Citation: Ru Wang, Zhikang Liu, Chao Yan, Long Qie, Yunhui Huang. Interface Strengthening of Composite Current Collectors for High-Safety Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2023, 39(2): 220304. doi: 10.3866/PKU.WHXB202203043 shu

Interface Strengthening of Composite Current Collectors for High-Safety Lithium-Ion Batteries

Ru Wang ^{1, 3, †} ,
Zhikang Liu ^{1, †} ,
Chao Yan ⁴ ,
Long Qie ^2,, ,
Yunhui Huang ^2,,

1.
School of Materials Science and Engineering, Tongji University, Shanghai 201804, China
2.
State Key Laboratory of Material Processing and Die & Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
3.
Nanjing Tongning Institude of New Materials, Nanjing 211161, China
4.
Zhejiang Rouzhen Technology Co. Ltd., Jiaxing 314499, Zhejiang Province, China

Corresponding author: Long Qie, qie@hust.edu.cn Yunhui Huang, huangyh@hust.edu.cn

^†

Received Date: 25 March 2022
Revised Date: 19 April 2022
Accepted Date: 26 April 2022
Available Online: 9 May 2022
Fund Project: the China Postdoctoral Science Foundation 2020M681386

The use of high-capacity ternary cathode materials for high-energy batteries can cause thermal runaway of lithium-ion batteries (LIBs), hindering their safe use and further development. Therefore, improving the energy density of LIBs while maintaining their safety is essential. Current collectors (CCs), which serve as the electron carrier during the electrochemical process, do not contribute to capacity and are regarded as "dead weight" to the cells. The use of composite CCs, which have a sandwich structure where a thin metal (e.g., Al and Cu) layer is deposited on both sides of polymer films, can reduce the weight of CCs owing to the use of the low-density insulating substrate and improve the safety of LIBs (evaluated by the nail penetration test). However, due to the weak interfacial adhesion between the substrate and metal coating layer, the composite CCs may easily delaminate in electrolytes during high-temperature immersion, which could not meet the requirement for the long-term stability. Herein, we introduced an oxide strengthening layer between the substrate (polyethylene terephthalate, PET) and Al layer. The objective of strengthening layer is to increase the interface binding force between the metal and polymer substrate by enhancing the mechanical interlocking effect between the layers and forming a stable chemical bond at the interface. This increased interface binding force effectively improved the electrolyte compatibility of composite CCs even at a high temperature of 85 ℃. Based on the results of atomic force microscopy and X-ray photoelectron spectroscopy, we proposed a mechanism for the enhancement of both mechanical interlocking and chemical bonding. Additionally, the composite CCs possessed good mechanical properties that ensure their compatibility with conventional battery fabrication technologies. LIBs using composite CCs exhibited a comparable electrochemical performance to that of aluminum-CC-based (Al CCs) cells, but better performance in nail penetration test. After 280 cycles at 0.2 C, the cell showed high-capacity retention. Al-CC-based cells and PET-AlO_x-Al-CC based cells remain 80.55% and 80.9% capacity retention respectively, which indicates the comparable performance. This shows that the composite CCs technology is fully adapted to the existing battery manufacturing technology, and has little influence on the electrochemical performance of LIBs. Specifically, cells with PET-AlO_x-Al CCs easily passed the nail penetration test under 100% state of charge without an obvious temperature rise. Furthermore, the voltage of the punctured batteries remained at ~4 V and could still be charged and discharged. The composite CCs successfully prevented the internal short circuit and markedly improved the safety of LIBs during the nail penetration test. Our findings provide theoretical guidance and solutions for the industrialization of composite CCs.
- Lithium-ion battery,
- Composite current collector,
- Interfacial strengthening,
- Oxide strengthening layer,
- Electrolyte compatibility
1. [1]
  Guo, Q. Solar Energy 2021, No. 12, 5. doi: 10.19911/j.1003-0417.tyn20210318.05
2. [2]
  Guan, J.; Li, N. W.; Yu, L. Acta Phys. -Chim. Sin. 2021, 37 (2), 2009011. doi: 10.3866/PKU.WHXB202009011
3. [3]
  Hua, G.; Fan, Y.; Zhang, Q. Acta Phys. -Chim. Sin. 2021, 37 (2), 2008089. doi: 10.3866/PKU.WHXB202008089
4. [4]
  Zhang, S.; Shen, Z.; Lu, Y. Acta Phys. -Chim. Sin. 2021, 37 (1), 2008065. doi: 10.3866/PKU.WHXB202008065
5. [5]
  Wu, F.; Li, Q.; Chen, L. Acta Phys. -Chim. Sin. 2020, 38 (5), 2007017. doi: 10.3866/PKU.WHXB202007017
6. [6]
  Dong, H; Zhang, S; Li, Y; Xian X; Yi, C; Liu, L; Yu, X; Han, G; Sheng, Y. Energy Storage Sci. Technol. 2019, 8 (S1), 65. doi: 10.19799/j.cnki.2095-4239.2019.0052
7. [7]
  Wang, Y.; Ren, D. S.; Feng, X. N.; Wang, L.; Ouyang, M. G. Appl. Energy 2022, 306, 117943. doi: 10.1016/j.apenergy.2021.117943 doi: 10.1016/j.apenergy.2021.117943
8. [8]
  Li, Y.; Liu, X.; Wang, L.; Feng, X. N.; Ren, D. S.; Wu, Y.; Xu, G. L.; Lu, L. G.; Hou, J. X.; Zhang, W. F.; et al. Nano Energy 2021, 85, 105878. doi: 10.1016/j.nanoen.2021.105878 doi: 10.1016/j.nanoen.2021.105878
9. [9]
  Yun, J. H.; Han, G. B.; Lee, Y. M.; Lee, Y. G.; Kim, K. M.; Park, J. K.; Cho, K. Y. Electrochem. Solid State Lett. 2011, 14 (8), A116. doi: 10.1149/1.3596721 doi: 10.1149/1.3596721
10. [10]
  Fritsch, M.; Coeler, M.; Kunz, K.; Krause, B.; Marcinkowski, P.; Potschke, P.; Wolter, M.; Michaelis, A. Batteries 2020, 6 (4), 60. doi: 10.3390/batteries6040060 doi: 10.3390/batteries6040060
11. [11]
  Ye, Y. S.; Chou, L. Y.; Liu, Y. Y.; Wang, H. S.; Lee, H. K.; Huang, W. X.; Wan, J. Y.; Liu, K.; Zhou, G. M.; Yang, Y. F.; et al. Nat. Energy 2020, 5(10), 786. doi: 10.1038/s41560-020-00702-8 doi: 10.1038/s41560-020-00702-8
12. [12]
  Pham, M. T. M.; Darst, J. J.; Walker, W. Q.; Heenan, T. M. M.; Patel, D.; Iacoviello, F.; Rack, A.; Olbinado, M. P.; Hinds, G.; Brett, D. J. L.; et al. Cell Rep. Phys. Sci. 2021, 2 (3), 100360. doi: 10.1016/j.xcrp.2021.100360 doi: 10.1016/j.xcrp.2021.100360
13. [13]
  Kang, H.; Park, H.; Park, Y.; Jung, M.; Kim, B. C.; Wallace, G.; Cho, G. Sci. Rep. 2014, 4 (1), 5387. doi: 10.1038/srep05387 doi: 10.1038/srep05387
14. [14]
  Shin, K. -H.; Nguyen, H. A. D.; Park, J.; Shin, D.; Lee, D. J. Coat. Technol. Res. 2017, 14 (1), 95. doi: 10.1007/s11998-016-9844-y doi: 10.1007/s11998-016-9844-y
15. [15]
  Struller, C. F.; Kelly, P. J.; Copeland, N. J. Surf. Coat. Technol. 2014, 241, 130. doi: 10.1016/j.surfcoat.2013.08.011 doi: 10.1016/j.surfcoat.2013.08.011
16. [16]
  Kouicem, M. M.; Tomasella, E.; Bousquet, A.; Batisse, N.; Monier, G.; Robert-Goumet, C.; Dubost, L. Appl. Surf. Sci. 2021, 564, 150322. doi: 10.1016/j.apsusc.2021.150322 doi: 10.1016/j.apsusc.2021.150322
17. [17]
  Schissel, P.; Kennedy, C.; Goggin, R. J. Adhes. Sci. Technol. 1995, 9 (4), 413. doi: 10.1163/156856195X00356 doi: 10.1163/156856195X00356
18. [18]
  Mwema, F. M.; Oladijo, O. P.; Akinlabi, S. A.; Akinlabi, E. T. J. Alloy. Compd. 2018, 747, 306. doi: 10.1016/j.jallcom.2018.03.006 doi: 10.1016/j.jallcom.2018.03.006
19. [19]
  Kim, S. H.; Kim, M.; Lee, J. H.; Lee, S. ACS Appl. Mater. Interfaces 2018, 10 (12), 10454. doi: 10.1021/acsami.8b00761 doi: 10.1021/acsami.8b00761
20. [20]
  Bichler, C.; Kerbstadt, T.; Langowski, H. C.; Moosheimer, U. Surf. Coat. Technol. 1999, 112 (1–3), 373. doi: 10.1016/s0257-8972(98)00780-4 doi: 10.1016/s0257-8972(98)00780-4
21. [21]
  Cueff, R.; Baud, G.; Benmalek, M.; Besse, J. P.; Butruille, J. R.; Dunlop, H. M.; Jacquet, M. Thin Solid Films 1995, 270 (1), 230. doi: 10.1016/0040-6090(95)06917-8 doi: 10.1016/0040-6090(95)06917-8
22. [22]
  Xie, C; Wang, K. Plast. Packag. 2018, 28 (2), 8.
23. [23]
  Liu, Y; Wang, J; Xiong, L. J. Wuhan Inst. Technol. 2010, 32 (5), 4. doi: 10.3969/j.issn.1674
24. [24]
  Sundararajan, M; Subramani, S. Devarajan, M; Jaafar, M. J. Mater. Sci: Mater Electron. 2020, 31, 9641. doi: 10.1007/s10854-020-03507-3 doi: 10.1007/s10854-020-03507-3
25. [25]
  Zhai, L; Ling, G; Li, J. Mater. Rep. 2006, No. S2, 274. doi: 10.3321/j.issn:1005-023X.2006.z2.080
26. [26]
  Drabold, D. A.; Adams, J. B.; Anderson, D. C.; Kieffer. J. Adhesion 1993, 42 (1–2), 55. doi: 10.1080/00218469308026570 doi: 10.1080/00218469308026570
27. [27]
  Liu, Z; Lin, J; Sun, Z; Gao, D. J. Vac. Sci. Technol. 2009, 29 (S1), 94. doi: 10.3969/j.issn.1672-7126.2009.z1.22
28. [28]
  Madocks, J; Rewhinkle, J; Barton, L. Mater. Sci. Eng. 2005, 119 (3). 2683. doi: 10.1016/j.mseb.2004.12.080 doi: 10.1016/j.mseb.2004.12.080
29. [29]
  Peacock, A. Handbook of Polyethylene: Structures: Properties, and Applications, 1st ed.; CRC Press. : Boca Raton, FL, USA, 2000; pp. 20–25
30. [30]
  Lv, D; Li, W. J. Power Sources 2007, 31 (10), 3. doi: 10.3969/j.issn.1002-087X.2007.10.020
31. [31]
  Chen, H. Study on the Anti-Corrosion of Alumium Current Collector for Lithium-Ion Battery. Master Dissertation, Harbin Institute of Technology, Harbin, 2009.
32. [32]
  Raveh, A.; Tsameret, Z. K.; Grossman, E. Surf. Coat. Technol. 1997, 88 (1–3), 103. doi: 10.1016/S0257-8972(95)02757-2 doi: 10.1016/S0257-8972(95)02757-2
33. [33]
  Alfonsetti, R.; Lozzi, L.; Passacantando, M.; Picozzi, P.; Santucci, S. Appl. Surf. Sci. 1993, s70–71, 222. doi: 10.1016/0169-4332(93)90431-A doi: 10.1016/0169-4332(93)90431-A
34. [34]
  Moulder, J. F.; Stickle, W. F.; Sobol, P. E. Handbook of X-Ray Photoelectron Spectroscopy, 1st ed.; Perkin-Elmer Corporation: Physical Electronics Division 6509 Flying Cloud Drive Eden Prairie, MN 55344, USA, 1992; pp. 55–58.
35. [35]
  Huang, C.; Liu, C. H.; Wu, S. Y. Surf. Interface Anal. 2009, 41 (1), 44. doi: 10.1002/sia.2975 doi: 10.1002/sia.2975
36. [36]
  Williams, K. R.; Gupta, K.; Wasilik, M. J. Microelectromech. Syst. 2003, 12, 761. doi: 10.1109/JMEMS.2003.820936 doi: 10.1109/JMEMS.2003.820936
37. [37]
  Williams, K. R.; Gupta, K.; Wasilik, M. J. Microelectromech. Syst. 2003, 12 (6), 761. doi: 10.1109/jmems.2003.820936 doi: 10.1109/jmems.2003.820936
1. [1]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
2. [2]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
3. [3]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
4. [4]
  Yuanchao LI , Weifeng HUANG , Pengchao LIANG , Zifang ZHAO , Baoyan XING , Dongliang YAN , Li YANG , Songlin WANG . Effect of heterogeneous dual carbon sources on electrochemical properties of LiMn_0.8Fe_0.2PO₄/C composites. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 751-760. doi: 10.11862/CJIC.20230252
5. [5]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
6. [6]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
7. [7]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
8. [8]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
9. [9]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
10. [10]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
11. [11]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
12. [12]
  Zhangshu Wang , Xin Zhang , Jixin Han , Xuebing Fang , Xiufeng Zhao , Zeyu Gu , Jinjun Deng . Exploration and Design of Experimental Teaching on Ultrasonic-Enhanced Synergistic Treatment of Ternary Composite Flooding Produced Water. University Chemistry, 2024, 39(5): 116-124. doi: 10.3866/PKU.DXHX202310056
13. [13]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
14. [14]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
15. [15]
  Qingyan JIANG , Yanyong SHA , Chen CHEN , Xiaojuan CHEN , Wenlong LIU , Hao HUANG , Hongjiang LIU , Qi LIU . Constructing a one-dimensional Cu-coordination polymer-based cathode material for Li-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 657-668. doi: 10.11862/CJIC.20240004
16. [16]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
17. [17]
  Jianmin Hao , Ruifeng Wu , Ying Wang , Yijia Bai , Xuechuan Gao , Yuying Du . Reform and Practice of Physical Chemistry Course Based on Enhanced Process Assessment and Evaluation. University Chemistry, 2024, 39(8): 78-83. doi: 10.3866/PKU.DXHX202311103
18. [18]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
19. [19]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
20. [20]
  Biao Zuo , Yizhi Zhang , Zhengkai Chen , Houkuan Tian , Yongneng Wang , Wei Zhang , Weizu Wang , Xuming Zheng , Xinping Wang . Strengthening the Functions of Academic Research and Promoting the Integration of Science and Education: Exploration Ways to Cultivate the Talents of Undergraduate Chemistry Students. University Chemistry, 2024, 39(11): 38-43. doi: 10.3866/PKU.DXHX202402066

Get Citation

PDF

XML

Metrics

PDF Downloads(83)
Abstract views(1452)
HTML views(458)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142