Citation: Liu Yuankai, Yu Tao, Guo Shaohua, Zhou Haoshen. Designing High-Performance Sulfide-Based All-Solid-State Lithium Batteries: From Laboratory to Practical Application[J]. Acta Physico-Chimica Sinica, ;2023, 39(8): 230102. doi: 10.3866/PKU.WHXB202301027 shu

Designing High-Performance Sulfide-Based All-Solid-State Lithium Batteries: From Laboratory to Practical Application

Liu Yuankai ^{1, 2} ,
Yu Tao ^{1, 2} ,
Guo Shaohua ^{1, 2,,} ,
Zhou Haoshen ^1,,

1.
College of Engineering and Applied Sciences, Nanjing University, Nanjing 210023, China
2.
Shenzhen Research Institute of Nanjing University, Shenzhen 518000, Guangdong Province, China

Corresponding author: Guo Shaohua, shguo@nju.edu.cn Zhou Haoshen, hszhou@nju.edu.cn
Received Date: 16 January 2023
Revised Date: 9 February 2023
Accepted Date: 13 February 2023
Available Online: 20 February 2023
Fund Project: The project was supported by the National Key R&D Program of China 2021YFA1202300the National Natural Science Foundation of China 22239002the National Natural Science Foundation of China 22075132the Science and Technology Innovation Fund for Emission Peak and Carbon Neutrality of Jiangsu Province BK20220034the Natural Science Foundation of Jiangsu Province, China BK20211556the Shenzhen Science and Technology Innovation Committee RCYX20200714114524165the Shenzhen Science and Technology Innovation Committee JCYJ20210324123002008the Shenzhen Science and Technology Innovation Committee 2021Szvup055the Open Fund of the Guangdong Provincial Key Laboratory of Advanced Energy Storage Materials aesm2021xx

All-solid-state lithium batteries (ASSB) have emerged as key components in energy storage applications owing to their superior safety characteristics and high energy density. The use of sulfide solid electrolytes has considerably promoted the development of all-solid-state lithium batteries because of advantages such as a high ionic conductivity, formability, and good interface compatibility with electrodes. In this review, we first discuss the issues hindering the use of sulfide-based all-solid-state lithium batteries, focusing on aspects related to the cathode/electrolyte interface, sulfide solid electrolytes, and the anode/electrolyte interface. At the cathode/electrolyte interface, interfacial side reactions inherently occur due to the narrow electrochemical window of sulfide electrolytes when used with high-voltage cathode materials, which degrades the battery performance. In addition, owing to the chemical potential difference between cathode materials and sulfide solid electrolytes, the space-charge layer generated due to the formation of a lithium depletion layer is also detrimental to the cell performance. To overcome these difficulties, inert coatings, replacing sulfide solid electrolytes with halide solid electrolytes, and replacing frequently used transitional metal oxide cathode materials with other materials that are better suited for sulfide solid electrolytes to modify the composite cathode have been explored. Improvements in the ionic conductivity and air stability are imperative for sulfide solid electrolytes. Strategies to optimize the solid electrolyte have mainly focused on doping or adjusting the synthesis routes of the sulfide solid electrolyte, which have resulted in notable improvements. At the anode/electrolyte interface, lithium dendrite formation and interfacial reactions between lithium metal and the sulfide solid electrolyte are the most notable challenges. Using artificial solid electrolyte interfaces with a low electronic conductivity, employing an alloy anode, and synthesizing composite electrolytes are typical approaches for overcoming these problems. In addition, from the perspective of the practical production of sulfide-based all-solid-state lithium batteries, electrode/electrolyte membrane-forming technology and the assembly of pouch cells are introduced. Membrane-forming technology has gained extensive attention with the aim of fabricating thin and mechanically stronger solid electrolyte membranes. High-loading cathode membranes as well as solid electrolyte membranes, dry processing, and wet processing are reviewed. Moreover, the improvement in the solid-solid contact of pouch cells, the design of high-loading cathodes, and the low-cost and scaled up production of sulfide solid electrolytes are introduced. Finally, we also propose research directions and future development trends for sulfide-based all-solid-state lithium batteries.
- Sulfide solid electrolyte,
- All-solid-state battery,
- Interface modification,
- Membrane-forming technology,
- Pouch cell
1. [1]
2. [2]
3. [3]
4. [4]
5. [5]
6. [6]
7. [7]
8. [8]
9. [9]
10. [10]
11. [11]
12. [12]
13. [13]
14. [14]
15. [15]
16. [16]
17. [17]
18. [18]
19. [19]
20. [20]
21. [21]
22. [22]
23. [23]
24. [24]
25. [25]
26. [26]
27. [27]
28. [28]
29. [29]
30. [30]
31. [31]
32. [32]
33. [33]
34. [34]
35. [35]
36. [36]
37. [37]
38. [38]
39. [39]
40. [40]
41. [41]
42. [42]
43. [43]
44. [44]
45. [45]
46. [46]
47. [47]
48. [48]
49. [49]
50. [50]
51. [51]
52. [52]
53. [53]
54. [54]
55. [55]
56. [56]
57. [57]
58. [58]
59. [59]
60. [60]
61. [61]
62. [62]
63. [63]
64. [64]
65. [65]
66. [66]
67. [67]
68. [68]
69. [69]
70. [70]
71. [71]
72. [72]
73. [73]
74. [74]
75. [75]
76. [76]
77. [77]
78. [78]
79. [79]
80. [80]
81. [81]
82. [82]
83. [83]
84. [84]
85. [85]
86. [86]
87. [87]
88. [88]
89. [89]
90. [90]
91. [91]
92. [92]
93. [93]
94. [94]
95. [95]
96. [96]
97. [97]
98. [98]
99. [99]
100. [100]
101. [101]
102. [102]
103. [103]
104. [104]
105. [105]
106. [106]
107. [107]
108. [108]
109. [109]
110. [110]
111. [111]
112. [112]
113. [113]
114. [114]
115. [115]
116. [116]
117. [117]
118. [118]
119. [119]
120. [120]
121. [121]
122. [122]
123. [123]
124. [124]
125. [125]
126. [126]
127. [127]
128. [128]
129. [129]
130. [130]
131. [131]
132. [132]
133. [133]
134. [134]
135. [135]
136. [136]
137. [137]
138. [138]
139. [139]
140. [140]
141. [141]
142. [142]
143. [143]
144. [144]
145. [145]
146. [146]
147. [147]
148. [148]
149. [149]
150. [150]
151. [151]
152. [152]
153. [153]
154. [154]
155. [155]
156. [156]
157. [157]
158. [158]
159. [159]
160. [160]
161. [161]
162. [162]
163. [163]
164. [164]
165. [165]
166. [166]
167. [167]
168. [168]
169. [169]
170. [170]
171. [171]
172. [172]
173. [173]
174. [174]
175. [175]
176. [176]
177. [177]
178. [178]
179. [179]
180. [180]
181. [181]
182. [182]
183. [183]
184. [184]
185. [185]
186. [186]
1. [1]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
2. [2]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
3. [3]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
4. [4]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
5. [5]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
6. [6]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
7. [7]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . 无碳酸乙烯酯电解液定向构筑正极电解质界面相实现高电压钴酸锂的宽温域稳定运行. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-. doi: 10.1016/j.actphy.2025.100087
8. [8]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
9. [9]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
10. [10]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
11. [11]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN改性PP隔膜用于高稳定性高效率锂硫电池. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-. doi: 10.1016/j.actphy.2025.100082
12. [12]
  Caiyun Jin , Zexuan Wu , Guopeng Li , Zhan Luo , Nian-Wu Li . 用于金属锂电池的磷腈基阻燃人工界面层. Acta Physico-Chimica Sinica, 2025, 41(8): 100094-. doi: 10.1016/j.actphy.2025.100094
13. [13]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
14. [14]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
15. [15]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
16. [16]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
17. [17]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
18. [18]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
19. [19]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
20. [20]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488

Get Citation

PDF

XML

Metrics

PDF Downloads(66)
Abstract views(1417)
HTML views(386)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142