Nat. Nanotechnol. 2019, 14, 426. doi: 10.1038/s41565-019-0394-1
22. [22]
  (22) Seyler, K. L.; Rivera, P.; Yu, H.; Wilson, N. P.; Ray, E. L.; Mandrus, D. G.; Yan, J.; Yao, W.; Xu, X. Nature 2019, 567, 66. doi: 10.1038/s41586-019-0957-1
23. [23]
  (23) Unuchek, D.; Ciarrocchi, A.; Avsar, A.; Sun, Z.; Watanabe, K.; Taniguchi, T.; Kis, A. Nat. Nanotechnol. 2019, 14, 1104. doi: 10.1038/s41565-019-0559-y
24. [24]
  (24) Yu, H.; Wang, Y.; Tong, Q.; Xu, X.; Yao, W. Phys. Rev. Lett. 2015, 115, 187002. doi: 10.1103/PhysRevLett.115.187002
25. [25]
26. [26]
27. [27]
  (27) Bandurin, D. A.; Monch, E.; Kapralov, K.; Phinney, I. Y.; Lindner, K.; Liu, S.; Edgar, J. H.; Dmitriev, I. A.; Jarillo-Herrero, P.; Svintsov, D.; et al. Nat. Phys. 2022, 18, 462. doi: 10.1038/s41567-021-01494-8
28. [28]
  (28) Ni, G. X.; Wang, L.; Goldflam, M. D.; Wagner, M.; Fei, Z.; McLeod, A. S.; Liu, M. K.; Keilmann, F.; Ozyilmaz, B.; Neto, A. H. C.; et al. Nat. Photon. 2016, 10, 244. doi: 10.1038/Nphoton.2016.45
29. [29]
  (29) Tian, Y.; Tian, H.; Wu, Y. L.; Zhu, L. L.; Tao, L. Q.; Zhang, W.; Shu, Y.; Xie, D.; Yang, Y.; Wei, Z. Y.; et al. Sci. Rep. 2015, 5, 10582. doi: 10.1038/srep10582
30. [30]
  (30) Chhowalla, M.; Shin, H. S.; Eda, G.; Li, L. J.; Loh, K. P.; Zhang, H. Nat. Chem. 2013, 5, 263. doi: 10.1038/nchem.1589
31. [31]
  (31) Kim, S. E.; Mujid, F.; Rai, A.; Eriksson, F.; Suh, J.; Poddar, P.; Ray, A.; Park, C.; Fransson, E.; Zhong, Y.; et al. Nature 2021, 597, 660. doi: 10.1038/s41586-021-03867-8
32. [32]
  (32) Kong, Y.; Li, X.; Wang, L.; Zhang, Z.; Feng, X.; Liu, J.; Chen, C.; Tong, L.; Zhang, J. ACS Nano 2022, 16, 11338. doi: 10.1021/acsnano.2c04984
33. [33]
  (33) Zhang, Y.; Lv, Q.; Wang, H.; Zhao, S.; Xiong, Q.; Lv, R.; Zhang, X. Science 2022, 378, 169. doi: 10.1126/science.abq0883
34. [34]
  (34) Wang, Y.; Kim, J. C.; Li, Y.; Ma, K. Y.; Hong, S.; Kim, M.; Shin, H. S.; Jeong, H. Y.; Chhowalla, M. Nature 2022, 610, 61. doi: 10.1038/s41586-022-05134-w
35. [35]
  (35) Ergoktas, M. S.; Soleymani, S.; Kakenov, N.; Wang, K. Y.; Smith, T. B.; Bakan, G.; Balci, S.; Principi, A.; Novoselov, K. S.; Ozdemir, S. K.; et al. Science 2022, 376, 184. doi: 10.1126/science.abn6528
36. [36]
  (36) Adhikari, S.; Spaeth, P.; Kar, A.; Baaske, M. D.; Khatua, S.; Orrit, M. ACS Nano 2020, 14, 16414. doi: 10.1021/acsnano.0c07638
37. [37]
  (37) Gaiduk, A.; Yorulmaz, M.; Ruijgrok, P. V.; Orrit, M. Science 2010, 330, 353. doi: 10.1126/science.1195475
38. [38]
  (38) Yang, W.; Wei, Z.; Nie, Y.; Tian, Y. J. Phys. Chem. Lett. 2022, 13, 9618. doi: 10.1021/acs.jpclett.2c02228
39. [39]
  (39) Xu, W.; Liu, W.; Schmidt, J. F.; Zhao, W.; Lu, X.; Raab, T.; Diederichs, C.; Gao, W.; Seletskiy, D. V.; Xiong, Q. Nature 2017, 541, 62. doi: 10.1038/nature20601
40. [40]
  (40) Li, H.; Li, H.; Wang, X.; Nie, Y.; Liu, C.; Dai, Y.; Ling, J.; Ding, M.; Ling, X.; Xie, D.; et al. Nano Lett. 2021, 21, 6773. doi: 10.1021/acs.nanolett.1c01356
41. [41]
  (41) Yang, W.; Li, M.; Xie, M.; Nie, Y.; Du, A.; Tian, Y. Rev. Sci. Instrum. 2021, 92, 083701. doi: 10.1063/5.0048239
42. [42]
  (42) Yang, W.; Li, M.; Xie, M.; Tian, Y. J. Phys. Chem. Lett. 2023, 14, 3506. doi: 10.1021/acs.jpclett.3c00491
43. [43]
  (43) Li, H.; Wu, J. M. T.; Huang, X.; Lu, G.; Yang, J.; Lu, X.; Zhang, Q. H.; Zhang, H. ACS Nano 2013, 7, 10344. doi: 10.1021/nn4047474
44. [44]
  (44) Graf, D.; Molitor, F.; Ensslin, K.; Stampfer, C.; Jungen, A.; Hierold, C.; Wirtz, L. Nano Lett. 2007, 7, 238. doi: 10.1021/nl061702a
45. [45]
  (45) Hao, Y.; Wang, Y.; Wang, L.; Ni, Z.; Wang, Z.; Wang, R.; Koo, C. K.; Shen, Z.; Thong, J. T. L. Small 2010, 6, 195. doi: 10.1002/smll.200901173
46. [46]
  (46) Ferrari, A. C.; Meyer, J. C.; Scardaci, V.; Casiraghi, C.; Lazzeri, M.; Mauri, F.; Piscanec, S.; Jiang, D.; Novoselov, K. S.; Roth, S.; et al. Phys. Rev. Lett. 2006, 97, 187401. doi: 10.1103/PhysRevLett.97.187401
47. [47]
  (47) Bonaccorso, F.; Sun, Z.; Hasan, T.; Ferrari, A. C. Nat. Photon. 2010, 4, 611. doi: 10.1038/Nphoton.2010.186
48. [48]
  (48) Li, W.; Cheng, G.; Liang, Y.; Tian, B.; Liang, X.; Peng, L.; Walker, A. R. H.; Gundlach, D. J.; Nguyen, N. V. Carbon 2016, 99, 348. doi: 10.1016/j.carbon.2015.12.007
49. [49]
  (49) Nair, R. R.; Blake, P.; Grigorenko, A. N.; Novoselov, K. S.; Booth, T. J.; Stauber, T.; Peres, N. M. R.; Geim, A. K. Science 2008, 320, 1308. doi: 10.1126/science.1156965
50. [50]
  (50) Gaiduk, A.; Ruijgrok, P. V.; Yorulmaz, M.; Orrit, M. Chem. Sci. 2010, 1, 343. doi: 10.1039/c0sc00210k
51. [51]
  (51) Ding, T.; Hou, L.; Meer, H. V. D.; Alivisatos, A. P.; Orrit, M. J. Phys. Chem. Lett. 2016, 7, 2524. doi: 10.1021/acs.jpclett.6b00964
52. [52]
  (52) Ghosh, S.; Bao, W.; Nika, D. L.; Subrina, S.; Pokatilov, E. P.; Lau, C. N.; Balandin, A. A. Nat. Mater. 2010, 9, 555. doi: 10.1038/Nmat2753
53. [53]
  (53) Li, H.; Ying, H.; Chen, X.; Nika, D. L.; Cocemasov, A. I.; Cai, W.; Balandin, A. A.; Chen, S. Nanoscale 2014, 6, 13402. doi: 10.1039/c4nr04455j
54. [54]
  (54) Gao, J.; Si, C.; Yang, Y. R.; Cao, B. Y.; Wang, X. D. ECS J. Solid State Sci. Technol. 2020, 9, 093005. doi: 10.1149/2162-8777/aba7fb
55. [55]
  (55) Ouyang, T.; Chen, Y.; Xie, Y.; Stocks, G. M.; Zhong, J. Appl. Phys. Lett. 2011, 99, 233101. doi: 10.1063/1.3665184
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