Citation: Jintao Dong, Sainan Ji, Yi Zhang, Mengxia Ji, Bin Wang, Yingjie Li, Zhigang Chen, Jiexiang Xia, Huaming Li. Construction of Z-Scheme MnO₂/BiOBr Heterojunction for Photocatalytic Ciprofloxacin Removal and CO₂ Reduction[J]. Acta Physico-Chimica Sinica, ;2023, 39(11): 221201. doi: 10.3866/PKU.WHXB202212011 shu

Construction of Z-Scheme MnO₂/BiOBr Heterojunction for Photocatalytic Ciprofloxacin Removal and CO₂ Reduction

Jintao Dong ¹ ,
Sainan Ji ² ,
Yi Zhang ¹ ,
Mengxia Ji ¹ ,
Bin Wang ¹ ,
Yingjie Li ¹ ,
Zhigang Chen ² ,
Jiexiang Xia ^1,, ,
Huaming Li ¹

1.
School of Chemistry and Chemical Engineering, Institute for Energy Research, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China
2.
School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, Jiangsu Province, China

Corresponding author: Jiexiang Xia, xjx@ujs.edu.cn
Received Date: 6 December 2022
Revised Date: 16 February 2023
Accepted Date: 17 February 2023
Available Online: 28 February 2023
Fund Project: the Postgraduate Research & Practice Innovation Program of Jiangsu Province KYCX22_3692the National Natural Science Foundation of China 21878134the National Natural Science Foundation of China 22108106the National Natural Science Foundation of China 22108108the China Postdoctoral Science Foundation 2020M680065the Hong Kong Scholar Program XJ2021021

Rapid increase in energy shortage and ecological environmental pollution has become a major issue that has been continuously drawing global attention, because it severely affects human health and limits sustainable social development. Various technologies have been developed and used to rationalize the utilization of new energy sources and pollution control. Among these technologies, photocatalysis has become a research priority in the field of environmental governance and energy development. Advantages such as low energy consumption, no secondary pollution, simple operation methods, and mild reaction conditions make photocatalysis an attractive choice. Notably, although photocatalysis is a promising approach for enhancing antibiotic removal and CO₂ reduction efficiency, the industrialization and large-scale application of photocatalysts is limited because of issues such as low photo-absorption efficiency, redox capacity, and photogenerated electron separation or migration efficiency. The progress of current research on the regulation of composition/structure and performance of photocatalysts has promoted the exploration of efficient and practical modification strategies to construct photocatalyst composites with improved performance by facilitating light absorption/utilization and enhancing photocatalytic surface/interface reaction performance. Among the many common modification strategies, the construction of a Z-scheme heterojunction can enhance the light absorption ability and significantly reduce the recombination rate of photogenerated electron-hole pairs. Additionally, this strategy maintains the strong reduction/oxidation ability of photogenerated electrons/holes to facilitate the oxidation of environmental pollutants and conversion to clean energy. In this study, Z-scheme MnO₂/BiOBr (MO/BiOBr) composites were effectively constructed using a mechanically assisted ball-milling process. In situ X-ray photoelectron spectroscopy under dark and light conditions confirmed that photoexcited electrons in MnO₂ can migrate directionally to BiOBr through Mn³⁺/Mn⁴⁺ redox couple to create a Z-scheme transfer path. A similar conclusion can also be deduced from the results of electron spin-resonance spectroscopy and band structure analysis. The formation of a Z-scheme heterojunction between MnO₂ and BiOBr, attributed to the Mn³⁺/Mn⁴⁺ redox couple from MnO₂ and staggered energy band, enabled the space separation of oxidation and reduction centers. Furthermore, compared with BiOBr, MO/BiOBr composites exhibited enhanced light absorption and a markedly reduced photoinduced electron-hole pair recombination rate, as confirmed by ultraviolet-visible diffuse reflectance spectroscopy and photoluminescence spectroscopy. Thus, the MO/BiOBr composites exhibited exceptional photocatalytic performance toward ciprofloxacin (CIP) oxidation and CO evolution. The CIP removal efficiency of the MO/BiOBr composites reached 77.3% in just 60 min, which is 1.28 times higher than that of BiOBr (60.2%). Simultaneously, the photocatalytic CO₂-to-CO performance of the MO/BiOBr composites (20.02 µmol·g⁻¹·h⁻¹) was found to be 2.20-fold higher than that of BiOBr (9.08 µmol·g⁻¹·h⁻¹). Photocurrent measurement and electrochemical impedance spectroscopy indicated that the MnO₂/BiOBr Z-scheme heterojunction has higher interfacial electron transfer efficiency than pure MnO₂ and BiOBr. Additionally, liquid chromatograph mass spectrometry and in situ Fourier transform infrared spectroscopy is conducted to study the generation of intermediates during the photocatalytic CIP removal and CO₂ reduction process. The toxicity of CIP and corresponding intermediates after the photocatalytic degradation of the MO/BiOBr composites was evaluated using toxicity estimation software (T.E.S.T.) to analyze the actual physiological toxicity, based on indexes such as Daphnia Magna lethal concentration 50% (LC₅₀, 48 h), Fathead Minnow lethal dose 50% (LD₅₀, 96 h), mutagenicity, and bioaccumulation factor. Thus, this study proposed a novel and simplified approach for constructing a Z-scheme heterojunction to facilitate solar-derived antibiotic removal and fuel synthesis.
- Z-scheme heterojunction,
- BiOBr,
- Ciprofloxacin removal,
- CO₂ reduction,
- Photocatalysis
1. [1]
  Wang, L.; Bahnemann, D. W.; Bian, L.; Dong, G. H.; Zhao, J.; Wang, C. Y. Angew. Chem. Int. Ed. 2019, 58, 8103. doi: 10.1002/anie.201903027 doi: 10.1002/anie.201903027
2. [2]
  Raziq, F.; Qu, Y.; Humayun, M.; Zada, A.; Yu, H.; Jing, L. Q. Appl. Catal. B 2017, 201, 486. doi: 10.1016/j.apcatb.2016.08.057 doi: 10.1016/j.apcatb.2016.08.057
3. [3]
  Chen, R. Y.; Xia, J. Z.; Chen, Y. G.; Shi, H. F. Acta Phys. -Chim. Sin. 2023, 39, 2209012. doi: 10.3866/PKU.WHXB202209012
4. [4]
  Chen, G. Y.; Yu, Y.; Liang, L.; Duan, X. G.; Li, R.; Lu, X. K.; Yan, B. B.; Li, N.; Wang, S. B. J. Hazard. Mater. 2021, 408, 124461. doi: 10.1016/j.jhazmat.2020.124461 doi: 10.1016/j.jhazmat.2020.124461
5. [5]
  Dautzenberg, F. M.; Lu, Y.; Xu, B. Acta Phys. -Chim. Sin. 2021, 37, 2008066. doi: 10.3866/PKU.WHXB202008066
6. [6]
  Wang, J. C.; Qiao, X.; Shi, W. N.; He, J.; Chen, J.; Zhang, W. Q. Acta Phys. -Chim. Sin. 2023, 39, 2210003. doi: 10.3866/PKU.WHXB202210003
7. [7]
  Li, S. J.; Dong, X.; Zhao, Y. H.; Mao, J. N.; Chen, W.; Chen, A. H.; Song, Y. F.; Li, G. H.; Jiang, Z.; Wei, W.; et al. Angew. Chem. Int. Ed. 2022, 61, 2210432. doi: 10.1002/anie.202210432 doi: 10.1002/anie.202210432
8. [8]
  Ru, R.; Zhang, F.; Sun, K. H.; Liu, Z. Y.; Xu, W. Q.; Stavitski, E.; Senanayake, D. S.; Rodriguez, J. A.; Liu, C. J. ACS Catal. 2020, 10, 11307. doi: 10.1021/acscatal.0c02120 doi: 10.1021/acscatal.0c02120
9. [9]
  Liu, S.; Jin, M. M.; Sun, J. Q.; Qin, Y. J.; Gao, S. S.; Chen, Y.; Zhang, S. S.; Luo, J.; Liu, X. J. Chem. Eng. J. 2022, 437, 135294. doi: 10.1016/j.cej.2022.135294 doi: 10.1016/j.cej.2022.135294
10. [10]
  Wang, B.; Zhu, X. W.; Huang, F. C.; Quan, Y.; Liu, G. P.; Zhang, X. L.; Xiong, F. Y.; Huang, C.; Ji, M. X.; Li, H. M.; et al. Appl. Catal. B 2022, 325, 122304. doi: 10.1016/j.apcatb.2022.122304 doi: 10.1016/j.apcatb.2022.122304
11. [11]
  Zhang, Y.; Zhan, G. P.; Di, J.; Xia, J. X. Curr. Opin. Green Sustain. Chem. 2023, 39, 100718. doi: 10.1016/j.cogsc.2022.100718 doi: 10.1016/j.cogsc.2022.100718
12. [12]
  Zhu, Q. H.; Xu, Q.; Du, M. M.; Zeng, X. F.; Zhong, G. F.; Qiu, B. C.; Zhang, J. L. Adv. Mater. 2022, 34, 2202929. doi: 10.1002/adma.202202929 doi: 10.1002/adma.202202929
13. [13]
  Fu, J. W.; Jiang, K. X.; Qiu, X. Q.; Yu, J. G.; Liu, M. Mater. Today 2020, 32, 222. doi: 10.1016/j.mattod.2019.06.009 doi: 10.1016/j.mattod.2019.06.009
14. [14]
  Zhang, L. Y.; Zhang, J. J.; Yu, H. G.; Yu, J. G. Adv. Mater. 2022, 34, 2107668. doi: 10.1002/adma.202107668 doi: 10.1002/adma.202107668
15. [15]
  Liao, G. F.; Li, C. X.; Liu, S. Y.; Fang, B. Z.; Yang, H. M. Trends Chem. 2022, 4, 111. doi: 10.1016/j.trechm.2021.11.005 doi: 10.1016/j.trechm.2021.11.005
16. [16]
  Low, J. X.; Yu, J. G.; Jaroniec, M.; Wageh, S.; Al-Ghamdi, A. A. Adv. Mater. 2017, 29, 1601694. doi: 10.1002/adma.201601694 doi: 10.1002/adma.201601694
17. [17]
  Hu, J. D.; Chen, D. Y.; Mo, Z.; Li, N. J.; Xu, Q. F.; Li, H.; He, J. H.; Xu, H.; Lu, J. M. Angew. Chem. Int. Ed. 2019, 58, 2073. doi: 10.1002/anie.201813417 doi: 10.1002/anie.201813417
18. [18]
  Zan, Z. Q.; Li, X. B.; Gao, X. M.; Huang, J. T.; Luo, Y. D.; Han, L. Acta Phys. -Chim. Sin. 2023, 39, 2209016. doi: 10.3866/PKU.WHXB202209016
19. [19]
  Dong, J. T.; Chen, F.; Xu, L.; Yan, P. C.; Qian, J. C.; Chen, Y.; Yang, M. Y.; Li, H. N. Microchem. J. 2022, 178, 107317. doi: 10.1016/j.microc.2022.107317 doi: 10.1016/j.microc.2022.107317
20. [20]
  Liu, G. P.; Wang, L.; Chen, X.; Zhu, X. W.; Wang, B.; Xu, X. Y.; Chen, Z. R.; Zhu, W. S.; Li, H. M.; Xia, J. X. Green Chem. Eng. 2022, 3, 157. doi: 10.1016/j.gce.2021.11.007 doi: 10.1016/j.gce.2021.11.007
21. [21]
  Wang, F.; Ma, N.; Zheng, L.; Zhang, L.; Bian, Z. Y.; Wang, H. Chemosphere 2022, 307, 135666. doi: 10.1016/j.chemosphere.2022.135666 doi: 10.1016/j.chemosphere.2022.135666
22. [22]
  Zhao, W. L.; Wang, W. L.; Han, T. Y.; Wang, H. T.; Zhang, H. C.; Shi, H. F. Sep. Purif. Technol. 2021, 269, 118693. doi: 10.1016/j.seppur.2021.118693 doi: 10.1016/j.seppur.2021.118693
23. [23]
  Mo, Z.; Xu, H.; Chen, Z. G.; She, X. J.; Song, Y. H.; Lian, J. B.; Zhu, X. W.; Yan, P. C.; Lei, Y. C.; Yuan, S. Q.; et al. Appl. Catal. B 2019, 241, 452. doi: 10.1016/j.apcatb.2018.08.073 doi: 10.1016/j.apcatb.2018.08.073
24. [24]
  Dhingra, S.; Chhabra, T.; Krishnan, V.; Nagaraja, C. M. ACS Appl. Energy Mater. 2020, 3, 7138. doi: 10.1021/acsaem.0c01189 doi: 10.1021/acsaem.0c01189
25. [25]
  Jin, Y.; Zou, L. F.; Liu, L. L.; Engelhard, M. H.; Patel, R. L.; Nie, Z. M.; Han, K. S.; Shao, Y. Y.; Wang, C. M.; Zhu, J.; et al. Adv. Mater. 2019, 31, 1900567. doi: 10.1002/adma.201900567 doi: 10.1002/adma.201900567
26. [26]
  Jiang, Q.; Ji, M. X.; Chen, R.; Zhang, Y.; Li, K.; Meng, C. X.; Chen, Z. G.; Li, H. M.; Xia, J. X. J. Colloid Interface Sci. 2020, 574, 131. doi: 10.1016/j.jcis.2020.04.018 doi: 10.1016/j.jcis.2020.04.018
27. [27]
  Zhang, M. L.; Duo, F. F.; Lan, J. H.; Li, L. X.; Zhou, J. W.; Chu, L. L.; Wang, C. B. Appl. Surf. Sci. 2022, 583, 152544. doi: 10.1016/j.apsusc.2022.152544 doi: 10.1016/j.apsusc.2022.152544
28. [28]
  Wang, X. J.; Yang, W. Y.; Li, F. T.; Zhao, J.; Liu, R. H.; Liu, S. J.; Li, B. J. Hazard. Mater. 2015, 292, 126. doi: 10.1016/j.jhazmat.2015.03.030 doi: 10.1016/j.jhazmat.2015.03.030
29. [29]
  Zhang, G. Q.; Cai, L.; Zhang, Y. F.; Wei, Y. Chem. - Eur. J. 2018, 24, 7434. doi: 10.1002/chem.201706164 doi: 10.1002/chem.201706164
30. [30]
  Wang, B.; Zhao, J. Z.; Chen, H. L.; Weng, Y. X.; Tang, H.; Chen, Z. R.; Zhu, W. S.; She, Y. B.; Xia, J. X.; Li, H. M. Appl. Catal. B 2021, 293, 120182. doi: 10.1016/j.apcatb.2021.120182 doi: 10.1016/j.apcatb.2021.120182
31. [31]
  Huang, S. H.; Wang, Y.; Wan, J. Q.; Yan, Z. C.; Ma, Y. W.; Zhang, G. H.; Wang, S. L. Appl. Catal. B 2022, 319, 121913. doi: 10.1016/j.apcatb.2022.121913 doi: 10.1016/j.apcatb.2022.121913
32. [32]
  Mu, Y. F.; Zhang, W.; Dong, G. X.; Su, K.; Zhang, M.; Lu, T. B. Small 2020, 16, 2002140. doi: 10.1002/smll.202002140 doi: 10.1002/smll.202002140
33. [33]
  Mu, Y. F.; Zhang, C.; Zhang, M. R.; Zhang, W.; Zhang, M.; Lu, T. B. ACS Appl. Mater. Interfaces 2021, 13, 22314. doi: 10.1021/acsami.1c01718 doi: 10.1021/acsami.1c01718
34. [34]
  Zhao, Y. X.; Chang, C.; Teng, F.; Zhao, Y. F.; Chen, G. B.; Shi, R.; Waterhouse, G. I. N.; Huang, W. F.; Zhang, T. R. Adv. Energy Mater. 2017, 7, 1700005. doi: 10.1002/aenm.201700005 doi: 10.1002/aenm.201700005
35. [35]
  Mo, Z.; Wu, G. Y.; Yan, P. C.; Zhu, X. W.; Qian, J. C.; Lei, Y. C.; Xu, L.; Xu, H.; Li, H. M. Mater. Today Chem. 2022, 25, 100956. doi: 10.1016/j.mtchem.2022.100956 doi: 10.1016/j.mtchem.2022.100956
36. [36]
  Chen, M. X.; Dai, Y. Z.; Guo, J.; Yang, H. T.; Liu, D. N.; Zhai, Y. L. Appl. Surf. Sci. 2019, 493, 1361. doi: 10.1016/j.apsusc.2019.04.160 doi: 10.1016/j.apsusc.2019.04.160
37. [37]
  Liu, H. J.; Wang, B. J.; Chen, M.; Zhang, H.; Peng, J. B.; Ding, L.; Wang, W. F. Sep. Purif. Technol. 2021, 261, 118286. doi: 10.1016/j.seppur.2020.118286 doi: 10.1016/j.seppur.2020.118286
38. [38]
  Zhang, D.; Wu, M. Q.; Hao, J. Y.; Zheng, S. L.; Yang, Y.; Yao, T. J.; Wang, Y. J. Colloid Interface Sci. 2022, 612, 550. doi: 10.1016/j.jcis.2021.12.152 doi: 10.1016/j.jcis.2021.12.152
39. [39]
  Liu, W. J.; Wang, S.; Zhao, Y.; Sun, C. X.; Xu, H. T.; Zhao, J. Z. J. Alloys Compd. 2021, 861, 157995. doi: 10.1016/j.jallcom.2020.157995 doi: 10.1016/j.jallcom.2020.157995
40. [40]
  Ma, Y. C.; Chen, Z. W.; Qu, D.; Shi, J. S. Appl. Surf. Sci. 2016, 361, 63. doi: 10.1016/j.apsusc.2015.11.130 doi: 10.1016/j.apsusc.2015.11.130
41. [41]
  Yan, M.; Hua, Y. Q.; Zhu, F. F.; Gu, W.; Jiang, J. H.; Shen, H. Q.; Shi W. D. Appl. Catal. B 2017, 202, 518. doi: 10.1016/j.apcatb.2016.09.039 doi: 10.1016/j.apcatb.2016.09.039
42. [42]
  Kandi, D.; Behera, A.; Sahoo, S.; Parida, K. Sep. Purif. Technol. 2020, 253, 117523. doi: 10.1016/j.seppur.2020.117523 doi: 10.1016/j.seppur.2020.117523
43. [43]
  Liu, G. P.; Wang, B.; Zhu, X. W.; Ding, P. H.; Zhao, J. Z.; Li, H. M.; Chen, Z. R.; Zhu, W. S.; Xia, J. X. Small 2021, 18, 2105228. doi: 10.1002/smll.202105228 doi: 10.1002/smll.202105228
44. [44]
  Zhu, B. C.; Hong, X. Y.; Tang, L. Y.; Liu, Q. Q.; Tang, H. Acta Phys. -Chim. Sin. 2022, 38, 2111008. doi: 10.3866/PKU.WHXB202111008
45. [45]
  Wang B.; Zhang W.; Liu G. P.; Chen, H. L.; Weng, Y. X.; Li, H. M.; Chu, P. K.; Xia, J. X. Adv. Funct. Mater. 2022, 32, 2202885. doi: 10.1002/adfm.202202885 doi: 10.1002/adfm.202202885
46. [46]
  Gao, M. C.; Yang, J. X.; Sun, T.; Zhang, Z. Z.; Zhang, D. F.; Huang, H. J.; Lin H. X.; Fang Y.; Wang X. X. Appl. Catal. B 2019, 234, 734. doi: 10.1016/j.apcatb.2018.11.020 doi: 10.1016/j.apcatb.2018.11.020
47. [47]
  Sun, N. C.; Zhou, M.; Ma, X. X.; Cheng, Z. H.; Wu, J.; Qi, Y. F.; Sun, Y. J.; Zhou, F. H.; Shen, Y. X.; Lu, S. Y. J. CO₂ Util. 2022, 65, 102220. doi: 10.1016/j.jcou.2022.102220 doi: 10.1016/j.jcou.2022.102220
48. [48]
  Zhao, X. Z.; Xia, Y. G.; Li, H. P.; Wang, X.; Wei, J.; Jiao, X. L.; Chen, D. R. Appl. Catal. B 2021, 297, 120426. doi: 10.1016/j.apcatb.2021.120426 doi: 10.1016/j.apcatb.2021.120426
49. [49]
  Li, D. S.; Zhu, B. C.; Sun, Z. T.; Liu, Q. Q.; Wang, L. L.; Tang, H. Front. Chem. 2021, 9, 804204. doi: 10.3389/fchem.2021.804204 doi: 10.3389/fchem.2021.804204
50. [50]
  Bai, Y.; Chen, T.; Wang, P. Q.; Wang, L.; Ye, L. Q.; Shi, X.; Bai, W. Sol. Energy Mater. Sol. Cells 2016, 157, 406. doi: 10.1016/j.solmat.2016.07.001 doi: 10.1016/j.solmat.2016.07.001
51. [51]
  Jin, X. L.; Cao, J.; Wang, H. Q.; Lv, C. D.; Xie, H. Q.; Su, F. Y.; Li, X.; Sun, R. X.; Shi, S. K.; Dang, M. F.; et al. Appl. Surf. Sci. 2022, 598, 153758. doi: 10.1016/j.apsusc.2022.153758 doi: 10.1016/j.apsusc.2022.153758
52. [52]
  Wu, D.; Ye, L. Q.; Yip, H. Y.; Wong, P. Y. Catal. Sci. Technol. 2017, 7, 265. doi: 10.1039/c6cy02040b doi: 10.1039/c6cy02040b
53. [53]
  Jin, X. L.; Lv, C. D.; Zhou, X.; Xie, H. Q.; Sun, S. F.; Liu, Y.; Meng, Q. Q.; Chen, G. Nano Energy 2019, 4, 103955. doi: 10.1016/j.nanoen.2019.103955 doi: 10.1016/j.nanoen.2019.103955
54. [54]
  Yan, X. W.; Wang, B.; Zhao, J. Z.; Liu, G. P.; Ji, M. X.; Zhang, X. L.; Chu, P. K.; Li, H. M.; Xia, J. X. Chem. Eng. J. 2023, 452, 139271. doi: 10.1016/j.cej.2022.139271 doi: 10.1016/j.cej.2022.139271
55. [55]
  Liu, D. N.; Chen, D. Y.; Li, N. J.; Xu, Q. F.; Li, H.; He, J. H.; Lu, J. M. Angew. Chem. Int. Ed. 2020, 59, 4519. doi: 10.1002/anie.201914949 doi: 10.1002/anie.201914949
56. [56]
  Gao, S.; Gu, B. C.; Jiao, X. C.; Sun, Y. F.; Zu, X. L.; Yang, F.; Zhu, W. G.; Wang, C. M.; Feng, Z. M.; Ye, B. J.; et al. J. Am. Chem. Soc. 2017, 139, 3438. doi: 10.1021/jacs.6b11263 doi: 10.1021/jacs.6b11263
57. [57]
  Zhao, J.; Nan, J.; Zhao, Z.; Li, N.; Liu, J.; Cui, F. Appl. Catal. B 2017, 202, 509. doi: 10.1016/j.apcatb.2016.09.065 doi: 10.1016/j.apcatb.2016.09.065
58. [58]
  Yu, L. M.; Mo, Z.; Zhu, X. L.; Deng, J. J.; Xu, F.; Song, Y. H.; She, Y. B.; Li, H. M.; Xu, H. Green Energy Environ. 2021, 6, 538. doi: 10.1016/j.gee.2020.05.011 doi: 10.1016/j.gee.2020.05.011
59. [59]
  Guo, J. R.; Wang, L. P.; Wei, X.; Alothman, Z. A.; Albaqami, M. D.; Malgras, V.; Yamauchi, Y.; Kang, Y. Q.; Wang, M. Q.; Guan, W. S.; et al. J. Hazard. Mater. 2020, 415, 125591. doi: 10.1016/j.jhazmat.2021.125591 doi: 10.1016/j.jhazmat.2021.125591
60. [60]
  Wen, X. J.; Lu, Q.; Lv, X. X.; Sun, J.; Guo, J.; Fei, Z. H.; Niu, Z. G. J. Hazard. Mater. 2020, 385, 121508. doi: 10.1016/j.jhazmat.2019.121508 doi: 10.1016/j.jhazmat.2019.121508
61. [61]
  Chen, Y.; Xu, L.; Yang, M. Y.; Jia, Y. F.; Yan, Y. T.; Qian, J. C.; Chen, F.; Li, H. N. Sens. Actuators B 2022, 353, 131187. doi: 10.1016/j.snb.2021.131187 doi: 10.1016/j.snb.2021.131187
62. [62]
  Li, L. L.; Zheng, X. Y.; Chi, Y. H.; Wang, Y.; Sun, X.; Yue, Q. Y.; Gao, B. Y.; Xu, S. P. J. Hazard. Mater. 2020, 383, 121211. doi: 10.1016/j.jhazmat.2019.121211 doi: 10.1016/j.jhazmat.2019.121211
63. [63]
  Sarkhosh, M.; Sadani, M.; Abtahi, M.; Mohseni, S. M.; Sheikhmohammadi, A.; Azarpira, H.; Najafpoor, A. A.; Atafar, Z.; Rezaei, S.; Alli, R.; et al. J. Hazard. Mater. 2019, 377, 418. doi: 10.1016/j.jhazmat.2019.05.090 doi: 10.1016/j.jhazmat.2019.05.090
64. [64]
  Liu, C.; Mao, S.; Shi, M. X.; Wang, F.Y.; Xia, M. Z.; Chen, Q.; Ju, X. H. J. Hazard. Mater. 2021, 420, 126613. doi: 10.1016/j.jhazmat.2021.126613 doi: 10.1016/j.jhazmat.2021.126613
65. [65]
  Yi, X. H.; Ji, H. D.; Wang, C. C.; Li, Y.; Li, Y. H.; Zhao, C.; Wang, A.; Fu, H. F.; Wang, P.; Zhao, X.; et al. Appl. Catal. B 2021, 293, 120229. doi: 10.1016/j.apcatb.2021.120229 doi: 10.1016/j.apcatb.2021.120229
66. [66]
  Wang, F.; Liu, S. S.; Feng, Z. Y.; Fu, H. F.; Wang, M. Y.; Wang, P.; Liu, W.; Wang, C. C. J. Hazard. Mater. 2022, 440, 129723. doi: 10.1016/j.jhazmat.2022.129723 doi: 10.1016/j.jhazmat.2022.129723
67. [67]
  Li, J.; Ye, Y. H.; Ye, L. Q.; Su, S. Y.; Ma, Z. Y.; Huang, J. D.; Xie, H. Q.; Doronkin, D. E.; Zimina, A.; Grunwaldt, J. D.; et al. J. Mater. Chem. A 2019, 7, 2821. doi: 10.1039/C8TA10922B doi: 10.1039/C8TA10922B
68. [68]
  Liang, J. L.; Zhang, W.; Liu, Z. Y.; Song, Q. Q.; Zhu, Z. H.; Guan, Z. Q.; Wang, H. Y.; Zhang, P. J.; Li, J.; Zhou, M.; et al. ACS Catal. 2022, 12, 12217. doi: 10.1021/acscatal.2c03970 doi: 10.1021/acscatal.2c03970
69. [69]
  Li, H.; Li, F.; Yu, J. G.; Cao S. W. Acta Phys. -Chim. Sin. 2021, 37, 2010073. doi: 10.3866/PKU.WHXB202010073
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3. [3]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
4. [4]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
5. [5]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
6. [6]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
7. [7]
  Xingmin Chen , Yunyun Wu , Yao Tang , Peishen Li , Shuai Gao , Qiang Wang , Wen Liu , Sihui Zhan . Construction of Z-scheme Cu-CeO₂/BiOBr heterojunction for enhanced photocatalytic degradation of sulfathiazole. Chinese Chemical Letters, 2024, 35(7): 109245-. doi: 10.1016/j.cclet.2023.109245
8. [8]
  Maosen Xu , Pengfei Zhu , Qinghong Cai , Meichun Bu , Chenghua Zhang , Hong Wu , Youzhou He , Min Fu , Siqi Li , Xingyan Liu . In-situ fabrication of TiO₂/NH₂−MIL-125(Ti) via MOF-driven strategy to promote efficient interfacial effects for enhancing photocatalytic NO removal activity. Chinese Chemical Letters, 2024, 35(10): 109524-. doi: 10.1016/j.cclet.2024.109524
9. [9]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
10. [10]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
11. [11]
  Tianhao Li , Wenguang Tu , Zhigang Zou . In situ photocatalytically enhanced thermogalvanic cells for electricity and hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(1): 100195-100195. doi: 10.1016/j.cjsc.2023.100195
12. [12]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
13. [13]
  Qiang ZHAO , Zhinan GUO , Shuying LI , Junli WANG , Zuopeng LI , Zhifang JIA , Kewei WANG , Yong GUO . Cu₂O/Bi₂MoO₆ Z-type heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 885-894. doi: 10.11862/CJIC.20230435
14. [14]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632
15. [15]
  Jing Wang , Zenghui Li , Xiaoyang Liu , Bochao Su , Honghong Gong , Chao Feng , Guoping Li , Gang He , Bin Rao . Fine-tuning redox ability of arylene-bridged bis(benzimidazolium) for electrochromism and visible-light photocatalysis. Chinese Chemical Letters, 2024, 35(9): 109473-. doi: 10.1016/j.cclet.2023.109473
16. [16]
  Zhenchun Yang , Bixiao Guo , Zhenyu Hu , Kun Wang , Jiahao Cui , Lina Li , Chun Hu , Yubao Zhao . Molecular engineering towards dual surface local polarization sites on poly(heptazine imide) framework for boosting H₂O₂ photo-production. Chinese Chemical Letters, 2024, 35(8): 109251-. doi: 10.1016/j.cclet.2023.109251
17. [17]
  Wenhao Wang , Guangpu Zhang , Qiufeng Wang , Fancang Meng , Hongbin Jia , Wei Jiang , Qingmin Ji . Hybrid nanoarchitectonics of TiO₂/aramid nanofiber membranes with softness and durability for photocatalytic dye degradation. Chinese Chemical Letters, 2024, 35(7): 109193-. doi: 10.1016/j.cclet.2023.109193
18. [18]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
19. [19]
  Zongyi Huang , Cheng Guo , Quanxing Zheng , Hongliang Lu , Pengfei Ma , Zhengzhong Fang , Pengfei Sun , Xiaodong Yi , Zhou Chen . Efficient photocatalytic biomass-alcohol conversion with simultaneous hydrogen evolution over ultrathin 2D NiS/Ni-CdS photocatalyst. Chinese Chemical Letters, 2024, 35(7): 109580-. doi: 10.1016/j.cclet.2024.109580
20. [20]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Construction of Z-Scheme MnO2/BiOBr Heterojunction for Photocatalytic Ciprofloxacin Removal and CO2 Reduction

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通讯作者: 陈斌, bchen63@163.com

Construction of Z-Scheme MnO₂/BiOBr Heterojunction for Photocatalytic Ciprofloxacin Removal and CO₂ Reduction