Citation: Ruyao Chen, Jiazeng Xia, Yigang Chen, Haifeng Shi. S-Scheme-Enhanced PMS Activation for Rapidly Degrading Tetracycline Using CuWO_4−x/Bi₁₂O₁₇Cl₂ Heterostructures[J]. Acta Physico-Chimica Sinica, ;2023, 39(6): 220901. doi: 10.3866/PKU.WHXB202209012 shu

S-Scheme-Enhanced PMS Activation for Rapidly Degrading Tetracycline Using CuWO_4−x/Bi₁₂O₁₇Cl₂ Heterostructures

Ruyao Chen ^{1, †} ,
Jiazeng Xia ^{2, †} ,
Yigang Chen ^2,, ,
Haifeng Shi ^{1, 3,,}

1.
School of Science, Jiangnan University, Wuxi 214122, Jiangsu Province, China
2.
Department of General Surgery, Wuxi No.2 People's Hospital, Affiliated Wuxi Clinical College of Nantong University, Wuxi 214002, Jiangsu Province, China
3.
National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China

Corresponding author: Yigang Chen, hfshi@jiangnan.edu.cn Haifeng Shi, wuxichen2512@njmu.edu.cn

^†

Received Date: 9 September 2022
Revised Date: 23 September 2022
Accepted Date: 30 September 2022
Available Online: 8 October 2022
Fund Project: the National Natural Science Foundation of China 22136002the National Natural Science Foundation of China 22172064the Special Fund Project of Jiangsu Province for Scientific and Technological Innovation in Carbon Peaking and Carbon Neutrality, China BK20220023the Project of Wuxi Science and Technology Development Fund, China Y20212004National Laboratory of Solid State Microstructures, Nanjing University, China M34047

The peroxymonosulfate (PMS) activation reaction based on photocatalysts has been widely employed for the removal of tetracycline (TC) and other antibiotics. The photocatalyst comprising CuWO₄ decorated with oxygen vacancies has attracted research attention owing to its narrow band gap, favorable oxidation ability, and good charge transfer efficiency. A single-component photocatalyst can influence the PMS activation efficiency due to the rapid recombination between photogenerated electron and hole pairs. Herein, oxygen vacancy-decorated CuWO_4−x/Bi₁₂O₁₇Cl₂ (CovB) photocatalysts were fabricated, and enabled an enhancement in the PMS activation efficiency for TC removal under visible-light irradiation. The crystalline structures and optical properties of CovB were measured by field-emission scanning electron microscopy, transmission electron microscopy, and UV-visible diffuse reflectance spectroscopy. Characterization of the O 1s bond by electron paramagnetic resonance (EPR) analyses and X-ray photoelectron spectra (XPS) showed that the oxygen vacancies were successfully introduced into the composites. CovB-30 (mass ratio of CuWO_4−x to Bi₁₂O₁₇Cl₂ was 3 : 7) achieved a TC removal rate of 94.74% in 30 min in the PMS activation system. The degradation efficiencies of CovB-30 were 2.67 and 2.21 times higher than those of CuWO₄ and Bi₁₂O₁₇Cl₂, respectively. The enhanced TC elimination performance can be ascribed to the synergetic effect between photocatalysis and the PMS activation reaction, which were promoted by the S-scheme heterojunction. The S-scheme heterojunction structure could maintain an excellent redox ability under light irradiation and generate an internal electric field, which possessed the ability to prevent the recombination of photogenerated carriers. The photoluminescence (PL) measurements and time-resolved photoluminescence (TRPL) spectra confirmed that the formation of the S-scheme heterojunction effectively increased the migration rates and separation efficiency of photogenerated hole and electron pairs, facilitating the activation of PMS for TC removal. CovB-30 retained the ability to eliminate TC in a wide pH range of 3.0–11.0 and different inorganic anion systems. The XPS profiles of fresh and used samples indicated that the Cu²⁺/Cu⁺ redox cycle and oxygen vacancies both participated in the activation of PMS. XPS analysis and experimental capture results illustrated that the charge transfer mechanism of the CovB composite followed that of an S-scheme heterojunction photocatalyst. CovB-30 maintained excellent PMS activation ability over a wide pH range of 3.0–11.0. This paper discusses the possible TC degradation pathways in the PMS activation system on the basis of the generated intermediates. Quenching experiments were conducted, and demonstrated that SO₄^•−/∙OH/∙O₂⁻/h⁺/¹O₂ served as the reactive species in TC removal. The CovB-30 composite possessed remarkable photocatalytic activity after five consecutive cycles, illustrating that it could be utilized for practical antibiotic degradation. This work proposes a promising method of introducing oxygen vacancies into an S-scheme photocatalyst for efficient PMS activation.
- CuWO₄,
- Bi₁₂O₁₇Cl₂,
- Peroxymonosulfate,
- Tetracycline,
- S-scheme
1. [1]
  Shi, H. Y.; Li, Y.; Wang, X. F.; Yu, H. G.; Yu, J. G. Appl. Catal. B Environ. 2021, 297, 120414. doi: 10.1016/j.apcatb.2021.120414 doi: 10.1016/j.apcatb.2021.120414
2. [2]
  Cai, S.; Zuo, X. X.; Zhao, H. Y.; Yang, S. J.; Chen, R. Z.; Chen, L. W.; Zhang, R. H.; Ding, D. H.; Cai, T. M. J. Mater. Chem. A 2022, 10, 9171. doi: 10.1039/D2TA00153E doi: 10.1039/D2TA00153E
3. [3]
  Ye, J. W.; Cheng, B.; Yu, J. G.; Ho, W. K.; Wageh, S.; Al-Ghamdi, A. A. Appl. Catal. B Environ. 2022, 430, 132715. doi: 10.1016/j.cej.2021.132715 doi: 10.1016/j.cej.2021.132715
4. [4]
  Cherifi, Y.; Addad, A.; Vezin, H.; Barras, A.; Ouddane, B.; Chaouchi, A.; Szunerits, S.; Boukherroub, R. Ultrason. Sonochem. 2019, 52, 164. doi: 10.1016/j.ultsonch.2018.11.012 doi: 10.1016/j.ultsonch.2018.11.012
5. [5]
  Liu, S. Y.; Zada, A.; Yu, X. Y.; Liu, F. Z.; Jin, G. Chemosphere 2022, 307, 135717. doi: 10.1016/j.chemosphere.2022.135717 doi: 10.1016/j.chemosphere.2022.135717
6. [6]
  Huang, C. F.; Wen, Y. P.; Ma, J.; Dong, D. D.; Shen, Y. F.; Liu, S. Q.; Ma, H. B.; Zhang, Y. J. Nat. Commun. 2021, 12, 320. doi: 10.1038/s41467-020-20521-5 doi: 10.1038/s41467-020-20521-5
7. [7]
  Han, G. W.; Xu, F. Y., Cheng, B., Li, Y. J., Yu, J. G., Zhang, L. Y. Acta Phys. -Chim. Sin. 2022, 38, 2112037. doi: 10.3866/PKU.WHXB202112037
8. [8]
  Yan, Q. Y.; Lian, C.; Huang, K.; Liang, L. H.; Yu, H. R.; Yin, P. C.; Zhang, J. L.; Xing, M. Y. Angew. Chem. Int. Ed. 2021, 60, 17155. doi: 10.1002/anie.202105736 doi: 10.1002/anie.202105736
9. [9]
  Zhao, W. L.; Wang, W. L.; Han, T. Y.; Wang, H. T.; Zhang, H. C.; Shi, H. F. Sep. Purif. Technol. 2021, 269, 118693. doi: 10.1016/j.seppur.2021.118693 doi: 10.1016/j.seppur.2021.118693
10. [10]
  Sabri, M.; Habibi-Yangjeh, A.; Ghosh, S. J. Photochem. Photobiol. A 2020, 391, 112397. doi: 10.1016/j.jphotochem.2020.112397 doi: 10.1016/j.jphotochem.2020.112397
11. [11]
  Li, J. B.; Yi, Y.; Shi, P. H.; Wang, Q.; Li, D. X.; Asif, H.; Yang, M. Acta Phys. -Chim. Sin. 2014, 30, 1720. doi: 10.3866/PKU.WHXB201407021
12. [12]
  Ming, H. B.; Wei, D. L.; Yang, Y.; Chen, B. Q.; Yang, C.; Zhang, J. S.; Hou, Y. D. Chem. Eng. J. 2021, 424, 130296. doi: 10.1016/j.cej.2021.130296 doi: 10.1016/j.cej.2021.130296
13. [13]
  Gao, H. H.; Yang, H. C.; Xu, J. Z.; Zhang, S. W.; Li, J. X. Small 2018, 14, 1801353. doi: 10.1002/smll.201801353 doi: 10.1002/smll.201801353
14. [14]
  Sarkar, P.; De, S.; Neogi, S. Appl. Catal. B Environ. 2022, 307, 121165. doi: 10.1016/j.apcatb.2022.121165 doi: 10.1016/j.apcatb.2022.121165
15. [15]
  Xu, L.; Liu, L. F. Appl. Catal. B Environ. 2022, 304, 120953. doi: 10.1016/j.apcatb.2021.120953 doi: 10.1016/j.apcatb.2021.120953
16. [16]
  Wang, W. X.; Liu, Y.; Yue, Y. F.; Wang, H. H.; Cheng, G.; Gao, C. Y.; Chen, C. L.; Ai, Y. J.; Chen, Z.; Wang, X. K. ACS Catal. 2021, 11, 11256. doi: 10.1021/acscatal.1c03331 doi: 10.1021/acscatal.1c03331
17. [17]
  Liu, W.; Zhou, J. B.; Zhou, Y.; Liu, D. Sep. Purif. Technol. 2021, 264, 118288. doi: 10.1016/j.seppur.2020.118288 doi: 10.1016/j.seppur.2020.118288
18. [18]
  Wang, M.; Jin, C. Y.; Kang, J.; Liu, J. Y.; Tang, Y. W.; Li, Z. L.; Li, S. Y. Chem. Eng. J. 2021, 416, 128118. doi: 10.1016/j.cej.2020.128118 doi: 10.1016/j.cej.2020.128118
19. [19]
  Rosa, W. S.; Rabelo, L. G.; Tiveron Zampaulo, L. G.; Gonçalves, R. V. ACS Appl. Mater. Interfaces 2022, 14, 22858. doi: 10.1021/acsami.1c21001 doi: 10.1021/acsami.1c21001
20. [20]
  Huang, R. Y.; Gu, X.; Sun, W. Z.; Chen, L.; Du, Q. Y.; Guo, X.; Lia, J.; Zhang, M. W.; Li, C. F. Sep. Purif. Technol. 2020, 250, 117174. doi: 10.1016/j.seppur.2020.117174 doi: 10.1016/j.seppur.2020.117174
21. [21]
  Chen, R. Y.; Dou, X. C.; Xia, J. Z.; Chen, Y. G.; Shi, H. F. Sep. Purif. Technol. 2022, 296, 121345. doi: 10.1016/j.seppur.2022.121345 doi: 10.1016/j.seppur.2022.121345
22. [22]
  Zhang, H.; Yilmaz, P.; Ansari, J. O.; Khan, F. F.; Binions, R.; Krause, S.; Dunn, S. J. Mater. Chem. A 2015, 3, 9638. doi: 10.1039/C4TA07213H doi: 10.1039/C4TA07213H
23. [23]
  Shadabipour, P.; Raithel, A. L.; Hamann, T. W. ACS Appl. Mater. Interfaces 2020, 12, 50592. doi: 10.1021/acsami.0c14705 doi: 10.1021/acsami.0c14705
24. [24]
  Dashtian, K.; Ghaedi, M.; Shirinzadeh, H.; Hajati, S.; Shahbazi, S. Chem. Eng. J. 2018, 339, 189. doi: 10.1016/j.cej.2018.01.107 doi: 10.1016/j.cej.2018.01.107
25. [25]
  Wen, M.; Wang, S.; Jiang, R. Q.; Wang, Y.; Wang, Z. J.; Yu, W. J.; Geng, P.; Xia, J. D.; Li, M. Q.; Chen, Z. G. Biomater. Sci. 2019, 7, 4651. doi: 10.1039/C9BM00995G doi: 10.1039/C9BM00995G
26. [26]
  Ma, Z.; Linnenberg, O.; Rokicinska, A.; Kustrowski, P.; Slabon, A. J. Phys. Chem. C 2018, 122, 19281. doi: 10.1021/acs.jpcc.8b02828 doi: 10.1021/acs.jpcc.8b02828
27. [27]
  Guo, W. L.; Duan, Z. Y.; Mabayoje, O.; Chemelewski, W. D.; Xiao, P.; Henkelman, G.; Zhang, Y. H.; Mullins, C. B. J. Electrochem. Soc. 2016, 163, H970. doi: 10.1149/2.0701610jes doi: 10.1149/2.0701610jes
28. [28]
  Bao, X. L.; Wang, X. K.; Li, X. Q.; Qin, L. X.; Han, S.; Kang, S. Z. Mater. Res. Bull. 2021, 136, 111171. doi: 10.1016/j.materresbull.2020.111171 doi: 10.1016/j.materresbull.2020.111171
29. [29]
  Guo, W. L; Wang, Y.; Lian, X.; Nie, Y.; Tian, S. J.; Wang, S. S.; Zhou, Y.; Henkelman, G. Catal. Sci. Technol. 2020, 10, 7344. doi: 10.1039/D0CY01430C doi: 10.1039/D0CY01430C
30. [30]
  Chu, D. W.; Zhao, C. Catal. Today 2020, 351, 125. doi: 10.1016/j.cattod.2018.10.006 doi: 10.1016/j.cattod.2018.10.006
31. [31]
  Yu, R. X.; Zhao, J. H.; Zhao, Z. W.; Cui, F. Y. J. Hazard. Mater. 2020, 390, 121998. doi: 10.1016/j.j hazmat.2019.121998 doi: 10.1016/j.jhazmat.2019.121998
32. [32]
  Zhang, H. X.; Li, C. W.; Lyu, L.; Hu, C. Appl. Catal. B Environ. 2020, 270, 118874. doi: 10.1016/j.apcatb.2020.118874 doi: 10.1016/j.apcatb.2020.118874
33. [33]
  Ye, J.; Dai, J. D.; Yang, D. Y.; Li, C. X.; Yan, Y. S.; Wang, Y. J. Hazard. Mater. 2022, 421, 126715. doi: 10.1016/j.jhazmat.2021.126715 doi: 10.1016/j.jhazmat.2021.126715
34. [34]
  Yang, H.; Zhang, J. F.; Dai, K. Chin. J. Catal. 2022, 43, 255. doi: 10.1016/S1872-2067(20)63784-6 doi: 10.1016/S1872-2067(20)63784-6
35. [35]
  Xu, Q. L.; Zhang, L. Y.; Cheng, B.; Fan, J. J.; Yu, J. G. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
36. [36]
  Fei, X. G.; Tan, H. Y.; Cheng, B.; Zhu, B. C.; Zhang, L. Y. Acta Phys. -Chim. Sin. 2022, 37, 2010027. doi: 10.3866/PKU.WHXB202010027
37. [37]
  Wang, W. L.; Zhang, H. C.; Chen, Y. G.; Shi, H. F. Acta Phys. -Chim. Sin. 2022, 38, 2104030. doi: 10.3866/PKU.WHXB202201008
38. [38]
  Zhang, L. Y.; Zhang, J. J.; Yu, H. G.; Yu, J. G. Adv. Mater. 2022, 34, 2107668. doi: 10.1002/adma.202107668 doi: 10.1002/adma.202107668
39. [39]
  Li, X.; Wang, Z.; Zhang, J.; Dai, K.; Fan, K.; Dawson, G. Mater. Today Phys. 2022, 26, 100729. doi: 10.1016/j.mtphys.2022.100729 doi: 10.1016/j.mtphys.2022.100729
40. [40]
  Xia, P. F.; Cao, S. W.; Zhu, B. C.; Liu, M. J.; Shi, M. S.; Yu, J. G.; Zhang, Y. F. Angew. Chem. Int. Ed. 2020, 59, 5218. doi: 10.1002/anie.201916012 doi: 10.1002/anie.201916012
41. [41]
  Li, Q. Q.; Zhao, W. L.; Zhai, Z. C.; Ren, K. X.; Wang, T. Y.; Guan, H.; Shi, H. F. J. Mater. Sci. Technol. 2020, 56, 216. doi: 10.1016/j.jmst.2020.03.038 doi: 10.1016/j.jmst.2020.03.038
42. [42]
  Wang, W. L.; Zhao, W. L.; Zhang, H. C.; Dou, X. C.; Shi, H. F. Chin. J. Catal. 2021, 42, 97. doi: 10.1016/S1872-2067(20)63602-6 doi: 10.1016/S1872-2067(20)63602-6
43. [43]
  Zhao, Z. W.; Li, X. F.; Dai, K.; Zhang, J. F.; Dawson, G. J. Mater. Sci. Technol. 2022, 117, 109. doi: 10.1016/j.jmst.2021.11.046 doi: 10.1016/j.jmst.2021.11.046
44. [44]
  Huang, Y.; Mei, F. F.; Zhang, J. F.; Dai, K.; Dawson, G. Acta Phys. -Chim. Sin. 2022, 38, 2108028. doi: 10.3866/PKU.WHXB202108028
45. [45]
  Mei, F. F.; Li, Z.; Dai, K.; Zhang, J. F.; Liang, C. H. Chin. J. Catal. 2020, 41, 41. doi: 10.1016/S1872-2067(19)63389-9 doi: 10.1016/S1872-2067(19)63389-9
46. [46]
  Zhou, C. Y.; Lai, C.; Xu, P.; Zeng, G. M.; Huang, D. L.; Li, Z. H.; Zhang, C.; Cheng, M.; Hu, L.; Wan, J.; et al. ACS Sustain. Chem. Eng. 2018, 6, 6941. doi: 10.1021/acssuschemeng.8b00782 doi: 10.1021/acssuschemeng.8b00782
47. [47]
  Zhai, Z. C.; Ren, K. X.; Zheng, X. Y.; Chen, Y. G.; Dong, Y. M.; Shi, H. F. Environ. Sci. : Nano 2022, 9, 1780. doi: 10.1039/D2EN00028H doi: 10.1039/D2EN00028H
48. [48]
  Lu, M. F.; Li, Q. Q.; Zhang, C. L.; Fan, X. X.; Li, L.; Dong, Y. M.; Chen, G. Q.; Shi, H. F. Carbon 2020, 160, 342. doi: 10.1016/j.carbon.2020.01.038 doi: 10.1016/j.carbon.2020.01.038
49. [49]
  Liu, Z. F.; Song, Q. G.; Zhou, M.; Guo, Z. G.; Kang, J. H.; Yan, H. Y. Chem. Eng. J. 2019, 374, 554. doi: 10.1016/j.cej.2019.05.191 doi: 10.1016/j.cej.2019.05.191
50. [50]
  Huo, Y.; Zhang, J. F.; Wang, Z. L.; Dai, K.; Pan, C. S.; Liang, C. H. J. Colloid Interface Sci. 2021, 585, 684. doi: 10.1016/j.jcis.2020.10.048 doi: 10.1016/j.jcis.2020.10.048
51. [51]
  Zhu, L. L.; Wu, Y. F.; Wu, S. J.; Dong, F.; Xia, J. X.; Jiang, B. ACS Appl. Mater. Interfaces 2021, 13, 9216. doi: 10.1021/acsami.0c21454 doi: 10.1021/acsami.0c21454
52. [52]
  Li, L.; Yang, L.; Xiong, Y. L.; Peng, L.; Dong, H. M.; Wei, X. J.; Xiao, P.; He, H. C. ACS Sustain. Chem. Eng. 2019, 7, 19640. doi: 10.1021/acssuschemeng.9b04787 doi: 10.1021/acssuschemeng.9b04787
53. [53]
  Liu, S. Y., Ru, J. L., Liu, F. Z. Chemosphere 2021, 267, 129220. doi: 10.1016/j.chemosphere.2020.129220 doi: 10.1016/j.chemosphere.2020.129220
54. [54]
  Biesinger, M. C. Surf. Interface Anal. 2017, 49, 1325. doi: 10.1002/sia.6239 doi: 10.1002/sia.6239
55. [55]
  Chen, H. X.; Xu, Y.; Zhu, K. M.; Zhang, H. Appl. Catal. B Environ. 2021, 284, 119732. doi: 10.1016/j.apcatb.2020.119732 doi: 10.1016/j.apcatb.2020.119732
56. [56]
  Hang, T. T. M.; Vy, N. H. T.; Hanh, N. T.; Pham, T. D. Sustain. Chem. Pharm. 2021, 21, 100407. doi: 10.1016/j.scp.2021.100407 doi: 10.1016/j.scp.2021.100407
57. [57]
  Wang, L.; Min, X. P.; Sui, X. Y.; Chen, J. H.; Wang, Y. J. Colloid Interface Sci. 2020, 560, 21. doi: 10.1016/j.jcis.2019.10.048 doi: 10.1016/j.jcis.2019.10.048
58. [58]
  Hill, J. C.; Choi, K. S. J. Mater. Chem. A 2013, 1, 5006. doi: 10.1039/C3TA10245A doi: 10.1039/C3TA10245A
59. [59]
  Chang, F.; Wu, F. Y.; Zheng, J. J.; Cheng, W. B.; Yan, W. J.; Deng, B. Q.; Hu, X. F. Chemosphere 2018, 210, 257. doi: 10.1016/j.chemosphere.2018.07.010 doi: 10.1016/j.chemosphere.2018.07.010
60. [60]
  Gordon, T. R.; Cargnello, M.; Paik, T.; Mangolini, F.; Weber, R. T.; Fornasiero, P.; Murray, C. B. J. Am. Chem. Soc. 2012, 134, 6751. doi: 10.1021/ja300823a doi: 10.1021/ja300823a
61. [61]
  Lim, J. H.; Yang, Y.; Hoffmann, M. R. Environ. Sci. Technol. 2019, 53, 6972. doi: 10.1021/acs.est.9b01449 doi: 10.1021/acs.est.9b01449
62. [62]
  Qin, Q. D.; Liu, T.; Zhang, J. X.; Wei, R.; You, S. J.; Xu, Y. J. Hazard. Mater. 2021, 419, 126447. doi: 10.1016/j.jhazmat.2021.126447 doi: 10.1016/j.jhazmat.2021.126447
63. [63]
  Dou, X. C.; Chen, Y. G.; Shi, H. F. Chem. Eng. J. 2022, 431, 134054. doi: 10.1016/j.cej.2021.134054 doi: 10.1016/j.cej.2021.134054
64. [64]
  Ma, J.; Chen, L.; Liu, Y.; Xu, T. Y.; Ji, H. D.; Duan, J.; Sun, F. B.; Liu, W. J. Hazard. Mater. 2021, 418, 126180. doi: 10.1016/j.jhazmat.2021.126180 doi: 10.1016/j.jhazmat.2021.126180
65. [65]
  Ren, J.; Jiang, L. S.; Li, Y.; Zhang, G. K. Sep. Purif. Technol. 2021, 275, 119100. doi: 10.1016/j.seppur.2021.119100 doi: 10.1016/j.seppur.2021.119100
66. [66]
  Dai, H. W.; Zhou, W. J.; Wang, W. Chem. Eng. J. 2021, 417, 127921. doi: 10.1016/j.cej.2020.127921 doi: 10.1016/j.cej.2020.127921
67. [67]
  Wang, H.; Gao, Q.; Li, H. T.; Han, B.; Xia, K. S.; Zhou, C. G. Chem. Eng. J. 2019, 368, 377. doi: 10.1016/j.cej.2019.02.124 doi: 10.1016/j.cej.2019.02.124
68. [68]
  Huang, X. X.; Zhu, N. W.; Mao, F. L.; Ding, Y.; Zhang, S. H.; Liu, H. R.; Li, F.; Wu, P. X.; Dang, Z.; Ke, Y. X. Chem. Eng. J. 2020, 392, 123636. doi: 10.1016/j.cej.2019.123636 doi: 10.1016/j.cej.2019.123636
69. [69]
  Huang, K. L.; Li, C. H.; Wang, L.; Wang, W. T.; Meng, X. C. Chem. Eng. J. 2021, 425, 131493. doi: 10.1016/j.cej.2021.131493 doi: 10.1016/j.cej.2021.131493
70. [70]
  Tan, B. H.; Fang, Y.; Chen, Q. L.; Ao, X. Q.; Cao, Y. J. Colloid Interface Sci. 2021, 601, 581. doi: 10.1016/j.jcis.2021.05.155 doi: 10.1016/j.jcis.2021.05.155
71. [71]
  Shi, H. F.; Li, X. K.; Wang, D. F.; Yuan, Y. P.; Zou, Z. G.; Ye, J. H. Catal. Lett. 2009, 132, 205. doi: 10.1007/s10562-009-0087-8 doi: 10.1007/s10562-009-0087-8
72. [72]
  Chen, T.; Zhu, Z. L.; Bao, Y. J.; Zhang, H.; Qiu, Y. L.; Yin, D. Q. Environ. Sci. Nano 2021, 8, 2618. doi: 10.1039/D1EN00426C doi: 10.1039/D1EN00426C
73. [73]
  Zhang, H.; Nengzi, L. C.; Li, X.; Wang, Z.; Li, B.; Liu, L.; Cheng, X. Chem. Eng. J. 2020, 386, 124011. doi: 10.1016/j.cej.2020.124011 doi: 10.1016/j.cej.2020.124011
74. [74]
  Denk, M.; Kuhness, D.; Wagner, M.; Surnev, S.; Negreiros, F. R.; Sementa, L.; Barcaro, G.; Vobornik, I.; Fortunelli, A.; Netzer, F. P. ACS Nano 2014, 8, 3947. doi: 10.1021/nn500867y doi: 10.1021/nn500867y
1. [1]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
2. [2]
  Hongrui Zhang , Miaoying Cui , Yongjie Lv , Yongfang Rao , Yu Huang . A short review on research progress of ZnIn₂S₄-based S-scheme heterojunction: Improvement strategies. Chinese Chemical Letters, 2025, 36(4): 110108-. doi: 10.1016/j.cclet.2024.110108
3. [3]
  Zheng Liu , Yuqing Bian , Graham Dawson , Jiawei Zhu , Kai Dai . Rational constructing of Zn_0.5Cd_0.5S-diethylenetriamine/g-C₃N₄ S-scheme heterojunction with enhanced photocatalytic H₂O₂ production. Chinese Chemical Letters, 2025, 36(9): 111272-. doi: 10.1016/j.cclet.2025.111272
4. [4]
  Yueting Ma , Zhiyan Feng , Yuxin Dong , Zhiyong Yan , Hou Wang , Yan Wu . Harnessing the interfacial sulfur-edge and metal-edge sites in ZnIn₂S₄/MnS heterojunctions boosts charge transfer for photocatalytic hydrogen production. Chinese Chemical Letters, 2025, 36(6): 110922-. doi: 10.1016/j.cclet.2025.110922
5. [5]
  Xin Li , Wanting Fu , Ruiqing Guan , Yue Yuan , Qinmei Zhong , Gang Yao , Sheng-Tao Yang , Liandong Jing , Song Bai . Nucleophiles promotes the decomposition of electrophilic functional groups of tetracycline in ZVI/H₂O₂ system: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(10): 109625-. doi: 10.1016/j.cclet.2024.109625
6. [6]
  Fengrui Yang , Debing Wang , Xinying Zhang , Jie Zhang , Zhichao Wu , Qiaoying Wang . Synergistic effects of peroxydisulfate on UV/O₃ process for tetracycline degradation: Mechanism and pathways. Chinese Chemical Letters, 2024, 35(10): 109599-. doi: 10.1016/j.cclet.2024.109599
7. [7]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
8. [8]
  Tianjun Ni , Hui Zhang , Liping Zhou , Roujie Ma , Yanyu Wang , Zhijun Yang , Dan Luo , Nithima Khaorapapong , Xingtao Xu , Yusuke Yamauchi , Dong Liu . Atomic cobalt catalysts on 3D interconnected g-C₃N₄ support for activation of peroxymonosulfate: The importance of Co-N coordination effect. Chinese Chemical Letters, 2025, 36(9): 110659-. doi: 10.1016/j.cclet.2024.110659
9. [9]
  Le Han , Zhou Yuan , Bohan Li , Yuchi Zhang , Lin Yang , Yan Xu . Highly-stable cesium lead halide perovskite CsPbBr₃/CsPb₂Br₅ heteronanocrystals in zeolitic imidazolate framework-8 for antibiotic photodegradation. Chinese Chemical Letters, 2025, 36(6): 110349-. doi: 10.1016/j.cclet.2024.110349
10. [10]
  Dan-Ying Xing , Xiao-Dan Zhao , Chuan-Shu He , Bo Lai . Kinetic study and DFT calculation on the tetracycline abatement by peracetic acid. Chinese Chemical Letters, 2024, 35(9): 109436-. doi: 10.1016/j.cclet.2023.109436
11. [11]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
12. [12]
  Yu Yao , Jinqiang Zhang , Yantao Wang , Kunsheng Hu , Yangyang Yang , Zhongshuai Zhu , Shuang Zhong , Huayang Zhang , Shaobin Wang , Xiaoguang Duan . Nitrogen-rich carbon for catalytic activation of peroxymonosulfate towards green synthesis. Chinese Chemical Letters, 2024, 35(11): 109633-. doi: 10.1016/j.cclet.2024.109633
13. [13]
  Yinyin Xu , Yuanyuan Li , Jingbo Feng , Chen Wang , Yan Zhang , Yukun Wang , Xiuwen Cheng . Covalent organic frameworks doped with manganese-metal organic framework for peroxymonosulfate activation. Chinese Chemical Letters, 2024, 35(4): 108838-. doi: 10.1016/j.cclet.2023.108838
14. [14]
  Mengmeng Ao , Jian Wei , Chuan-Shu He , Heng Zhang , Zhaokun Xiong , Yonghui Song , Bo Lai . Insight into the activation of peroxymonosulfate by N-doped copper-based carbon for efficient degradation of organic pollutants: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(1): 109882-. doi: 10.1016/j.cclet.2024.109882
15. [15]
  Yun-Xin Huang , Lin-Qian Yu , Ke-Yu Chen , Hao Wang , Shou-Yan Zhao , Bao-Cheng Huang , Ren-Cun Jin . Biochar with self-doped N to activate peroxymonosulfate for bisphenol-A degradation via electron transfer mechanism: The active edge graphitic N site. Chinese Chemical Letters, 2024, 35(9): 109437-. doi: 10.1016/j.cclet.2023.109437
16. [16]
  Huiyuan Deng , Na Zhao , Junjie You , Zhicheng Pan , Bo Xing , Yuling Ye , Bo Lai , Yuxi Wang , Tongrui Lu , Xiaonan Liu . Removal of bisphenol a through peroxymonosulfate activation with N-doped graphite carbon spheres coated cobalt nanoparticles catalyst: Synergy of nonradicals. Chinese Chemical Letters, 2025, 36(8): 110650-. doi: 10.1016/j.cclet.2024.110650
17. [17]
  Siyang Xue , Chen Cheng , Jieqiong Kang , Kaixuan Zheng , Adela Jing Li , Renli Yin . Oxygen vacancies-rich BiOBr bridged direct electron transfer with peroxymonosulfate for integrating superoxide radical and singlet oxygen on selective pollutants degradation. Chinese Chemical Letters, 2025, 36(10): 110776-. doi: 10.1016/j.cclet.2024.110776
18. [18]
  Jiaqi Yang , Xuqiang Hao , Jiejie Jing , Yuqiang Hao , Zhiliang Jin . 3D/2D ReSe₂/ZnCdS S-scheme photocatalyst with efficient interfacial charge separation for optimized hydrogen production. Acta Physico-Chimica Sinica, 2025, 41(10): 100131-0. doi: 10.1016/j.actphy.2025.100131
19. [19]
  Dong Cheng , Youyou Feng , Bingxi Feng , Ke Wang , Guoxin Song , Gen Wang , Xiaoli Cheng , Yonghui Deng , Jing Wei . Polyphenol-mediated interfacial deposition strategy for supported manganese oxide catalysts with excellent pollutant degradation performance. Chinese Chemical Letters, 2024, 35(5): 108623-. doi: 10.1016/j.cclet.2023.108623
20. [20]
  Kexin Yin , Jingren Yang , Yanwei Li , Qian Li , Xing Xu . Metal-free diatomaceous carbon-based catalyst for ultrafast and anti-interference Fenton-like oxidation. Chinese Chemical Letters, 2024, 35(12): 109847-. doi: 10.1016/j.cclet.2024.109847

Get Citation

PDF

XML

Metrics

PDF Downloads(14)
Abstract views(903)
HTML views(99)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

S-Scheme-Enhanced PMS Activation for Rapidly Degrading Tetracycline Using CuWO4−x/Bi12O17Cl2 Heterostructures

Metrics

通讯作者: 陈斌, bchen63@163.com

S-Scheme-Enhanced PMS Activation for Rapidly Degrading Tetracycline Using CuWO_4−x/Bi₁₂O₁₇Cl₂ Heterostructures