Citation: Liang Zhou, Yunfeng Li, Yongkang Zhang, Liewei Qiu, Yan Xing. A 0D/2D Bi₄V₂O₁₁/g-C₃N₄ S-Scheme Heterojunction with Rapid Interfacial Charges Migration for Photocatalytic Antibiotic Degradation[J]. Acta Physico-Chimica Sinica, ;2022, 38(7): 211202. doi: 10.3866/PKU.WHXB202112027 shu

A 0D/2D Bi₄V₂O₁₁/g-C₃N₄ S-Scheme Heterojunction with Rapid Interfacial Charges Migration for Photocatalytic Antibiotic Degradation

Liang Zhou ¹ ,
Yunfeng Li ^1,, ,
Yongkang Zhang ¹ ,
Liewei Qiu ^1,, ,
Yan Xing ²

1.
College of Environmental and Chemical Engineering, Xi'an Key Laboratory of Textile Chemical Engineering Auxiliaries, Xi'an Polytechnic University, Xi'an 710048, China
2.
Jilin Provincial Key Laboratory of Advanced Energy Materials, Department of Chemistry, Northeast Normal University, Changchun 130024, China

Corresponding author: Yunfeng Li, liyf377@nenu.edu.cn Liewei Qiu, 20190607@xpu.edu.cn
Received Date: 20 December 2021
Revised Date: 9 January 2022
Accepted Date: 17 January 2022
Available Online: 20 January 2022
Fund Project: the National Natural Science Foundation of China 22008185the National Natural Science Foundation of China 21872023Natural Science Basic Research Program of Shaanxi Province 2021JQ-669College Students' Innovative Training Plan Program of Xi'an Polytechnic University 202110709042Graduate Innovation Fund Project of Xi'an Polytechnic University chx2021020

With the rapid development of industrial technology, a large number of organic pollutants are routinely released into the environment, which has caused serious problems. Semiconductor photocatalysis is an environmentally-friendly and effective method to degrade and remove typical pollutants, and photocatalysts play a key role in the application of this technology. Therefore, various semiconductor materials have been tried and used in the field of pollutant removal. Graphite carbon nitride (g-C₃N₄) has attracted great interest because of its two-dimensional layered structure and good visible light response range. Owing to a narrow bandgap, adjustable band structure, and high physicochemical stability, g-C₃N₄ absorbs wavelengths up to 450 nm in the visible spectrum, leading to an opportunity for visible-light photocatalytic performance. Nevertheless, there are still some drawbacks that limit the photocatalytic efficiency of g-C₃N₄ in the removal of antibiotics and dyes under visible light, such as the rapid recombination of photoinduced charges and the weak oxidation capacity of holes. To advance this promising photocatalytic material, multiple methods have been tried to optimize the electronic band structure of g-C₃N₄, such as doping with various elements, morphology control, and functional group modification. Recently, a novel type of Step-scheme (S-scheme) heterojunction composed of two n-type semiconductor photocatalysts has been proposed, which can utilize a more positive valance band and a more negative conduction band. It was demonstrated that the formation of S-scheme heterojunctions is a valid way to increase photocatalytic activity of g-C₃N₄. Herein, novel 0D/2D Bi₄V₂O₁₁/g-C₃N₄ S-scheme heterojunctions were prepared by a simple in situ solvothermal growth method. The Bi₄V₂O₁₁/g-C₃N₄ composites displayed a high photocatalytic activity through the removal of oxytetracycline (OTC) and Reactive Red 2. In particular, the BVCN-50 composite showed the highest degradation efficiency for OTC of 74.1% and for Reactive Red 2 of 84.2% with ·O₂^- as the primary active species. This highly improved photocatalytic performance can be ascribed to the generation of S-scheme heterojunctions, which provides for a high redox capacity of the heterojunction system (strong oxidative ability of Bi₄V₂O₁₁ and strong reductive capacity of g-C₃N₄) and facilitates the space separation of photo-generated charges. Moreover, the surface plasmon resonance effect of metallic Bi⁰ broadens the light utilization range of the heterojunction system. In addition, the possible degradation pathway and intermediates throughout the degradation process of OTC based on liquid chromatograph mass spectrometer (LC-MS) analysis were also studied. This work provides a novel tactic for the design and fabrication of g-C₃N₄-based S-scheme heterojunctions with enhanced photocatalytic performance.
- S-scheme,
- Photocatalysis,
- Oxytetracycline,
- g-C₃N₄
1. [1]
  Bie, C.; Yu, H.; Cheng, B.; Ho, W.; Fan, J.; Yu, J. Adv. Mater. 2021, 33, 2003521. doi: 10.1002/adma.202003521 doi: 10.1002/adma.202003521
2. [2]
  Yang, Y.; Tan, H.; Cheng, B.; Fan, J.; Yu, J.; Ho, W. Small Methods 2021, 5, 2001042. doi: 10.1002/smtd.202001042 doi: 10.1002/smtd.202001042
3. [3]
  Li, Y.; Zhou, M.; Cheng, B.; Shao, Y. J. Mater. Sci. Technol. 2020, 56, 1. doi: 10.1016/j.jmst.2020.04.028 doi: 10.1016/j.jmst.2020.04.028
4. [4]
  Li, Y.; Gu, M.; Zhang, X.; Fan, J.; Lv, K.; Carabineiro, S.; Dong, F. J. Mater. Today 2020, 41, 270. doi: 10.1016/j.mattod.2020.09.004 doi: 10.1016/j.mattod.2020.09.004
5. [5]
  Cheng, L.; Yue, X.; Wang, L.; Zhang, D.; Zhang, P.; Fan, J.; Xiang, Q. Adv. Mater. 2021, 33, 2105135. doi: 10.1002/adma.202105135 doi: 10.1002/adma.202105135
6. [6]
  Li, Y.; Wang, H.; Zhang, X.; Wang, S.; Jin, S.; Xu, X.; Liu, W.; Zhao, Z.; Xie, Y. Angew. Chem. Int. Ed. 2021, 60, 2. doi: 10.1002/anie.202101090 doi: 10.1002/anie.202101090
7. [7]
  Kuang, P.; Low, J.; Cheng, B.; Yu, J.; Fan, J. J. Mater. Sci. Technol. 2020, 56, 18. doi: 10.1016/j.jmst.2020.02.037 doi: 10.1016/j.jmst.2020.02.037
8. [8]
  Jing, L.; Xu, Y.; Zhou, M.; Deng, J.; Wei, W.; Xie, M.; Song, Y.; Xu, H.; Li, H. J. Hazard. Mater. 2020, 396, 122659. doi: 10.1016/j.jhazmat.2020.122659 doi: 10.1016/j.jhazmat.2020.122659
9. [9]
  Cheng, L.; Zhang, H.; Li, X.; Fan, J.; Xiang, Q. Small 2021, 17, 2005231. doi: 10.1002/smll.202005231 doi: 10.1002/smll.202005231
10. [10]
  Li, Y.; Ouyang, S.; Xu, H.; Hou, W.; Zhao, M.; Chen, H.; Ye, J. Adv. Funct. Mater. 2019, 29, 1901024. doi: 10.1002/adfm.201901024 doi: 10.1002/adfm.201901024
11. [11]
  Jiang, Z.; Zhang, X.; Chen, H.; Yang, P.; Jiang, S. Small 2020, 16, 2003910. doi: 10.1002/smll.202003910 doi: 10.1002/smll.202003910
12. [12]
  Yi, J.; El-Alami, W.; Song, Y.; Li, H.; Ajayan, P.; Xu, H. Chem. Eng. J. 2020, 382, 122812. doi: 10.1016/j.cej.2019.122812 doi: 10.1016/j.cej.2019.122812
13. [13]
  Chen, X.; Wang, J.; Chai, Y.; Zhang, Z.; Zhu, Y. Adv. Mater. 2021, 33, 2007479. doi: 10.1002/adma.202007479 doi: 10.1002/adma.202007479
14. [14]
  Chen, X.; Shi, R.; Chen, Q.; Zhang, Z.; Jiang, W.; Zhu, Y.; Zhang, T. Nano Energy 2019, 59, 644. doi: 10.1016/j.nanoen.2019.03.010 doi: 10.1016/j.nanoen.2019.03.010
15. [15]
  Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33, 2100317. doi: 10.1002/adma.202100317 doi: 10.1002/adma.202100317
16. [16]
  Mo, Z.; Di, J.; Yan, P.; Lv, C.; Zhu, X.; Liu, D.; Song, Y.; Liu, C.; Yu, Q.; Li, H.; et al. Small 2020, 16, 2003914. doi: 10.1002/smll.202003914 doi: 10.1002/smll.202003914
17. [17]
  Li, Y.; Zhang, M.; Zhou, L.; Yang, S.; Wu, Z.; Ma, Y. Acta Phys. -Chim. Sin. 2021, 37, 2009030. doi: 10.3866/PKU.WHXB202009030
18. [18]
  Wang, J.; Lin, S.; Tian, N.; Ma, T.; Zhang, Y.; Huang, H. Adv. Funct. Mater. 2020, 31, 2008008. doi: 10.1002/adfm.202008008 doi: 10.1002/adfm.202008008
19. [19]
  Chen, P.; Lei, B.; Dong, X.; Wang, H.; Sheng, J.; Cui, W.; Li, J.; Sun, Y.; Wang, Z.; Dong, F. ACS Nano 2020, 14, 15841. doi: 10.1021/acsnano.0c07083 doi: 10.1021/acsnano.0c07083
20. [20]
  Li, Z.; Huang, W.; Liu, J.; Lv, K.; Li, Q. ACS Catal. 2021, 11, 8510. doi: 10.1021/acscatal.1c02018 doi: 10.1021/acscatal.1c02018
21. [21]
  Chen, Y.; Li, L.; Xu, Q.; Düren, T.; Fan, J.; Ma, D. Acta Phys. -Chim. Sin. 2021, 37, 2009080. doi: 10.3866/PKU.WHXB202009080
22. [22]
  Wu, B.; Zhang, L.; Jiang, B.; Li, Q.; Tian, C.; Xie, Y.; Li, W.; Fu, H. Angew. Chem. Int. Ed. 2021, 60, 4815. doi: 10.1002/anie.202013753 doi: 10.1002/anie.202013753
23. [23]
  Li, Y.; Wang, S.; Chang, W.; Zhang, L.; Wu, Z.; Jin, R.; Xing, Y. Appl. Catal. B 2020, 274, 119116. doi: 10.1016/j.apcatb.2020.119116 doi: 10.1016/j.apcatb.2020.119116
24. [24]
  Zhou, L.; Lei, J.; Wang, F.; Wang, L.; Hoffmann, M.; Liu, Y.; In, S.; Zhang, J. Appl. Catal. B 2021, 288, 119993. doi: 10.1016/j.apcatb.2021.119993 doi: 10.1016/j.apcatb.2021.119993
25. [25]
  Deng, H.; Fei, X.; Yang, Y.; Fan, J.; Yu, J., Cheng, B.; Zhang, L. Chem. Eng. J. 2021, 409, 127377. doi: 10.1016/j.cej.2020.127377 doi: 10.1016/j.cej.2020.127377
26. [26]
  Liang, Z.; Shen, R.; Ng, Y.; Zhang, P.; Xiang, Q.; Li, X. J. Mater. Sci. Technol. 2020, 56, 89. doi: 10.1016/j.jmst.2020.04.032 doi: 10.1016/j.jmst.2020.04.032
27. [27]
  Wageh, S.; Al-Ghamdi, A.; Jafer, R.; Li, X.; Zhang, P. Chin. J. Catal. 2021, 42, 667. doi: 10.1016/S1872-2067(20)63705-6 doi: 10.1016/S1872-2067(20)63705-6
28. [28]
  Xu, F.; Meng, K.; Cao, S.; Jiang, C.; Chen, T.; Xu, J.; Yu, J. ACS Catal. 2022, 12, 164. doi: 10.1021/acscatal.1c04903 doi: 10.1021/acscatal.1c04903
29. [29]
  Peng, J.; Shen, J.; Yu, X.; Tang, H.; Zulfiqar; Liu, Q. Chin. J. Catal. 2021, 42, 87. doi: 10.1016/S1872-2067(20)63595-1 doi: 10.1016/S1872-2067(20)63595-1
30. [30]
  Mei, Z.; Wang, G.; Yan, S.; Wang, J. Acta Phys. -Chim. Sin. 2021, 37, 2009097. doi: 10.3866/PKU.WHXB202009097
31. [31]
  Liang, X.; Zhao, J.; Wang, T.; Zhang, Z.; Qu, M.; Wang, C. ACS Appl. Mater. Interfaces 2021, 13, 33034. doi: 10.1021/acsami.1c07757 doi: 10.1021/acsami.1c07757
32. [32]
  Chen, X.; Wang, J.; Chai, Y.; Zhang, Z.; Zhu, Y. Adv. Mater. 2021, 33, 2007479. doi: 10.1002/adma.202007479 doi: 10.1002/adma.202007479
33. [33]
  Liu, D.; Chen, S.; Li, R.; Peng, T. Acta Phys. -Chim. Sin. 2021, 37, 2010017. doi: 10.3866/PKU.WHXB202010017
34. [34]
  Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
35. [35]
  Zhou, L.; Li, Y.; Yang, S.; Zhang, M.; Wu, Z.; Jin, R.; Xing, Y. Chem. Eng. J. 2021, 420, 130361. doi: 10.1016/j.cej.2021.130361 doi: 10.1016/j.cej.2021.130361
36. [36]
  Xia, P.; Cao, S.; Zhu, B.; Liu, M.; Shi, M.; Yu, J.; Zhang, Y. Angew. Chem. Int. Ed. 2020, 59, 5218. doi: 10.1002/anie.201916012 doi: 10.1002/anie.201916012
37. [37]
  Xie, Q.; He, W.; Liu, S.; Li, C.; Zhang, J.; Wong, P. Chin. J. Catal. 2020, 41, 140. doi: S1872-2067(19)63481-9
38. [38]
  Li, Q.; Zhao, W.; Zhai, Z.; Ren, K.; Wang, T.; Guan, H.; Shi, H. J. Mater. Sci. Technol. 2020, 56, 216. doi: 10.1016/j.jmst.2020.03.038 doi: 10.1016/j.jmst.2020.03.038
39. [39]
  Wang, L.; Cheng, B.; Zhang, L.; Yu, J. Small 2021, 17, 2103447. doi: 10.1002/smll.202103447 doi: 10.1002/smll.202103447
40. [40]
  Liu, Y.; Hao, X.; Hu, H.; Jin, Z. Acta Phys. -Chim. Sin. 2021, 37, 2008030. doi: 10.3866/PKU.WHXB202008030
41. [41]
  Li, X.; Liu, J.; Huang, J.; He, C.; Feng, Z.; Chen, Z.; Wan, L.; Deng, F. Acta Phys. -Chim. Sin. 2021, 37, 2010030. doi: 10.3866/PKU.WHXB202010030
42. [42]
  Liu, L.; Hu, T.; Dai, K.; Zhang, J., Liang, C. Chin. J. Catal. 2021, 42, 46. doi: 10.1016/S1872-2067(20)63560-4 doi: 10.1016/S1872-2067(20)63560-4
43. [43]
  He, R.; Chen, R.; Luo, J.; Zhang, S.; Xu, D. Acta Phys. -Chim. Sin. 2021, 37, 2011022. doi: 10.3866/PKU.WHXB202011022
44. [44]
  Wang, K.; Li, Y.; Zhang, G.; Li, J.; Wu, X. Appl. Catal. B 2019, 240, 39. doi: 10.1016/j.apcatb.2018.08.063 doi: 10.1016/j.apcatb.2018.08.063
45. [45]
  Lv, C.; Chen, G.; Sun, J.; Zhou, Y.; Fan, S.; Zhang, C. Appl. Catal. B 2015, 179, 54. doi: 10.1016/j.apcatb.2015.05.022 doi: 10.1016/j.apcatb.2015.05.022
46. [46]
  Lv, T.; Li, D.; Hong, Y.; Luo, B.; Xu, D.; Chen, M.; Shi, W. Dalton Trans. 2017, 46, 12675. doi: 10.1039/c7dt02151h doi: 10.1039/c7dt02151h
47. [47]
  Wen, X.; Lu, Q.; Lv, X.; Sun, J.; Guo, J.; Fei, Z.; Niu, C. J. Hazard. Mater. 2020, 385, 121508. doi: 10.1016/j.jhazmat.2019.121508 doi: 10.1016/j.jhazmat.2019.121508
48. [48]
  Lv, C.; Chen, G.; Zhou, X.; Zhang, C.; Wang, Z.; Zhao, B.; Li, D. ACS Appl. Mater. Interfaces 2017, 9, 23748. doi: 10.1021/acsami.7b05302 doi: 10.1021/acsami.7b05302
49. [49]
  Zhu, B.; Tan, H.; Fan, J.; Cheng, B.; Yu, J.; Ho, W. J. Materiomics 2021, 7, 988. doi: 10.1016/j.jmat.2021.02.015 doi: 10.1016/j.jmat.2021.02.015
50. [50]
  Fei, X.; Tan, H.; Cheng, B.; Zhu, B.; Zhang, L. Acta Phys. -Chim. Sin. 2021, 37, 2010027. doi: 10.3866/PKU.WHXB202010027
51. [51]
  Rosa, F.; Papac, J.; Garcia-Ballesteros, S.; Kovačić, M.; Katančić, Z.; Kušić, H.; Božić, A. Adv. Sustain. Syst. 2021, 5, 2100119. doi: 10.1002/adsu.202100119 doi: 10.1002/adsu.202100119
52. [52]
  Zhou, X.; Shao, C.; Li, X.; Wang, X.; Guo, X.; Liu, Y. J. Hazard. Mater. 2018, 344, 113. doi: 10.1016/j.jhazmat.2017.10.006 doi: 10.1016/j.jhazmat.2017.10.006
53. [53]
  Zhang, M.; Li, Y.; Chang, W.; Zhu, W.; Zhang, L.; Jin, R.; Xing, Y. Chin. J. Catal. 2022, 43, 526. doi: 10.1016/S1872-2067(21)63872-X doi: 10.1016/S1872-2067(21)63872-X
54. [54]
  Liu, B.; Bie, C.; Zhang, Y.; Wang, L.; Li, Y.; Yu, J. Langmuir 2021, 37, 14114. doi: 10.1021/acs.langmuir.1c02360 doi: 10.1021/acs.langmuir.1c02360
55. [55]
  Wang, W.; Zhao, W.; Zhang, H.; Dou, X.; Shi, H. Chin. J. Catal. 2021, 42, 97. doi: 10.1016/S1872-2067(20)63602-6 doi: 10.1016/S1872-2067(20)63602-6
56. [56]
  Guaraldo, T.; Wenk, J.; Mattia, D. Adv. Sustain. Syst. 2021, 5, 2000208. doi: 10.1002/adsu.202000208 doi: 10.1002/adsu.202000208
57. [57]
  Jiang, Z.; Chen, Q.; Zheng, Q.; Shen, R.; Zhang, P.; Li, X. Acta Phys. -Chim. Sin. 2021, 37, 2010059. doi: 10.3866/PKU.WHXB202010059
58. [58]
  Wang, J.; Wang, G.; Cheng, B.; Yu, J.; Fan, J. Chin. J. Catal. 2021, 42, 56. doi: 10.1016/S1872-2067(20)63634-8 doi: 10.1016/S1872-2067(20)63634-8
59. [59]
  Ren, Y.; Li, Y.; Wu, X.; Wang, J.; Zhang, G. Chin. J. Catal. 2021, 42, 69. doi: 10.1016/S1872-2067(20)63631-2 doi: 10.1016/S1872-2067(20)63631-2
60. [60]
  Sayed, M.; Zhu, B.; Kuang, P.; Liu, X.; Cheng, B.; Ghamdi, A.; Wageh, S.; Zhang, L.; Yu, J. Adv. Sustain. Syst. 2021, doi: 10.1002/adsu.202100264 doi: 10.1002/adsu.202100264
61. [61]
  Shen, R.; Ren, D.; Ding, Y.; Guan, Y.; Ng, Y. H.; Zhang, P.; Li, X. Sci. China Mater. 2020, 63, 2153. doi: 10.1007/s40843-020-1456-x doi: 10.1007/s40843-020-1456-x
62. [62]
  Qin, D.; Xia, Y.; Li, Q.; Yang, C.; Qin, Y.; Lv, K. J. Mater. Sci. Technol. 2020, 56, 206. doi: 10.1016/j.jmst.2020.03.034 doi: 10.1016/j.jmst.2020.03.034
63. [63]
  Li, Q.; Xia, Y.; Yang, C.; Lv, K.; Lei, M.; Li, M. Chem. Eng. J. 2018, 349, 287. doi: 10.1016/j.cej.2018.05.094 doi: 10.1016/j.cej.2018.05.094
64. [64]
  Zhang, L.; Zhang, J.; Yu, H.; Yu, J. Adv. Mater. 2022, 34, 2107668. doi: 10.1002/adma.202107668 doi: 10.1002/adma.202107668
1. [1]
  Hongrui Zhang , Miaoying Cui , Yongjie Lv , Yongfang Rao , Yu Huang . A short review on research progress of ZnIn₂S₄-based S-scheme heterojunction: Improvement strategies. Chinese Chemical Letters, 2025, 36(4): 110108-. doi: 10.1016/j.cclet.2024.110108
2. [2]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
3. [3]
  Jianyu Qin , Yuejiao An , Yanfeng Zhang . In Situ Assembled ZnWO₄/g-C₃N₄ S-Scheme Heterojunction with Nitrogen Defect for CO₂ Photoreduction. Acta Physico-Chimica Sinica, 2024, 40(12): 2408002-. doi: 10.3866/PKU.WHXB202408002
4. [4]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . 微观结构调控的g-C₃N₄在光催化NO转化中的最新进展：吸附/活化位点的关键作用. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-. doi: 10.1016/j.actphy.2024.100039
5. [5]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2024.100463
6. [6]
  Yanghanbin Zhang , Dongxiao Wen , Wei Sun , Jiahe Peng , Dezhong Yu , Xin Li , Yang Qu , Jizhou Jiang . State-of-the-art evolution of g-C3N4-based photocatalytic applications: A critical review. Chinese Journal of Structural Chemistry, 2024, 43(12): 100469-100469. doi: 10.1016/j.cjsc.2024.100469
7. [7]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
8. [8]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
9. [9]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
10. [10]
  Guangming YIN , Huaiyao WANG , Jianhua ZHENG , Xinyue DONG , Jian LI , Yi'nan SUN , Yiming GAO , Bingbing WANG . Preparation and photocatalytic degradation performance of Ag/protonated g-C₃N₄ nanorod materials. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1491-1500. doi: 10.11862/CJIC.20240086
11. [11]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
12. [12]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
13. [13]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
14. [14]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
15. [15]
  Kai Han , Guohui Dong , Ishaaq Saeed , Tingting Dong , Chenyang Xiao . Morphology and photocatalytic tetracycline degradation of g-C3N4 optimized by the coal gangue. Chinese Journal of Structural Chemistry, 2024, 43(2): 100208-100208. doi: 10.1016/j.cjsc.2023.100208
16. [16]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
17. [17]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
18. [18]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
19. [19]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453
20. [20]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466

Get Citation

PDF

XML

Metrics

PDF Downloads(58)
Abstract views(1318)
HTML views(372)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A 0D/2D Bi4V2O11/g-C3N4 S-Scheme Heterojunction with Rapid Interfacial Charges Migration for Photocatalytic Antibiotic Degradation

Metrics

通讯作者: 陈斌, bchen63@163.com

A 0D/2D Bi₄V₂O₁₁/g-C₃N₄ S-Scheme Heterojunction with Rapid Interfacial Charges Migration for Photocatalytic Antibiotic Degradation