Citation: Yao Chen, Cun Chen, Xuesong Cao, Zhenyu Wang, Nan Zhang, Tianxi Liu. Recent Advances in Defect and Interface Engineering for Electroreduction of CO₂ and N₂[J]. Acta Physico-Chimica Sinica, ;2023, 39(8): 221205. doi: 10.3866/PKU.WHXB202212053 shu

Recent Advances in Defect and Interface Engineering for Electroreduction of CO₂ and N₂

Yao Chen ^{1, †} ,
Cun Chen ^{1, †} ,
Xuesong Cao ² ,
Zhenyu Wang ² ,
Nan Zhang ^1,, ,
Tianxi Liu ^1,,

1.
Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, International Joint Research Laboratory for Nano Energy Composites, Jiangnan University, Wuxi 214122, Jiangsu Province, China
2.
Institute of Environmental Processes and Pollution Control, School of Environment and Civil Engineering, Jiangnan University, Wuxi 214122, Jiangsu Province, China

Corresponding author: Nan Zhang, nzhang@jiangnan.edu.cn Tianxi Liu, txliu@jiangnan.edu.cn

^†

Received Date: 17 December 2022
Revised Date: 21 January 2023
Accepted Date: 29 January 2023
Available Online: 8 February 2023
Fund Project: the National Natural Science Foundation of China 52161135302

The realization of carbon and nitrogen cycles is an urgent requirement for the development of human society, and is also a hot research topic in the field of catalysis. Electrocatalysis driven by renewable energy has attracted considerable attention, and the target products can be obtained by varying the applied potentials. Accordingly, electrocatalysis is considered to be an effective strategy to alleviate the current energy crisis and environmental problems and is of great significance in realizing carbon neutrality. Electrocatalytic CO₂ reduction reaction (CO₂RR) and N₂ reduction reaction (N₂RR) are also promising strategies for the conversion of small molecules. However, the high dissociation energies of the C＝O and N≡N bonds in the linear molecules of CO₂ and N₂, respectively, lead to their high chemical inactivity. In addition, the large energy gap between the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) further results in high chemical stability. Besides, the low proton affinity of CO₂ and N₂ makes direct protonated difficult. However, because of the similar redox potentials of CO₂RR, N₂RR, and hydrogen evolution reaction (HER), HER competes with CO₂RR and N₂RR, affecting the CO₂RR and N₂RR performance. Therefore, both CO₂RR and N₂RR still face challenges, such as high overpotential and low Faradaic efficiency. To overcome these bottlenecks, considerable efforts have been made to improve the performance of the CO₂RR and N₂RR electrocatalysts. The electrocatalytic process primarily occurs on the catalyst surface and involves mass diffusion and electron transfer; thus, the performance of the catalysts is closely related to their mass and electron transfer abilities. Modulating the catalyst surface structure can regulate the mass and electron transfer behavior of the active sites during the electrocatalytic process. Defect and interface engineering of electrocatalysts is important for enhancing the adsorption of gas, inhibiting HER, enriching the gas, stabilizing the intermediates, and modifying the electronic structure by engineering the surface atoms. To date, various defective and composite electrocatalysts have shown great potential to enhance the CO₂RR and N₂RR performance. Herein, recent advances in defect and interface engineering for CO₂RR and N₂RR are reviewed. The effects of four different defects (vacancy, high-index facet, lattice stain, and lattice disorder) on the CO₂RR and N₂RR performance are discussed. Then, the main roles of interface engineering of polymer-inorganic composite catalysts are further reviewed, and representative examples are presented. Finally, the opportunities and challenges for defect and interface engineering in the electroreduction of CO₂ and N₂ are also proposed, suggesting directions for the future development of highly efficient CO₂RR and N₂RR catalysts.
- Defect,
- Interface,
- Nanocomposites,
- CO₂ Reduction reaction,
- N₂ Reduction reaction
1. [1]
  De Luna, P.; Hahn, C.; Higgins, D.; Jaffer, S. A.; Jaramillo, T. F.; Sargent, E. H. Science 2019, 364, eaav3506. doi: 10.1126/science.aav3506 doi: 10.1126/science.aav3506
2. [2]
  Zhu, D. D.; Liu, J. L.; Qiao, S. Z. Adv. Mater. 2016, 28, 3423. doi: 10.1002/adma.201504766 doi: 10.1002/adma.201504766
3. [3]
  Chu, S.; Majumdar, A. Nature 2012, 488, 294. doi: 10.1038/nature11475 doi: 10.1038/nature11475
4. [4]
  Armaroli, N.; Balzani, V. Angew. Chem. Int. Ed. 2007, 46, 52. doi: 10.1002/anie.200602373 doi: 10.1002/anie.200602373
5. [5]
  Martín, A. J.; Shinagawa, T.; Pérez-Ramírez, J. Chem 2019, 5, 263. doi: 10.1016/j.chempr.2018.10.010 doi: 10.1016/j.chempr.2018.10.010
6. [6]
  Tang, C.; Qiao, S. Z. Chem. Soc. Rev. 2019, 48, 3166. doi: 10.1039/C9CS00280D doi: 10.1039/C9CS00280D
7. [7]
  Liu, H.; Wei, L.; Liu, F.; Pei, Z.; Shi, J.; Wang, Z.-J.; He, D.; Chen, Y. ACS Catal. 2019, 9, 5245. doi: 10.1021/acscatal.9b00994 doi: 10.1021/acscatal.9b00994
8. [8]
  Fan, L.; Xia, C.; Yang, F.; Wang, J.; Wang, H.; Lu, Y. Sci. Adv. 2020, 6, eaay3111. doi: 10.1126/sciadv.aay3111 doi: 10.1126/sciadv.aay3111
9. [9]
  Han, N.; Ding, P.; He, L.; Li, Y.; Li, Y. Adv. Energy Mater. 2020, 10, 1902338. doi: 10.1002/aenm.201902338 doi: 10.1002/aenm.201902338
10. [10]
  Vasileff, A.; Xu, C.; Jiao, Y.; Zheng, Y.; Qiao, S. Z. Chem 2018, 4, 1809. doi: 10.1016/j.chempr.2018.05.001 doi: 10.1016/j.chempr.2018.05.001
11. [11]
  Qing, G.; Ghazfar, R.; Jackowski, S. T.; Habibzadeh, F.; Ashtiani, M. M.; Chen, C.-P.; Smith III, M. R.; Hamann, T. W. Chem. Rev. 2020, 120, 5437. doi: 10.1021/acs.chemrev.9b00659 doi: 10.1021/acs.chemrev.9b00659
12. [12]
  Li, L.; Li, X.; Sun, Y.; Xie, Y. Chem. Soc. Rev. 2022, 51, 1234. doi: 10.1039/D1CS00893E doi: 10.1039/D1CS00893E
13. [13]
  Shen, H.; Choi, C.; Masa, J.; Li, X.; Qiu, J.; Jung, Y.; Sun, Z. Chem 2021, 7, 1708. doi: 10.1016/j.chempr.2021.01.009 doi: 10.1016/j.chempr.2021.01.009
14. [14]
  Pan, F.; Yang, Y. Energy Environ. Sci. 2020, 13, 2275. doi: 10.1039/D0EE00900H doi: 10.1039/D0EE00900H
15. [15]
  Lv, J.-J.; Yin, R.; Zhou, L.; Li, J.; Kikas, R.; Xu, T.; Wang, Z.-J.; Jin, H.; Wang, X.; Wang, S. Angew. Chem. Int. Ed. 2022, 61, e202207252. doi: 10.1002/anie.202207252 doi: 10.1002/anie.202207252
16. [16]
  Ren, Y.; Yu, C.; Tan, X.; Huang, H.; Wei, Q.; Qiu, J. Energy Environ. Sci. 2021, 14, 1176. doi: 10.1039/D0EE03596C doi: 10.1039/D0EE03596C
17. [17]
  Singh, A. R.; Rohr, B. A.; Schwalbe, J. A.; Cargnello, M.; Chan, K.; Jaramillo, T. F.; Chorkendorff, I.; Nøørskov, J. K. ACS Catal. 2017, 7, 706. doi: 10.1021/acscatal.6b03035 doi: 10.1021/acscatal.6b03035
18. [18]
  Birdja, Y. Y.; Pérez-Gallent, E.; Figueiredo, M. C.; Göttle, A. J.; Calle-Vallejo, F.; Koper, M. T. M. Nat. Energy 2019, 4, 732. doi: 10.1038/s41560-019-0450-y doi: 10.1038/s41560-019-0450-y
19. [19]
  Yang, C.; Zhu, Y.; Liu, J.; Qin, Y.; Wang, H.; Liu, H.; Chen, Y.; Zhang, Z.; Hu, W. Nano Energy 2020, 77, 105126. doi: 10.1016/j.nanoen.2020.105126 doi: 10.1016/j.nanoen.2020.105126
20. [20]
  Liang, J.; Liu, Q.; Alshehri, A. A.; Sun, X. Nano Res. Energy 2022, 1, e9120010. doi: 10.26599/NRE.2022.9120010 doi: 10.26599/NRE.2022.9120010
21. [21]
  Liu, C.; Li, S.; Li, Z.; Zhang, L.; Chen, H.; Zhao, D.; Sun, S.; Luo, Y.; Alshehri, A. A.; Hamdy, M. S.; et al. Sustain. Energy Fuels 2022, 6, 3344. doi: 10.1039/D2SE00557C doi: 10.1039/D2SE00557C
22. [22]
  Li, Q.; Shen, P.; Tian, Y.; Li, X.; Chu, K. J. Colloid Interface Sci. 2022, 606, 204. doi: 10.1016/j.jcis.2021.08.032 doi: 10.1016/j.jcis.2021.08.032
23. [23]
  Chen, H.; Liang, J.; Dong, K.; Yue, L.; Li, T.; Luo, Y.; Feng, Z.; Li, N.; Hamdy, M. S.; Alshehri, A. A.; et al. Inorg. Chem. Front. 2022, 9, 1514. doi: 10.1039/D2QI00140C doi: 10.1039/D2QI00140C
24. [24]
  Liu, Q.; Xu, T.; Luo, Y.; Kong, Q.; Li, T.; Lu, S.; Alshehri, A. A.; Alzahrani, K. A.; Sun, X. Curr. Opin. Electrochem. 2021, 29, 100766. doi: 10.1016/j.coelec.2021.100766 doi: 10.1016/j.coelec.2021.100766
25. [25]
  Xu, T.; Ma, B.; Liang, J.; Yue, L.; Liu, Q.; Li, T.; Zhao, H.; Luo, Y.; Lu, S.; Sun, X. Acta Phys.-Chim. Sin. 2021, 37, 2009043. doi: 10.3866/PKU.WHXB202009043
26. [26]
  Hao, D.; Sun, Z. Acta Phys.-Chim. Sin. 2021, 37, 2009033. doi: 10.3866/PKU.WHXB202009033
27. [27]
  Wang, Y.; Han, P.; Lv, X.; Zhang, L.; Zheng, G. Joule 2018, 2, 2551. doi: 10.1016/j.joule.2018.09.021 doi: 10.1016/j.joule.2018.09.021
28. [28]
  Wang, Q.; Lei, Y.; Wang, D.; Li, Y. Energy Environ. Sci. 2019, 12, 1730. doi: 10.1039/C8EE03781G doi: 10.1039/C8EE03781G
29. [29]
  Kong, X.; Peng, H.-Q.; Bu, S.; Gao, Q.; Jiao, T.; Cheng, J.; Liu, B.; Hong, G.; Lee, C.-S.; Zhang, W. J. Mater. Chem. A 2020, 8, 7457. doi: 10.1039/D0TA01453B doi: 10.1039/D0TA01453B
30. [30]
  Yan, D.; Li, H.; Chen, C.; Zou, Y.; Wang, S. Small Methods 2019, 3, 1800331. doi: 10.1002/smtd.201800331 doi: 10.1002/smtd.201800331
31. [31]
  Guo, D.; Wang, S.; Xu, J.; Zheng, W.; Wang, D. J. Energy Chem. 2022, 65, 448. doi: 10.1016/j.jechem.2021.06.012 doi: 10.1016/j.jechem.2021.06.012
32. [32]
  Li, W.; Wang, D.; Zhang, Y.; Tao, L.; Wang, T.; Zou, Y.; Wang, Y.; Chen, R.; Wang, S. Adv. Mater. 2020, 32, 1907879. doi: 10.1002/adma.201907879 doi: 10.1002/adma.201907879
33. [33]
  Lu, Y.; Zhou, L.; Wang, S.; Zou, Y. Nano Res. 2022, doi: 10.1007/s12274-022-4858-5 doi: 10.1007/s12274-022-4858-5
34. [34]
  Wang, J.; Liu, J.; Zhang, B.; Cheng, F.; Ruan, Y.; Ji, X.; Xu, K.; Chen, C.; Miao, L.; Jiang, J. Nano Energy 2018, 53, 144. doi: 10.1016/j.nanoen.2018.08.022 doi: 10.1016/j.nanoen.2018.08.022
35. [35]
  Bai, S.; Zhang, N.; Gao, C.; Xiong, Y. Nano Energy 2018, 53, 296. doi: 10.1016/j.nanoen.2018.08.058 doi: 10.1016/j.nanoen.2018.08.058
36. [36]
  Chen, H.-J.; Xu, Z.-Q.; Sun, S.; Luo, Y.; Liu, Q.; Hamdy, M. S.; Feng, Z.-S.; Sun, X.; Wang, Y. Inorg. Chem. Front. 2022, 9, 4608. doi: 10.1039/D2QI01173E doi: 10.1039/D2QI01173E
37. [37]
  Chu, K.; Liu, F.; Zhu, J.; Fu, H.; Zhu, H.; Zhu, Y.; Zhang, Y.; Lai, F.; Liu, T. Adv. Energy Mater. 2021, 11, 2003799. doi: 10.1002/aenm.202003799 doi: 10.1002/aenm.202003799
38. [38]
  Zheng, H.; Zhang, Y.; Wang, Y.; Wu, Z.; Lai, F.; Chao, G.; Zhang, N.; Zhang, L.; Liu, T. Small 2022, doi: 10.1002/smll.202205625 doi: 10.1002/smll.202205625
39. [39]
  Chu, K.; Ras, M. D.; Rao, D.; Martens, J. A.; Hofkens, J.; Lai, F.; Liu, T. ACS Appl. Mater. Interfaces 2021, 13, 13347. doi: 10.1021/acsami.1c01510 doi: 10.1021/acsami.1c01510
40. [40]
  Chu, K.; Qin, J.; Zhu, H.; De Ras, M.; Wang, C.; Xiong, L.; Zhang, L.; Zhang, N.; Martens, J. A.; Hofkens, J.; et al. Sci. China Mater. 2022, 65, 2711. doi: 10.1007/s40843-022-2021-y doi: 10.1007/s40843-022-2021-y
41. [41]
  Gao, S.; Sun, Z.; Liu, W.; Jiao, X.; Zu, X.; Hu, Q.; Sun, Y.; Yao, T.; Zhang, W.; Wei, S.; et al. Nat. Commun. 2017, 8, 14503. doi: 10.1038/ncomms14503 doi: 10.1038/ncomms14503
42. [42]
  Lai, F.; Zong, W.; He, G.; Xu, Y.; Huang, H.; Weng, B.; Rao, D.; Martens, J. A.; Hofkens, J.; Parkin, I. P.; et al. Angew. Chem. Int. Ed. 2020, 59, 13320. doi: 10.1002/anie.202003129 doi: 10.1002/anie.202003129
43. [43]
  Zhang, N.; Zheng, F.; Huang, B.; Ji, Y.; Shao, Q.; Li, Y.; Xiao, X.; Huang, X. Adv. Mater. 2020, 32, 1906477. doi: 10.1002/adma.201906477 doi: 10.1002/adma.201906477
44. [44]
  Tian, N.; Zhou, Z.-Y.; Sun, S.-G.; Ding, Y.; Wang, Z. L. Science 2007, 316, 732. doi: 10.1126/science.1140484 doi: 10.1126/science.1140484
45. [45]
  Bu, L.; Ding, J.; Guo, S.; Zhang, X.; Su, D.; Zhu, X.; Yao, J.; Guo, J.; Lu, G.; Huang, X. Adv. Mater. 2015, 27, 7204. doi: 10.1002/adma.201502725 doi: 10.1002/adma.201502725
46. [46]
  Bu, L.; Guo, S.; Zhang, X.; Shen, X.; Su, D.; Lu, G.; Zhu, X.; Yao, J.; Guo, J.; Huang, X. Nat. Commun. 2016, 7, 11850. doi: 10.1038/ncomms11850 doi: 10.1038/ncomms11850
47. [47]
  Zhang, N.; Li, L.; Wang, J.; Hu, Z.; Shao, Q.; Xiao, X.; Huang, X. Angew. Chem. Int. Ed. 2020, 59, 8066. doi: 10.1002/anie.201915747 doi: 10.1002/anie.201915747
48. [48]
  Choi, C.; Kwon, S.; Cheng, T.; Xu, M.; Tieu, P.; Lee, C.; Cai, J.; Lee, H. M.; Pan, X.; Duan, X.; et al. Nat. Catal. 2020, 3, 804. doi: 10.1038/s41929-020-00504-x doi: 10.1038/s41929-020-00504-x
49. [49]
  Jansonius, R. P.; Reid, L. M.; Virca, C. N.; Berlinguette, C. P. ACS Energy Lett. 2019, 4, 980. doi: 10.1021/acsenergylett.9b00191 doi: 10.1021/acsenergylett.9b00191
50. [50]
  Mistry, H.; Varela, A. S.; Kühl, S.; Strasser, P.; Cuenya, B. R. Nat. Rev. Mater. 2016, 1, 16009. doi: 10.1038/natrevmats.2016.9 doi: 10.1038/natrevmats.2016.9
51. [51]
  Yu, D.; Gao, L.; Sun, T.; Guo, J.; Yuan, Y.; Zhang, J.; Li, M.; Li, X.; Liu, M.; Ma, C.; et al. Nano Lett. 2021, 21, 1003. doi: 10.1021/acs.nanolett.0c04051 doi: 10.1021/acs.nanolett.0c04051
52. [52]
  Chen, Y.; Pei, J.; Chen, Z.; Li, A.; Ji, S.; Rong, H.; Xu, Q.; Wang, T.; Zhang, A.; Tang, H.; et al. Nano Lett. 2022, 22, 7563. doi: 10.1021/acs.nanolett.2c02572 doi: 10.1021/acs.nanolett.2c02572
53. [53]
  Bu, L.; Zhang, N.; Guo, S.; Zhang, X.; Li, J.; Yao, J.; Wu, T.; Lu, G.; Ma, J.-Y.; Su, D.; et al. Science 2016, 354, 1410. doi: 10.1126/science.aah6133 doi: 10.1126/science.aah6133
54. [54]
  Xia, Z.; Guo, S. Chem. Soc. Rev. 2019, 48, 3265. doi: 10.1039/C8CS00846A doi: 10.1039/C8CS00846A
55. [55]
  Luo, M.; Guo, S. Nat. Rev. Mater. 2017, 2, 17059. doi: 10.1038/natrevmats.2017.59 doi: 10.1038/natrevmats.2017.59
56. [56]
  Li, H.; Zhang, N.; Bai, S.; Zhang, L.; Lai, F.; Chen, Y.; Zhu, X.; Liu, T. Chem. Mater. 2022, 34, 7995. doi: 10.1021/acs.chemmater.2c01917 doi: 10.1021/acs.chemmater.2c01917
57. [57]
  Feng, Y.; Huang, B.; Yang, C.; Shao, Q.; Huang, X. Adv. Funct. Mater. 2019, 29, 1904429. doi: 10.1002/adfm.201904429 doi: 10.1002/adfm.201904429
58. [58]
  Pi, Y.; Xu, Y.; Li, L.; Sun, T.; Huang, B.; Bu, L.; Ma, Y.; Hu, Z.; Pao, C.-W.; Huang, X. Adv. Funct. Mater. 2020, 30, 2004375. doi: 10.1002/adfm.202004375 doi: 10.1002/adfm.202004375
59. [59]
  Tao, L.; Sun, M.; Zhou, Y.; Luo, M.; Lv, F.; Li, M.; Zhang, Q.; Gu, L.; Huang, B.; Guo, S. J. Am. Chem. Soc. 2022, 144, 10582. doi: 10.1021/jacs.2c03544 doi: 10.1021/jacs.2c03544
60. [60]
  Han, G.; Li, M.; Liu, H.; Zhang, W.; He, L.; Tian, F.; Liu, Y.; Yu, Y.; Yang, W.; Guo, S. Adv. Mater. 2022, 34, 2202943. doi: 10.1002/adma.202202943 doi: 10.1002/adma.202202943
61. [61]
  Wang, H.; Fang, Q.; Gu, W.; Du, D.; Lin, Y.; Zhu, C. ACS Appl. Mater. Interfaces 2020, 12, 52234. doi: 10.1021/acsami.0c14007 doi: 10.1021/acsami.0c14007
62. [62]
  Cai, B.; Eychmüller, A. Adv. Mater. 2019, 31, 1804881. doi: 10.1002/adma.201804881 doi: 10.1002/adma.201804881
63. [63]
  Du, R.; Joswig, J.-O.; Hübner, R.; Zhou, L.; Wei, W.; Hu, Y.; Eychmüller, A. Angew. Chem. Int. Ed. 2020, 59, 8293. doi: 10.1002/anie.201916484 doi: 10.1002/anie.201916484
64. [64]
  Du, R.; Fan, X.; Jin, X.; Hübner, R.; Hu, Y.; Eychmüller, A. Matter 2019, 1, 39. doi: 10.1016/j.matt.2019.05.006 doi: 10.1016/j.matt.2019.05.006
65. [65]
  Jiang, X.; Du, R.; Hübner, R.; Hu, Y.; Eychmüller, A. Matter 2021, 4, 54. doi: 10.1016/j.matt.2020.10.001 doi: 10.1016/j.matt.2020.10.001
66. [66]
  Zhang, Z.; Hu, J.; Li, B.; Qi, Q.; Zhang, Y.; Chen, J.; Dong, P.; Zhang, C.; Zhang, Y.; Leung, M. K. H. J. Alloys Compd. 2022, 918, 165585. doi: 10.1016/j.jallcom.2022.165585 doi: 10.1016/j.jallcom.2022.165585
67. [67]
  Zhai, Y.; Ren, X.; Wang, B.; Liu, S. Adv. Funct. Mater. 2022, 32, 2207536. doi: 10.1002/adfm.202207536 doi: 10.1002/adfm.202207536
68. [68]
  Löffler, T.; Ludwig, A.; Rossmeisl, J.; Schuhmann, W. Angew. Chem. Int. Ed. 2021, 60, 26894. doi: 10.1002/anie.202109212 doi: 10.1002/anie.202109212
69. [69]
  Zhan, C.; Xu, Y.; Bu, L.; Zhu, H.; Feng, Y.; Yang, T.; Zhang, Y.; Yang, Z.; Huang, B.; Shao, Q.; et al. Nat. Commun. 2021, 12, 6261. doi: 10.1038/s41467-021-26425-2 doi: 10.1038/s41467-021-26425-2
70. [70]
  Hu, J.; Cao, L.; Wang, Z.; Liu, J.; Zhang, J.; Cao, Y.; Lu, Z.; Cheng, H. Compos. Commun. 2021, 27, 100866. doi: 10.1016/j.coco.2021.100866 doi: 10.1016/j.coco.2021.100866
71. [71]
  Li, H.; Huang, H.; Chen, Y.; Lai, F.; Fu, H.; Zhang, L.; Zhang, N.; Bai, S.; Liu, T. Adv. Mater. 2023, 35, 2209242. doi: 10.1002/adma.202209242 doi: 10.1002/adma.202209242
72. [72]
  Wakerley, D.; Lamaison, S.; Ozanam, F.; Menguy, N.; Mercier, D.; Marcus, P.; Fontecave, M.; Mougel, V. Nat. Mater. 2019, 18, 1222. doi: 10.1038/s41563-019-0445-x doi: 10.1038/s41563-019-0445-x
73. [73]
  Ge, W.; Chen, Y.; Fan, Y.; Zhu, Y.; Liu, H.; Song, L.; Liu, Z.; Lian, C.; Jiang, H.; Li, C. J. Am. Chem. Soc. 2022, 144, 6613. doi: 10.1021/jacs.2c02486 doi: 10.1021/jacs.2c02486
74. [74]
  Chen, Y.; Shen, L.; Wang, C.; Feng, S.; Zhang, N.; Xiang, S.; Feng, T.; Yang, M.; Zhang, K.; Yang, B. Appl. Catal. B-Environ. 2020, 274, 119112. doi: 10.1016/j.apcatb.2020.119112 doi: 10.1016/j.apcatb.2020.119112
75. [75]
  Ma, Y.; Wang, J.; Yu, J.; Zhou, J.; Zhou, X.; Li, H.; He, Z.; Long, H.; Wang, Y.; Lu, P.; et al. Matter 2021, 4, 888. doi: 10.1016/j.matt.2021.01.007 doi: 10.1016/j.matt.2021.01.007
76. [76]
  Liu, H.; Xiang, K.; Liu, Y.; Zhu, F.; Zou, M.; Yan, X.; Chai, L. ChemElectroChem 2018, 5, 3991. doi: 10.1002/celc.201801132 doi: 10.1002/celc.201801132
77. [77]
  Zhang, L.; Wei, Z.; Thanneeru, S.; Meng, M.; Kruzyk, M.; Ung, G.; Liu, B.; He, J. Angew. Chem. Int. Ed. 2019, 58, 15834. doi: 10.1002/anie.201909069 doi: 10.1002/anie.201909069
78. [78]
  An, P.; Wei, L.; Li, H.; Yang, B.; Liu, K.; Fu, J.; Li, H.; Liu, H.; Hu, J.; Lu, Y.-R.; et al. J. Mater. Chem. A 2020, 8, 15936. doi: 10.1039/D0TA03645E doi: 10.1039/D0TA03645E
79. [79]
  Ahn, S.; Klyukin, K.; Wakeham, R. J.; Rudd, J. A.; Lewis, A. R.; Alexander, S.; Carla, F.; Alexandrov, V.; Andreoli, E. ACS Catal. 2018, 8, 4132. doi: 10.1021/acscatal.7b04347 doi: 10.1021/acscatal.7b04347
80. [80]
  Lee, J. H.; Kattel, S.; Xie, Z.; Tackett, B. M.; Wang, J.; Liu, C.-J.; Chen, J. G. Adv. Funct. Mater. 2018, 28, 1804762. doi: 10.1002/adfm.201804762 doi: 10.1002/adfm.201804762
81. [81]
  Zhou, X.; Liu, H.; Xia, B. Y.; Ostrikov, K.; Zheng, Y.; Qiao, S. Z. SmartMat 2022, 3, 111. doi: 10.1002/smm2.1109 doi: 10.1002/smm2.1109
82. [82]
  Shi, R.; Shang, L.; Zhang, T. ACS Appl. Energy Mater. 2021, 4, 1045. doi: 10.1021/acsaem.0c02989 doi: 10.1021/acsaem.0c02989
83. [83]
  Niu, Z.-Z.; Gao, F.-Y.; Zhang, X.-L.; Yang, P.-P.; Liu, R.; Chi, L.-P.; Wu, Z.-Z.; Qin, S.; Yu, X.; Gao, M.-R. J. Am. Chem. Soc. 2021, 143, 8011. doi: 10.1021/jacs.1c01190 doi: 10.1021/jacs.1c01190
84. [84]
  Buckley, A. K.; Lee, M.; Cheng, T.; Kazantsev, R. V.; Larson, D. M.; Goddard III, W. A.; Toste, F. D.; Toma, F. M. J. Am. Chem. Soc. 2019, 141, 7355. doi: 10.1021/jacs.8b13655 doi: 10.1021/jacs.8b13655
85. [85]
  Sheng, X.; Ge, W.; Jiang, H.; Li, C. Adv. Mater. 2022, 34, 2201295. doi: 10.1002/adma.202201295 doi: 10.1002/adma.202201295
86. [86]
  Xing, Z.; Hu, L.; Ripatti, D. S.; Hu, X.; Feng, X. Nat. Commun. 2021, 12, 136. doi: 10.1038/s41467-020-20397-5 doi: 10.1038/s41467-020-20397-5
87. [87]
  Liu, S.; Qian, T.; Wang, M.; Ji, H.; Shen, X.; Wang, C.; Yan, C. Nat. Catal. 2021, 4, 322. doi: 10.1038/s41929-021-00599-w doi: 10.1038/s41929-021-00599-w
88. [88]
  Zheng, W.; Nayak, S.; Yuan, W.; Zeng, Z.; Hong, X.; Vincent, K. A.; Tsang, S. C. E. Chem. Commun. 2016, 52, 13901. doi: 10.1039/C6CC07212G doi: 10.1039/C6CC07212G
89. [89]
  Wang, J.; Cheng, T.; Fenwick, A. Q.; Baroud, T. N.; Rosas-Hernández, A.; Ko, J. H.; Gan, Q.; Goddard III, W. A.; Grubbs, R. H. J. Am. Chem. Soc. 2021, 143, 2857. doi: 10.1021/jacs.0c12478 doi: 10.1021/jacs.0c12478
90. [90]
  Chen, C.; Yan, X.; Wu, Y.; Liu, S.; Zhang, X.; Sun, X.; Zhu, Q.; Wu, H.; Han, B. Angew. Chem. Int. Ed. 2022, 61, e202202607. doi: 10.1002/anie.202202607 doi: 10.1002/anie.202202607
91. [91]
  Jeong, S.; Ohto, T.; Nishiuchi, T.; Nagata, Y.; Fujita, J.-I.; Ito, Y. ACS Catal. 2021, 11, 9962. doi: 10.1021/acscatal.1c02646 doi: 10.1021/acscatal.1c02646
92. [92]
  Ozden, A.; Li, F.; Garcı́a de Arquer, F. P.; Rosas-Hernández, A.; Thevenon, A.; Wang, Y.; Hung, S.-F.; Wang, X.; Chen, B.; Li, J.; et al. ACS Energy Lett. 2020, 5, 2811. doi: 10.1021/acsenergylett.0c01266 doi: 10.1021/acsenergylett.0c01266
93. [93]
  Shen, X.; Liu, S.; Xia, X.; Wang, M.; Ji, H.; Wang, Z.; Liu, J.; Zhang, X.; Yan, C.; Qian, T. Adv. Funct. Mater. 2022, 32, 2109422. doi: 10.1002/adfm.202109422 doi: 10.1002/adfm.202109422
94. [94]
  Sa, Y. J.; Lee, C. W.; Lee, S. Y.; Na, J.; Lee, U.; Hwang, Y. J. Chem. Soc. Rev. 2020, 49, 6632. doi: 10.1039/D0CS00030B doi: 10.1039/D0CS00030B
95. [95]
  Li, F.; Zhao, S.-F.; Chen, L.; Khan, A.; MacFarlane, D. R.; Zhang, J. Energy Environ. Sci. 2016, 9, 216. doi: 10.1039/C5EE02879E doi: 10.1039/C5EE02879E
96. [96]
  Li, J.; Li, F.; Liu, C.; Wei, F.; Gong, J.; Li, W.; Xue, L.; Yin, J.; Xiao, L.; Wang, G.; et al. ACS Energy Lett. 2022, 7, 4045. doi: 10.1021/acsenergylett.2c01955 doi: 10.1021/acsenergylett.2c01955
97. [97]
  Wei, X.; Yin, Z.; Lyu, K.; Li, Z.; Gong, J.; Wang, G.; Xiao, L.; Lu, J.; Zhuang, L. ACS Catal. 2020, 10, 4103. doi: 10.1021/acscatal.0c00049 doi: 10.1021/acscatal.0c00049
98. [98]
  Chen, X.; Chen, J.; Alghoraibi, N. M.; Henckel, D. A.; Zhang, R.; Nwabara, U. O.; Madsen, K. E.; Kenis, P. J. A.; Zimmerman, S. C.; Gewirth, A. A. Nat. Catal. 2021, 4, 20. doi: 10.1038/s41929-020-00547-0 doi: 10.1038/s41929-020-00547-0
99. [99]
  Peterson, A. A.; Nørskov, J. K. J. Phys. Chem. Lett. 2012, 3, 251. doi: 10.1021/jz201461p doi: 10.1021/jz201461p
100. [100]
  Fan, Q.; Zhang, X.; Ge, X.; Bai, L.; He, D.; Qu, Y.; Kong, C.; Bi, J.; Ding, D.; Cao, Y.; et al. Adv. Energy Mater. 2021, 11, 2101424. doi: 10.1002/aenm.202101424 doi: 10.1002/aenm.202101424
1. [1]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
2. [2]
  Lijun Yan , Shiqi Chen , Penglu Wang , Xiangyu Liu , Lupeng Han , Tingting Yan , Yuejin Li , Dengsong Zhang . Hydrothermally stable metal oxide-zeolite composite catalysts for low-temperature NO_x reduction with improved N₂ selectivity. Chinese Chemical Letters, 2024, 35(6): 109132-. doi: 10.1016/j.cclet.2023.109132
3. [3]
  Liang Ma , Zhou Li , Zhiqiang Jiang , Xiaofeng Wu , Shixin Chang , Sónia A. C. Carabineiro , Kangle Lv . Effect of precursors on the structure and photocatalytic performance of g-C3N4 for NO oxidation and CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100416-100416. doi: 10.1016/j.cjsc.2023.100416
4. [4]
  Muhammad Humayun , Mohamed Bououdina , Abbas Khan , Sajjad Ali , Chundong Wang . Designing single atom catalysts for exceptional electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100193-100193. doi: 10.1016/j.cjsc.2023.100193
5. [5]
  Hong Dong , Feng-Ming Zhang . Covalent organic frameworks for artificial photosynthetic diluted CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(7): 100307-100307. doi: 10.1016/j.cjsc.2024.100307
6. [6]
  Ping Wang , Tianbao Zhang , Zhenxing Li . Reconstruction mechanism of Cu surface in CO2 reduction process. Chinese Journal of Structural Chemistry, 2024, 43(8): 100328-100328. doi: 10.1016/j.cjsc.2024.100328
7. [7]
  Tengjia Ni , Xianbiao Hou , Huanlei Wang , Lei Chu , Shuixing Dai , Minghua Huang . Controllable defect engineering based on cobalt metal-organic framework for boosting oxygen evolution reaction. Chinese Journal of Structural Chemistry, 2024, 43(1): 100210-100210. doi: 10.1016/j.cjsc.2023.100210
8. [8]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
9. [9]
  Zixuan Zhu , Xianjin Shi , Yongfang Rao , Yu Huang . Recent progress of MgO-based materials in CO₂ adsorption and conversion: Modification methods, reaction condition, and CO₂ hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954
10. [10]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
11. [11]
  Tianbo Jia , Lili Wang , Zhouhao Zhu , Baikang Zhu , Yingtang Zhou , Guoxing Zhu , Mingshan Zhu , Hengcong Tao . Modulating the degree of O vacancy defects to achieve selective control of electrochemical CO₂ reduction products. Chinese Chemical Letters, 2024, 35(5): 108692-. doi: 10.1016/j.cclet.2023.108692
12. [12]
  Yufei Jia , Fei Li , Ke Fan . Surface reconstruction of Cu-based bimetallic catalysts for electrochemical CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100255-100255. doi: 10.1016/j.cjsc.2024.100255
13. [13]
  Qin Cheng , Ming Huang , Qingqing Ye , Bangwei Deng , Fan Dong . Indium-based electrocatalysts for CO₂ reduction to C1 products. Chinese Chemical Letters, 2024, 35(6): 109112-. doi: 10.1016/j.cclet.2023.109112
14. [14]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
15. [15]
  Qian-Qian Tang , Li-Fang Feng , Zhi-Peng Li , Shi-Hao Wu , Long-Shuai Zhang , Qing Sun , Mei-Feng Wu , Jian-Ping Zou . Single-atom sites regulation by the second-shell doping for efficient electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(9): 109454-. doi: 10.1016/j.cclet.2023.109454
16. [16]
  Tinghui Yang , Min Kuang , Jianping Yang . Mesoporous CuCe dual-metal catalysts for efficient electrochemical reduction of CO2 to methane. Chinese Journal of Structural Chemistry, 2024, 43(8): 100350-100350. doi: 10.1016/j.cjsc.2024.100350
17. [17]
  Di Wang , Qing-Song Chen , Yi-Ran Lin , Yun-Xin Hou , Wei Han , Juan Yang , Xin Li , Zhen-Hai Wen . Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid. Chinese Journal of Structural Chemistry, 2024, 43(8): 100346-100346. doi: 10.1016/j.cjsc.2024.100346
18. [18]
  Yuxiang Zhang , Jia Zhao , Sen Lin . Nitrogen doping retrofits the coordination environment of copper single-atom catalysts for deep CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(11): 100415-100415. doi: 10.1016/j.cjsc.2024.100415
19. [19]
  Maomao Liu , Guizeng Liang , Ningce Zhang , Tao Li , Lipeng Diao , Ping Lu , Xiaoliang Zhao , Daohao Li , Dongjiang Yang . Electron-rich Ni2+ in Ni3S2 boosting electrocatalytic CO2 reduction to formate and syngas. Chinese Journal of Structural Chemistry, 2024, 43(8): 100359-100359. doi: 10.1016/j.cjsc.2024.100359
20. [20]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201

Get Citation

PDF

XML

Metrics

PDF Downloads(11)
Abstract views(439)
HTML views(49)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Recent Advances in Defect and Interface Engineering for Electroreduction of CO2 and N2

Metrics

通讯作者: 陈斌, bchen63@163.com

Recent Advances in Defect and Interface Engineering for Electroreduction of CO₂ and N₂