Citation: Zhongqi Zan, Xibao Li, Xiaoming Gao, Juntong Huang, Yidan Luo, Lu Han. 0D/2D Carbon Nitride Quantum Dots (CNQDs)/BiOBr S-Scheme Heterojunction for Robust Photocatalytic Degradation and H₂O₂ Production[J]. Acta Physico-Chimica Sinica, ;2023, 39(6): 220901. doi: 10.3866/PKU.WHXB202209016 shu

0D/2D Carbon Nitride Quantum Dots (CNQDs)/BiOBr S-Scheme Heterojunction for Robust Photocatalytic Degradation and H₂O₂ Production

Zhongqi Zan ¹ ,
Xibao Li ^1,, ,
Xiaoming Gao ² ,
Juntong Huang ^1,, ,
Yidan Luo ¹ ,
Lu Han ^3,,

1.
School of Materials Science and Engineering, Nanchang Hangkong University, Nanchang 330063, China
2.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, Shaanxi Province, China
3.
School of Materials and Metallurgy, University of Science and Technology Liaoning, Anshan 114051, Liaoning Province, China

Corresponding author: Xibao Li, lixibao@nchu.edu.cn Juntong Huang, huangjt@nchu.edu.cn Lu Han, hanlu@ustl.edu.cn
Received Date: 12 September 2022
Revised Date: 1 November 2022
Accepted Date: 24 November 2022
Available Online: 29 November 2022
Fund Project: the National Natural Science Foundation of China 51962023the National Natural Science Foundation of China 22262024the National Natural Science Foundation of China 51862024the Natural Science Foundation of Jiangxi Province, China 20212BAB204045the Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, China (Nanchang Hangkong University) ES202002077

The construction of heterojunctions is a method employed to inhibit the rapid recombination of photogenerated carriers. In this work, zero-dimensional (0D) g-C₃N₄ quantum dots (CNQDs) were composited with two-dimensional (2D) BiOBr for the first time using the typical hydrothermal method under the conditions of a high temperature and high pressure, and a 0D/2D CNQD/BiOBr S-scheme heterojunction with an intimate-contact interface was formed. The π-electrons in the heterocycle of the CNQDs were bound to BiOBr by interaction. The apparent reaction rate constants generated by CNQDs/BiOB-1.50% for tetracycline (TC) and ciprofloxacin (CIP) degradation and H₂O₂ production were 2.02, 2.91, and 1.54 times that of the original BiOBr, respectively. In the cycle test, CNQDs/BiOBr-1.50% displayed a relatively high photocatalytic activity and structural stability. X-ray photoelectron spectroscopy (XPS) analysis showed that the π electrons in the CNQDs interacted with BiOBr, and also confirmed the flow of photogenerated electrons in this heterojunction. This successfully constructed S-scheme exhibited extraordinary photocatalytic activity and stability. The more active species and stable catalytic activity were attributed to the distinctive transfer mechanism of the carriers. This work will provide reference for constructing 0D/2D S-scheme heterojunctions for the degradation of organic pollutants and in situ production of H₂O₂.
- Photocatalysis,
- Quantum dots,
- S-scheme,
- Catalytic activity,
- H₂O₂
1. [1]
  Dong, S. Y.; Zhao, Y. L.; Yang, J. Y.; Liu, X. D.; Li, W.; Zhang, L. Y.; Wu, Y. H.; Sun, J. H.; Feng, J. L.; Zhu, Y. F. Appl. Catal. B 2021, 291, 120127. doi: 10.1016/j.apcatb.2021.120127 doi: 10.1016/j.apcatb.2021.120127
2. [2]
  Li, X. B.; Wang, W. W.; Dong, F.; Zhang, Z. Q.; Han, L.; Luo, X. D.; Huang, J. T.; Feng, Z. J.; Chen, Z.; Jia, G. H.; et al. ACS Catal. 2021, 11, 4739. doi: 10.1021/acscatal.0c05354 doi: 10.1021/acscatal.0c05354
3. [3]
  Huo, J. R.; Fu, L.; Zhao, C. X.; He, C. Z. Chin. Chem. Lett. 2021, 32, 2269. doi: 10.1016/j.cclet.2020.12.059 doi: 10.1016/j.cclet.2020.12.059
4. [4]
  Jiang, Y. J.; Wei, X. D.; He, H. P.; She, J. Y.; Liu, J.; Fang, F.; Zhang, W. H.; Liu, Y. Y.; Wang, J.; Xiao, T. F.; et al. J. Hazard. Mater. 2021, 423, 126997. doi: 10.1016/j.jhazmat.2021.126997 doi: 10.1016/j.jhazmat.2021.126997
5. [5]
  Yin, M. L.; Zhou, Y. T.; Tsang, D. C. W.; Beiyuan, J. Z.; Song, L.; She, J. Y.; Wang, J.; Zhu, L.; Fang, F.; Wang, L. L.; et al. J. Hazard. Mater. 2020, 407, 124402. doi: 10.1016/j.jhazmat.2020.124402 doi: 10.1016/j.jhazmat.2020.124402
6. [6]
  Zhang, L.; Hu, Z. H.; Huang, J. T.; Chen, Z.; Li, X. B.; Feng, Z. J.; Yang, H. Y.; Huang, S. F.; Luo, R. Y. J. Adv. Ceram. 2022, 11, 1294. doi: 10.1007/s40145-022-0610-6 doi: 10.1007/s40145-022-0610-6
7. [7]
  Xia, B. H.; Deng, F.; Zhang, S. Q.; Hua, L.; Luo, X. B.; Ao, M. Y. J. Hazard. Mater. 2020, 392, 122345. doi: 10.1016/j.jhazmat.2020.122345 doi: 10.1016/j.jhazmat.2020.122345
8. [8]
  Dong, S. Y.; Cui, L. F.; Tian, Y. I.; Xia, L. J.; Wu, Y. H.; Yu, J. J.; Bagley, D. M.; Sun, J. H.; Fan, M. H. J. Hazard. Mater. 2020, 399, 123017. doi: 10.1016/j.jhazmat.2020.123017 doi: 10.1016/j.jhazmat.2020.123017
9. [9]
  Guo, L. X.; Chen, Y. D.; Ren, Z. Q.; Li, X.; Zhang, Q. W.; Wu, J. Z.; Li, Y. Q.; Liu, W. L.; Li, P.; Fu, Y. M.; et al. Ultrason. Sonochem. 2021, 81, 105849. doi: 10.1016/j.ultsonch.2021.105849 doi: 10.1016/j.ultsonch.2021.105849
10. [10]
  Guo, R. B.; Zeng, D. D.; Xie, Y.; Ling, Y.; Zhou, D.; Jiang, L. S.; Jiao, W. Y.; Zhao, J. S.; Li, S. Q. Int. J. Hydrog. Energy 2020, 45, 22534. doi: 10.1016/j.ijhydene.2020.06.096 doi: 10.1016/j.ijhydene.2020.06.096
11. [11]
  Wang, F. L.; Chen, P.; Feng, Y. P.; Xie, Z. J.; Liu, Y.; Su, Y. H.; Zhang, Q. X.; Wang, Y. F.; Yao, K.; Lv, W. Y.; et al. Appl. Catal. B 2017, 207, 103. doi: 10.1016/j.apcatb.2017.02.024 doi: 10.1016/j.apcatb.2017.02.024
12. [12]
  An, R. S.; Zhao, Y.; Bai, H. C.; Wang, L.; Li, C. H. J. Solid State Chem. 2022, 306, 122722. doi: 10.1016/j.jssc.2021.122722 doi: 10.1016/j.jssc.2021.122722
13. [13]
  Li, H.; Deng, F.; Zheng, Y.; Hua, L.; Qu, C. H.; Luo, X. B. Environ. Sci. : Nano 2019, 6, 3670. doi: 10.1039/C9EN00957D doi: 10.1039/C9EN00957D
14. [14]
  Dong, S. Y.; Xia, L. J.; Chen, X. Y.; Cui, L. F.; Zhu, W.; Lu, Z. S.; Sun, J. H.; Fan, M. H. Compos. Part B 2021, 215, 108765. doi: 10.1016/j.compositesb.2021.108765 doi: 10.1016/j.compositesb.2021.108765
15. [15]
  Fu, Y. M.; Ren, Z. Q.; Wu, J. Z.; Li, Y. Q.; Liu, W. L.; Li, P.; Xing, L. L.; Ma, J.; Wang, H.; Xue, X. Y. Appl. Catal. B 2021, 285, 119785. doi: 10.1016/j.apcatb.2020.119785 doi: 10.1016/j.apcatb.2020.119785
16. [16]
  Guo, J. Q.; Liao, X.; Lee, M. H.; Hyett, G.; Huang, C. C.; Hewak, D. W.; Mailis, S.; Zhou, W.; Jiang, Z. Appl. Catal. B 2019, 243, 502. doi: 10.1016/j.apcatb.2018.09.089 doi: 10.1016/j.apcatb.2018.09.089
17. [17]
  Miao, Z. R.; Wang, Q. L.; Zhang, Y. F.; Meng, L. P.; Wang, X. X. Appl. Catal. B 2022, 301, 120802. doi: 10.1016/j.apcatb.2021.120802 doi: 10.1016/j.apcatb.2021.120802
18. [18]
  Li, L. L.; Ma, D. K.; Xu, Q. L.; Huang, S. M. Chem. Eng. J. 2022, 437, 135153. doi: 10.1016/j.cej.2022.135153 doi: 10.1016/j.cej.2022.135153
19. [19]
  Wu, Y. Y.; Ji, H. D.; Liu, Q. M.; Sun, Z. Y.; Li, P. S.; Ding, P. R.; Guo, M.; Yi, X. H.; Xu, W. L.; Wang, C. C.; et al. J. Hazard. Mater. 2022, 424, 127563. doi: 10.1016/j.jhazmat.2021.127563 doi: 10.1016/j.jhazmat.2021.127563
20. [20]
  Li, N.; Han, L.; Zhang, H. N.; Huang, J. T.; Luo, X. D.; Li, X. B.; Wang, Y. H.; Qian, W. Q.; Yang, Y. Nano Res. 2022, 15, 8836. doi: 10.1007/s12274-022-4588-8 doi: 10.1007/s12274-022-4588-8
21. [21]
  Li, X. B.; Liu, Q.; Deng, F.; Huang, J. T.; Han, L.; He, C. Z.; Chen, Z.; Luo, Y. D.; Zhu, Y. F. Appl. Catal. B 2022, 314, 121502. doi: 10.1016/j.apcatb.2022.121502 doi: 10.1016/j.apcatb.2022.121502
22. [22]
  Li, X. B.; Luo, Q. N.; Han, L.; Deng, F.; Yang, Y.; Dong, F. J. Mater. Sci. Technol. 2022, 114, 222. doi: 10.1016/j.jmst.2021.10.030 doi: 10.1016/j.jmst.2021.10.030
23. [23]
  Zhao, G. Q.; Hu, J.; Zou, J.; Long, X.; Jiao, F. P. J. Environ. Chem. Eng. 2022, 10, 107226. doi: 10.1016/j.jece.2022.107226 doi: 10.1016/j.jece.2022.107226
24. [24]
  Li, S. J.; Cai, M. J.; Liu, Y. P.; Wang, C. C.; Lv, K. L.; Chen, X. B. Chin. J. Catal. 2022, 43, 2652. doi: 10.1016/S1872-2067(22)64106-8 doi: 10.1016/S1872-2067(22)64106-8
25. [25]
  Guo, Y. C.; Yan, B. G.; Deng, F.; Shao, P. H.; Zou, J. P.; Luo, X. B.; Zhang, S. Q.; Li, X. B. Chin. Chem. Lett. 2022, doi: 10.1016/j.cclet.2022.04.066 doi: 10.1016/j.cclet.2022.04.066
26. [26]
  Deng, J.; Lei, W. Y.; Fu, J. W.; Jin, H. L.; Xu, Q. L.; Wang, S. Sol. RRL 2022, 6, 202200279. doi: 10.1002/solr.202200279 doi: 10.1002/solr.202200279
27. [27]
  Wang, W. L.; Zhang, H. C.; Chen, Y. G.; Shi, H. F. Acta Phys. - Chim. Sin. 2022, 38 (7), 2201008.
28. [28]
  Li, S. J.; Cai, M. J.; Wang, C. C.; Liu, Y. P.; Li, N.; Zhang, P.; Li, X. J. Mater. Sci. Technol. 2022, 123, 177. doi: 10.1016/j.jmst.2022.02.012 doi: 10.1016/j.jmst.2022.02.012
29. [29]
  Li, S. J.; Cai, M. J.; Liu, Y. P.; Wang, C. C.; Yan, R. Y.; Chen, X. B. Adv. Powder Mater. 2023, 2, 100073. doi: 10.1016/j.apmate.2022.100073 doi: 10.1016/j.apmate.2022.100073
30. [30]
  Li, S. J.; Wang, C. C.; Cai, M. J.; Yang, F.; Liu, Y. P.; Chen, J. L.; Zhang, P.; Li, X.; Chem. Eng. J. 2022, 428, 131158. doi: 10.1016/j.cej.2021.131158 doi: 10.1016/j.cej.2021.131158
31. [31]
  Li, S. J.; Wang, C. C.; Cai, M. J.; Liu, Y. P.; Dong, K. X.; Zhang, J. L. J. Colloid Interface Sci. 2022, 624, 219. doi: 10.1016/j.jcis.2022.05.151 doi: 10.1016/j.jcis.2022.05.151
32. [32]
  Liu, T. T.; Wang, Y. W. Inorg. Chem. Commun. 2020, 114, 107846. doi: 10.1016/j.inoche.2020.107846 doi: 10.1016/j.inoche.2020.107846
33. [33]
  Han, G. W.; Xu, F. Y.; Cheng, B.; Li, Y. J.; Yu, J. G.; Zhang, L. Y. Acta Phys. -Chim. Sin. 2022, 38 (7), 2112037.
34. [34]
  Liu, B. W.; Bie, C. B.; Zhang, Y.; Wang, L. X.; Li, Y. J.; Yu, J. G. Langmuir 2021, 37, 14114. doi: 10.1021/acs.langmuir.1c02360 doi: 10.1021/acs.langmuir.1c02360
35. [35]
  Vinoth, S.; Pandikumar, A. Renew. Energy 2021, 173, 507. doi: 10.1016/j.renene.2021.03.121 doi: 10.1016/j.renene.2021.03.121
36. [36]
  Liu, D. N.; Chen, D. Y.; Li, N. J.; Xu, Q. F.; Li, H.; He, J. H.; Lu, J. M. Angew. Chem. Int. Ed. 2020, 59, 4519. doi: 10.1002/anie.201914949 doi: 10.1002/anie.201914949
37. [37]
  Wang, Z. L.; Cheng, B.; Zhang, L. Y.; Yu, J. G.; Tan, H. Y. Sol. RRL 2022, 6, 2100587. doi: 10.1002/solr.202100587 doi: 10.1002/solr.202100587
38. [38]
  Zhang, L. Y.; Zhang, J. J.; Yu, H. G.; Yu, J. G. Adv. Mater. 2022, 34, 2107668. doi: 10.1002/adma.202107668 doi: 10.1002/adma.202107668
39. [39]
  Xu, Q. L.; Zhang, L. Y.; Cheng, B.; Fan, J. J.; Yu, J. G. Chem. 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
40. [40]
  Xu, Q. L.; Wageh, S.; Al-Ghamdi, A. A.; Li, X. J. Mater. Sci. Technol. 2022, 124, 171. doi: 10.1016/j.jmst.2022.02.016 doi: 10.1016/j.jmst.2022.02.016
41. [41]
  Wageh, S.; Al-Ghamdi, A. A.; Jafer, R.; Xin, L.; Peng, Z. Chin. J. Catal. 2021, 42, 667. doi: 10.1016/s1872-2067(20)63705-6 doi: 10.1016/s1872-2067(20)63705-6
42. [42]
  Li, X. B.; Xiong, J.; Gao, X. M.; Ma, J.; Chen, Z.; Kang, B. B.; Liu, J. Y.; Li, H.; Feng, Z. J.; Huang, J. T. J. Hazard. Mater. 2020, 387, 121690. doi: 10.1016/j.jhazmat.2019.121690 doi: 10.1016/j.jhazmat.2019.121690
43. [43]
  Wang, L.; Chen, D. L.; Miao, S. Q.; Chen, F.; Guo, C. F.; Ye, P. C.; Ning, J. Q.; Zhong, Y. J.; Hu, Y. Chem. Eng. J. 2022, 434, 133867. doi: 10.1016/j.cej.2021.133867 doi: 10.1016/j.cej.2021.133867
44. [44]
  Li, X. B.; Kang, B. B.; Dong, F.; Zhang, Z. Q.; Luo, X. D.; Han, L.; Huang, J. T.; Feng, Z. J.; Chen, Z.; Xu, J. L.; et al. Nano Energy 2021, 81, 105671. doi: 10.1016/j.nanoen.2020.105671 doi: 10.1016/j.nanoen.2020.105671
45. [45]
  Liu, Y.; Hao, X. Q.; Hu, H. Q.; Jin, Z. L. Acta Phys. -Chim. Sin. 2021, 37, 2008030.
46. [46]
  Li, X. B.; Liu, J. Y.; Huang, J. T.; He, C. Z.; Feng, Z. J.; Chen, Z.; Wan, L. Y.; Deng, F. Acta Phys. -Chim. Sin. 2021, 37, 2010030.
47. [47]
  Lian, X. Y.; Chen, S. H.; He, F. Y.; Dong, S.; Liu, E. Z.; Li, H.; Xu, K. Z. Sep. Purif. Technol. 2022, 286, 120449. doi: 10.1016/j.seppur.2022.120449 doi: 10.1016/j.seppur.2022.120449
48. [48]
  Li, X. B.; Xiong, J.; Gao, X. M.; Huang, J. T.; Feng, Z. J.; Chen, Z.; Zhu, Y. F. J. Alloy. Compd. 2019, 802, 196. doi: 10.1016/j.jallcom.2019.06.185 doi: 10.1016/j.jallcom.2019.06.185
49. [49]
  Hu, Y.; Li, X. B.; Wang, W. W.; Deng, F.; Han, L.; Gao, X. M.; Feng, Z. J.; Chen, Z.; Huang, J. T.; Zeng, F. Y.; et al. Chin. J. Struct. Chem. 2022, 41 (6), 2206069. doi: 10.14102/j.cnki.0254-5861.2022-0103 doi: 10.14102/j.cnki.0254-5861.2022-0103
50. [50]
  Shen, R. C.; Hao, L.; Chen, Q.; Zheng, Q. Q.; Zhang, P.; Li, X. Acta Phys. -Chim. Sin. 2022, 38, 2110014.
51. [51]
  Shen, R. C.; He, K. L.; Zhang, A. P.; Li, N.; Ng, Y. H.; Zhang, P.; Hu, J.; Li, X. Appl. Catal. B 2021, 291, 120104. doi: 10.1016/j.apcatb.2021.120104 doi: 10.1016/j.apcatb.2021.120104
52. [52]
  Zou, J.; Liao, G. D.; Jiang, J. Z.; Xiong, Z. G.; Bai, S. S.; Wang, H. T.; Wu, P. X.; Zhang, P.; Li, X. Chin. J. Struct. Chem. 2022, 41, 25. doi: 10.14102/j.cnki.0254-5861.2021-0039 doi: 10.14102/j.cnki.0254-5861.2021-0039
53. [53]
  Liu, J. J.; Fu, W.; Liao, Y. L.; Fan, J. J.; Xiang, Q. J. J. Mater. Sci. Technol. 2021, 91, 224. doi: 10.1016/j.jmst.2021.03.017 doi: 10.1016/j.jmst.2021.03.017
54. [54]
  Cao, S.; Low, J.; Yu, J.; Jaroniec, M. Adv Mater. 2015, 27. doi: 10.1002/adma.201500033 doi: 10.1002/adma.201500033
55. [55]
  Wang, Y.; Yu, H. T.; Wang, D. B.; Xing, M. M.; Zhang, Y. N.; Song, C. X. Chem. Eng. J. 2022, 437, 135321. doi: 10.1016/j.cej.2022.135321 doi: 10.1016/j.cej.2022.135321
56. [56]
  Lee, J. S.; Kumar, A.; Yang, T.; Liu, X. H.; Jadhav, A. R.; Park, G. H.; Hwang, Y.; Yu, J. M.; Nguyen, T. K. C.; Liu, Y.; et al. Energy Environ. Sci. 2020, 13, 5152. doi: 10.1039/d0ee03183f doi: 10.1039/d0ee03183f
57. [57]
  Zhou, J.; Yang, Y.; Zhang, C. Y. Chem. Commun. 2013, 49, 8605. doi: 10.1039/c3cc42266f doi: 10.1039/c3cc42266f
58. [58]
  Lin, X.; Liu, C.; Wang, J. B.; Yang, S.; Shi, J. Y.; Hong, Y. Z. Sep. Purif. Technol. 2019, 226, 117. doi: 10.1016/j.seppur.2019.05.093 doi: 10.1016/j.seppur.2019.05.093
59. [59]
  Moon, G. H.; Kim, W.; Bokare, A. D.; Sung, N. E.; Choi, W. Energy Environ. Sci. 2014, 7, 4023. doi: 10.1039/C4EE02757D doi: 10.1039/C4EE02757D
60. [60]
  Ong, W. J.; Putri, L. K.; Tan, Y. C.; Tan, L. L.; Li, N.; Ng, Y. H.; Wen, X.; Chai, S. Nano Res. 2017, 10, 1673. doi: 10.1007/s12274-016-1391-4 doi: 10.1007/s12274-016-1391-4
61. [61]
  Xiong, J.; Li, X. B.; Huang, J. T.; Gao, X. M.; Chen, Z.; Liu, J. Y.; Li, H.; Kang, B. B.; Yao, W. Q.; Zhu, Y. F. Appl. Catal. B 2020, 266, 118602. doi: 10.1016/j.apcatb.2020.118602 doi: 10.1016/j.apcatb.2020.118602
62. [62]
  Chen, G. H.; Wang, Y.; Shen, Q. Y.; Xiong, X. Q.; Ren, S. B.; Dai, G. L.; Wu, C. C. Ceram. Int. 2020, 46, 21304. doi: 10.1016/j.ceramint.2020.05.224 doi: 10.1016/j.ceramint.2020.05.224
63. [63]
  Liu, X.; Wang, P.; Liang, X.; Zhang, Q.; Wang, Z.; Liu, Y.; Zheng, Z.; Dai, Y.; Huang, B. Today Energy 2020, 18, 100524. doi: 10.1016/j.mtener.2020.100524 doi: 10.1016/j.mtener.2020.100524
64. [64]
  Chen, J. Y.; Xiao, X. Y.; Wang, Y.; Lu, M. L.; Zeng, X. Y. J. Alloy. Compd. 2019, 800, 88. doi: 10.1016/j.jallcom.2019.06.004 doi: 10.1016/j.jallcom.2019.06.004
65. [65]
  Li, Y. B.; Zhang, H. M.; Liu, P. R.; Wang, D.; Li, Y.; Zhao, H. J. Small 2013, 9, 3336. doi: 10.1002/smll.201203135 doi: 10.1002/smll.201203135
66. [66]
  Wang, W. W.; Li, X. B.; Deng, F.; Liu, J. Y.; Gao, X. M.; Huang, J. T.; Xu, J. L.; Feng, Z. J.; Chen, Z.; Han, L. Chin. Chem. Lett. 2022, 33, 5200. doi: 10.1016/j.cclet.2022.01.058 doi: 10.1016/j.cclet.2022.01.058
67. [67]
  Xu, Q. L.; Ma, D. K.; Yang, S. B.; Tian, Z. F.; Cheng, B.; Fan, J. J. Appl. Surf. Sci. 2019, 495, 143555. doi: 10.1016/j.apsusc.2019.143555 doi: 10.1016/j.apsusc.2019.143555
68. [68]
  Xian, T.; Li, H. Q.; Gao, Y. S.; Sun, X. F.; Di, L. J.; Yang, H. Opt. Mater. 2022, 123, 111842. doi: 10.1016/j.optmat.2021.111842 doi: 10.1016/j.optmat.2021.111842
69. [69]
  Li, H. P.; Hu, T. X.; Du, N.; Zhang, R. J.; Liu, J. Q.; Hou, W. G. Appl. Catal. B 2016, 187, 342. doi: 10.1016/j.apcatb.2016.01.053 doi: 10.1016/j.apcatb.2016.01.053
70. [70]
  Mei, F. F.; Dai, K.; Zhang, J. F.; Li, W. Y.; Liang, C. H. Appl. Surf. Sci. 2019, 488, 151. doi: 10.1016/j.apsusc.2019.05.257 doi: 10.1016/j.apsusc.2019.05.257
71. [71]
  Wang, Y.; Liu, Q.; Wong, N. H.; Sunarso, J.; Huang, J. T.; Dai, G. L.; Hou, X. F.; Li, X. B. Ceram. Int. 2022, 48, 2459. doi: 10.1016/j.ceramint.2021.10.027 doi: 10.1016/j.ceramint.2021.10.027
72. [72]
  Dang, L. Y.; Liu, M. Q.; Wang, G. G.; Zhao, D. Q.; Han, J. C.; Zhu, J. Q.; Liu, Z. Adv. Funct. Mater. 2022, 32. 2201020 doi: 10.1002/adfm.202201020 doi: 10.1002/adfm.202201020
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6. [6]
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8. [8]
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17. [17]
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18. [18]
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19. [19]
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

0D/2D Carbon Nitride Quantum Dots (CNQDs)/BiOBr S-Scheme Heterojunction for Robust Photocatalytic Degradation and H2O2 Production

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通讯作者: 陈斌, bchen63@163.com

0D/2D Carbon Nitride Quantum Dots (CNQDs)/BiOBr S-Scheme Heterojunction for Robust Photocatalytic Degradation and H₂O₂ Production