Citation: Kuangyu Wang, Kai Liu, Hui Wu. Molten Alkali Metal Batteries Based on Solid Electrolytes[J]. Acta Physico-Chimica Sinica, ;2023, 39(12): 230100. doi: 10.3866/PKU.WHXB202301009 shu

Molten Alkali Metal Batteries Based on Solid Electrolytes

Kuangyu Wang ¹ ,
Kai Liu ^2,, ,
Hui Wu ^1,,

1.
State Key Lab of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
2.
State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources, School of New Energy, North China Electric Power University, Beijing 102206, China

Corresponding author: Kai Liu, liukai21@ncepu.edu.cn Hui Wu, huiwu@tsinghua.edu.cn
Received Date: 5 January 2023
Revised Date: 6 February 2023
Accepted Date: 15 February 2023
Available Online: 27 February 2023
Fund Project: the National Natural Science Foundation of China 51788104the Beijing Natural Science Foundation JQ19005

The development of energy storage technologies with high safety, low cost, and high energy densities is essential for the widespread use of renewable energy sources. Battery technology is one of the most promising candidates because of its pollution-free operation, high round-trip efficiency, flexible power and energy characteristics, long cycle life, and low maintenance cost. Although most batteries operate at room temperature, high-temperature systems are expected to perform better owing to improved electrolyte conductivity, faster reaction kinetics, and reduced interface impedance. The reported high-temperature batteries can be classified into liquid and solid electrolyte-based systems, with the latter having the potential to achieve higher energy densities while avoiding self-discharge effects. This review summarizes solid electrolyte-based liquid sodium and lithium batteries (SELS and SELL batteries). SELS batteries primarily use beta-Al₂O₃ and NASICON electrolytes, while SELL battery systems use garnet electrolytes. Because the microstructures and compositions of ceramic electrolytes significantly affect their conductivity and stability, novel manufacturing and element doping methods are being intensively investigated. Surface modification technology is also a major research focus to improve the wetting properties of molten alkali metals on the ceramic electrolyte, which assists to decrease interfacial resistance and increase the rate performance and power density of the battery. In addition, the selection of the cathode materials of SELS and SELL batteries has a significant impact on the energy and power densities, cycling stability, material cost, and application scenarios of the real devices. Until now, lead alloys, metal chlorides, sulfur, selenium, and iodine have been reported as potential choices. We describe in detail the reaction mechanisms, existing problems, and the latest research progress of these battery systems, with their electrochemical performance and raw material costs systematically summarized and compared. It is worth noting that the SELS and SELL batteries have different levels of technological maturity. In 2019, an energy storage system using SELS batteries with a capacity of 108 MW/648 MWh was built, whereas SELL battery research is a relatively emerging field. However, SELL batteries demonstrate promising application prospects because of their higher energy densities, lower operating temperatures, and competitive raw material costs. In addition, we believe that several research advancements and technical achievements related to these two types of batteries can be shared, with the future research directions listed in the conclusion section.
- High-temperature battery,
- Solid electrolyte,
- Grid-scale energy storage,
- beta-Al₂O₃ electrolyte,
- NASICON electrolyte,
- Garnet electrolyte
1. [1]
  Chu, S.; Cui, Y.; Liu, N. Nat. Mater. 2016, 16 (1), 16. doi: 10.1038/nmat4834 doi: 10.1038/nmat4834
2. [2]
  Chu, S.; Majumdar, A. Nature 2012, 488 (7411), 294. doi: 10.1038/nature11475 doi: 10.1038/nature11475
3. [3]
  Dunn, B.; Kamath, H.; Tarascon, J.-M. Science 2011, 334 (6058), 928. doi: 10.1126/science.1212741 doi: 10.1126/science.1212741
4. [4]
  Henke, M.; Hailu, G. Energies 2020, 13 (6), 4194. doi: 10.3390/en13164194 doi: 10.3390/en13164194
5. [5]
  Rashidi, S.; Karimi, N.; Sunden, B.; Kim, K. C.; Olabi, A. G.; Mahian, O. Prog. Energy Combust. Sci. 2022, 88, 100966. doi: 10.1016/j.pecs.2021.100966 doi: 10.1016/j.pecs.2021.100966
6. [6]
  Lin, X.; Salari, M.; Arava, L. M. R.; Ajayan, P. M.; Grinstaff, M. W. Chem. Soc. Rev. 2016, 45 (21), 5848. doi: 10.1039/c6cs00012f doi: 10.1039/c6cs00012f
7. [7]
  Xu, K. Chem. Rev. 2014, 114 (23), 11503. doi: 10.1021/cr500003w doi: 10.1021/cr500003w
8. [8]
  Jiang, C.; Li, H.; Wang, C. Sci. Bull. 2017, 62 (21), 1473. doi: 10.1016/j.scib.2017.10.011 doi: 10.1016/j.scib.2017.10.011
9. [9]
  Masset, P.; Guidotti, R. A. J. Power Sources 2007, 164 (1), 397. doi: 10.1016/j.jpowsour.2006.10.080 doi: 10.1016/j.jpowsour.2006.10.080
10. [10]
  Newhouse, J. M.; Sadoway, D. R. J. Electrochem. Soc. 2017, 164 (12), A2665. doi: 10.1149/2.1571712jes doi: 10.1149/2.1571712jes
11. [11]
  Kinzer, B.; Davis, A. L.; Krauskopf, T.; Hartmann, H.; LePage, W. S.; Kazyak, E.; Janek, J.; Dasgupta, N. P.; Sakamoto, J. Matter 2021, 4 (6), 1947. doi: 10.1016/j.matt.2021.04.016 doi: 10.1016/j.matt.2021.04.016
12. [12]
  Wang, K.; Jiang, K.; Chung, B.; Ouchi, T.; Burke, P. J.; Boysen, D. A.; Bradwell, D. J.; Kim, H.; Muecke, U.; Sadoway, D. R. Nature 2014, 514 (7522), 348. doi: 10.1038/nature13700 doi: 10.1038/nature13700
13. [13]
  Bradwell, D. J.; Kim, H.; Sirk, A. H. C.; Sadoway, D. R. J. Am. Chem. Soc. 2012, 134 (4), 1895. doi: 10.1021/ja209759s doi: 10.1021/ja209759s
14. [14]
  Ashour, R. F.; Yin, H.; Ouchi, T.; Kelley, D. H.; Sadoway, D. R. J. Electrochem. Soc. 2017, 164 (2), A535. doi: 10.1149/2.1451702jes doi: 10.1149/2.1451702jes
15. [15]
  Kim, J.; Shin, D.; Jung, Y.; Hwang, S. M.; Song, T.; Kim, Y.; Paik, U. J. Power Sources 2018, 377, 87. doi: 10.1016/j.jpowsour.2017.11.081 doi: 10.1016/j.jpowsour.2017.11.081
16. [16]
  Ouchi, T.; Sadoway, D. R. J. Power Sources 2017, 357, 158. doi: 10.1016/j.jpowsour.2017.04.104 doi: 10.1016/j.jpowsour.2017.04.104
17. [17]
  Ning, X.; Phadke, S.; Chung, B.; Yin, H.; Burke, P.; Sadoway, D. R. J. Power Sources 2015, 275, 370. doi: 10.1016/j.jpowsour.2014.10.173 doi: 10.1016/j.jpowsour.2014.10.173
18. [18]
  Yin, H.; Chung, B.; Chen, F.; Ouchi, T.; Zhao, J.; Tanaka, N.; Sadoway, D. R. Nat. Energy 2018, 3 (2), 127. doi: 10.1038/s41560-017-0072-1 doi: 10.1038/s41560-017-0072-1
19. [19]
  Mushtaq, K.; Zhao, J.; Weber, N.; Mendes, A.; Sadoway, D. R. J. Energy Chem. 2022, 66, 390. doi: 10.1016/j.jechem.2021.08.015 doi: 10.1016/j.jechem.2021.08.015
20. [20]
  Xu, J.; Martinez, A. M.; Osen, K. S.; Kjos, O. S.; Kongstein, O. E.; Haarberg, G. M. J. Electrochem. Soc. 2017, 164 (12), A2335. doi: 10.1149/2.0591712jes doi: 10.1149/2.0591712jes
21. [21]
  Ding, W.; Gong, Q.; Liang, S.; Hoffmann, R.; Zhou, H.; Li, H.; Wang, K.; Zhang, T.; Weisenburger, A.; Müller, G.; et al. J. Power Sources 2023, 553, 232254. doi: 10.1016/j.jpowsour.2022.232254 doi: 10.1016/j.jpowsour.2022.232254
22. [22]
  Kim, H.; Boysen, D. A.; Newhouse, J. M.; Spatocco, B. L.; Chung, B.; Burke, P. J.; Bradwell, D. J.; Jiang, K.; Tomaszowska, A. A.; Wang, K.; et al. Chem. Rev. 2013, 113 (3), 2075. doi: 10.1021/cr300205k doi: 10.1021/cr300205k
23. [23]
  Zhou, H.; Li, H.; Gong, Q.; Yan, S.; Zhou, X.; Liang, S.; Ding, W.; He, Y.; Jiang, K.; Wang, K. Energy Storage Mater. 2022, 50, 572. doi: 10.1016/j.ensm.2022.05.032 doi: 10.1016/j.ensm.2022.05.032
24. [24]
  Zhao, J.; Wang, Y.; Lu, G. J. Electrochem. Soc. 2022, 169 (5), 056517. doi: 10.1149/1945-7111/ac6e0c doi: 10.1149/1945-7111/ac6e0c
25. [25]
  Wang, Y.; Wang, Y.; Wang, Y. X.; Feng, X.; Chen, W.; Ai, X.; Yang, H.; Cao, Y. Chem 2019, 5 (10), 2547. doi: 10.1016/j.chempr.2019.05.026 doi: 10.1016/j.chempr.2019.05.026
26. [26]
  Yung-Fang Yu Yao; Kummer, J. T. J. Inorg. Nucl. Chem. 1967, 29 (9), 2453. doi: 10.1016/0022-1902(67)80301-4 doi: 10.1016/0022-1902(67)80301-4
27. [27]
  Jinzhi, W.; Xiaolei, H. A. N.; Chaofeng, X. U.; Jingwen, Z.; Yue, T.; Guanglei, C. U. I. Energy Storage Sci. Technol. 2022, 11 (9), 2834. doi: 10.19799/j.cnki.2095-4239.2022.0424 doi: 10.19799/j.cnki.2095-4239.2022.0424
28. [28]
  Lalère, F.; Leriche, J. B.; Courty, M.; Boulineau, S.; Viallet, V.; Masquelier, C.; Seznec, V. J. Power Sources 2014, 247, 975. doi: 10.1016/j.jpowsour.2013.09.051 doi: 10.1016/j.jpowsour.2013.09.051
29. [29]
  Hueso, K. B.; Palomares, V.; Armand, M.; Rojo, T. Nano Res. 2017, 10 (12), 4082. doi: 10.1007/s12274-017-1602-7 doi: 10.1007/s12274-017-1602-7
30. [30]
  Hueso, K. B.; Armand, M.; Rojo, T. Energy Environ. Sci. 2013, 6 (3), 734. doi: 10.1039/c3ee24086j doi: 10.1039/c3ee24086j
31. [31]
  Fertig, M. P.; Skadell, K.; Schulz, M.; Dirksen, C.; Adelhelm, P.; Stelter, M. Batter. Supercaps 2022, 5 (1), e202100131. doi: 10.1002/batt.202100131 doi: 10.1002/batt.202100131
32. [32]
  Ma, Q.; Tietz, F. ChemElectroChem 2020, 7 (13), 2693. doi: 10.1002/celc.202000164 doi: 10.1002/celc.202000164
33. [33]
  Zhang, C.; Zhang, L.; Zhang, X.; Zheng, P.; Li, F. Ceram. Int. 2020, 46 (3), 3009. doi: 10.1016/j.ceramint.2019.09.300 doi: 10.1016/j.ceramint.2019.09.300
34. [34]
  Bay, M. C.; Heinz, M. V. F.; Figi, R.; Schreiner, C.; Basso, D.; Zanon, N.; Vogt, U. F.; Battaglia, C. ACS Appl. Energy Mater. 2019, 2 (1), 687. doi: 10.1021/acsaem.8b01715 doi: 10.1021/acsaem.8b01715
35. [35]
  Li, K.; Yang, Y.; Zhang, X.; Liang, S. J. Mater. Sci. 2020, 55 (20), 8435. doi: 10.1007/s10853-020-04423-x doi: 10.1007/s10853-020-04423-x
36. [36]
  Heinz, M. V. F.; Bay, M. C.; Vogt, U. F.; Battaglia, C. Acta Mater. 2021, 213, 116940. doi: 10.1016/j.actamat.2021.116940 doi: 10.1016/j.actamat.2021.116940
37. [37]
  Mortalò, C.; Rosa, R.; Veronesi, P.; Fasolin, S.; Zin, V.; Deambrosis, S. M.; Miorin, E.; Dimitrakis, G.; Fabrizio, M.; Leonelli, C. Ceram. Int. 2020, 46 (18), 28767. doi: 10.1016/j.ceramint.2020.08.039 doi: 10.1016/j.ceramint.2020.08.039
38. [38]
  Moghadam, H. A.; Paydar, M. H. Adv. Appl. Ceram. 2021, 120 (3), 156. doi: 10.1080/17436753.2021.1911582 doi: 10.1080/17436753.2021.1911582
39. [39]
  Kim, Y. H.; Lee, D. H.; Lee, D. G.; Jung, K.; Lim, S. K. Mater. Res. Bull. 2022, 145, 111524. doi: 10.1016/j.materresbull.2021.111524 doi: 10.1016/j.materresbull.2021.111524
40. [40]
  Li, H.; Fan, H.; Wang, B.; Wang, C.; Zhang, M.; Chen, G.; Jiang, X.; Zhao, N.; Lu, J.; Zhang, J. J. Eur. Ceram. Soc. 2020, 40 (8), 3072. doi: 10.1016/j.jeurceramsoc.2020.02.037 doi: 10.1016/j.jeurceramsoc.2020.02.037
41. [41]
  Dirksen, C. L.; Skadell, K.; Schulz, M.; Stelter, M. Sep. Purif. Technol. 2019, 213, 88. doi: 10.1016/j.seppur.2018.12.028 doi: 10.1016/j.seppur.2018.12.028
42. [42]
  Dirksen, C. L.; Skadell, K.; Schulz, M.; Fertig, M. P.; Stelter, M. Materials 2021, 14 (18), 5389. doi: 10.3390/ma14185389 doi: 10.3390/ma14185389
43. [43]
  Lee, D. H.; Lee, D. G.; Lim, S. K. Ceram. Int. 2021, 47 (17), 24743. doi: 10.1016/j.ceramint.2021.05.197 doi: 10.1016/j.ceramint.2021.05.197
44. [44]
  Wang, Z.; Feng, X.; Zhang, T.; Xie, Z.; Song, F.; Li, Y. Ceram. Int. 2020, 46 (15), 24668. doi: 10.1016/j.ceramint.2020.06.256 doi: 10.1016/j.ceramint.2020.06.256
45. [45]
  Virkar, A. V.; Viswanathan, L.; Biswas, D. R. J. Mater. Sci. 1980, 15 (2), 302. doi: 10.1007/PL00020062 doi: 10.1007/PL00020062
46. [46]
  Jonghe, L. C.; Feldman, L.; Beuchele, A. J. Mater. Sci. 1981, 16 (3), 780. doi: 10.1007/bf00552217 doi: 10.1007/bf00552217
47. [47]
  Li, M. M.; Tripathi, S.; Polikarpov, E.; Canfield, N. L.; Han, K. S.; Weller, J. M.; Buck, E. C.; Engelhard, M. H.; Reed, D. M.; Sprenkle, V. L.; et al. ACS Appl. Mater. Interfaces 2022, 14 (22), 25534. doi: 10.1021/acsami.2c05245 doi: 10.1021/acsami.2c05245
48. [48]
  Wang, J.; Hu, Y.; Li, Y.; Gao, X.; Wu, X.; Wen, Z. J. Power Sources 2020, 453, 227843. doi: 10.1016/j.jpowsour.2020.227843 doi: 10.1016/j.jpowsour.2020.227843
49. [49]
  Lai, H.; Wang, J.; Cai, M.; Song, Z.; Gao, X.; Wu, X.; Wen, Z. Chem. Eng. J. 2022, 433, 133545. doi: 10.1016/j.cej.2021.133545 doi: 10.1016/j.cej.2021.133545
50. [50]
  Wu, T.; Wen, Z.; Sun, C.; Wu, X.; Zhang, S.; Yang, J. J. Mater. Chem. A 2018, 6 (26), 12623. doi: 10.1039/c8ta01883a doi: 10.1039/c8ta01883a
51. [51]
  Hu, Y.; Wen, Z.; Wu, X.; Lu, Y. J. Power Sources 2013, 240, 786. doi: 10.1016/j.jpowsour.2013.04.056 doi: 10.1016/j.jpowsour.2013.04.056
52. [52]
  Jin, D.; Choi, S.; Jang, W.; Soon, A.; Kim, J.; Moon, H.; Lee, W.; Lee, Y.; Son, S.; Park, Y. C.; et al. ACS Appl. Mater. Interfaces 2019, 11 (3), 2917. doi: 10.1021/acsami.8b13954 doi: 10.1021/acsami.8b13954
53. [53]
  Jin, D.; Lee, H. G.; Choi, S.; Kim, S.; Lee, Y.; Son, S.; Park, Y. C.; Lee, J. S.; Jung, K.; Shim, W. Nano Lett. 2019, 19 (12), 8811. doi: 10.1021/acs.nanolett.9b03646 doi: 10.1021/acs.nanolett.9b03646
54. [54]
  Li, M. M.; Lu, X.; Zhan, X.; Engelhard, M. H.; Bonnett, J. F.; Polikarpov, E.; Jung, K.; Reed, D. M.; Sprenkle, V. L.; Li, G. Chem. Commun. 2021, 57 (1), 45. doi: 10.1039/d0cc06987f doi: 10.1039/d0cc06987f
55. [55]
  Hou, W.; Guo, X.; Shen, X.; Amine, K.; Yu, H.; Lu, J. Nano Energy 2018, 52, 279. doi: 10.1016/j.nanoen.2018.07.036 doi: 10.1016/j.nanoen.2018.07.036
56. [56]
  Hong, H. Y. P. Mater. Res. Bull. 1976, 11 (2), 173. doi: 10.1016/0025-5408(76)90073-8 doi: 10.1016/0025-5408(76)90073-8
57. [57]
  Ma, Q.; Guin, M.; Naqash, S.; Tsai, C. L.; Tietz, F.; Guillon, O. Chem. Mater. 2016, 28 (13), 4821. doi: 10.1021/acs.chemmater.6b02059 doi: 10.1021/acs.chemmater.6b02059
58. [58]
  Song, S.; Duong, H. M.; Korsunsky, A. M.; Hu, N.; Lu, L. Sci. Rep. 2016, 6, 32330. doi: 10.1038/srep32330 doi: 10.1038/srep32330
59. [59]
  Yang, J.; Liu, G.; Avdeev, M.; Wan, H.; Han, F.; Shen, L.; Zou, Z.; Shi, S.; Hu, Y. S.; Wang, C.; Yao, X. ACS Energy Lett. 2020, 5 (9), 2835. doi: 10.1021/acsenergylett.0c01432 doi: 10.1021/acsenergylett.0c01432
60. [60]
  Gross, M. M.; Small, L. J.; Peretti, A. S.; Percival, S. J.; Rodriguez, M. A.; Spoerke, E. D. J. Mater. Chem. A 2020, 8 (33), 17012. doi: 10.1039/d0ta03571h doi: 10.1039/d0ta03571h
61. [61]
  Wang, Y. X.; Zhang, B.; Lai, W.; Xu, Y.; Chou, S. L.; Liu, H. K.; Dou, S. X. Adv. Energy Mater. 2017, 7 (24), 1602829. doi: 10.1002/aenm.201602829 doi: 10.1002/aenm.201602829
62. [62]
  Hu, Y.; Wu, X.; Wen, Z. Energy Storage Sci. Technol. 2021, 10 (3), 781. doi: 10.19799/j.cnki.2095-4239.2021.0139 doi: 10.19799/j.cnki.2095-4239.2021.0139
63. [63]
  Kim, G.; Park, Y. C.; Lee, Y.; Cho, N.; Kim, C. S.; Jung, K. J. Power Sources 2016, 325, 238. doi: 10.1016/j.jpowsour.2016.06.035 doi: 10.1016/j.jpowsour.2016.06.035
64. [64]
  Li, Y.; Tang, Y.; Li, X.; Tu, W.; Zhang, L.; Huang, J. Small 2021, 17 (23), 2100846. doi: 10.1002/smll.202100846 doi: 10.1002/smll.202100846
65. [65]
  Oshima, T.; Kajita, M.; Okuno, A. Int. J. Appl. Ceram. Technol. 2005, 1 (3), 269. doi: 10.1111/j.1744-7402.2004.tb00179.x doi: 10.1111/j.1744-7402.2004.tb00179.x
66. [66]
  Nikiforidis, G.; Van de Sanden, M. C. M.; Tsampas, M. N. RSC Adv. 2019, 9 (10), 5649. doi: 10.1039/c8ra08658c doi: 10.1039/c8ra08658c
67. [67]
  Lu, X.; Xia, G.; Lemmon, J. P.; Yang, Z. J. Power Sources 2010, 195 (9), 2431. doi: 10.1016/j.jpowsour.2009.11.120 doi: 10.1016/j.jpowsour.2009.11.120
68. [68]
  Wen, Z.; Hu, Y.; Wu, X.; Han, J.; Gu, Z. Adv. Funct. Mater. 2013, 23 (8), 1005. doi: 10.1002/adfm.201200473 doi: 10.1002/adfm.201200473
69. [69]
  Vudata, S. P.; Bhattacharyya, D. Int. J. Heat Mass Transf. 2021, 181, 122025. doi: 10.1016/j.ijheatmasstransfer.2021.122025 doi: 10.1016/j.ijheatmasstransfer.2021.122025
70. [70]
  Zhan, X.; Li, M. M.; Weller, J. M.; Sprenkle, V. L.; Li, G. Materials 2021, 14 (12), 3260. doi: 10.3390/ma14123260 doi: 10.3390/ma14123260
71. [71]
  Frusteri, L.; Leonardi, S. G.; Samperi, M.; Antonucci, V.; D'Urso, C. J. Energy Storage 2022, 55, 105503. doi: 10.1016/j.est.2022.105503 doi: 10.1016/j.est.2022.105503
72. [72]
  Graeber, G.; Landmann, D.; Svaluto-Ferro, E.; Vagliani, F.; Basso, D.; Turconi, A.; Heinz, M. V. F.; Battaglia, C. Adv. Funct. Mater. 2021, 31 (46), 2106367. doi: 10.1002/adfm.202106367 doi: 10.1002/adfm.202106367
73. [73]
  Landmann, D.; Svaluto-Ferro, E.; Heinz, M. V. F.; Schmutz, P.; Battaglia, C. Adv. Sci. 2022, 9 (17), 2201019. doi: 10.1002/advs.202201019 doi: 10.1002/advs.202201019
74. [74]
  Lee, Y.; Kim, H. J.; Byun, D. J.; Cho, K. K.; Ahn, J. H.; Kim, C. S. J. Power Sources 2019, 440, 227110. doi: 10.1016/j.jpowsour.2019.227110 doi: 10.1016/j.jpowsour.2019.227110
75. [75]
  Kim, J.; Jo, S. H.; Bhavaraju, S.; Eccleston, A.; Kang, S. O. J. Electroanal. Chem. 2015, 759, 201. doi: 10.1016/j.jelechem.2015.11.022 doi: 10.1016/j.jelechem.2015.11.022
76. [76]
  Gross, M. M.; Percival, S. J.; Small, L. J.; Lamb, J.; Peretti, A. S.; Spoerke, E. D. ACS Appl. Energy Mater. 2020, 3 (11), 11456. doi: 10.1021/acsaem.0c02385 doi: 10.1021/acsaem.0c02385
77. [77]
  Hu, Y.; Wu, X.; Wen, Z.; Hou, M.; Yi, B. Chinese J. Eng. Sci. 2021, 23 (5), 94. doi: 10.15302/j-sscae-2021.05.013 doi: 10.15302/j-sscae-2021.05.013
78. [78]
  Gao, X.; Hu, Y.; Zha, W.; Li, Y.; Wang, J.; Lai, H.; Wu, X.; Yang, J.; Chen, C.; Wen, Z. Mater. Today Energy 2022, 23, 100894. doi: 10.1016/j.mtener.2021.100894 doi: 10.1016/j.mtener.2021.100894
79. [79]
  Li, Y.; Shi, L.; Gao, X.; Wang, J.; Hu, Y.; Wu, X.; Wen, Z. Chem. Eng. J. 2021, 421, 127853. doi: 10.1016/j.cej.2020.127853 doi: 10.1016/j.cej.2020.127853
80. [80]
  Gao, X.; Hu, Y.; Li, Y.; Wang, J.; Wu, X.; Yang, J.; Wen, Z. ACS Appl. Mater. Interfaces 2020, 12 (22), 24767. doi: 10.1021/acsami.0c04470 doi: 10.1021/acsami.0c04470
81. [81]
  Xu, L.; Lu, Y.; Zhao, C.; Yuan, H.; Zhu, G.; Hou, L.; Zhang, Q.; Huang, J. Adv. Energy Mater. 2021, 11 (4), 2002360. doi: 10.1002/aenm.202002360 doi: 10.1002/aenm.202002360
82. [82]
  Miao, X.; Wang, H.; Sun, R.; Wang, C.; Zhang, Z.; Li, Z.; Yin, L. Energy Environ. Sci. 2020, 13 (11), 3780. doi: 10.1039/D0EE01435D doi: 10.1039/D0EE01435D
83. [83]
  Cao, D.; Sun, X.; Li, Q.; Natan, A.; Xiang, P.; Zhu, H. Matter 2020, 3, 57. doi: 10.1016/j.matt.2020.03.015 doi: 10.1016/j.matt.2020.03.015
84. [84]
  Hatzell, K. B.; Chen, X. C.; Cobb, C. L.; Dasgupta, N. P.; Dixit, M. B.; Marbella, L. E.; McDowell, M. T.; Mukherjee, P. P.; Verma, A.; Viswanathan, V.; et al. ACS Energy Lett. 2020, 5 (3), 922. doi: 10.1021/acsenergylett.9b02668 doi: 10.1021/acsenergylett.9b02668
85. [85]
  Jin, Y.; Liu, K.; Lang, J.; Zhuo, D.; Huang, Z.; Wang, C. C.; Wu, H.; Cui, Y. Nat. Energy 2018, 3 (9), 732. doi: 10.1038/s41560-018-0198-9 doi: 10.1038/s41560-018-0198-9
86. [86]
  Abouali, S.; Yim, C. H.; Merati, A.; Abu-Lebdeh, Y.; Thangadurai, V. ACS Energy Lett. 2021, 6 (5), 1920. doi: 10.1021/acsenergylett.1c00401 doi: 10.1021/acsenergylett.1c00401
87. [87]
  Wang, D.; Zhu, C.; Fu, Y.; Sun, X.; Yang, Y. Adv. Energy Mater. 2020, 10 (39), 2001318. doi: 10.1002/aenm.202001318 doi: 10.1002/aenm.202001318
88. [88]
  Wang, C.; Fu, K.; Kammampata, S. P.; McOwen, D. W.; Samson, A. J.; Zhang, L.; Hitz, G. T.; Nolan, A. M.; Wachsman, E. D.; Mo, Y.; et al. Chem. Rev. 2020, 120 (10), 4257. doi: 10.1021/acs.chemrev.9b00427 doi: 10.1021/acs.chemrev.9b00427
89. [89]
  Zhu, Y.; He, X.; Mo, Y. ACS Appl. Mater. Interfaces 2015, 7 (42), 23685. doi: 10.1021/acsami.5b07517 doi: 10.1021/acsami.5b07517
90. [90]
  Huo, H.; Luo, J.; Thangadurai, V.; Guo, X.; Nan, C. W.; Sun, X. ACS Energy Lett. 2020, 5 (1), 252. doi: 10.1021/acsenergylett.9b02401 doi: 10.1021/acsenergylett.9b02401
91. [91]
  Yamada, H.; Ito, T.; Kammampata, S. P.; Thangadurai, V. ACS Appl. Mater. Interfaces 2020, 12 (32), 36119. doi: 10.1021/acsami.0c09135 doi: 10.1021/acsami.0c09135
92. [92]
  Hofstetter, K.; Samson, A. J.; Narayanan, S.; Thangadurai, V. J. Power Sources 2018, 390, 297. doi: 10.1016/j.jpowsour.2018.04.016 doi: 10.1016/j.jpowsour.2018.04.016
93. [93]
  Sharafi, A.; Kazyak, E.; Davis, A. L.; Yu, S.; Thompson, T.; Siegel, D. J.; Dasgupta, N. P.; Sakamoto, J. Chem. Mater. 2017, 29 (18), 7961. doi: 10.1021/acs.chemmater.7b03002 doi: 10.1021/acs.chemmater.7b03002
94. [94]
  Zheng, H.; Wu, S.; Tian, R.; Xu, Z.; Zhu, H.; Duan, H.; Liu, H. Adv. Funct. Mater. 2020, 30 (6), 1906189. doi: 10.1002/adfm.201906189 doi: 10.1002/adfm.201906189
95. [95]
  Zheng, Z. J.; Ye, H.; Guo, Z. P. Adv. Sci. 2020, 7 (22), 2002212. doi: 10.1002/advs.202002212 doi: 10.1002/advs.202002212
96. [96]
  Samson, A. J.; Hofstetter, K.; Bag, S.; Thangadurai, V. Energy Environ. Sci. 2019, 12 (10), 2957. doi: 10.1039/c9ee01548e doi: 10.1039/c9ee01548e
97. [97]
  Wang, Y.; Wu, Y.; Wang, Z.; Chen, L.; Li, H.; Wu, F. J. Mater. Chem. A 2022, 10 (9), 4517. doi: 10.1039/d1ta10966a doi: 10.1039/d1ta10966a
98. [98]
  Liu, Q.; Geng, Z.; Han, C.; Fu, Y.; Li, S.; He, Y.; Kang, F.; Li, B. J. Power Sources 2018, 389, 120. doi: 10.1016/j.jpowsour.2018.04.019 doi: 10.1016/j.jpowsour.2018.04.019
99. [99]
  Xu, L.; Li, J.; Deng, W.; Shuai, H.; Li, S.; Xu, Z.; Li, J.; Hou, H.; Peng, H.; Zou, G.; Ji, X. Adv. Energy Mater. 2020, 10, 2000648. doi: 10.1002/aenm.202000648 doi: 10.1002/aenm.202000648
100. [100]
  Allen, J. L.; Wolfenstine, J.; Rangasamy, E.; Sakamoto, J. J. Power Sources 2012, 206, 315. doi: 10.1016/j.jpowsour.2012.01.131 doi: 10.1016/j.jpowsour.2012.01.131
101. [101]
  Deviannapoorani, C.; Dhivya, L.; Ramakumar, S.; Murugan, R. J. Power Sources 2013, 240, 18. doi: 10.1016/j.jpowsour.2013.03.166 doi: 10.1016/j.jpowsour.2013.03.166
102. [102]
  Ohta, S.; Kobayashi, T.; Asaoka, T. J. Power Sources 2011, 196 (6), 3342. doi: 10.1016/j.jpowsour.2010.11.089 doi: 10.1016/j.jpowsour.2010.11.089
103. [103]
  Ramakumar, S.; Satyanarayana, L.; Manorama, S. V.; Murugan, R. Phys. Chem. Chem. Phys. 2013, 15 (27), 11327. doi: 10.1039/c3cp50991e doi: 10.1039/c3cp50991e
104. [104]
  Lang, J.; Liu, K.; Jin, Y.; Long, Y.; Qi, L.; Wu, H.; Cui, Y. Energy Storage Mater. 2020, 24, 412. doi: 10.1016/j.ensm.2019.07.027 doi: 10.1016/j.ensm.2019.07.027
105. [105]
  Lang, J.; Jin, Y.; Liu, K.; Long, Y.; Zhang, H.; Qi, L.; Wu, H.; Cui, Y. Nat. Sustain. 2020, 3 (5), 386. doi: 10.1038/s41893-020-0485-x doi: 10.1038/s41893-020-0485-x
106. [106]
  Zhang, H.; Lang, J.; Liu, K.; Jin, Y.; Wang, K.; Wu, Y.; Shi, S.; Wang, L.; Xu, H.; He, X.; Wu, H. Energy Environ. Mater. 2023,e12425. doi: 10.1002/eem2.12425 doi: 10.1002/eem2.12425
107. [107]
  Liu, K.; Lang, J.; Yang, M.; Xu, J.; Sun, B.; Wu, Y.; Wang, K.; Zheng, Z.; Huang, Z.; Wang, C.; Wu, H.; Jin, Y.; Cui, Y. Matter 2020, 3 (5), 1714. doi: 10.1016/j.matt.2020.08.022 doi: 10.1016/j.matt.2020.08.022
108. [108]
  Xu, J.; Liu, K.; Jin, Y.; Sun, B.; Zhang, Z.; Chen, Y.; Su, D.; Wang, G.; Wu, H.; Cui, Y. Adv. Mater. 2020, 32 (32), 2000960. doi: 10.1002/adma.202000960 doi: 10.1002/adma.202000960
109. [109]
  Zeng, L. C.; Li, W. H.; Jiang, Y.; Yu, Y. Rare Met. 2017, 36 (5), 339. doi: 10.1007/s12598-017-0891-z doi: 10.1007/s12598-017-0891-z
110. [110]
  Jin, Y.; Liu, K.; Lang, J.; Jiang, X.; Zheng, Z.; Su, Q.; Huang, Z.; Long, Y.; Wang, C.; Wu, H.; Cui, Y. Joule 2020, 4 (1), 262. doi: 10.1016/j.joule.2019.09.003 doi: 10.1016/j.joule.2019.09.003
111. [111]
  Huang, S.; Wang, Z.; Von Lim, Y.; Wang, Y.; Li, Y.; Zhang, D.; Yang, H. Y. Adv. Energy Mater. 2021, 11 (10), 2003689. doi: 10.1002/aenm.202003689 doi: 10.1002/aenm.202003689
112. [112]
  Li, Y.; Guo, S. Matter 2021, 4 (4), 1142. doi: 10.1016/j.matt.2021.01.012 doi: 10.1016/j.matt.2021.01.012
113. [113]
  Chen, Y.; Wang, T.; Tian, H.; Su, D.; Zhang, Q.; Wang, G. Adv. Mater. 2021, 33 (29), 2003666. doi: 10.1002/adma.202003666 doi: 10.1002/adma.202003666
114. [114]
  Zhao, H.; Deng, N.; Yan, J.; Kang, W.; Ju, J.; Ruan, Y.; Wang, X.; Zhuang, X.; Li, Q.; Cheng, B. Chem. Eng. J. 2018, 347, 343. doi: 10.1016/j.cej.2018.04.112 doi: 10.1016/j.cej.2018.04.112
115. [115]
  Sun, B.; Wang, P.; Xu, J.; Jin, Q.; Zhang, Z.; Wu, H.; Jin, Y. Nano Res. 2022, 15 (5), 4076. doi: 10.1007/s12274-021-4010-y doi: 10.1007/s12274-021-4010-y
116. [116]
  Huang, Y.; Li, J. Adv. Energy Mater. 2022, 12 (48), 2202197. doi: 10.1002/aenm.202202197 doi: 10.1002/aenm.202202197
117. [117]
  Sun, X.; Ouyang, M.; Hao, H. Joule 2022, 6 (8), 1738. doi: 10.1016/j.joule.2022.06.028 doi: 10.1016/j.joule.2022.06.028
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