Citation: Jingwen Zhang, Hualong Ma, Jun Ma, Meixue Hu, Qihao Li, Sheng Chen, Tianshu Ning, Chuangxin Ge, Xi Liu, Li Xiao, Lin Zhuang, Yixiao Zhang, Liwei Chen. Cone Shaped Surface Array Structure on an Alkaline Polymer Electrolyte Membrane Improves Fuel Cell Performance[J]. Acta Physico-Chimica Sinica, ;2023, 39(2): 211103. doi: 10.3866/PKU.WHXB202111037 shu

Cone Shaped Surface Array Structure on an Alkaline Polymer Electrolyte Membrane Improves Fuel Cell Performance

  • Corresponding author: Yixiao Zhang, yxzhang2019@sjtu.edu.cn Liwei Chen, lwchen2018@sjtu.edu.cn
  • Received Date: 29 November 2021
    Revised Date: 28 December 2021
    Accepted Date: 30 December 2021
    Available Online: 15 January 2022

    Fund Project: the National Natural Science Foundation of China 21991153the National Natural Science Foundation of China 21991150

  • Fuel cells are essential energy conversion devices for future renewable energy structures. Mainstream proton exchange membrane fuel cells (PEMFCs) generally exhibit satisfactory performance despite requiring noble metal catalysts to be stable in acidic environments. Alkaline polymer electrolyte fuel cells (APEFCs), in contrast, offer the benefit of employing non-noble metal catalysts in fuel cells, but their overall performance and especially their long-term stability require further improvement. A critical component within APEFCs is the membrane electrode assembly (MEA), which comprises a hydroxide ion conductive polymer membrane, a cathode, and an anode (including a catalyst layer and a gas diffusion layer). MEA is where electrochemical reactions occur; thus, it plays a crucial role in determining fuel cell performance. Herein, the fabrication of a cone-shaped array on the surface of an alkaline polymer electrolyte membrane for improving the overall device performance is presented. The cone array was prepared using a sacrificial anodic aluminum oxide (AAO) template, and the array side of the polymer electrolyte was used as the cathode to construct the MEA, denoted as A-MEA. The control sample with no cone arrays on the polymer electrolyte surface is denoted as P-MEA. The Pt loadings on both the anode and cathode sides were approximately 0.2 mg∙cm−2. APEFCs with A-MEA and P-MEA were separately assembled and tested in an 850e Fuel Cell Test System at a cell temperature of 80 ℃. Fully humidified hydrogen and oxygen were both supplied at a flow rate of 1000 mL·min−1. The back pressure for both the anode and the cathode was 0.2 MPa. As a result, the APEFC with A-MEA exhibited a higher peak power density than that of the APEFC with P-MEA (1.48 vs. 1.04 W∙cm−2). The enhanced electrochemical performance of the APEFC with A-MEA was ascribed to the array-structured cathode, which improved the hydrophilicity of the polymer electrolyte membrane and increased the utilization efficiency of the catalyst. The hydrophilicity of the polymer electrolyte membrane with cone arrays was confirmed using contact angle measurements. The contact angles of the membranes with and without cone arrays were ~0° and 70.8°, respectively. The hydrophilic membrane promotes the electrode reaction at the cathode side. The electrochemically active surface area (ECSA) was also measured using cyclic voltammetry (CV) between 0.08 and 1 V (vs. reversible hydrogen electrode, RHE) at a scan rate of 20 mV∙s-1, using fully humidified H2 and N2. A flow rate of 1000 mL∙min−1 and back pressure of 0 MPa were employed. Results revealed that the ECSA of the cathode without the array was smaller than that of the array-structured cathode (21.17 vs. 24.89 m2∙g−1), indicating that the array structure improved the catalyst utilization efficiency compared to that of the control sample. This study provides an effective strategy for the structural design and optimization of the MEAs in APEFCs.
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    1. [1]

      Stern, P. C.; Sovacool, B. K.; Dietz, T. Nat. Clim. Change 2016, 6 (6), 547. doi: 10.1038/NCLIMATE3027  doi: 10.1038/NCLIMATE3027

    2. [2]

      Schrag, D. P. Elements 2007, 3 (3), 171. doi: 10.2113/gselements.3.3.171  doi: 10.2113/gselements.3.3.171

    3. [3]

      Schultz, M. G.; Diehl, T.; Brasseur, G. P.; Zittel, W. Science 2003, 302 (5645), 624. doi: 10.1126/science.1089527  doi: 10.1126/science.1089527

    4. [4]

      Liang, J.; Liu, X.; Li, Q. Acta Phys. -Chim. Sin. 2021, 37 (9), 2010072.  doi: 10.3866/PKU.WHXB202010072

    5. [5]

      Wang, J.; Ding, W.; Wei, Z. Acta Phys. -Chim. Sin. 2021, 37 (9), 2009094.  doi: 10.3866/PKU.WHXB202009094

    6. [6]

      Ralph, T. R.; Hogarth, M. P. Platin Met. Rev. 2002, 46 (3), 117. doi: 10.3390/books978-3-03842-659-2  doi: 10.3390/books978-3-03842-659-2

    7. [7]

      Hickner, M. A.; Herring, A. M.; Coughlin, E. B. J. Polym. Sci. Part Polym. Phys. 2013, 51 (24), 1727. doi: 10.1002/polb.23395  doi: 10.1002/polb.23395

    8. [8]

      Mehta, V.; Cooper, J. S. J. Power Sources 2003, 114 (1), 32. doi: 10.1016/S0378-7753(02)00542-6  doi: 10.1016/S0378-7753(02)00542-6

    9. [9]

      Han, A.; Yan, X.; Chen, J.; Cheng, X.; Zhang, J. Acta Phys. -Chim. Sin. 2022, 38 (3), 1912052.  doi: 10.3866/PKU.WHXB201912052

    10. [10]

      Ding, L.; Tang, T.; Hu, J. Acta Phys. -Chim. Sin. 2021, 37 (9), 2010048.  doi: 10.3866/PKU.WHXB202010048

    11. [11]

      Wang, Y.; Li, L.; Hu, L.; Zhuang, L.; Lu, J.; Xu, B. Electrochem. Commun. 2003, 5 (8), 662. doi: 10.1016/S1388-2481(03)00148-6  doi: 10.1016/S1388-2481(03)00148-6

    12. [12]

      Xue, Y.; Wang, X.; Zhang, X.; Fang, J.; Xu, Z.; Zhang, Y.; Liu, X.; Liu, M.; Zhu, W.; Zhuang, Z. Acta Phys. -Chim. Sin. 2021, 37 (9), 2009103.  doi: 10.3866/PKU.WHXB202009103

    13. [13]

      Huang, G.; Mandal, M.; Peng, X.; Yang-Neyerlin, A. C.; Pivovar, B. S.; Mustain, W. E.; Kohl, P. A. J. Electrochem. Soc. 2019, 166 (10), F637. doi: 10.1149/2.1301910jes  doi: 10.1149/2.1301910jes

    14. [14]

      Hou, H. Acta Phys. -Chim. Sin. 2014, 30 (8), 1393.  doi: 10.3866/PKU.WHXB201406171

    15. [15]

      Li, N.; Leng, Y.; Hickner, M. A.; Wang, C. J. Am. Chem. Soc. 2013, 135, 10124. doi: 10.1021/ja403671u  doi: 10.1021/ja403671u

    16. [16]

      Wang, L.; Brink, J. J.; Varcoe, J. R. Chem. Commun. 2017, 53, 11771. doi: 10.1039/c7cc06392j  doi: 10.1039/c7cc06392j

    17. [17]

      Chen, S.; Peng, H.; Hu, M.; Wang, G.; Xiao, L.; Lu, J.; Zhuang, L. ACS Appl. Energy Mater. 2021, 4 (5), 4297. doi: 10.1021/acsaem.1c00433  doi: 10.1021/acsaem.1c00433

    18. [18]

      Peng, H.; Li, Q.; Hu, M.; Xiao, L.; Lu, J.; Zhuang, L. J. Power Sources 2018, 390, 165. doi: 10.1016/j.jpowsour.2018.04.047  doi: 10.1016/j.jpowsour.2018.04.047

    19. [19]

      Klingele, M.; Britton, B.; Breitwieser, M.; Vierrath, S.; Zengerle, R.; Holdcroft, S.; Thiele, S. Electrochem. Commun. 2016, 70, 65. doi: 10.1016/j.elecom.2016.06.017  doi: 10.1016/j.elecom.2016.06.017

    20. [20]

      Kim, K. H; Lee, K. Y.; Kim, H. J.; Cho, E. Lee, S. Y.; Lim T. H.; Yoon, S. P.; Hwang I. C.; Jang, J. H. Int. J. Hydrogen Energy 2010, 35 (5), 2119. doi: 10.1016/j.ijhydene.2009.11.058  doi: 10.1016/j.ijhydene.2009.11.058

    21. [21]

      Debe, M. K. Nature 2012, 486 (7401), 43. doi: 10.1038/nature11115  doi: 10.1038/nature11115

    22. [22]

      Gottesfeld, S.; Dekel, D. R.; Page, M.; Page, M.; Bae, C. Yan, Y.; Zelenay, P.; Kim, Y. J. Power Sources 2018, 375, 170. doi: 10.1016/j.jpowsour.2017.08.010  doi: 10.1016/j.jpowsour.2017.08.010

    23. [23]

      Zhang, J.; Wang, Y.; Zhang, J.; Xu, L. Acta Phys. -Chim. Sin. 2015, 31 (12), 2316.  doi: 10.3866/PKU.WHXB20151022

    24. [24]

      Liu, C. Y.; Sung, C. C. J. Power Sources 2012, 220, 348. doi: 10.1016/j.jpowsour.2012.07.090  doi: 10.1016/j.jpowsour.2012.07.090

    25. [25]

      Moreira, J.; Ocampo, A. L.; Sebastian, P. J.; Smit, M. A.; Salazar, M. D.; Angel, P. D.; Montoya, J. A.; Pérez, R.; Martínez, L. Int. J. Hydrogen Energy 2003, 28 (6), 625. doi: 10.1016/S0360-3199(02)00143-X  doi: 10.1016/S0360-3199(02)00143-X

    26. [26]

      Lobato, J.; Rodrigo, M. A.; Linares, J. J.; Scott, K. J. Power Sources 2002, 157 (2006), 284. doi: 10.1016/j.jpowsour.2005.07.040  doi: 10.1016/j.jpowsour.2005.07.040

    27. [27]

      Chen, M.; Wang, M.; Yang, Z.; Wang, X. Appl. Surf. Sci. 2017, 406, 69. doi: 10.1016/j.apsusc.2017.01.296  doi: 10.1016/j.apsusc.2017.01.296

    28. [28]

      Wang, G.; Zou, L.; Huang, Q.; Zou, Z. Yang, H. J. Mater. Chem. A 2019, 7 (16), 9447. doi: 10.1039/c8ta12382a  doi: 10.1039/c8ta12382a

    29. [29]

      Zhang, W.; Minett, A. I.; Gao, M.; Zhao, J.; Razal, J. M.; Wallace, G. G.; Romeo, T.; Chen, J. Adv. Energy Mater. 2011, 1 (4), 671. doi: 10.1002/aenm.201100092  doi: 10.1002/aenm.201100092

    30. [30]

      Zhang, C.; Yu, H.; Li, Y.; Gao, Y.; Zhao, Y.; Song, W.; Shao, Z.; Yi, B. ChemSusChem 2013, 6 (4), 659. doi: 10.1002/cssc.201200828  doi: 10.1002/cssc.201200828

    31. [31]

      Ning, F.; Bai, C.; Qin, J.; Song, Y.; Zhang, T.; Chen, J.; Wei, J.; Lu, G.; Wang, H.; Li, Y.; et al. J. Mater. Chem. A 2020, 8 (11), 5489. doi: 10.1039/c9ta13666e  doi: 10.1039/c9ta13666e

    32. [32]

      Dekel, D. R.; Rasion I, G.; Page, M.; Brandon, S. J. Power Sources 2018, 375, 191. doi: 10.1016/j.jpowsour.2017.07.012  doi: 10.1016/j.jpowsour.2017.07.012

    33. [33]

      Sheng, W.; Zhuang, Z.; Gao, M.; Zheng, J.; Chen, J.; Yan, Y. Nat. Commun. 2015, 6 (1), 1. doi: 10.1038/ncomms6848  doi: 10.1038/ncomms6848

    34. [34]

      Essalik, A.; Amouzegar, K.; Savadogo, O. J. Appl. Electrochem. 1995, 25, 404. doi: 10.1007/BF00249660  doi: 10.1007/BF00249660

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