Citation: Yongqing Xu, Yuyao Yang, Mengna Wu, Xiaoxiao Yang, Xuan Bie, Shiyu Zhang, Qinghai Li, Yanguo Zhang, Chenwei Zhang, Robert E. Przekop, Bogna Sztorch, Dariusz Brzakalski, Hui Zhou. Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels[J]. Acta Physico-Chimica Sinica, ;2024, 40(4): 230400. doi: 10.3866/PKU.WHXB202304003 shu

Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels

1.
Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Beijing Key Laboratory of CO₂Utilization and Reduction Technology, Department of Energy and Power Engineering, Tsinghua University, Beijing 100084, China;
2.
Centre for Advanced Technologies, Adam Mickiewicz University in Poznan, Poznan 61-614, Poland

Corresponding author: Hui Zhou, huizhou@tsinghua.edu.cn
Received Date: 3 April 2023
Revised Date: 12 June 2023
Accepted Date: 12 June 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (52276202, 52206147), International Joint Mission On Climate Change and Carbon Neutrality, Tsinghua-Toyota Joint Research Fund, State Key Laboratory of Chemical Engineering, China (SKL-ChE-22A03), Huaneng Group Science and Technology Research Project, China (KTHT-U22YYJC12), and Tsinghua University-Shanxi Clean Energy Research Institute Innovation Project Seed Fund, China.

CO₂ hydrogenation is critical to producing high-value-added carbon-based chemicals and fuels to achieving both hydrogen energy storage and CO₂ utilization. Examples of CO₂ hydrogenation include methanation (Sabatier process) to produce methane, reverse water-gas shift reaction (RWGS) to generate CO, methanol synthesis for the methanol economy, and CO₂ direct Fischer-Tropsch (CO₂-FT) reaction to produce olefins. The precious metal catalysts used in these reactions are efficient but too expensive to be used on a large scale. Further, although some non-precious metal catalysts can be used for these hydrogenation reactions, they suffer from deactivation during long-term processes. Over the past few decades, molybdenum carbides, which are transition metal carbides (TMCs), have attracted significant attention owing to their low cost and similar catalytic performance to precious metal catalysts in CO₂ hydrogenation reactions. Recently, two-dimensional molybdenum carbide MXenes have shown impressive activity in CO₂ hydrogenation reactions. Owing to the presence of carbon, the MXene lattice is expanded; this leads to an increase in valence electrons and endows the two-dimensional molybdenum carbide-based catalyst with different properties than metallic Mo. The two-dimensional molybdenum carbide-based materials can be prepared by temperature-programmed carburization, selective etching, mechanical alloying synthesis, chemical vapor deposition, in situ thermal carburization, and solution-phase synthesis methods. Thus far, a host of studies have been performed on CO₂ conversion with molybdenum carbide-based materials, which show promising activity during CO₂ conversion and selectivity towards target products. Both α-MoC_1−x and β-MoC_y have shown outstanding thermocatalytic activity, product selectivity, and reaction stability during CO₂ hydrogenation to CO at 300-600 ℃. In addition, molybdenum carbide-based materials were also found to be an interesting catalyst for direct CO₂ Fischer-Tropsch synthesis. The application potential of the molybdenum carbide-based materials could be further tuned by changing the C/Mo ratio in the bulk molybdenum carbide, strengthening the interactions between molybdenum carbide and the supported metal, and tailoring the interface structure of the materials. However, the thermal catalytic CO₂ conversion based on molybdenum carbide-based materials is still in its infancy. This paper summarizes the progress toward molybdenum carbide catalysis of CO₂ hydrogenation process for producing high-value-added chemicals and fuels. Furthermore, the challenges and opportunities for molybdenum carbide materials as catalysts for CO₂ hydrogenation are discussed to provide insights for future development in this emerging field.
- CO₂ hydrogenation,
- Molybdenum carbide,
- Thermal catalysis,
- Heterogeneous catalysis,
- MXenes
1. [1]
  (1) Bork, A. H.; Rekhtina, M.; Willinger, E.; Castro-Fernández, P.; Drnec, J.; Abdala, P. M.; Müller, C. R. Proc. Natl. Acad. Sci. 2021, 118 (26), 1. doi: 10.1073/pnas.2103971118
2. [2]
  (2) Shi, X.; Xiao, H.; Kanamori, K.; Yonezu, A.; Lackner, K. S.; Chen, X. Joule 2020, 4 (8), 1823. doi: 10.1016/j.joule.2020.07.005
3. [3]
  (3) Chen, J.; Xu, Y.; Liao, P.; Wang, H.; Zhou, H. Carbon Capture Sci. Technol. 2022, 4, 100052. doi: 10.1016/j.ccst.2022.100052
4. [4]
  (4) Xu, Y.; Donat, F.; Luo, C.; Chen, J.; Kierzkowska, A.; Awais Naeem, M.; Zhang, L.; Müller, C. R. Chem. Eng. J. 2023, 453, 139913. doi: 10.1016/j.cej.2022.139913
5. [5]
  (5) Senthilkumaran, M.; Saravanan, C.; Aravinth, K.; Sethuraman, V.; Puthiaraj, P.; Muthu Mareeswaran, P.; Ramasamy, P. Carbon Capture Sci. Technol. 2022, 2, 100021. doi: 10.1016/j.ccst.2021.100021
6. [6]
  (6) Xu, Y.; Ding, H.; Luo, C.; Zheng, Y.; Xu, Y.; Li, X.; Zhang, Z.; Shen, C.; Zhang, L. Chem. Eng. J. 2018, 334, 2520. doi: 10.1016/j.cej.2017.11.160
7. [7]
  (7) Lu, B.; Xu, Y.; Zhang, Z.; Wu, F.; Li, X.; Luo, C.; Zhang, L. J. CO₂ Util. 2021, 54, 101757. doi: 10.1016/j.jcou.2021.101757
8. [8]
  (8) Xu, Y.; Lu, B.; Luo, C.; Wu, F.; Li, X.; Zhang, L. Chem. Eng. J. 2022, 435, 134852. doi: 10.1016/j.cej.2022.134852
9. [9]
  (9) Kim, S. M.; Abdala, P. M.; Broda, M.; Hosseini, D.; Copéret, C.; Müller, C. ACS Catal. 2018, 8 (4), 2815. doi: 10.1021/acscatal.7b03063
10. [10]
  (10) Naeem, M. A.; Abdala, P. M.; Armutlulu, A.; Kim, S. M.; Fedorov, A.; Müller, C. R. ACS Catal. 2020, 10 (3), 1923. doi: 10.1021/acscatal.9b04555
11. [11]
  (11) Tian, S.; Yan, F.; Zhang, Z.; Jiang, J. Sci. Adv. 2019, 5 (4), eaav5077. doi: 10.1126/sciadv.aav5077
12. [12]
  (12) Ye, R.-P.; Ding, J.; Gong, W.; Argyle, M. D.; Zhong, Q.; Wang, Y.; Russell, C. K.; Xu, Z.; Russell, A. G.; Li, Q.; et al. Nat. Commun. 2019, 10 (1), 5698. doi: 10.1038/s41467-019-13638-9
13. [13]
  (13) Cai, T.; Sun, H.; Qiao, J.; Zhu, L.; Zhang, F.; Zhang, J.; Tang, Z.; Wei, X.; Yang, J.; Yuan, Q.; et al. Science 2021, 373 (6562), 1523. doi: 10.1126/science.abh4049
14. [14]
  (14) Porosoff, M. D.; Yan, B.; Chen, J. G. Energy Environ. Sci. 2016, 9 (1), 62. doi: 10.1039/C5EE02657A
15. [15]
  (15) Frei, M. S.; Mondelli, C.; García-Muelas, R.; Kley, K. S.; Puértolas, B.; López, N.; Safonova, O. V.; Stewart, J. A.; Curulla Ferré, D.; Pérez-Ramírez, J. Nat. Commun. 2019, 10 (1), 3377. doi: 10.1038/s41467-019-11349-9
16. [16]
  (16) Ruland, H.; Song, H.; Laudenschleger, D.; Stürmer, S.; Schmidt, S.; He, J.; Kähler, K.; Muhler, M.; Schlögl, R. ChemCatChem 2020, 12 (12), 3216. doi: 10.1002/cctc.202000195
17. [17]
  (17) Wang, Y.; Kattel, S.; Gao, W.; Li, K.; Liu, P.; Chen, J. G.; Wang, H. Nat. Commun. 2019, 10 (1), 1166. doi: 10.1038/s41467-019-09072-6
18. [18]
  (18) Xu, Y.; Gao, Z.; Peng, L.; Liu, K.; Yang, Y.; Qiu, R.; Yang, S.; Wu, C.; Jiang, J.; Wang, Y.; et al. J. Catal. 2022, 414, 236. doi: 10.1016/j.jcat.2022.09.011
19. [19]
  (19) Tsoukalou, A.; Bushkov, N. S.; Docherty, S. R.; Mance, D.; Serykh, A. I.; Abdala, P. M.; Copéret, C.; Fedorov, A.; Müller, C. R. J. Phys. Chem. C 2022, 126 (4), 1793. doi: 10.1021/acs.jpcc.1c08814
20. [20]
  (20) Jian, Y.; Jiang, Z.; He, C.; Tian, M.; Song, W.; Gao, G.; Chai, S. Catal. Sci. Technol. 2021, 11 (3), 1089. doi: 10.1039/D0CY01749C
21. [21]
  (21) Li, Z.; Cui, Y.; Wu, Z.; Milligan, C.; Zhou, L.; Mitchell, G.; Xu, B.; Shi, E.; Miller, J. T.; Ribeiro, F. H.; et al. Nat. Catal. 2018, 1 (5), 349. doi: 10.1038/s41929-018-0067-8
22. [22]
  (22) Yao, S.; Zhang, X.; Zhou, W.; Gao, R.; Xu, W.; Ye, Y.; Lin, L.; Wen, X.; Liu, P.; Chen, B.; et al. Science 2017, 357 (6349), 389. doi: 10.1126/science.aah4321
23. [23]
  (23) Kurlov, A.; Deeva, E. B.; Abdala, P. M.; Lebedev, D.; Tsoukalou, A.; Comas-Vives, A.; Fedorov, A.; Müller, C. R. Nat. Commun. 2020, 11 (1), 4920. doi: 10.1038/s41467-020-18721-0
24. [24]
  (24) Lin, L.; Zhou, W.; Gao, R.; Yao, S.; Zhang, X.; Xu, W.; Zheng, S.; Jiang, Z.; Yu, Q.; Li, Y.-W.; et al. Nature 2017, 544 (7648), 80. doi: 10.1038/nature21672
25. [25]
  (25) Lin, L.; Yu, Q.; Peng, M.; Li, A.; Yao, S.; Tian, S.; Liu, X.; Li, A.; Jiang, Z.; Gao, R.; et al. J. Am. Chem. Soc. 2021, 143 (1), 309. doi: 10.1021/jacs.0c10776
26. [26]
  (26) Morse, J. R.; Juneau, M.; Baldwin, J. W.; Porosoff, M. D.; Willauer, H. D. J. CO₂ Util. 2020, 35, 38. doi: 10.1016/j.jcou.2019.08.024
27. [27]
  (27) Yang, Y.; Xu, Y.; Li, Q.; Zhang, Y.; Zhou, H. J. Mater. Chem. A 2022, 10, 19444. doi: 10.1039/D2TA03481F
28. [28]
  (28) Halim, J.; Kota, S.; Lukatskaya, M. R.; Naguib, M.; Zhao, M.-Q.; Moon, E. J.; Pitock, J.; Nanda, J.; May, S. J.; Gogotsi, Y.; et al. Adv. Funct. Mater. 2016, 26 (18), 3118. doi: 10.1002/adfm.201505328
29. [29]
  (29) Shahzad, F.; Alhabeb, M.; Hatter, C. B.; Anasori, B.; Man Hong, S.; Koo, C. M.; Gogotsi, Y. Science 2016, 353 (6304), 1137. doi: 10.1126/science.aag2421
30. [30]
  (30) Zhou, P.; Chao, Y.; Lv, F.; Lai, J.; Wang, K.; Guo, S. Sci. Bull. 2020, 65 (9), 720. doi: 10.1016/j.scib.2019.12.025
31. [31]
  (31) VahidMohammadi, A.; Rosen, J.; Gogotsi, Y. Science 2021, 372 (6547), eabf1581. doi: 10.1126/science.abf1581
32. [32]
  (32) Zhou, H.; Chen, Z.; López, A. V.; López, E. D.; Lam, E.; Tsoukalou, A.; Willinger, E.; Kuznetsov, D. A.; Mance, D.; Kierzkowska, A.; et al. Nat. Catal. 2021, 4 (10), 860. doi: 10.1038/s41929-021-00684-0
33. [33]
  (33) Zhou, H.; Chen, Z.; Kountoupi, E.; Tsoukalou, A.; Abdala, P. M.; Florian, P.; Fedorov, A.; Müller, C. R. Nat. Commun. 2021, 12 (1), 5510. doi: 10.1038/s41467-021-25784-0
34. [34]
  (34) Niu, J.; Liu, H.; Jin, Y.; Fan, B.; Qi, W.; Ran, J. Int. J. Hydrog. Energy 2022, 47 (15), 9183. doi: 10.1016/j.ijhydene.2022.01.021
35. [35]
  (35) Wang, W.-H.; Himeda, Y.; Muckerman, J. T.; Manbeck, G. F.; Fujita, E. Chem. Rev. 2015, 115 (23), 12936. doi: 10.1021/acs.chemrev.5b00197
36. [36]
  (36) Saeidi, S.; Najari, S.; Fazlollahi, F.; Nikoo, M. K.; Sefidkon, F.; Klemeš, J. J.; Baxter, L. L. Renew. Sustain. Energy Rev. 2017, 80, 1292. doi: 10.1016/j.rser.2017.05.204
37. [37]
  (37) Saeidi, S.; Najari, S.; Hessel, V.; Wilson, K.; Keil, F. J.; Concepción, P.; Suib, S. L.; Rodrigues, A. E. Prog. Energy Combust. Sci. 2021, 85, 100905. doi: 10.1016/j.pecs.2021.100905
38. [38]
39. [39]
  (39) Lee, J. S.; Oyama, S. T.; Boudart, M. J. Catal. 1987, 106 (1), 125. doi: 10.1016/0021-9517(87)90218-1
40. [40]
  (40) Lee, J. S.; Volpe, L.; Ribeiro, F. H.; Boudart, M. J. Catal. 1988, 112 (1), 44. doi: 10.1016/0021-9517(88)90119-4
41. [41]
  (41) Wang, H.; Diao, Y.; Gao, Z.; Smith, K. J.; Guo, X.; Ma, D.; Shi, C. ACS Catal. 2022, 24, 15501. doi: 10.1021/acscatal.2c04619
42. [42]
  (42) Zhang, Q.; Jiang, Z.; Tackett, B. M.; Denny, S. R.; Tian, B.; Chen, X.; Wang, B.; Chen, J. G. ACS Catal. 2019, 9 (3), 2415. doi: 10.1021/acscatal.8b03990
43. [43]
  (43) Zhang, X.; Zhang, Z.; Zhou, Z. J. Energy Chem. 2018, 27 (1), 73. doi: 10.1016/j.jechem.2017.08.004
44. [44]
  (44) Dasireddy, V. D. B. C.; Vengust, D.; Likozar, B.; Kovač, J.; Mrzel, A. Renew. Energy 2021, 176, 251. doi: 10.1016/j.renene.2021.05.051
45. [45]
  (45) Zhong, Y.; Xia, X.; Shi, F.; Zhan, J.; Tu, J.; Fan, H. J. Adv. Sci. 2016, 3 (5), 1500286. doi: 10.1002/advs.201500286
46. [46]
  (46) Wu, K.; Yang, C.; Zhu, Y.; Wang, J.; Wang, X.; Liu, C.; Liu, Y.; Lu, H.; Liang, B.; Li, Y. Ind. Eng. Chem. Res. 2019, 58, 20270. doi: 10.1021/acs.iecr.9b04910
47. [47]
  (47) Chen, J. G. Chem. Rev. 1996, 96 (4), 1477. doi: 10.1021/cr950232u
48. [48]
  (48) Choi, J.-S.; Bugli, G.; Djéga-Mariadassou, G. J. Catal. 2000, 193 (2), 238. doi: 10.1006/jcat.2000.2894
49. [49]
  (49) Hanif, A.; Xiao, T.; York, A. P. E.; Sloan, J.; Green, M. L. H. Chem. Mater. 2002, 14 (3), 1009. doi: 10.1021/cm011096e
50. [50]
  (50) Wang, T.; Liu, X.; Wang, S.; Huo, C.; Li, Y.-W.; Wang, J.; Jiao, H. J. Phys. Chem. C 2011, 115 (45), 22360. doi: 10.1021/jp205950x
51. [51]
  (51) Hwu, H. H.; Chen, J. G. Chem. Rev. 2005, 105 (1), 185. doi: 10.1021/cr0204606
52. [52]
  (52) Zhou, Y.; Wang, W.; Zhang, C.; Huang, D.; Lai, C.; Cheng, M.; Qin, L.; Yang, Y.; Zhou, C.; Li, B.; et al. Adv. Colloid Interface Sci. 2020, 279, 102144. doi: 10.1016/j.cis.2020.102144
53. [53]
  (53) Posada-Pérez, S.; Ramírez, P. J.; Evans, J.; Viñes, F.; Liu, P.; Illas, F.; Rodriguez, J. A. J. Am. Chem. Soc. 2016, 138 (26), 8269. doi: 10.1021/jacs.6b04529
54. [54]
  (54) Kunkel, C.; Viñes, F.; Illas, F. Energy Environ. Sci. 2016, 9 (1), 141. doi: 10.1039/C5EE03649F
55. [55]
  (55) Posada-Pérez, S.; Viñes, F.; Ramirez, P. J.; Vidal, A. B.; Rodriguez, J. A.; Illas, F. Phys. Chem. Chem. Phys. 2014, 16 (28), 14912. doi: 10.1039/C4CP01943A
56. [56]
  (56) Posada-Pérez, S.; Viñes, F.; Valero, R.; Rodriguez, J. A.; Illas, F. Surf. Sci. 2017, 656, 24. doi: 10.1016/j.susc.2016.10.001
57. [57]
  (57) Yu, Y.; Guo, Z.; Peng, Q.; Zhou, J.; Sun, Z. J. Mater. Chem. A 2019, 7 (19), 12145. doi: 10.1039/C9TA02650A
58. [58]
  (58) Guo, Y.; Jin, S.; Wang, L.; He, P.; Hu, Q.; Fan, L.-Z.; Zhou, A. Ceram. Int. 2020, 46 (11, Part B), 19550. doi: 10.1016/j.ceramint.2020.05.008
59. [59]
  (59) Meshkian, R.; Näslund, L.-Å.; Halim, J.; Lu, J.; Barsoum, M. W.; Rosen, J. Scr. Mater. 2015, 108, 147. doi: 10.1016/j.scriptamat.2015.07.003
60. [60]
  (60) Mei, J.; Ayoko, G. A.; Hu, C.; Bell, J. M.; Sun, Z. Sustain. Mater. Technol. 2020, 25, e00156. doi: 10.1016/j.susmat.2020.e00156
61. [61]
  (61) Li, Z.; Xiao, Y.; Chowdhury, P. R.; Wu, Z.; Ma, T.; Chen, J. Z.; Wan, G.; Kim, T.-H.; Jing, D.; He, P.; et al. Nat. Catal. 2021, 4 (10), 882. doi: 10.1038/s41929-021-00686-y
62. [62]
  (62) Choi, J.; Chacon, B.; Park, H.; Hantanasirisakul, K.; Kim, T.; Shevchuk, K.; Lee, J.; Kang, H.; Cho, S.-Y.; Kim, J.; et al. ACS Sens. 2022, 7 (8), 2225. doi: 10.1021/acssensors.2c00658
63. [63]
  (63) Çakır, D.; Sevik, C.; Gülseren, O.; Peeters, F. M. J. Mater. Chem. A 2016, 4 (16), 6029. doi: 10.1039/C6TA01918H
64. [64]
  (64) Kurlov, A.; Stoian, D.; Baghizadeh, A.; Kountoupi, E.; Deeva, E. B.; Willinger, M.; Abdala, P. M.; Fedorov, A.; Müller, C. R. Catal. Sci. Technol. 2022, 12 (18), 5620. doi: 10.1039/D2CY00729K
65. [65]
  (65) Deeva, E. B.; Kurlov, A.; Abdala, P. M.; Lebedev, D.; Kim, S. M.; Gordon, C. P.; Tsoukalou, A.; Fedorov, A.; Müller, C. R. Chem. Mater. 2019, 31 (12), 4505. doi: 10.1021/acs.chemmater.9b01105
66. [66]
  (66) Rebrov, E. V. Advances in Clean Hydrocarbon Fuel Processing; Elsevier, Belfast, UK, 2011; p. 387. doi: 10.1533/9780857093783.4.387
67. [67]
  (67) Zhang, X.; Zhang, M.; Deng, Y.; Xu, M.; Artiglia, L.; Wen, W.; Gao, R.; Chen, B.; Yao, S.; Zhang, X.; et al. Nature 2021, 589 (7842), 396. doi: 10.1038/s41586-020-03130-6
68. [68]
  (68) Xu, W.; Ramirez, P. J.; Stacchiola, D.; Rodriguez, J. A. Catal. Lett. 2014, 144 (8), 1418. doi: 10.1007/s10562-014-1278-5
69. [69]
  (69) Liang, P.; Gao, H.; Yao, Z.; Jia, R.; Shi, Y.; Sun, Y.; Fan, Q.; Wang, H. Catal. Sci. Technol. 2017, 7 (15), 3312. doi: 10.1039/C7CY00708F
70. [70]
  (70) Liu, X.; Kunkel, C.; Ramírez de la Piscina, P.; Homs, N.; Viñes, F.; Illas, F. ACS Catal. 2017, 7 (7), 4323. doi: 10.1021/acscatal.7b00735
71. [71]
  (71) Sun, X.; Yu, J.; Cao, S.; Zimina, A.; Sarma, B. B.; Grunwaldt, J.-D.; Xu, H.; Li, S.; Liu, Y.; Sun, J. J. Am. Chem. Soc. 2022, 144 (49), 22589. doi: 10.1021/jacs.2c08979
72. [72]
  (72) Jung, K. T.; Kim, W. B.; Rhee, C. H.; Lee, J. S. Chem. Mater. 2004, 16 (2), 307. doi: 10.1021/cm030395w
73. [73]
  (73) Matteazzi, P.; Le Caër, G. J. Am. Ceram. Soc. 1991, 74 (6), 1382. doi: 10.1111/j.1151-2916.1991.tb04116.x
74. [74]
  (74) Gaffet, E.; Bernard, F.; Niepce, J.-C.; Charlot, F.; Gras, C.; Caër, G. L.; Guichard, J.-L.; Delcroix, P.; Mocellin, A.; Tillement, O. J. Mater. Chem. 1999, 9 (1), 305. doi: 10.1039/A804645J
75. [75]
  (75) Xia, Z. P.; Shen, Y. Q.; Shen, J. J.; Li, Z. Q. J. Alloy. Compd. 2008, 453 (1–2), 185. doi: 10.1016/j.jallcom.2006.11.166
76. [76]
  (76) Khabbaz, S.; Honarbakhsh-Raouf, A.; Ataie, A.; Saghafi, M. Int. J. Refract. Met. Hard Mater. 2013, 41, 402. doi: 10.1016/j.ijrmhm.2013.05.014
77. [77]
  (77) Upadhyay, S.; Pandey, O. P. J. Electrochem. Soc. 2022, 169 (1), 016511. doi: 10.1149/1945-7111/ac4a52
78. [78]
  (78) Mu, Y.; Zhang, Y.; Fang, L.; Liu, L.; Zhang, H.; Wang, Y. Electrochim. Acta 2016, 215, 357. doi: 10.1016/j.electacta.2016.08.104
79. [79]
  (79) Dai, W.; Lu, L.; Han, Y.; Wang, L.; Wang, J.; Hu, J.; Ma, C.; Zhang, K.; Mei, T. ACS Omega 2019, 4 (3), 4896. doi: 10.1021/acsomega.8b02856
80. [80]
  (80) Ren, J.-T.; Song, Y.-J.; Yuan, Z.-Y. J. Energy Chem. 2019, 32, 78. doi: 10.1016/j.jechem.2018.07.006
81. [81]
  (81) Malpica-Maldonado, J. J.; Melo-Banda, J. A.; Martínez-Salazar, A. L.; Garcia-Hernández, M.; Díaz Z, N. P.; Meraz M, M. A. Int. J. Hydrog. Energy 2019, 44 (24), 12446. doi: 10.1016/j.ijhydene.2018.08.152
82. [82]
  (82) Liao, L.; Bian, X.; Xiao, J.; Liu, B.; D. Scanlon, M.; H. Girault, H. Phys. Chem. Chem. Phys. 2014, 16 (21), 10088. doi: 10.1039/C3CP54754J
83. [83]
  (83) Li, Q.; Zhu, W.; Fu, J.; Zhang, H.; Wu, G.; Sun, S. Nano Energy 2016, 24, 1. doi: 10.1016/j.nanoen.2016.03.024
84. [84]
  (84) Sun, X.; Li, Y. Angew. Chem. 2004, 116 (5), 607. doi: 10.1002/ange.200352386
85. [85]
  (85) Baddour, F. G.; Roberts, E. J.; To, A. T.; Wang, L.; Habas, S. E.; Ruddy, D. A.; Bedford, N. M.; Wright, J.; Nash, C. P.; Schaidle, J. A.; et al. J. Am. Chem. Soc. 2020, 142 (2), 1010. doi: 10.1021/jacs.9b11238
86. [86]
87. [87]
  (87) Safaei, J.; Wang, G. Nano Res. Energy 2022, 1, e9120008. doi: 10.26599/NRE.2022.9120008
88. [88]
89. [89]
  (89) Lukatskaya, M. R.; Kota, S.; Lin, Z.; Zhao, M.-Q.; Shpigel, N.; Levi, M. D.; Halim, J.; Taberna, P.-L.; Barsoum, M. W.; Simon, P.; et al. Nat. Energy 2017, 2 (8), 1. doi: 10.1038/nenergy.2017.105
90. [90]
  (90) Mendoza-Sánchez, B.; Gogotsi, Y. Adv. Mater. 2016, 28 (29), 6104. doi: 10.1002/adma.201506133
91. [91]
  (91) Kuznetsov, D. A.; Chen, Z.; Kumar, P. V.; Tsoukalou, A.; Kierzkowska, A.; Abdala, P. M.; Safonova, O. V.; Fedorov, A.; Müller, C. R. J. Am. Chem. Soc. 2019, 141 (44), 17809. doi: 10.1021/jacs.9b08897
92. [92]
  (92) Qin, B.; Ma, H.; Hossain, M.; Zhong, M.; Xia, Q.; Li, B.; Duan, X. Chem. Mater. 2020, 32 (24), 10321. doi: 10.1021/acs.chemmater.0c03549
93. [93]
  (93) Cai, Z.; Liu, B.; Zou, X.; Cheng, H.-M. Chem. Rev. 2018, 118 (13), 6091. doi: 10.1021/acs.chemrev.7b00536
94. [94]
95. [95]
  (95) Han, R.; Gao, J.; Wei, S.; Su, Y.; Qin, Y. J. Mater. Chem. A 2018, 6 (8), 3462. doi: 10.1039/C7TA09960F.
96. [96]
  (96) Geng, D.; Zhao, X.; Chen, Z.; Sun, W.; Fu, W.; Chen, J.; Liu, W.; Zhou, W.; Loh, K. P. Adv. Mater. 2017, 29 (35), 1700072. doi: /10.1002/adma.201700072
97. [97]
  (97) Zhao, H.; Cai, K.; Ma, Z.; Cheng, Z.; Jia, T.; Kimura, H.; Fu, Q.; Tao, H.; Xiong, L. J. Appl. Phys. 2018, 123 (5), 053301. doi: 10.1063/1.5010101
98. [98]
  (98) Ba, K.; Wang, G.; Ye, T.; Wang, X.; Sun, Y.; Liu, H.; Hu, A.; Li, Z.; Sun, Z. ACS Catal. 2020, 10 (14), 7864. doi: 10.1021/acscatal.0c01127
99. [99]
  (99) Naguib, M.; Mashtalir, O.; Carle, J.; Presser, V.; Lu, J.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. ACS Nano 2012, 6 (2), 1322. doi: 10.1021/nn204153h
100. [100]
  (100) Naguib, M.; Kurtoglu, M.; Presser, V.; Lu, J.; Niu, J.; Heon, M.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. Adv. Mater. 2011, 23 (37), 4248. doi: 10.1002/adma.201102306
101. [101]
  (101) Anasori, B.; Lukatskaya, M. R.; Gogotsi, Y. Nat. Rev. Mater. 2017, 2 (2), 1. doi: 10.1038/natrevmats.2016.98
102. [102]
  (102) Zhang, J.; Zhao, Y.; Guo, X.; Chen, C.; Dong, C.-L.; Liu, R.-S.; Han, C.-P.; Li, Y.; Gogotsi, Y.; Wang, G. Nat. Catal. 2018, 1 (12), 985. doi: 10.1038/s41929-018-0195-1
103. [103]
  (103) Sun, S.; Lv, Z.; Qiao, Y.; Qin, C.; Xu, S.; Wu, C. Carbon Capture Sci. Technol. 2021, 1, 100001. doi: 10.1016/j.ccst.2021.100001
104. [104]
  (104) Wang, G.; Guo, Y.; Yu, J.; Liu, F.; Sun, J.; Wang, X.; Wang, T.; Zhao, C. Chem. Eng. J. 2022, 428, 132110. doi: 10.1016/j.cej.2021.132110
105. [105]
  (105) Lu, B.; Zhang, Z.; Li, X.; Luo, C.; Xu, Y.; Zhang, L. Fuel 2020, 276, 118135. doi: 10.1016/j.fuel.2020.118135
106. [106]
  (106) Bahmanpour, A. M.; Signorile, M.; Kröcher, O. Appl. Catal. B Environ. 2021, 295, 120319. doi: 10.1016/j.apcatb.2021.120319
107. [107]
  (107) Bikbaeva, V.; Nesterenko, N.; Konnov, S.; Nguyen, T.-S.; Gilson, J.-P.; Valtchev, V. Appl. Catal. B Environ. 2023, 320, 122011. doi: 10.1016/j.apcatb.2022.122011
108. [108]
  (108) Gao, J.; Wu, Y.; Jia, C.; Zhong, Z.; Gao, F.; Yang, Y.; Liu, B. Catal. Commun. 2016, 84, 147. doi: 10.1016/j.catcom.2016.06.026
109. [109]
  (109) Porosoff, M. D.; Yang, X.; Boscoboinik, J. A.; Chen, J. G. Angew. Chem. Int. Ed. 2014, 53 (26), 6705. doi: 10.1002/anie.201404109
110. [110]
  (110) Zhang, X.; Zhu, X.; Lin, L.; Yao, S.; Zhang, M.; Liu, X.; Wang, X.; Li, Y.-W.; Shi, C.; Ma, D. ACS Catal. 2017, 7 (1), 912. doi: 10.1021/acscatal.6b02991
111. [111]
  (111) Xu, J.; Gong, X.; Hu, R.; Liu, Z.; Liu, Z. Mol. Catal. 2021, 516, 111954. doi: 10.1016/j.mcat.2021.111954
112. [112]
  (112) Juneau, M.; Vonglis, M.; Hartvigsen, J.; Frost, L.; Bayerl, D.; Dixit, M.; Mpourmpakis, G.; Morse, J. R.; Baldwin, J. W.; Willauer, H. D.; et al. Energy Environ. Sci. 2020, 13 (8), 2524. doi: 10.1039/D0EE01457E
113. [113]
  (113) Figueras, M.; Gutiérrez, R. A.; Viñes, F.; Ramírez, P. J.; Rodriguez, J. A.; Illas, F. ACS Catal. 2021, 11 (15), 9679. doi: 10.1021/acscatal.1c01738
114. [114]
  (114) Abou Hamdan, M.; Nassereddine, A.; Checa, R.; Jahjah, M.; Pinel, C.; Piccolo, L.; Perret, N. Front. Chem. 2020, 8, 1. doi: 10.3389/fchem.2020.00452
115. [115]
  (115) Posada-Pérez, S.; Ramírez, P. J.; Gutiérrez, R. A.; Stacchiola, D. J.; Viñes, F.; Liu, P.; Illas, F.; Rodriguez, J. A. Catal. Sci. Technol. 2016, 6 (18), 6766. doi: 10.1039/C5CY02143J
116. [116]
  (116) Wang, T.; Li, Y.-W.; Wang, J.; Beller, M.; Jiao, H. J. Phys. Chem. C 2014, 118 (15), 8079. doi: 10.1021/jp501471u
117. [117]
  (117) Jo, S.; Lee, J. H.; Kim, T. Y.; Woo, J. H.; Ryu, H.-J.; Hwang, B.; Lee, S. C.; Kim, J. C.; Gilliard-AbdulAziz, K. L. Fuel 2022, 311, 122602. doi: 10.1016/j.fuel.2021.122602
118. [118]
  (118) Aziz, M. a. A.; Jalil, A. A.; Triwahyono, S.; Ahmad, A. Green Chem. 2015, 17 (5), 2647. doi: 10.1039/C5GC00119F
119. [119]
  (119) Zhou, Z.; Sun, N.; Wang, B.; Han, Z.; Cao, S.; Hu, D.; Zhu, T.; Shen, Q.; Wei, W. ChemSusChem 2020, 13 (2), 360. doi: 10.1002/cssc.201902828
120. [120]
  (120) Xu, Y.; Lu, B.; Luo, C.; Chen, J.; Zhang, Z.; Zhang, L. Chem. Eng. J. 2021, 406, 126903. doi: 10.1016/j.cej.2020.126903
121. [121]
  (121) Cruz-Hernández, A.; Mendoza-Nieto, J. A.; Pfeiffer, H. J. Energy Chem. 2017, 26 (5), 942. doi: 10.1016/j.jechem.2017.07.002
122. [122]
  (122) Wang, S.; Farrauto, R. J.; Karp, S.; Jeon, J. H.; Schrunk, E. T. Parametric, J. CO₂ Util. 2018, 27, 390. doi: 10.1016/j.jcou.2018.08.012
123. [123]
  (123) Wang, S.; Schrunk, E. T.; Mahajan, H.; Farrauto, A. R. J. Catalysts 2017, 7 (3), 88. doi: 10.3390/catal7030088
124. [124]
  (124) Arellano-Treviño, M. A.; He, Z.; Libby, M. C.; Farrauto, R. J. J. CO₂ Util. 2019, 31, 143. doi: 10.1016/j.jcou.2019.03.009
125. [125]
  (125) Duyar, M. S.; Treviño, M. A. A.; Farrauto, R. J. Appl. Catal. B Environ. 2015, 168, 370. doi: 10.1016/j.apcatb.2014.12.025
126. [126]
  (126) Weatherbee, G. D.; Bartholomew, C. H. J. Catal. 1982, 77 (2), 460. doi: 10.1016/0021-9517(82)90186-5
127. [127]
  (127) Li, J.; Wan, Q.; Dong, H.; Lin, S. Int. J. Hydrog. Energy 2022, S0360319922046523. doi: 10.1016/j.ijhydene.2022.10.029
128. [128]
  (128) Yan, Y.; Wong, R. J.; Ma, Z.; Donat, F.; Xi, S.; Saqline, S.; Fan, Q.; Du, Y.; Borgna, A.; He, Q.; et al. Appl. Catal. B Environ. 2022, 306, 121098. doi: 10.1016/j.apcatb.2022.121098
129. [129]
  (129) Dubois J.; Sayama K.; Arakawa H. Chem. Lett. 1992, 21 (1), 5. doi: 10.1246/cl.1992.5
130. [130]
  (130) Dongil, A. B.; Zhang, Q.; Pastor-Pérez, L.; Ramírez-Reina, T.; Guerrero-Ruiz, A.; Rodríguez-Ramos, I. Catalysts 2020, 10 (10), 1213. doi: 10.3390/catal10101213
131. [131]
  (131) Dongil, A. B.; Blanco, E.; Villora-Picó, J. J.; Sepúlveda-Escribano, A.; Rodríguez-Ramos, I. Nanomaterials 2022, 12 (7), 1048. doi: 10.3390/nano12071048
132. [132]
  (132) Dongil, A. B.; Conesa, J. M.; Pastor-Pérez, L.; Sepúlveda-Escribano, A.; Guerrero-Ruiz, A.; Rodríguez-Ramos, I. Catal. Sci. Technol. 2021, 11 (12), 4051. doi: 10.1039/D1CY00410G
133. [133]
  (133) Geng, W.; Han, H.; Liu, F.; Liu, X.; Xiao, L.; Wu, W. J. CO₂ Util. 2017, 21, 64. doi: 10.1016/j.jcou.2017.06.016
134. [134]
  (134) Chen, Y.; Choi, S.; Thompson, L. T. J. Catal. 2016, 343, 147. doi: 10.1016/j.jcat.2016.01.016
135. [135]
  (135) Li, T.; Virginie, M.; Khodakov, A. Y. Appl. Catal. Gen. 2017, 542, 154. doi: 10.1016/j.apcata.2017.05.018
136. [136]
  (136) Chernyak, S. A.; Corda, M.; Dath, J.-P.; Ordomsky, V. V.; Khodakov, A. Y. Chem. Soc. Rev. 2022, 51 (18), 7994. doi: 10.1039/D1CS01036K
137. [137]
  (137) Raghav, H.; Siva Kumar Konathala, L. N.; Mishra, N.; Joshi, B.; Goyal, R.; Agrawal, A.; Sarkar, B. J. CO₂ Util. 2021, 50, 101607. doi: 10.1016/j.jcou.2021.101607
138. [138]
  (138) Lin, T.; An, Y.; Yu, F.; Gong, K.; Yu, H.; Wang, C.; Sun, Y.; Zhong, L. ACS Catal. 2022, 12 (19), 12092. doi: 10.1021/acscatal.2c03404
139. [139]
  (139) Gao, P.; Li, S.; Bu, X.; Dang, S.; Liu, Z.; Wang, H.; Zhong, L.; Qiu, M.; Yang, C.; Cai, J.; et al. Nat. Chem. 2017, 9 (10), 1019. doi: 10.1038/nchem.2794
140. [140]
  (140) Zhou, Z.; Gao, P. Chin. J. Catal. 2022, 43 (8), 2045. doi: 10.1016/S1872-2067(22)64107-X
141. [141]
  (141) Schaidle, J. A.; Thompson, L. T. J. Catal. 2015, 329, 325. doi: 10.1016/j.jcat.2015.05.020
142. [142]
  (142) Amoyal, M.; Vidruk-Nehemya, R.; Landau, M. V.; Herskowitz, M. J. Catal. 2017, 348, 29. doi: 10.1016/j.jcat.2017.01.020
143. [143]
  (143) Jiang, Y.; Wang, K.; Wang, Y.; Liu, Z.; Gao, X.; Zhang, J.; Ma, Q.; Fan, S.; Zhao, T.-S.; Yao, M. J. CO₂ Util. 2023, 67, 102321. doi: 10.1016/j.jcou.2022.102321
144. [144]
  (144) Landau, M. V.; Meiri, N.; Utsis, N.; Vidruk Nehemya, R.; Herskowitz, M. Ind. Eng. Chem. Res. 2017, 56 (45), 13334. doi: 10.1021/acs.iecr.7b01817
145. [145]
  (145) Xu, Y.; Luo, C.; Sang, H.; Lu, B.; Wu, F.; Li, X.; Zhang, L. Chem. Eng. J. 2022, 435, 134960. doi: 10.1016/j.cej.2022.134960
146. [146]
  (146) Shao, B.; Zhang, Y.; Sun, Z.; Li, J.; Gao, Z.; Xie, Z.; Hu, J.; Liu, H. Green Chem. Eng. 2022, 3, 189. doi: 10.1016/j.gce.2021.11.009
147. [147]
  (147) Gu, J.; Jian, M.; Huang, L.; Sun, Z.; Li, A.; Pan, Y.; Yang, J.; Wen, W.; Zhou, W.; Lin, Y.; et al. Nat. Nanotechnol. 2021, 16 (10), 1141. doi: 10.1038/s41565-021-00951-y
148. [148]
  (148) Li, H.; Xiao, J.; Fu, Q.; Bao, X. Proc. Natl. Acad. Sci. 2017, 114 (23), 5930. doi: 10.1073/pnas.1701280114
149. [149]
  (149) Martín, A. J.; Mitchell, S.; Mondelli, C.; Jaydev, S.; Pérez-Ramírez, J. Nat. Catal. 2022, 5 (10), 854. doi: 10.1038/s41929-022-00842-y
150. [150]
  (150) de Smit, E.; Weckhuysen, B. M. Chem. Soc. Rev. 2008, 37 (12), 2758. doi: 10.1039/B805427D
151. [151]
  (151) Cao, F.; Zhang, Y.; Wang, H.; Khan, K.; Tareen, A. K.; Qian, W.; Zhang, H.; Ågren, H. Adv. Mater. 2022, 34 (13), 2107554. doi: 10.1002/adma.202107554
152. [152]
  (152) Zhao, X.; Holta, D. E.; Tan, Z.; Oh, J.-H.; Echols, I. J.; Anas, M.; Cao, H.; Lutkenhaus, J. L.; Radovic, M.; Green, M. J. ACS Appl. Nano Mater. 2020, 3 (11), 10578. doi: 10.1021/acsanm.0c02473
153. [153]
  (153) Wang, H.; Wang, L.; Lin, D.; Feng, X.; Niu, Y.; Zhang, B.; Xiao, F.-S. Nat. Catal. 2021, 4, 418. doi: 10.1038/s41929-021-00611-3
154. [154]
  (154) Zhang, X.; Xu, Y.; Liu, Y.; Niu, L.; Diao, Y.; Gao, Z.; Chen, B.; Xie, J.; Bi, M.; Wang, M.; et al. Chem 2022, 9, 1. doi: 10.1016/j.chempr.2022.09.007
155. [155]
  (155) Karlsson, L. H.; Birch, J.; Halim, J.; Barsoum, M. W.; Persson, P. O. Å. Nano Lett. 2015, 15 (8), 4955. doi: 10.1021/acs.nanolett.5b00737
156. [156]
  (156) Wang, Y.; Kazumi, S.; Gao, W.; Gao, X.; Li, H.; Guo, X.; Yoneyama, Y.; Yang, G.; Tsubaki, N. Appl. Catal. B Environ. 2020, 269, 118792. doi: 10.1016/j.apcatb.2020.118792
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Review on Using Molybdenum Carbides for the Thermal Catalysis of CO₂ Hydrogenation to Produce High-Value-Added Chemicals and Fuels