Citation: Xin Feng, Kexin Guo, Chunguang Jia, Bowen Liu, Suqin Ci, Junxiang Chen, Zhenhai Wen. 耦合甘油高选择性转化为甲酸盐与制氢的酸碱双电解液流动电解器[J]. Acta Physico-Chimica Sinica, ;2024, 40(5): 230305. doi: 10.3866/PKU.WHXB202303050 shu

耦合甘油高选择性转化为甲酸盐与制氢的酸碱双电解液流动电解器

1.
Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, Nanchang Hangkong University, Nanchang 330063, China;
2.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Received Date: 28 March 2023
Revised Date: 31 May 2023
Accepted Date: 1 June 2023

Fund Project: The project was supported by the National Natural Science Foundation of China (22168025) and the Natural Science Foundation of Jiangxi Province (20192BAB203013, 20202ACBL203003).

氢气因其高能量密度、可持续性和燃烧后无污染等优点，被认为是取代传统化石燃料的最具前途的新兴能源载体之一。其中，电解水制氢技术因为其高效和绿色的特性而备受关注。然而电解水制氢过程通常受到阳极析氧反应(Oxygen Evolution Reaction，OER)的限制，因此这种方法的大规模应用面临重大挑战。克服这一难题的一个有前途的解决方法是在阳极上使用电催化甘油氧化反应(Glycerol Oxidation Reaction，GOR)代替OER，这种替代反应可以实现节能降耗的同时提高电解水制氢的效率，进一步推动氢气作为清洁能源的发展。然而，这一目标的实现需要高效、低成本且高选择性的GOR电催化剂。在这篇文章中，我们报告了一种新型的酸碱双电解质流电解器(AADEF-electrolyzer)，用于在碱性阳极GOR耦合酸性阴极析氢反应(Hydrogen Evolution Reaction，HER)。我们通过一种简单的水热煅烧方法制备了一种在镍泡沫(NF)上原位生长的自支撑的NiCo₂O₄纳米针电极材料(NiCo₂O₄/NF)。该电极在GOR中表现出优异的电催化性能，在低电位下实现了高的电解电流密度，对甲酸盐的生产表现出优异的选择性，法拉第效率超过85%。密度泛函理论计算表明，NiCo₂O₄对GOR具有较低的反应能垒，Ni的存在有利于降低Co的电子态密度，从而实现NiCo₂O₄与中间体的高效解离，促进甲酸的生成。基于NiCo₂O₄/NF出色的GOR性能和电化学中和能(ENE)理论，我们构建了一个新型的AADEF-electrolyzer，利用NiCo₂O₄/NF作为GOR的阳极，配合酸性阴极进行析氢反应(HER)。实验结果表明，AADEF-electrolyzer对GOR具有低过电位和高选择性产甲酸的优异性能，仅需0.36 V的电压即可实现10 mA·cm^-2的电流密度，平均产甲酸的法拉第效率为85%。同时该电解槽表现出良好的长期稳定性和辅助产氢性能，阴极产氢的法拉第效率接近100%。这种低成本、易于制备的自支撑电极材料和新型酸碱双电解质流动电解器为促进化学品的增值转化和开发新型混合电解系统或其他相关电化学反应的混合电解装置提供了创新策略。
- Hydrogen production,
- Glycerol oxidation,
- Electrocatalysis,
- Electrolyzer
1. [1]
  (1) Su, H.; Jiang, J.; Song, S.; An, B.; Li, N.; Gao, Y.; Ge, L. Chin. J. Catal. 2023, 44, 7. doi: 10.1016/s1872-2067(22)64149-4
2. [2]
  (2) Chen, H.; Chen, J.; He, H.; Chen, X.; Jia, C.; Chen, D.; Liang, J.; Yu, D.; Yao, X.; Qin, L.; et al. Appl. Catal. B 2023, 323, 122187. doi: 10.1016/j.apcatb.2022.122187
3. [3]
4. [4]
  (4) Moreira, R.; Bimbela, F.; Gandía, L. M.; Ferreira, A.; Sánchez, J. L.; Portugal, A. Renew. Sust. Energ. Rev. 2021, 148, 111299. doi: 10.1016/j.rser.2021.111299
5. [5]
  (5) Li, X.; Hao, X.; Abudula, A.; Guan, G. J. Mater. Chem. A 2016, 4 (31), 11973. doi: 10.1039/c6ta02334g
6. [6]
  (6) Li, X.; Yu, J.; Jaroniec, M. Chem. Soc. Rev. 2016, 45 (9), 2603. doi: 10.1039/c5cs00838g
7. [7]
  (7) Sun, L.; Dai, Z.; Zhong, L.; Zhao, Y.; Cheng, Y.; Chong, S.; Chen, G.; Yan, C.; Zhang, X.; Tan, H.; et al. Appl. Catal. B 2021, 297, 120477. doi: 10.1016/j.apcatb.2021.120477
8. [8]
  (8) Yang, S.; Du, R.; Yu, Y.; Zhang, Z.; Wang, F. Nano Energy 2020, 77, 105057. doi: 10.1016/j.nanoen.2020.105057
9. [9]
  (9) Ding, M.; Chen, J.; Jiang, M.; Zhang, X.; Wang, G. J. Mater. Chem. A 2019, 7 (23), 14163. doi: 10.1039/c9ta00708c
10. [10]
11. [11]
12. [12]
  (12) Zhou, B.; Dong, C.-L.; Huang, Y.-C.; Zhang, N.; Wu, Y.; Lu, Y.; Yue, X.; Xiao, Z.; Zou, Y.; Wang, S. J. Energy Chem. 2021, 61, 179. doi: 10.1016/j.jechem.2021.02.026
13. [13]
  (13) Song, Y.; Xie, W.; Song, Y.; Li, H.; Li, S.; Jiang, S.; Lee, J. Y.; Shao, M. Appl. Catal. B 2022, 312, 121400. doi: 10.1016/j.apcatb.2022.121400
14. [14]
  (14) Xie, Y.; Zhou, Z.; Yang, N.; Zhao, G. Adv. Funct. Mater. 2021, 31 (34), 2102886. doi: 10.1002/adfm.202102886
15. [15]
  (15) Li, J.; Wei, R.; Wang, X.; Zuo, Y.; Han, X.; Arbiol, J.; Llorca, J.; Yang, Y.; Cabot, A.; Cui, C. Angew. Chem. Int. Ed. 2020, 59 (47), 20826. doi: 10.1002/anie.202004301
16. [16]
  (16) Zhou, B.; Li, Y.; Zou, Y.; Chen, W.; Zhou, W.; Song, M.; Wu, Y.; Lu, Y.; Liu, J.; Wang, Y.;et al. Angew. Chem. Int. Ed. 2021, 60 (42), 22908. doi: 10.1002/anie.202109211
17. [17]
  (17) Zheng, D.; Li, J.; Ci, S.; Cai, P.; Ding, Y.; Zhang, M.; Wen, Z. Appl. Catal. B 2020, 277, 119178. doi: 10.1016/j.apcatb.2020.119178
18. [18]
  (18) Xiang, K.; Wu, D.; Deng, X.; Li, M.; Chen, S.; Hao, P.; Guo, X.; Luo, J. L.; Fu, X. Z. Adv. Funct. Mater. 2020, 30 (10), 1909610. doi: 10.1002/adfm.201909610
19. [19]
  (19) Liu, W. J.; Xu, Z.; Zhao, D.; Pan, X. Q.; Li, H. C.; Hu, X.; Fan, Z. Y.; Wang, W. K.; Zhao, G. H.; Jin, S.; et al. Nat. Commun. 2020, 11 (1), 265. doi: 10.1038/s41467-019-14157-3
20. [20]
  (20) Han, X.; Sheng, H.; Yu, C.; Walker, T. W.; Huber, G. W.; Qiu, J.; Jin, S. ACS Catal. 2020, 10 (12), 6741. doi: 10.1021/acscatal.0c01498
21. [21]
  (21) Vo, T.-G.; Ho, P.-Y.; Chiang, C.-Y. Appl. Catal. B 2022, 300, 120723. doi: 10.1016/j.apcatb.2021.120723
22. [22]
  (22) Talebian-Kiakalaieh, A.; Amin, N. A. S.; Rajaei, K.; Tarighi, S. Appl. Energy 2018, 230, 1347. doi: 10.1016/j.apenergy.2018.09.006
23. [23]
  (23) Jamil, F.; Al-Haj, L.; Al-Muhtaseb, A. H.; Al-Hinai, M. A; Baawain, M.; Rashid, U.; Ahmad, M. N. M. Rev. Chem. Eng. 2018, 34 (2), 267. doi: 10.1515/revce-2016-0026
24. [24]
  (24) Deng, C.-Q.; Deng, J.; Fu, Y. Green Chem. 2022, 24 (21), 8477. doi: 10.1039/d2gc03235j
25. [25]
  (25) Fan, L.; Ji, Y.; Wang, G.; Chen, J.; Chen, K.; Liu, X.; Wen, Z. J. Am. Chem. Soc. 2022, 144 (16), 7224. doi: 10.1021/jacs.1c13740
26. [26]
  (26) Fan, L.; Liu, B.; Liu, X.; Senthilkumar, N.; Wang, G.; Wen, Z. Energy Technol. 2020, 9 (2), 2000804. doi: 10.1002/ente.202000804
27. [27]
  (27) Duan, Y.; Liu, Z.; Zhao, B.; Liu, J. RSC Adv. 2020, 10 (27), 15769. doi: 10.1039/d0ra00564a
28. [28]
  (28) Bai, J.; Huang, H.; Li, F.-M.; Zhao, Y.; Chen, P.; Jin, P.-J.; Li, S.-N.; Yao, H.-C.; Zeng, J.-H.; Chen, Y. J. Mater. Chem. A 2019, 7 (37), 21149. doi: 10.1039/c9ta08806g
29. [29]
  (29) Brix, A. C.; Morales, D. M.; Braun, M.; Jambrec, D.; Junqueira, J. R.; Cychy, S.; Seisel, S.; Masa, J.; Muhler, M.; Andronescu, C.; et al. ChemElectroChem 2021, 8 (12), 2336. doi: 10.1002/celc.202100739
30. [30]
  (30) Kim, H. J.; Kim, Y.; Lee, D.; Kim, J.-R.; Chae, H.-J.; Jeong, S.-Y.; Kim, B.-S.; Lee, J.; Huber, G. W.; Byun, J.; et al. ACS Sustain Chem. Eng. 2017, 5 (8), 6626. doi: 10.1021/acssuschemeng.7b00868
31. [31]
  (31) Dodekatos, G.; Schünemann, S.; Tüysüz, H. ACS Catal. 2018, 8 (7), 6301. doi: 10.1021/acscatal.8b01317
32. [32]
  (32) Alaba, P. A.; Lee, C. S.; Abnisa, F.; Aroua, M. K.; Cognet, P.; Pérès, Y.; Wan Daud, W. M. A. Rev. Chem. Eng. 2021, 37 (7), 779. doi: 10.1515/revce-2019-0013
33. [33]
  (33) Yang, F.; Ye, J.; Yuan, Q.; Yang, X.; Xie, Z.; Zhao, F.; Zhou, Z.; Gu, L.; Wang, X. Adv. Funct. Mater. 2020, 30 (11), 1908235. doi: 10.1002/adfm.201908235
34. [34]
  (34) Lam, C. H.; Bloomfield, A. J.; Anastas, P. T. Green Chem. 2017, 19 (8), 1958. doi: 10.1039/c7gc00371d
35. [35]
  (35) Lee, S.; Kim, H. J.; Lim, E. J.; Kim, Y.; Noh, Y.; Huber, G. W.; Kim, W. B. Green Chem. 2016, 18 (9), 2877. doi: 10.1039/c5gc02865e
36. [36]
  (36) De Souza, M. B.; Vicente, R. A.; Yukuhiro, V. Y.; Pires, C. T.; Cheuquepán, W.; Bott-Neto, J. L.; Solla-Gullón, J.; Fernández, P. S. ACS Catal. 2019, 9 (6), 5104. doi: 10.1021/acscatal.9b00190
37. [37]
  (37) Zhou, Z.; Chen, C.; Gao, M.; Xia, B.; Zhang, J. Green Chem. 2019, 21 (24), 6699. doi: 10.1039/c9gc02880c
38. [38]
  (38) Lu, Y.; Liu, T.; Dong, C. L.; Yang, C.; Zhou, L.; Huang, Y. C.; Li, Y.; Zhou, B.; Zou, Y.; Wang, S. Adv. Mater. 2022, 34 (2), e2107185. doi: 10.1002/adma.202107185
39. [39]
  (39) Wang, Y.; Zhu, Y.-Q.; Xie, Z.; Xu, S.-M.; Xu, M.; Li, Z.; Ma, L.; Ge, R.; Zhou, H.; Li, Z.; et al. ACS Catal. 2022, 12432. doi: 10.1021/acscatal.2c03162
40. [40]
  (40) Lv, J.; Wang, L.; Li, R.; Zhang, K.; Zhao, D.; Li, Y.; Li, X.; Huang, X.; Wang, G. ACS Catal. 2021, 14338. doi: 10.1021/acscatal.1c03960
41. [41]
  (41) Zhou, H.; Zheng, M.; Pang, H. Chem. Eng. J. 2020, 38, 127884. doi: 10.1016/j.cej.2020.127884
42. [42]
  (42) Wei, T. Y.; Chen, C. H.; Chien, H. C.; Lu, S. Y.; Hu, C.C. Adv. Mater. 2010, 22 (3), 347. doi: 10.1002/adma.200902175
43. [43]
  (43) Liu, Q.; Xie, L.; Liang, J.; Ren, Y.; Wang, Y.; Zhang, L.; Yue, L.; Li, T.; Luo, Y.; Li, N.; et al. Small 2022, 18 (13), e2106961. doi: 10.1002/smll.202106961
44. [44]
  (44) Jo, H. J.; Shit, A.; Jhon, H. S.; Park, S. Y. J. Ind. Eng. Chem. 2020, 89, 485. doi: 10.1016/j.jiec.2020.06.028
45. [45]
  (45) Hu, L.; Wu, L.; Liao, M.; Hu, X.; Fang, X. Adv. Funct. Mater. 2012, 22 (5), 998. doi: 10.1002/adfm.201102155
46. [46]
  (46) Zhao, Q.; Yan, Z.; Chen, C.; Chen, J. Chem. Rev. 2017, 117 (15), 10121. doi: 10.1021/acs.chemrev.7b00051
47. [47]
  (47) Ding, Y.; Cai, P.; Wen, Z. Chem. Soc. Rev. 2021, 50 (3), 1495. doi: 10.1039/d0cs01239d
48. [48]
  (48) Zhang, C.; Ci, S.; Peng, X.; Huang, J.; Cai, P.; Ding, Y.; Wen, Z. J. Energy Chem. 2021, 54, 30. doi: 10.1016/j.jechem.2020.04.073
49. [49]
  (49) Wang, G.; Chen, J.; Cai, P.; Jia, J.; Wen, Z. J. Mater. Chem. A 2018, 6 (36), 17763. doi: 10.1039/c8ta06827e
50. [50]
  (50) Zhang, M.; Chen, J.; Li, H.; Cai, P.; Li, Y.; Wen, Z. Nano Energy 2019, 61, 576. doi: 10.1016/j.nanoen.2019.04.050
51. [51]
  (51) Liu, B.; Wang, G.; Feng, X.; Dai, L.; Wen, Z.; Ci, S. Nanoscale 2022, 14, 12841. doi: 10.1039/d2nr02689a
52. [52]
  (52) Li, Y.; Wei, X.; Chen, L.; Shi, J.; He, M. Nat. Commun. 2019, 10 (1), 5335. doi: 10.1038/s41467-019-13375-z
53. [53]
  (53) Xu, Y.; Liu, M.; Wang, S.; Ren, K.; Wang, M.; Wang, Z.; Li, X.; Wang, L.; Wang, H. Appl. Catal. B 2021, 298, 120493. doi: 10.1016/j.apcatb.2021.120493
54. [54]
  (54) Giannozzi, P.; Baroni, S.; Bonini, N.; Calandra, M.; Car, R.; Cavazzoni, C.; Ceresoli, D.; Chiarotti, G. L.; Cococcioni, M.; Dabo, I.; et al. J. Phys. Condens. Matter 2009, 21 (39), 395502. doi: 10.1088/0953-8984/21/39/395502
55. [55]
  (55) Yan, X.; Zhang, W.-D.; Hu, Q.-T.; Liu, J.; Li, T.; Liu, Y.; Gu, Z.-G. Int. J. Hydrogen Energy 2019, 44 (51), 27664. doi: 10.1016/j.ijhydene.2019.09.004
56. [56]
  (56) Sun, B.; Miao, F.; Tao, B.; Wang, Y.; Zang, Y.; Chu, P. K. J. Phys. Chem. Solids 2021, 158, 110255. doi: 10.1016/j.jpcs.2021.110255
57. [57]
  (57) Qian, L.; Luo, S.; Wu, L.; Hu, X.; Chen, W.; Wang, X. Appl. Surf. Sci. 2020, 503, 144306. doi: 10.1016/j.apsusc.2019.144306
58. [58]
  (58) Norskov, J. K.; Rossmeisl, J.; Logadottir, A.; Lindqvist, L.; Kitchin, J. R.; Bligaard, T.; Jonsson, H. J. Phys. Chem. B 2004, 108 (46), 17886. doi: 10.1021/jp047349j
59. [59]
  (59) Norskov, J. K.; Bligaard, T.; Rossmeisl, J.; Christensen, C. H. Nat. Chem. 2009, 1 (1), 37. doi: 10.1038/nchem.121
1. [1]
  Tongtong Zhao , Yan Wang , Shiyue Qin , Liang Xu , Zhenhua Li . New Experiment Development: Upgrading and Regeneration of Discarded PET Plastic through Electrocatalysis. University Chemistry, 2024, 39(3): 308-315. doi: 10.3866/PKU.DXHX202309003
2. [2]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
3. [3]
  Kai CHEN , Fengshun WU , Shun XIAO , Jinbao ZHANG , Lihua ZHU . PtRu/nitrogen-doped carbon for electrocatalytic methanol oxidation and hydrogen evolution by water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1357-1367. doi: 10.11862/CJIC.20230350
4. [4]
  Xi Xu , Chaokai Zhu , Leiqing Cao , Zhuozhao Wu , Cao Guan . Experiential Education and 3D-Printed Alloys: Innovative Exploration and Student Development. University Chemistry, 2024, 39(2): 347-357. doi: 10.3866/PKU.DXHX202308039
5. [5]
  Qingqing SHEN , Xiangbowen DU , Kaicheng QIAN , Zhikang JIN , Zheng FANG , Tong WEI , Renhong LI . Self-supporting Cu/α-FeOOH/foam nickel composite catalyst for efficient hydrogen production by coupling methanol oxidation and water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1953-1964. doi: 10.11862/CJIC.20240028
6. [6]
  Yongmei Liu , Lisen Sun , Zhen Huang , Tao Tu . Curriculum-Based Ideological and Political Design for the Experiment of Methanol Oxidation to Formaldehyde Catalyzed by Electrolytic Silver. University Chemistry, 2024, 39(2): 67-71. doi: 10.3866/PKU.DXHX202308020
7. [7]
  Kaihui Huang , Dejun Chen , Xin Zhang , Rongchen Shen , Peng Zhang , Difa Xu , Xin Li . Constructing Covalent Triazine Frameworks/N-Doped Carbon-Coated Cu₂O S-Scheme Heterojunctions for Boosting Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(12): 2407020-. doi: 10.3866/PKU.WHXB202407020
8. [8]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
9. [9]
  Asif Hassan Raza , Shumail Farhan , Zhixian Yu , Yan Wu . 用于高效制氢的双S型ZnS/ZnO/CdS异质结构光催化剂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406020-. doi: 10.3866/PKU.WHXB202406020
10. [10]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
11. [11]
  Shuang Yang , Qun Wang , Caiqin Miao , Ziqi Geng , Xinran Li , Yang Li , Xiaohong Wu . Ideological and Political Education Design for Research-Oriented Experimental Course of Highly Efficient Hydrogen Production from Water Electrolysis in Aerospace Perspective. University Chemistry, 2024, 39(11): 269-277. doi: 10.12461/PKU.DXHX202403044
12. [12]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
13. [13]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Nickel phosphide modified phosphorus doped gallium oxide for visible light photocatalytic water splitting to hydrogen. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 736-750. doi: 10.11862/CJIC.20230346
14. [14]
  Rui PAN , Yuting MENG , Ruigang XIE , Daixiang CHEN , Jiefa SHEN , Shenghu YAN , Jianwu LIU , Yue ZHANG . Selective electrocatalytic reduction of Sn(Ⅳ) by carbon nitrogen materials prepared with different precursors. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1015-1024. doi: 10.11862/CJIC.20230433
15. [15]
  Meng Lin , Hanrui Chen , Congcong Xu . Preparation and Study of Photo-Enhanced Electrocatalytic Oxygen Evolution Performance of ZIF-67/Copper(I) Oxide Composite: A Recommended Comprehensive Physical Chemistry Experiment. University Chemistry, 2024, 39(4): 163-168. doi: 10.3866/PKU.DXHX202308117
16. [16]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462
17. [17]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
18. [18]
  Minna Ma , Yujin Ouyang , Yuan Wu , Mingwei Yuan , Lijuan Yang . Green Synthesis of Medical Chemiluminescence Reagents by Photocatalytic Oxidation. University Chemistry, 2024, 39(5): 134-143. doi: 10.3866/PKU.DXHX202310093
19. [19]
  Xingyang LI , Tianju LIU , Yang GAO , Dandan ZHANG , Yong ZHOU , Meng PAN . A superior methanol-to-propylene catalyst: Construction via synergistic regulation of pore structure and acidic property of high-silica ZSM-5 zeolite. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1279-1289. doi: 10.11862/CJIC.20240026
20. [20]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(82)
HTML views(1)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142