Citation: Jingjing Wang, Guiqiang Cao, Ruixian Duan, Xiangyang Li, Xifei Li. Advances in Single Metal Atom Catalysts Enhancing Kinetics of Sulfur Cathode[J]. Acta Physico-Chimica Sinica, ;2023, 39(5): 221200. doi: 10.3866/PKU.WHXB202212005 shu

Advances in Single Metal Atom Catalysts Enhancing Kinetics of Sulfur Cathode

Jingjing Wang ^{1, 2, †} ,
Guiqiang Cao ^{1, 2, †} ,
Ruixian Duan ^{1, 2} ,
Xiangyang Li ^3,, ,
Xifei Li ^{1, 2,,}

1.
Institute of Advanced Electrochemical Energy, School of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, China
2.
Engineering Research Center of Conducting Materials and Composite Technology, Ministry of Education, Xi'an 710048, China
3.
Science and Technology on Electromechanical Dynamic Control Laboratory, Xi'an Institute of Electromechanical Information Technology, Xi'an 710065, China

Corresponding author: Xiangyang Li, liyang2039@163.com Xifei Li, xfli@xaut.edu.cn

^†

Received Date: 3 December 2022
Revised Date: 30 December 2022
Accepted Date: 2 January 2023
Available Online: 16 January 2023
Fund Project: the Scientific Research Program Funded by Education Department of Shaanxi Provincial Government 22JP056

Sulfur has been considered as an ideal cathode of lithium sulfur batteries (LSBs) owing to its high theoretical energy density (2600 Wh∙Kg^-1), excellent discharge capacity (1672 mAh∙g^-1), and low cost. During sulfur reduction and oxidation processes, nevertheless, the sluggish redox reaction kinetics of the sulfur cathode and severe shuttle effect of soluble lithium polysulfides intermediates significantly result in poor battery performance. It has been demonstrated that a sulfur host with high adsorption energy and excellent catalytic activity/selectivity can effectively enhance the cycle stability and rate capability of LSBs. As a result, a variety of hosts, such as metal compounds, heterojunctions, defect matrices, and single metal atom catalysts, have been widely developed. Interestingly, single metal atom catalysts with a unique electronic structure, low metal content, theoretical 100% atom utilization efficiency, and high catalytic performance can effectively promote the conversion of different lithium polysulfides intermediates and provide abundant absorption sites for sulfur-contained species, thereby optimizing the redox reaction kinetics of the sulfur cathode and shuttle behavior of the soluble lithium polysulfides. Various single metal atom catalysts, mainly including iron, cobalt, nickel, zinc, tungsten, vanadium, molybdenum, and manganese, have been developed via atomic bonding, spatial confinement, and defect engineering strategies to solve the key challenges of sulfur cathode since single metal atom catalysts were for the first time to be utilized as catalytic agents for LSBs. In this review, the interaction among support materials in single metal atom catalysts, atomically dispersed metal catalytic sites, and the sulfur cathode were addressed in detail, providing a basis for the development of high-performance single metal atom catalysts. Furthermore, advanced characterization techniques such as in situ Raman spectroscopy, X-ray absorption spectroscopy, cyclic voltammograms, and electrochemical impedance spectroscopy, were employed to investigate the catalytic effect of single metal atom catalysts. Notably, the effects of the coordination environment on the catalytic activity and selectivity of single metal atom catalysts were systematically discussed. Simultaneously, the catalytic mechanism of single metal atom catalysts with different metal/nonmetallic atoms and coordination configurations was elucidated using theoretical calculations. In addition, some significant challenges of single metal atom catalyst in LSBs were proposed. It is believed that this review will provide a novel insight into the optimization of atomic catalysts with high activity and catalytic selectivity toward long-lifespan LSBs.
- Sulfur cathode,
- Reaction kinetics,
- Single metal atom catalyst,
- Polysulfide conversion,
- Lithium sulfur battery
1. [1]
  Liang, Z. W.; Shen, J. D.; Xu, X. J.; Li, F. K.; Liu, J.; Yuan, B.; Yu, Y.; Zhu, M. Adv. Mater. 2022, 34, e2200102. doi: 10.1002/adma.202200102 doi: 10.1002/adma.202200102
2. [2]
  Zhou, L.; Danilov, D. L.; Qiao, F.; Wang, J. F.; Li, H. T.; Eichel, R. A.; Notten, P. H. L. Adv. Energy Mater. 2022, 12, 2202094. doi: 10.1002/aenm.202202094 doi: 10.1002/aenm.202202094
3. [3]
  Yang, X. F.; Li, X.; Adair, K.; Zhang, H. M.; Sun, X. L. Electrochem. Energy Rev. 2018, 1, 239. doi: 10.1007/s41918-018-0010-3 doi: 10.1007/s41918-018-0010-3
4. [4]
  Liu, A. M.; Liang, X. Y.; Ren, X. F.; Guan, W. X.; Ma, T. L. Electrochem. Energy Rev. 2022, 5, 112. doi: org/10.1007/s41918-021-00110-w
5. [5]
  Liu, S.; Yao, L.; Zhang, Q.; Li, L. L.; Hu, N. T.; Wei, L. M.; Wei, H. Acta Phys. -Chim. Sin. 2017, 33, 2339. doi: 10.3866/PKU.WHXB201706021
6. [6]
  Zhang, M. D.; Chen, B.; Wu, M. B. Acta Phys. -Chim. Sin. 2022, 38, 2101001. doi: 10.3866/PKU.WHXB202101001
7. [7]
  Xue, W. J.; Shi, Z.; Suo, L. M.; Wang, C.; Wang, Z. Q.; Wang, H. Z.; So, K. P.; Maurano, A.; Yu, D. W.; Chen, Y. M.; et al. Nat. Energy 2019, 4, 374. doi: 10.1038/s41560-019-0351-0 doi: 10.1038/s41560-019-0351-0
8. [8]
  Zhou, G. M.; Xu, L.; Hu, G. W.; Mai, L. Q.; Cui, Y. Chem. Rev. 2019, 119, 11042. doi: 10.1021/acs.chemrev.9b00326 doi: 10.1021/acs.chemrev.9b00326
9. [9]
  Han, Z. L.; Li, S. P.; Wu, Y. K.; Yu, C.; Cheng, S. J.; Xie, J. J. Mater. Chem. A 2021, 9, 24215. doi: 10.1039/d1ta06499a doi: 10.1039/d1ta06499a
10. [10]
  Cao, G. Q.; Duan, R. X.; Li, X. F. EnergyChem 2022, 5, 100096. doi: 10.1016/j.enchem.2022.100096 doi: 10.1016/j.enchem.2022.100096
11. [11]
  Zhao, G. X.; Ahmed, W. H. Z.; Zhu, F. L. J. Electrochem. 2021, 27, 614. doi: 10.13208/j.electrochem.201210 doi: 10.13208/j.electrochem.201210
12. [12]
  Gao, R. H.; Zhang, Q.; Zhao, Y.; Han, Z. Y.; Sun, C. B.; Sheng, J. Z.; Zhong, X. W.; Chen, B.; Li, C.; Ni, S. Y.; et al. Adv. Funct. Mater. 2021, 32, 2110313. doi: 10.1002/adfm.202110313 doi: 10.1002/adfm.202110313
13. [13]
  Cheng, M. H.; Yan, R.; Yang, Z.; Tao, X. F.; Ma, T.; Cao, S. J.; Ran, F.; Li, S.; Yang, W.; Cheng, C. Adv. Sci. 2022, 9, 2102217. doi: 10.1002/advs.202102217 doi: 10.1002/advs.202102217
14. [14]
  Han, Z. Y.; Gao, R. H.; Jia, Y. Y.; Zhang, M. T.; Lao, Z. J.; Chen, B.; Zhang, Q.; Li, C.; Lv, W.; Zhou, G. M. Mater. Today 2022, 57, 84. doi: 10.1016/j.mattod.2022.05.017 doi: 10.1016/j.mattod.2022.05.017
15. [15]
  Zhang, T. T.; Yang, C. Y.; Qu, J.; Chang, W.; Liu, Y. H.; Zhai, X. Z.; Liu, H. J.; Jiang, Z. G.; Yu, Z. Z. Chem. Eur. J. 2022, 28, e202200363. doi: 10.1002/chem.202200363 doi: 10.1002/chem.202200363
16. [16]
  Zhang, T.; Zhang, L.; Zhao, L.; Huang, X. X.; Hou, Y. L. EnergyChem 2020, 2, 100036. doi: 10.1016/j.enchem.2020.100036 doi: 10.1016/j.enchem.2020.100036
17. [17]
  Chen, L. P.; Xu, Y. H.; Cao, G. Q.; Sari, H. M. K.; Duan, R. X.; Wang, J. J.; Xie, C.; Li, W. B.; Li, X. F. Adv. Funct. Mater. 2021, 32, 2107838. doi: 10.1002/adfm.202107838 doi: 10.1002/adfm.202107838
18. [18]
  Mahankali, K.; Gottumukkala, S. V.; Masurkar, N.; Thangavel, N. K.; Jayan, R.; Sawas, A.; Nagarajan, S.; Islam, M. M.; Arava, L. M. R. ACS Appl. Mater. Interfaces 2022, 14, 24486. doi: 10.1021/acsami.2c05508 doi: 10.1021/acsami.2c05508
19. [19]
  Guo, J.; Wang, H. Y.; Luo, Y. H.; An, H. L.; Zhang, Z. S.; Liu, G. H.; Li, J. D. Nanoscale 2021, 13, 17929. doi: 10.1039/d1nr04876g doi: 10.1039/d1nr04876g
20. [20]
  Cai, J. S.; Sun, Z. T.; Cai, W. L.; Wei, N.; Fan, Y.; Liu, Z. F.; Zhang, Q.; Sun, J. Y. Adv. Funct. Mater. 2021, 31, 2100586. doi: 10.1002/adfm.202100586 doi: 10.1002/adfm.202100586
21. [21]
  Wang, R. C.; Luo, C.; Wang, T. S.; Zhou, G. M.; Deng, Y. Q.; He, Y. B.; Zhang, Q. F.; Kang, F. Y.; Lv, W.; Yang, Q. H. Adv. Mater. 2020, 32, e2000315. doi: 10.1002/adma.202000315 doi: 10.1002/adma.202000315
22. [22]
  Liu, B. T.; Li, H.; Shi, C. L.; Sun, J. L.; Xiao, S. H.; Pang, Y. Y.; Yang, J. W.; Li, Y. W. Nanoscale 2022, 14, 4557. doi: 10.1039/d1nr08292b doi: 10.1039/d1nr08292b
23. [23]
  Jia, Y.; Zhang, L. Z.; Zhuang, L. Z.; Liu, H. L.; Yan, X. C.; Wang, X.; Liu, J. D.; Wang, J. C.; Zheng, Y. R.; Xiao, Z. H.; et al. Nat. Catal. 2019, 2, 688. doi: 10.1038/s41929-019-0297-4 doi: 10.1038/s41929-019-0297-4
24. [24]
  Dong, Y. T.; Zhang, R.; Peng, H. Q.; Han, D. D.; Zheng, X. F.; Han, Y. M.; Zhang, J. M. ACS Appl. Mater. Interfaces 2022, 14, 32474. doi: 10.1021/acsami.2c06067 doi: 10.1021/acsami.2c06067
25. [25]
  Zou, K. Y.; Chen, X. X.; Jing, W. T.; Dai, X.; Wang, P. F.; Liu, Y.; Qiao, R.; Shi, M.; Chen, Y. Z.; Sun, J. J.; et al. Energy Storage Mater. 2022, 48, 133. doi: 10.1016/j.ensm.2022.03.003 doi: 10.1016/j.ensm.2022.03.003
26. [26]
  Du, Z. Z.; Chen, X. J.; Hu, W.; Chuang, C. H.; Xie, S.; Hu, A. J.; Yan, W. S.; Kong, X. H.; Wu, X. J.; Ji, H. X.; et al. J. Am. Chem. Soc. 2019, 141, 3977. doi: 10.1021/jacs.8b12973 doi: 10.1021/jacs.8b12973
27. [27]
  Zhang, Y. G.; Liu, J. B.; Wang, J. Y.; Zhao, Y.; Luo, D.; Yu, A. P.; Wang, X.; Chen, Z. W. Angew. Chem. Int. Ed. 2021, 60, 26622. doi: 10.1002/anie.202108882 doi: 10.1002/anie.202108882
28. [28]
  Liu, Y.; Wei, Z. Y.; Zhong, B.; Wang, H. T.; Xia, L.; Zhang, T.; Duan, X. M.; Jia, D. C.; Zhou, Y.; Huang, X. X. Energy Storage Mater. 2021, 35, 12. doi: 10.1016/j.ensm.2020.11.011 doi: 10.1016/j.ensm.2020.11.011
29. [29]
  Fang, L. Z.; Feng, Z.; Cheng, L.; Winans, R. E.; Li, T. Small Methods 2020, 4, 2000315. doi: 10.1002/smtd.202000315 doi: 10.1002/smtd.202000315
30. [30]
  Qin, R. X.; Liu, P. X.; Fu, G.; Zheng, N. F. Small Methods 2018, 2, 1700286. doi: 10.1002/smtd.201700286 doi: 10.1002/smtd.201700286
31. [31]
  Wang, J.; Li, Z. J.; Wu, Y.; Li, Y. D. Adv. Mater. 2018, 30, e1801649. doi: 10.1002/adma.201801649 doi: 10.1002/adma.201801649
32. [32]
  Jiao, D. X.; Liu, Y. J.; Cai, Q. H.; Zhao, J. X. J. Mater. Chem. A 2021, 9, 1240. doi: 10.1039/d0ta09496j doi: 10.1039/d0ta09496j
33. [33]
  Qiao, S. M.; Lei, D.; Wang, Q.; Shi, X. S.; Zhang, Q.; Huang, C. H.; Liu, A. M.; He, G. H.; Zhang, F. X. Chem. Eng. J. 2022, 442, 136258. doi: 10.1016/j.cej.2022.136258 doi: 10.1016/j.cej.2022.136258
34. [34]
  Liu, P. T.; Wang, Y. Y.; Liu, J. H. J. Energy Chem. 2019, 34, 171. doi: 10.1016/j.jechem.2018.10.005 doi: 10.1016/j.jechem.2018.10.005
35. [35]
  Zhang, L. L.; Wang, Y. J.; Niu, Z. Q.; Chen, J. Carbon 2019, 141, 400. doi: 10.1016/j.carbon.2018.09.067 doi: 10.1016/j.carbon.2018.09.067
36. [36]
  Xiang, Y. Y.; Lu, L. Q.; Kottapalli, A. G. P.; Pei, Y. T. Carbon Energy 2022, 4, 346. doi: 10.1002/cey2.185 doi: 10.1002/cey2.185
37. [37]
  Sui, X. L.; Zhang, L.; Li, J. J.; Doyle-Davis, K.; Li, R. Y.; Wang, Z. B.; Sun, X. L. Adv. Energy Mater. 2021, 12, 2102556. doi: 10.1002/aenm.202102556 doi: 10.1002/aenm.202102556
38. [38]
  Zeng, Z. H.; Nong, W.; Li, Y.; Wang, C. X. Adv. Sci. 2021, 8, 2102809. doi: 10.1002/advs.202102809 doi: 10.1002/advs.202102809
39. [39]
  Zhang, D.; Wang, S.; Hu, R. M.; Gu, J.; Cui, Y. L. S.; Li, B.; Chen, W. H.; Liu, C. T.; Shang, J. X.; Yang, S. B. Adv. Funct. Mater. 2020, 30, 2002471. doi: 10.1002/adfm.202002471 doi: 10.1002/adfm.202002471
40. [40]
  Chen, K.; Sun, Z. H.; Fang, R. P.; Shi, Y.; Cheng, H. M.; Li, F. Adv. Funct. Mater. 2018, 28, 1707592. doi: 10.1002/adfm.201707592 doi: 10.1002/adfm.201707592
41. [41]
  Liu, X.; Huang, J. Q.; Zhang, Q.; Mai, L. Q. Adv. Mater. 2017, 29, 1601759. doi: 10.1002/adma.201601759 doi: 10.1002/adma.201601759
42. [42]
  Wang, F.; Zuo, Z. C.; Li, L.; He, F.; Li, Y. L. Nano Energy 2020, 68, 104307. doi: 10.1016/j.nanoen.2019.104307 doi: 10.1016/j.nanoen.2019.104307
43. [43]
  Xiao, Q.; Yang, J. L.; Wang, X. D.; Deng, Y. R.; Han, P.; Yuan, N.; Zhang, L.; Feng, M.; Wang, C. A.; Liu, R. P. Carbon Energy 2021, 3, 271. doi: 10.1002/cey2.96 doi: 10.1002/cey2.96
44. [44]
  Wu, J. L.; Chen, J. M.; Huang, Y.; Feng, K.; Deng, J.; Huang, W.; Wu, Y. L.; Zhong, J.; Li, Y. G. Sci. Bull. 2019, 64, 1875. doi: 10.1016/j.scib.2019.08.016 doi: 10.1016/j.scib.2019.08.016
45. [45]
  Li, Y. J.; Chen, G. L.; Mou, J. R.; Liu, Y. Z.; Xue, S. F.; Tan, T.; Zhong, W. T.; Deng, Q.; Li, T.; Hu, J. H.; et al. Energy Storage Mater. 2020, 28, 196. doi: 10.1016/j.ensm.2020.03.008 doi: 10.1016/j.ensm.2020.03.008
46. [46]
  Huang, T.; Sun, Y. J.; Wu, J. H.; Jin, J.; Wei, C. H.; Shi, Z. X.; Wang, M. L.; Cai, J. S.; An, X. T.; Wang, P.; et al. ACS Nano 2021, 15, 14105. doi: 10.1021/acsnano.1c04642 doi: 10.1021/acsnano.1c04642
47. [47]
  Liu, Z. Z.; Zhou, L.; Ge, Q.; Chen, R. J.; Ni, M.; Utetiwabo, W.; Zhang, X. L.; Yang, W. ACS Appl. Mater. Interfaces 2018, 10, 19311. doi: 10.1021/acsami.8b03830 doi: 10.1021/acsami.8b03830
48. [48]
  Ding, Y. F.; Cheng, Q. S.; Wu, J. H.; Yan, T. R.; Shi, Z. X.; Wang, M. L.; Yang, D. Z.; Wang, P.; Zhang, L.; Sun, J. Y. Adv. Mater. 2022, 34, 2202256. doi: 10.1002/adma.202202256 doi: 10.1002/adma.202202256
49. [49]
  Fan, X. Y.; Chen, S.; Gong, W. B.; Meng, X. D.; Jia, Y. C.; Wang, Y. L.; Hong, S.; Zheng, L.; Zheng, L. R.; Bielawski, C. W.; et al. Energy Storage Mater. 2021, 41, 14. doi: 10.1016/j.ensm.2021.05.043 doi: 10.1016/j.ensm.2021.05.043
50. [50]
  Zhang, S. L.; Ao, X.; Huang, J.; Wei, B.; Zhai, Y. L.; Zhai, D.; Deng, W. Q.; Su, C. L.; Wang, D. S.; Li, Y. D. Nano Lett. 2021, 21, 9691. doi: 10.1021/acs.nanolett.1c03499 doi: 10.1021/acs.nanolett.1c03499
51. [51]
  Shi, H. D.; Ren, X. M.; Lu, J. M.; Dong, C.; Liu, J.; Yang, Q. H.; Chen, J.; Wu, Z. S. Adv. Energy Mater. 2020, 10, 2002271. doi: 10.1002/aenm.202002271 doi: 10.1002/aenm.202002271
52. [52]
  Wang, P.; Xi, B. J.; Zhang, Z.; Huang, M.; Feng, J. K.; Xiong, S. L. Angew. Chem. Int. Ed. 2021, 60, 15563. doi: 10.1002/anie.202104053 doi: 10.1002/anie.202104053
53. [53]
  Andritsos, E. I.; Lekakou, C.; Cai, Q. J. Phys. Chem. C 2021, 125, 18108. doi: 10.1021/acs.jpcc.1c04491 doi: 10.1021/acs.jpcc.1c04491
54. [54]
  Guo, D. Y.; Zhang, X.; Liu, M. L.; Yu, Z. S.; Chen, X. A.; Yang, B.; Zhou, Z.; Wang, S. Adv. Funct. Mater. 2022, 32, 2204458. doi: 10.1002/adfm.202204458 doi: 10.1002/adfm.202204458
55. [55]
  Wang, C. G.; Song, H. W.; Yu, C. C.; Ullah, Z. K.; Guan, Z. X.; Chu, R. R.; Zhang, Y. F.; Zhao, L. Y.; Li, Q.; Liu, L. W. J. Mater. Chem. A 2020, 8, 3421. doi: 10.1039/c9ta11680j doi: 10.1039/c9ta11680j
56. [56]
  Gorlin, Y.; Patel, M. U. M.; Freiberg, A.; He, Q.; Piana, M.; Tromp, M.; Gasteiger, H. A. J. Electrochem. Soc. 2016, 163, A930. doi: 10.1149/2.0631606jes doi: 10.1149/2.0631606jes
57. [57]
  Cuisinier, M.; Cabelguen, P. -E.; Evers, S.; He, G.; Kolbeck, M.; Garsuch, A.; Bolin, T.; Balasubramanian, M.; Nazar, L. F. J. Phys. Chem. Lett. 2013, 4, 3227. doi: 10.1021/jz401763d doi: 10.1021/jz401763d
58. [58]
  Li, Y. J.; Wu, J. B.; Zhang, B.; Wang, W. Y.; Zhang, G. Q.; Seh, Z. W.; Zhang, N.; Sun, J.; Huang, L.; Jiang, J. J.; et al. Energy Storage Mater. 2020, 30, 250. doi: 10.1016/j.ensm.2020.05.022 doi: 10.1016/j.ensm.2020.05.022
59. [59]
  Li, Y. X.; Zeng, Y. X.; Chen, Y.; Luan, D. Y.; Gao, S. Y.; Lou, X. W. Angew. Chem. Int. Ed. 2022, 61, e202212680. doi: 10.1002/anie.202212680 doi: 10.1002/anie.202212680
60. [60]
  Xie, S.; Chen, X. J.; Wang, C.; Lu, Y. R.; Chan, T. S.; Chuang, C. H.; Zhang, J.; Yan, W. S.; Jin, S.; Jin, H. C.; et al. Small 2022, 18, 2200395. doi: 10.1002/smll.202200395 doi: 10.1002/smll.202200395
61. [61]
  Zhou, G. M.; Zhao, S. Y.; Wang, T. S.; Yang, S. Z.; Johannessen, B.; Chen, H.; Liu, C. W.; Ye, Y. S.; Wu, Y. C.; Peng, Y. C.; et al. Nano Lett. 2020, 20, 1252. doi: 10.1021/acs.nanolett.9b04719 doi: 10.1021/acs.nanolett.9b04719
62. [62]
  Zhang, Y.; Jiao, L.; Yang, W. J.; Xie, C. F.; Jiang, H. L. Angew. Chem. Int. Ed. 2021, 60, 7607. doi: 10.1002/anie.202016219 doi: 10.1002/anie.202016219
63. [63]
  Tang, H.; Gu, H. F.; Li, Z. Y.; Chai, J.; Qin, F. J.; Lu, C. Q.; Yu, J. Y.; Zhai, H. Z.; Zhang, L.; Li, X. Y.; et al. ACS Appl. Mater. Interfaces 2022, 14, 46401. doi: 10.1021/acsami.2c09107 doi: 10.1021/acsami.2c09107
64. [64]
  Wang, J. Y.; Qiu, W. B.; Li, G. R.; Liu, J. B.; Luo, D.; Zhang, Y. G.; Zhao, Y.; Zhou, G. F.; Shui, L. L.; Wang, X.; et al. Energy Storage Mater. 2022, 46, 269. doi: 10.1016/j.ensm.2021.12.040 doi: 10.1016/j.ensm.2021.12.040
65. [65]
  Zhou, W. L.; Su, H.; Li, Y. L.; Liu, M. H.; Zhang, H.; Zhang, X. X.; Sun, X.; Xu, Y. Z.; Liu, Q. H.; Wei, S. Q. ACS Energy Lett. 2021, 6, 3359. doi: 10.1021/acsenergylett.1c01316 doi: 10.1021/acsenergylett.1c01316
66. [66]
  Wang, X. Q.; Chen, Z.; Zhao, X. Y.; Yao, T.; Chen, W. X.; You, R.; Zhao, C. M.; Wu, G.; Wang, J.; Huang, W. X.; et al. Angew. Chem. Int. Ed. 2018, 57, 1944. doi: 10.1002/anie.201712451 doi: 10.1002/anie.201712451
67. [67]
  Zhou, Y. Z.; Tao, X. F.; Chen, G. B.; Lu, R. H.; Wang, D.; Chen, M. X.; Jin, E. Q.; Yang, J.; Liang, H. W.; Zhao, Y.; et al. Nat. Commun. 2020, 11, 5892. doi: 10.1038/s41467-020-19599-8 doi: 10.1038/s41467-020-19599-8
68. [68]
  Jiang, R.; Li, L.; Sheng, T.; Hu, G. F.; Chen, Y. G.; Wang, L. Y. J. Am. Chem. Soc. 2018, 140, 11594. doi: 10.1021/jacs.8b07294 doi: 10.1021/jacs.8b07294
69. [69]
  Zhang, L. Z.; Jia, Y.; Gao, G. P.; Yan, X. C.; Chen, N.; Chen, J.; Soo, M. T.; Wood, B.; Yang, D. J.; Du, A. J.; Yao, X. D. Chem 2018, 4, 285. doi: 10.1016/j.chempr.2017.12.005 doi: 10.1016/j.chempr.2017.12.005
70. [70]
  Tsounis, C.; Subhash, B.; Kumar, P. V.; Bedford, N. M.; Zhao, Y. F.; Shenoy, J.; Ma, Z. P.; Zhang, D.; Toe, C. Y.; Cheong, S.; et al. Adv. Funct. Mater. 2022, 32, 2203067. doi: 10.1002/adfm.202203067 doi: 10.1002/adfm.202203067
71. [71]
  Wang, X. P.; Ding, S. S.; Yue, T.; Zhu, Y.; Fang, M. W.; Li, X. Y.; Xiao, G. Z.; Zhu, Y.; Dai, L. M. Nano Energy 2021, 82, 105689. doi: 10.1016/j.nanoen.2020.105689 doi: 10.1016/j.nanoen.2020.105689
72. [72]
  Chen, X.; Ma, D. D.; Chen, B.; Zhang, K. X.; Zou, R. Q.; Wu, X. T.; Zhu, Q. L. Appl. Catal. B: Environ. 2020, 267, 118720. doi: 10.1016/j.apcatb.2020.118720 doi: 10.1016/j.apcatb.2020.118720
73. [73]
  Zhuo, H. Y.; Zhang, X.; Liang, J. X.; Yu, Q.; Xiao, H.; Li, J. Chem. Rev. 2020, 120, 12315. doi: 10.1021/acs.chemrev.0c00818 doi: 10.1021/acs.chemrev.0c00818
74. [74]
  Jiang, Q.; Zhang, J. F.; Huang, H. J.; Wu, Y. P.; Ao, Z. M. J. Mater. Chem. A 2020, 8, 287. doi: 10.1039/c9ta08525d doi: 10.1039/c9ta08525d
75. [75]
  Li, B. Q.; Kong, L.; Zhao, C. X.; Jin, Q.; Chen, X.; Peng, H. J.; Qin, J. L.; Chen, J. X.; Yuan, H.; Zhang, Q.; Huang, J. Q. InfoMat 2019, 1, 533. doi: 10.1002/inf2.12056 doi: 10.1002/inf2.12056
76. [76]
  Xie, J.; Li, B. Q.; Peng, H. J.; Song, Y. W.; Zhao, M.; Chen, X.; Zhang, Q.; Huang, J. Q. Adv. Mater. 2019, 31, 1903813. doi: 10.1002/adma.201903813 doi: 10.1002/adma.201903813
77. [77]
  Zeng, Q. W.; Hu, R. M.; Chen, Z. B.; Shang, J. X. Mater. Res. Express 2019, 6, 095620. doi: 10.1088/2053-1591/ab33ad doi: 10.1088/2053-1591/ab33ad
78. [78]
  Chen, Y. J.; Gao, R.; Ji, S. F.; Li, H. J.; Tang, K.; Jiang, P.; Hu, H. B.; Zhang, Z. D.; Hao, H. G.; Qu, Q. Y.; et al. Angew. Chem. Int. Ed. 2021, 60, 3212. doi: 10.1002/anie.202012798 doi: 10.1002/anie.202012798
79. [79]
  Pan, Y.; Lin, R.; Chen, Y. J.; Liu, S. J.; Zhu, W.; Cao, X.; Chen, W. X.; Wu, K. L.; Cheong, W. C.; Wang, Y.; et al. J. Am. Chem. Soc. 2018, 140, 4218. doi: 10.1021/jacs.8b00814 doi: 10.1021/jacs.8b00814
80. [80]
  Chen, H. H.; Guo, X.; Kong, X. D.; Xing, Y. L.; Liu, Y.; Yu, B. L.; Li, Q. X.; Geng, Z. G.; Si, R.; Zeng, J. Green Chem. 2020, 22, 7529. doi: 10.1039/d0gc02689a doi: 10.1039/d0gc02689a
81. [81]
  Lin, H. B.; Zhang, S. L.; Zhang, T. R.; Ye, H. L.; Yao, Q. F.; Zheng, G. W.; Lee, J. Y. Adv. Energy Mater. 2018, 8, 1801868. doi: 10.1002/aenm.201801868 doi: 10.1002/aenm.201801868
82. [82]
  Qiu, Y.; Fan, L. S.; Wang, M. X.; Yin, X. J.; Wu, X.; Sun, X.; Tian, D.; Guan, B.; Tang, D. Y.; Zhang, N. Q. ACS Nano 2020, 14, 16105. doi: 10.1021/acsnano.0c08056 doi: 10.1021/acsnano.0c08056
83. [83]
  Ma, F.; Wan, Y. Y.; Wang, X. M.; Wang, X. C.; Liang, J. S.; Miao, Z. P.; Wang, T. Y.; Ma, C.; Lu, G.; Han, J. T.; et al. ACS Nano 2020, 14, 10115. doi: 10.1021/acsnano.0c03325 doi: 10.1021/acsnano.0c03325
84. [84]
  Zhang, J. Q.; Zhao, Y. F.; Chen, C.; Huang, Y. C.; Dong, C. L.; Chen, C. J.; Liu, R. S.; Wang, C. Y.; Yan, K.; Li, Y. D.; et al. J. Am. Chem. Soc. 2019, 141, 20118. doi: 10.1021/jacs.9b09352 doi: 10.1021/jacs.9b09352
85. [85]
  Wang, M. R.; Yang, W. J.; Li, X. Z.; Xu, Y. S.; Zheng, L. R.; Su, C. L.; Liu, B. ACS Energy Lett. 2021, 6, 379. doi: 10.1021/acsenergylett.0c02484 doi: 10.1021/acsenergylett.0c02484
86. [86]
  Yu, J.; Li, J.; Xu, C. Y.; Li, Q. Q.; Liu, Q.; Liu, J. Y.; Chen, R. R.; Zhu, J. H.; Wang, J. Nano Energy 2022, 98, 107266. doi: 10.1016/j.nanoen.2022.107266 doi: 10.1016/j.nanoen.2022.107266
87. [87]
  Yuan, K.; Lutzenkirchen Hecht, D.; Li, L. B.; Shuai, L.; Li, Y. Z.; Cao, R.; Qiu, M.; Zhuang, X. D.; Leung, M. K. H.; Chen, Y. W.; Scherf, U. J. Am. Chem. Soc. 2020, 142, 2404. doi: 10.1021/jacs.9b11852 doi: 10.1021/jacs.9b11852
88. [88]
  Liu, G. L.; Wang, W. M.; Zeng, P.; Yuan, C.; Wang, L.; Li, H. T.; Zhang, H.; Sun, X. H.; Dai, K. H.; Mao, J.; Li, X.; Zhang, L. Nano Lett. 2022, 22, 6366. doi: 10.1021/acs.nanolett.2c02183 doi: 10.1021/acs.nanolett.2c02183
89. [89]
  Huang, T.; Sun, Y. J.; Wu, J. H.; Shi, Z. X.; Ding, Y. F.; Wang, M. L.; Su, C. L.; Li, Y. Y.; Sun, J. Y. Adv. Funct. Mater. 2022, 32, 2203902. doi: 10.1002/adfm.202203902 doi: 10.1002/adfm.202203902
90. [90]
  Zhao, H.; Tian, B. B.; Su, C. L.; Li, Y. ACS Appl. Mater. Interfaces 2021, 13, 7171. doi: 10.1021/acsami.0c20446 doi: 10.1021/acsami.0c20446
91. [91]
  Zhang, S. J.; Shao, Q. J.; Su, Y.; Xu, L.; Jiang, Q. K.; Chen, J. J. Alloys Compd. 2022, 910, 164799. doi: 10.1016/j.jallcom.2022.164799 doi: 10.1016/j.jallcom.2022.164799
92. [92]
  Faheem, M.; Yin, X.; Shao, R. W.; Zhou, L.; Zeng, C. Y.; Ahmad, N.; Tufail, M. K.; Yang, W. J. Alloys Compd. 2022, 922, 166132. doi: 10.1016/j.jallcom.2022.166132 doi: 10.1016/j.jallcom.2022.166132
93. [93]
  Yu, H.; Zeng, P.; Zhou, X.; Guo, C. M.; Liu, X. L.; Wang, K. F.; Guo, X. W.; Chang, B. B.; Chen, M. F.; Wang, X. Y. ACS Appl. Mater. Interfaces 2021, 13, 54113. doi: 10.1021/acsami.1c18645 doi: 10.1021/acsami.1c18645
94. [94]
  Zhu, J.; Wang, X. Y.; Ke, T.; Jia, M. J.; Jin, B. Y.; Li, Y. Y.; Yang, Q. W.; Ren, L. H.; Ren, Y. Y.; Cheng, D. G.; et al. J. Energy Chem. 2022, 78, 203. doi: 10.1016/j.jechem.2022.08.041 doi: 10.1016/j.jechem.2022.08.041
95. [95]
  Liu, K.; Wang, X. Y.; Gu, S.; Yuan, H. M.; Jiang, F.; Li, Y. Z.; Tan, W.; Long, Q. R.; Chen, J. J.; Xu, Z. H.; et al. Small 2022, 18, 2204707. doi: 10.1002/smll.202204707 doi: 10.1002/smll.202204707
96. [96]
  Lu, C.; Chen, Y.; Yang, Y.; Chen, X. Nano Lett. 2020, 20, 5522. doi: 10.1021/acs.nanolett.0c02167 doi: 10.1021/acs.nanolett.0c02167
97. [97]
  Wang, J.; Jia, L. J.; Zhong, J.; Xiao, Q. B.; Wang, C.; Zang, K. T.; Liu, H. T.; Zheng, H. C.; Luo, J.; Yang, J.; et al. Energy Storage Mater. 2019, 18, 246. doi: 10.1016/j.ensm.2018.09.006 doi: 10.1016/j.ensm.2018.09.006
98. [98]
  Li, S.; Lin, J. D.; Chang, B.; Yang, D. W.; Wu, D. Y.; Wang, J. H.; Zhou, W. J.; Liu, H.; Sun, S. H.; Zhang, L. Energy Storage Mater. 2023, 55, 94. doi: 10.1016/j.ensm.2022.11.045 doi: 10.1016/j.ensm.2022.11.045
99. [99]
  Tian, W. Z.; Xi, B. J.; Feng, Z. Y.; Li, H. B.; Feng, J. K.; Xiong, S. L. Adv. Energy Mater. 2019, 9, 1901896. doi: 10.1002/aenm.201901896 doi: 10.1002/aenm.201901896
100. [100]
  Li, Z.; Zhang, J. T.; Lou, X. W. Angew. Chem. Int. Ed. 2015, 127, 13078. doi: 10.1002/anie.201506972 doi: 10.1002/anie.201506972
101. [101]
  Pang, Q.; Kundu, D. P.; Cuisinier, M.; Nazar, L. F. Nat. Commun. 2014, 5, 4759. doi: 10.1038/ncomms5759 doi: 10.1038/ncomms5759
102. [102]
  Wang, S. Z.; Wang, Y.; Song, Y. C.; Jia, X. H.; Yang, J.; Li, Y.; Liao, J. X.; Song, H. J. Energy Storage Mater. 2021, 43, 422. doi: 10.1016/j.ensm.2021.09.020 doi: 10.1016/j.ensm.2021.09.020
103. [103]
  Niu, L. Q.; Wu, T. L.; Zhou, D.; Qi, J.; Xiao, Z. B. Energy Storage Mater. 2022, 45, 840. doi: 10.1016/j.ensm.2021.12.039 doi: 10.1016/j.ensm.2021.12.039
104. [104]
  Zhou, G. M.; Tian, H. Z.; Jin, Y.; Tao, X. Y.; Liu, B. F.; Zhang, R. F.; Seh, Z. W.; Zhuo, D.; Liu, Y. Y.; Sun, J.; et al. Proc. Natl. Acad. Sci. USA 2017, 114, 840. doi: 10.1073/pnas.1615837114 doi: 10.1073/pnas.1615837114
105. [105]
  Sun, Z. H.; Zhang, J. Q.; Yin, L. C.; Hu, G. J.; Fang, R. P.; Cheng, H. M.; Li, F. Nat. Commun. 2017, 8, 14627. doi: 10.1038/ncomms14627 doi: 10.1038/ncomms14627
106. [106]
  Zhou, K. L.; Wang, Z. L.; Han, C. B.; Ke, X. X.; Wang, C. H.; Jin, Y. H.; Zhang, Q. Q.; Liu, J. B.; Wang, H.; Yan, H. Nat. Commun. 2021, 12, 3783. doi: 10.1038/s41467-021-24079-8 doi: 10.1038/s41467-021-24079-8
107. [107]
  Zhang, J. Q.; Zhao, Y. F.; Guo, X.; Chen, C.; Dong, C. L.; Liu, R. S.; Han, C. P.; Li, Y. D.; Gogotsi, Y.; Wang, G. X. Nat. Catal. 2018, 1, 985. doi: 10.1038/s41929-018-0195-1 doi: 10.1038/s41929-018-0195-1
108. [108]
  Jiang, K.; Liu, B. Y.; Luo, M.; Ning, S. C.; Peng, M.; Zhao, Y.; Lu, Y. R.; Chan, T. S.; De Groot, F. M. F.; Tan, Y. W. Nat. Commun. 2019, 10, 1743. doi: 10.1038/s41467-019-09765-y doi: 10.1038/s41467-019-09765-y
109. [109]
  Liu, D. B.; Li, X. Y.; Chen, S. M.; Yan, H.; Wang, C. D.; Wu, C. Q.; Haleem, Y. A.; Duan, S.; Lu, J. L.; Ge, B. H.; et al. Nat. Energy 2019, 4, 512. doi: 10.1038/s41560-019-0402-6 doi: 10.1038/s41560-019-0402-6
110. [110]
  Qiao, B. T.; Wang, A. Q.; Yang, X. F.; Allard, L. F.; Jiang, Z.; Cui, Y. T.; Liu, J. Y.; Li, J.; Zhang, T. Nat. Chem. 2011, 3, 634. doi: 10.1038/nchem.1095 doi: 10.1038/nchem.1095
111. [111]
  Liu, P. X.; Zhao, Y.; Qin, R. X.; Mo, S. G.; Chen, G. X.; Gu, L.; Chevrier, D. M.; Zhang, P.; Guo, Q.; Zang, D. D.; et al. Science 2016, 352, 797. doi: 10.1126/science.aaf5251 doi: 10.1126/science.aaf5251
112. [112]
  Zheng, J. W.; Lebedev, K.; Wu, S.; Huang, C.; Ayvalı, T. C. E.; Wu, T. S.; Li, Y. Y.; Ho, P. L.; Soo, Y. L.; Kirkland, A.; et al. J. Am. Chem. Soc. 2021, 143, 7979. doi: 10.1021/jacs.1c01097 doi: 10.1021/jacs.1c01097
113. [113]
  Nahian, M. S.; Jayan, R.; Islam, M. M. ACS Catal. 2022, 12, 7664. doi: 10.1021/acscatal.2c01174 doi: 10.1021/acscatal.2c01174
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