Citation: Yuanhao Shen, Qingyu Wang, Jie Liu, Cheng Zhong, Wenbin Hu. Spontaneous Reduction and Adsorption of K₃[Fe(CN)₆] on Zn Anodes in Alkaline Electrolytes: Enabling a Long-Life Zn-Ni Battery[J]. Acta Physico-Chimica Sinica, ;2022, 38(11): 220404. doi: 10.3866/PKU.WHXB202204048 shu

Spontaneous Reduction and Adsorption of K₃[Fe(CN)₆] on Zn Anodes in Alkaline Electrolytes: Enabling a Long-Life Zn-Ni Battery

Yuanhao Shen ¹ ,
Qingyu Wang ¹ ,
Jie Liu ¹ ,
Cheng Zhong ^{1, 2,,} ,
Wenbin Hu ^{1, 2}

1.
Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
2.
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou 350207, China

Corresponding author: Cheng Zhong, cheng.zhong@tju.edu.cn
Received Date: 26 April 2022
Revised Date: 5 June 2022
Accepted Date: 19 June 2022
Available Online: 27 June 2022
Fund Project: the National Natural Science Foundation of China 52125404the National Natural Science Foundation of China 51722403the Tianjin Natural Science Foundation 18JCJQJC46500the Natural Science Foundation of Guangdong Province U1601216

In view of the continuously worsening environmental problems, fossil fuels will not be able to support the development of human life in the future. Hence, it is of great importance to work on the efficient utilization of cleaner energy resources. In this case, cheap, reliable, and eco-friendly grid-scale energy storage systems can play a key role in optimizing our energy usage. When compared with lithium-ion and lead-acid batteries, the excellent safety, environmental benignity, and low toxicity of aqueous Zn-based batteries make them competitive in the context of large-scale energy storage. Among the various Zn-based batteries, due to a high open-circuit voltage and excellent rate performance, Zn-Ni batteries have great potential in practical applications. Nevertheless, the intrinsic obstacles associated with the use of Zn anodes in alkaline electrolytes, such as dendrite, shape change, passivation, and corrosion, limit their commercial application. Hence, we have focused our current efforts on inhibiting the corrosion and dissolution of Zn species. Based on a previous study from our research group, the failure of the Zn-Ni battery was caused by the shape change of the Zn anode, which stemmed from the dissolution of Zn and uneven current distribution on the anode. Therefore, for the current study, we selected K₃[Fe(CN)₆] as an electrolyte additive that would help minimize the corrosion and dissolution of the Zn anode. In the alkaline electrolyte, [Fe(CN)₆]^3– was reduced to [Fe(CN)₆]^4– by the metallic Zn present in the Zn-Ni battery. Owing to its low solubility in the electrolyte, K₄[Fe(CN)₆] adhered to the active Zn anode, thereby inhibiting the aggregation and corrosion of Zn. Ultimately, the shape change of the anode was effectively eliminated, which improved the cycling life of the Zn-Ni battery by more than three times (i.e., from 124 cycles to more than 423 cycles). As for capacity retention, the Zn-Ni battery with the pristine electrolyte only exhibited 40% capacity retention after 85 cycles, while the Zn-Ni battery with the modified electrolyte (i.e., containing K₃[Fe(CN)₆]) showed 72% capacity retention. Moreover, unlike conventional organic additives that increase electrode polarization, the addition of K₃[Fe(CN)₆] not only significantly reduced the charge-transfer resistance in a simplified three-electrode system, but also improved the discharge capacity and rate performance of the Zn-Ni battery. Importantly, considering that this strategy was easy to achieve and minimized additional costs, K₃[Fe(CN)₆], as an electrolyte additive with almost no negative effect, has tremendous potential in commercial Zn-Ni batteries.
- Zn-Ni battery,
- K₃[Fe(CN)₆],
- Electrolyte additive,
- K₄[Fe(CN)₆],
- Shape change
1. [1]
  Goodenough, J. B. Energy Environ. Sci. 2014, 7, 14. doi: 10.1039/c3ee42613k doi: 10.1039/c3ee42613k
2. [2]
  Zhao, Z.; Fan, X.; Ding, J.; Hu, W.; Zhong, C.; Lu, J. ACS Energy Lett. 2019, 4, 2259. doi: 10.1021/acsenergylett.9b01541 doi: 10.1021/acsenergylett.9b01541
3. [3]
  Ji, J.; Liu, X.; Huang, H.; Jiang, H.; Duan, M.; Liu, B.; Cui, P.; Li, Y.; Li, M. Acta Phys. -Chim. Sin. 2021, 37, 2008095. doi: 10.3866/PKU.WHXB202008095
4. [4]
  Xue, Y.; Wang, X.; Zhang, X.; Fang, J.; Xu, Z.; Zhang, Y.; Liu, X.; Liu, M.; Zhu, W.; Zhuang, Z. Acta Phys. -Chim. Sin. 2021, 37, 2009103. doi: 10.3866/PKU.WHXB202009103
5. [5]
  Liu, X.; Fan, X.; Liu, B.; Ding, J.; Deng, Y.; Han, X.; Zhong, C.; Hu, W. Adv. Mater. 2021, 33, e2006461. doi: 10.1002/adma.202006461 doi: 10.1002/adma.202006461
6. [6]
  Han, Y.; Liu, S. -Y.; Cui, L.; Xu, L.; Xie, J.; Xia, X. -K.; Hao, W. -K.; Wang, B.; Li, H.; Gao, J. Int. J. Miner. Metall. Mater. 2018, 25, 88. doi: 10.1007/s12613-018-1550-6 doi: 10.1007/s12613-018-1550-6
7. [7]
  Shen, Y.; Liu, B.; Liu, X.; Liu, J.; Ding, J.; Zhong, C.; Hu, W. Energy Storage Mater. 2021, 34, 461. doi: 10.1016/j.ensm.2020.10.011 doi: 10.1016/j.ensm.2020.10.011
8. [8]
  Wang, L.; Chen, G.; Shen, Q.; Li, G.; Guan, S.; Li, B. Int. J. Miner. Metall. Mater. 2018, 25, 1027. doi: 10.1007/s12613-018-1653-0 doi: 10.1007/s12613-018-1653-0
9. [9]
  Zhao, Z.; Liu, B.; Shen, Y.; Wu, T.; Zang, X.; Zhao, Y.; Zhong, C.; Ma, F.; Hu, W. J. Power Sources 2021, 510, 230393. doi: 10.1016/j.jpowsour.2021.230393 doi: 10.1016/j.jpowsour.2021.230393
10. [10]
  Lu, Q.; Zou, X.; Liao, K.; Ran, R.; Zhou, W.; Ni, M.; Shao, Z. Carbon Energy 2020, 2, 461. doi: 10.1002/cey2.50 doi: 10.1002/cey2.50
11. [11]
  Wang, P.; Shi, X.; Wu, Z.; Guo, S.; Zhou, J.; Liang, S. Carbon Energy 2020, 2, 294. doi: 10.1002/cey2.39 doi: 10.1002/cey2.39
12. [12]
  Wu, J.; Liu, B.; Fan, X.; Ding, J.; Han, X.; Deng, Y.; Hu, W.; Zhong, C. Carbon Energy 2020, 2, 370. doi: 10.1002/cey2.60 doi: 10.1002/cey2.60
13. [13]
  Yu, L.; Yi, Q.; Yang, X.; Chen, Y. Sci. China Mater. 2019, 62, 1251. doi: 10.1007/s40843-019-9439-9 doi: 10.1007/s40843-019-9439-9
14. [14]
  Wang, L.; Yang, Z.; Chen, X.; Qin, H.; Yan, P. J. Power Sources 2018, 396, 615. doi: 10.1016/j.jpowsour.2018.06.031 doi: 10.1016/j.jpowsour.2018.06.031
15. [15]
  Chao, D.; Zhou, W.; Xie, F.; Ye, C.; Li, H.; Jaroniec, M.; Qiao, S. -Z. Sci. Adv. 2020, 6, eaba4098. doi: 10.1126/sciadv.aba4098 doi: 10.1126/sciadv.aba4098
16. [16]
  Zheng, X.; Ahmad, T.; Chen, W. Energy Storage Mater. 2021, 39, 365. doi: 10.1016/j.ensm.2021.04.027 doi: 10.1016/j.ensm.2021.04.027
17. [17]
  Lai, S. B.; Jamesh, M. I.; Wu, X. C.; Dong, Y. L.; Wang, J. H.; Gao, M.; Liu, J. F.; Sun, X. M. Rare Met. 2017, 36, 381. doi: 10.1007/s12598-017-0905-x doi: 10.1007/s12598-017-0905-x
18. [18]
  Renuka, R.; Srinivasan, L.; Ramamurthy, S.; Veluchamy, A.; Venkatakrishnan, N. J. Appl. Electrochem. 2001, 31, 655. doi: 10.1023/A:1017562514934 doi: 10.1023/A:1017562514934
19. [19]
  Moser, F.; Fourgeot, F.; Rouget, R.; Crosnier, O.; Brousse, T. Electrochim. Acta 2013, 109, 110. doi: 10.1016/j.electacta.2013.07.023 doi: 10.1016/j.electacta.2013.07.023
20. [20]
  Sato, Y.; Takahashi, M.; Asakura, H.; Yoshida, T.; Tada, K.; Kobayakawa, K.; Chiba, N.; Yoshida, K. J. Power Sources 1992, 38, 317. doi: 10.1016/0378-7753(92)80121-Q doi: 10.1016/0378-7753(92)80121-Q
21. [21]
  McLarnon, F. R.; Cairns, E. J. J. Electrochem. Soc. 1991, 138, 645. doi: 10.1149/1.2085653 doi: 10.1149/1.2085653
22. [22]
  Schröder, D.; Sinai Borker, N. N.; König, M.; Krewer, U. J. Appl. Electrochem. 2015, 45, 427. doi: 10.1007/s10800-015-0817-0 doi: 10.1007/s10800-015-0817-0
23. [23]
  Zhu, A. L.; Duch, D.; Roberts, G. A.; Li, S. X. X.; Wang, H.; Duch, K.; Bae, E.; Jung, K. S.; Wilkinson, D.; Kulinich , S. A. ChemElectroChem 2015, 2, 134. doi: 10.1002/celc.201402251 doi: 10.1002/celc.201402251
24. [24]
  Azhagurajan, M.; Nakata, A.; Arai, H.; Ogumi, Z.; Kajita, T.; Itoh, T.; Itaya, K. J. Electrochem. Soc. 2017, 164, A2407. doi: 10.1149/2.0221712jes doi: 10.1149/2.0221712jes
25. [25]
  Zhou, H.; Huang, Q.; Liang, M.; Lv, D.; Xu, M.; Li, H.; Li, W. Mater. Chem. Phys. 2011, 128, 214. doi: 10.1016/j.matchemphys.2011.02.061 doi: 10.1016/j.matchemphys.2011.02.061
26. [26]
  Lin, M.; Huang, C.; Cheng, P.; Cheng, J.; Wang, C. J. Mater. Chem. A 2020, 8, 20637. doi: 10.1039/d0ta06929a doi: 10.1039/d0ta06929a
27. [27]
  Sun, K. E. K.; Hoang, T. K. A.; The Nam Long, D.; Zhu, Y. Y. X.; Tian, Y.; Chen, P. ACS Appl. Mater. Interfaces 2017, 9, 9681. doi: 10.1021/acsami.6b16560 doi: 10.1021/acsami.6b16560
28. [28]
  Hosseini, S.; Abbasi, A.; Uginet, L. O.; Haustraete, N.; Praserthdam, S.; Yonezawa, T.; Kheawhom, S. Sci. Rep. 2019, 9, 14958. doi: 10.1038/s41598-019-51412-5 doi: 10.1038/s41598-019-51412-5
29. [29]
  Hosseini, S.; Han, S. J.; Arponwichanop, A.; Yonezawa, T.; Kheawhom, S. Sci. Rep. 2018, 8, 11273. doi: 10.1038/s41598-018-29630-0 doi: 10.1038/s41598-018-29630-0
30. [30]
  Einerhand, R. E. F.; Visscher, W.; de Goeij, J. J. M.; Barendrecht, E. J. Electrochem. Soc. 1991, 138, 1. doi: 10.1149/1.2085538 doi: 10.1149/1.2085538
31. [31]
  Einerhand, R. E. F.; Visscher, W.; de Goeij, J. J. M.; Barendrecht, E. J. Electrochem. Soc. 1991, 138, 7. doi: 10.1149/1.2085582 doi: 10.1149/1.2085582
32. [32]
  Horn, Q. C.; Shao-Horn, Y. J. Electrochem. Soc. 2003, 150, A652. doi: 10.1149/1.1566014 doi: 10.1149/1.1566014
33. [33]
  Yang, Q.; Li, Q.; Liu, Z.; Wang, D.; Guo, Y.; Li, X.; Tang, Y.; Li, H.; Dong, B.; Zhi, C. Adv. Mater. 2020, 32, 2001854. doi: 10.1002/adma.202001854 doi: 10.1002/adma.202001854
34. [34]
  Shen, Y.; Xu, L.; Wang, Q.; Zhao, Z.; Dong, Z.; Liu, J.; Zhong, C.; Hu, W. ACS Appl. Mater. Interfaces 2021, 13, 51141. doi: 10.1021/acsami.1c17204 doi: 10.1021/acsami.1c17204
35. [35]
  Lee, S. -M.; Kim, Y. -J.; Eom, S. -W.; Choi, N. -S.; Kim, K. -W.; Cho, S. -B. J. Power Sources 2013, 227, 177. doi: 10.1016/j.jpowsour.2012.11.046 doi: 10.1016/j.jpowsour.2012.11.046
36. [36]
  El-Sayed, A. -R.; Mohran, H. S.; Abd El-Lateef, H. M. J. Power Sources 2011, 196, 6573. doi: 10.1016/j.jpowsour.2011.03.057 doi: 10.1016/j.jpowsour.2011.03.057
37. [37]
  Cheng, Q.; Fan, W.; He, Y.; Ma, P.; Vanka, S.; Fan, S.; Mi, Z.; Wang, D. Adv. Mater. 2017, 29, 1700312. doi: 10.1002/adma.201700312 doi: 10.1002/adma.201700312
38. [38]
  Lin, K.; Chen, Q.; Gerhardt, M. R.; Tong, L.; Kim, S. B.; Eisenach, L.; Valle, A. W.; David, Hardee, R. G. G.; Aziz, M. J.; Marshak, M. P. Science 2015, 349, 1529. doi: 10.1126/science.aab3033 doi: 10.1126/science.aab3033
39. [39]
  Lin, K.; Gómez-Bombarelli, R.; Beh, E. S.; Tong, L.; Chen, Q.; Valle, A.; Aspuru-Guzik, A.; Aziz, M. J.; Gordon, R. G. Nat. Energy 2016, 1, 16102. doi: 10.1038/nenergy.2016.102 doi: 10.1038/nenergy.2016.102
40. [40]
  Forment-Aliaga, A.; Weitz, R. T.; Sagar, A. S.; Lee, E. J.; Konuma, M.; Burghard, M.; Kern, K. Small 2008, 4, 1671. doi: 10.1002/smll.200800803 doi: 10.1002/smll.200800803
41. [41]
  He, X.; Tian, L.; Qiao, M.; Zhang, J.; Geng, W.; Zhang, Q. J. Mater. Chem. A 2019, 7, 11478. doi: 10.1039/c9ta02265a doi: 10.1039/c9ta02265a
42. [42]
  Wang, H.; Yuan, X.; Wu, Y.; Zeng, G.; Chen, X.; Leng, L.; Wu, Z.; Jiang, L.; Li, H. J. Hazard. Mater. 2015, 286, 187. doi: 10.1016/j.jhazmat.2014.11.039 doi: 10.1016/j.jhazmat.2014.11.039
43. [43]
  Kwak, B. S.; Kim, D. Y.; Park, S. S.; Kim, B. S.; Kang, M. Chem. Eng. J. 2015, 281, 368. doi: 10.1016/j.cej.2015.06.062 doi: 10.1016/j.cej.2015.06.062
44. [44]
  Pei, Y.; Mu, C.; Li, H.; Li, F.; Chen, J. ChemSusChem 2018, 11, 1285. doi: 10.1002/cssc.201800057 doi: 10.1002/cssc.201800057
45. [45]
  Hao, P.; Zhu, T.; Su, Q.; Lin, J.; Cui, R.; Cao, X.; Wang, Y.; Pan, A. Front. Chem. 2018, 6, 195. doi: 10.3389/fchem.2018.00195 doi: 10.3389/fchem.2018.00195
46. [46]
  Wu, Z. -G.; Zhong, Y. -J.; Li, J. -T.; Wang, K.; Guo, X. -D.; Huang, L.; Zhong, B. -H.; Sun, S. -G. RSC Adv. 2016, 6, 54404. doi: 10.1039/c6ra09707c doi: 10.1039/c6ra09707c
47. [47]
  Xia, A.; Pu, X.; Tao, Y.; Liu, H.; Wang, Y. Appl. Surf. Sci. 2019, 481, 852. doi: 10.1016/j.apsusc.2019.03.197 doi: 10.1016/j.apsusc.2019.03.197
48. [48]
  Yan, M.; Xu, C.; Sun, Y.; Pan, H.; Li, H. Nano Energy 2021, 82, 105739. doi: 10.1016/j.nanoen.2020.105739 doi: 10.1016/j.nanoen.2020.105739
49. [49]
  Zhao, K.; Liu, F.; Fan, G.; Liu, J.; Yu, M.; Yan, Z.; Zhang, N.; Cheng, F. ACS Appl. Mater. Interfaces 2021, 13, 47650. doi: 10.1021/acsami.1c14407 doi: 10.1021/acsami.1c14407
50. [50]
  Al-Jibbouri, S.; Ulrich, J. Cryst. Res. Technol. 2001, 36, 1365. doi: 10.1002/1521-4079(200112)36:12<1365::AID-CRAT1365>3.0.CO;2-H doi: 10.1002/1521-4079(200112)36:12<1365::AID-CRAT1365>3.0.CO;2-H
51. [51]
  Al-Jibbouri, S.; Ulrich, J. J. Cryst. Growth 2002, 234, 237. doi: 10.1016/S0022-0248(01)01656-6 doi: 10.1016/S0022-0248(01)01656-6
52. [52]
  Skvortsova, Z. N.; Traskin, V. Y. Colloid J. 2018, 80, 349. doi: 10.1134/s1061933x18040129 doi: 10.1134/s1061933x18040129
53. [53]
  Mohammadi Ghaleni, M.; Al Balushi, A.; Kaviani, S.; Tavakoli, E.; Bavarian, M.; Nejati, S. ACS Appl. Mater. Interfaces 2018, 10, 44871. doi: 10.1021/acsami.8b16621 doi: 10.1021/acsami.8b16621
54. [54]
  Hunke, H.; Soin, N.; Shah, T.; Kramer, E.; Pascual, A.; Karuna, M.; Siores, E. Materials 2015, 8, 2258. doi: 10.3390/ma8052258 doi: 10.3390/ma8052258
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Spontaneous Reduction and Adsorption of K₃[Fe(CN)₆] on Zn Anodes in Alkaline Electrolytes: Enabling a Long-Life Zn-Ni Battery