Citation: Yue Huang, Feifei Mei, Jinfeng Zhang, Kai Dai, Graham Dawson. Construction of 1D/2D W₁₈O₄₉/Porous g-C₃N₄ S-Scheme Heterojunction with Enhanced Photocatalytic H₂ Evolution[J]. Acta Physico-Chimica Sinica, ;2022, 38(7): 210802. doi: 10.3866/PKU.WHXB202108028 shu

Construction of 1D/2D W₁₈O₄₉/Porous g-C₃N₄ S-Scheme Heterojunction with Enhanced Photocatalytic H₂ Evolution

Yue Huang ^{1, †} ,
Feifei Mei ^{1, †} ,
Jinfeng Zhang ^1,, ,
Kai Dai ^1,, ,
Graham Dawson ²

1.
Anhui Province Key Laboratory of Pollutant Sensitive Materials and Environmental Remediation, Huaibei Normal University, Huaibei 235000, Anhui Province, China
2.
Department of Chemistry, Xi'an Jiaotong Liverpool University, Suzhou 215123, Jiangsu Province, China

Corresponding author: Jinfeng Zhang, jfzhang@chnu.edu.cn Kai Dai, daikai940@chnu.edu.cn

^†

Received Date: 19 August 2021
Revised Date: 30 August 2021
Accepted Date: 4 September 2021
Available Online: 9 September 2021
Fund Project: the National Natural Science Foundation of China 51572103the National Natural Science Foundation of China 51973078the Distinguished Young Scholar of Anhui Province, China 1808085J14the Major projects of Education Department of Anhui Province, China KJ2020ZD005

Photocatalytic hydrogen production is an effective strategy for addressing energy shortage and converting solar energy into chemical energy. Exploring effective strategies to improve photocatalytic H₂ production is a key challenge in the field of energy conversion. There are numerous oxygen vacancies on the surface of non-stoichiometric W₁₈O₄₉ (WO), which result in suitable light absorption performance, but the hydrogen evolution effect is not ideal because the band potential does not reach the hydrogen evolution potential. A suitable heterojunction is constructed to optimize defects such as high carrier recombination rate and low photocatalytic performance in a semiconductor. Herein, 2D porous carbon nitride (PCN) is synthesized, followed by the in situ growth of 1D WO on the PCN to realize a step-scheme (S-scheme) heterojunction. When WO and PCN are composited, the difference between the Fermi levels of WO and PCN leads to electron migration, which balances the Fermi levels of WO and PCN. Electron transfer leads to the formation of an interfacial electric field and bends the energy bands of WO and PCN, thereby resulting in the recombination of unused electrons and holes while leaving used electrons and holes, which can accelerate the separation and charge transfer at the interface and endow the WO/PCN system with better redox capabilities. In addition, PCN with a porous structure provides more catalytic active sites. The photocatalytic performance of the sample can be investigated using the amount of hydrogen released. Compared to WO and PCN, 20%WO/PCN composite has a higher H₂ production rate (1700 μmol·g^-1·h^-1), which is 56 times greater than that of PCN (30 μmol·g^-1·h^-1). This study shows the possibility of the application of S-scheme heterojunction in the field of photocatalytic H₂ production.
- S-scheme,
- Photocatalytic H₂ production,
- W₁₈O₄₉,
- Porous carbon nitride,
- Heterojunction
1. [1]
  Ren, Y.; Li, Y.; Wu, X.; Wang, J.; Zhang, G. Chin. J. Catal. 2021, 42, 69. doi: 10.1016/s1872-2067(20)63631-2 doi: 10.1016/s1872-2067(20)63631-2
2. [2]
  Kuang, P.; Wang, Y.; Zhu, B.; Xia, F.; Tung, C. W.; Wu, J.; Chen, H. M.; Yu, J. Adv. Mater. 2021, 33, 2008599. doi: 10.1002/adma.202008599 doi: 10.1002/adma.202008599
3. [3]
  Zhang, Y.; Xu, J.; Mei, J.; Sarina, S.; Wu, Z.; Liao, T.; Yan, C.; Sun, Z. J. Hazard. Mater. 2020, 394, 122529. doi: 10.1016/j.jhazmat.2020.122529 doi: 10.1016/j.jhazmat.2020.122529
4. [4]
  He, R.; Chen, R.; Luo, J.; Zhang, S.; Xu, D. Acta Phys. -Chim. Sin. 2021, 37, 2011022. doi: 10.3866/PKU.WHXB202011022
5. [5]
  Su, Q.; Li, Y.; Hu, R.; Song, F.; Liu, S.; Guo, C.; Zhu, S.; Liu, W.; Pan, J. Adv. Sustain. Syst. 2020, 4, 2000130. doi: 10.1002/adsu.202000130 doi: 10.1002/adsu.202000130
6. [6]
  Li, Z.; Huang, W.; Liu, J.; Lv, K.; Li, Q. ACS Catal. 2021, 11, 8510. doi: 10.1021/acscatal.1c02018 doi: 10.1021/acscatal.1c02018
7. [7]
  Zhao, Y.; Shao, C.; Lin, Z.; Jiang, S.; Song, S. Small 2020, 16, 2000944. doi: 10.1002/smll.202000944 doi: 10.1002/smll.202000944
8. [8]
  Liu, H.; Yu, J.; Chen, Y.; Zhou, Z.; Xiong, G.; Zeng, L.; Li, H.; Liu, Z.; Zhao, L.; Wang, J.; et al. ACS Appl. Mater. Interfaces 2020, 12, 2362. doi: 10.1021/acsami.9b17216 doi: 10.1021/acsami.9b17216
9. [9]
  Moniruddin, M.; Oppong, E.; Stewart, D.; McCleese, C.; Roy, A.; Warzywoda, J.; Nuraje, N. Inorg. Chem. 2019, 58, 12325. doi: 10.1021/acs.inorgchem.9b01854 doi: 10.1021/acs.inorgchem.9b01854
10. [10]
  Mo, Z.; Xu, H.; She, X.; Song, Y.; Yan, P.; Yi, J.; Zhu, X.; Lei, Y.; Yuan, S.; Li, H. Appl. Surf. Sci. 2019, 467, 151. doi: 10.1016/j.apsusc.2018.10.115 doi: 10.1016/j.apsusc.2018.10.115
11. [11]
  Jiang, Z.; Chen, Q.; Zheng, Q.; Shen, R.; Zhang, P.; Li, X. Acta Phys. -Chim. Sin. 2021, 37, 2010059. doi: 10.3866/PKU.WHXB202010059
12. [12]
  Xu, F.; Meng, K.; Cheng, B.; Wang, S.; Xu, J.; Yu, J. Nat. Commun. 2020, 11, 4613. doi: 10.1038/s41467-020-18350-7 doi: 10.1038/s41467-020-18350-7
13. [13]
  Kshirsagar, A. S.; Khanna, P. K. Mater. Chem. Front. 2019, 3, 437. doi: 10.1039/c8qm00537k doi: 10.1039/c8qm00537k
14. [14]
  Lin, J.; Sun, T.; Li, M.; Yang, J.; Shen, J.; Zhang, Z.; Wang, Y.; Zhang, X.; Wang, X. J. Catal. 2019, 372, 8. doi: 10.1016/j.jcat.2019.02.019 doi: 10.1016/j.jcat.2019.02.019
15. [15]
  Wang, J.; Wang, G.; Cheng, B.; Yu, J.; Fan, J. Chin. J. Catal. 2021, 42, 56. doi: 10.1016/s1872-2067(20)63634-8 doi: 10.1016/s1872-2067(20)63634-8
16. [16]
  Mei, Z.; Wang, G.; Yan, S.; Wang, J. Acta Phys. -Chim. Sin. 2021, 37, 2009097. doi: 10.3866/PKU.WHXB202009097
17. [17]
  Wu, Q.; Cheng, Y.; Huang, F.; Li, X.; Cui, X.; Xu, J.; Wang, Y. J. Hazard. Mater. 2019, 374, 287. doi: 10.1016/j.jhazmat.2019.04.035 doi: 10.1016/j.jhazmat.2019.04.035
18. [18]
  Meng, A.; Cheng, B.; Tan, H.; Fan, J.; Su, C.; Yu, J. Appl. Catal. B 2021, 289, 120039. doi: 10.1016/j.apcatb.2021.120039 doi: 10.1016/j.apcatb.2021.120039
19. [19]
  Jeon, J. P.; Kweon, D. H.; Jang, B. J.; Ju, M. J.; Baek, J. B. Adv. Sustain. Syst. 2020, 4, 2000197. doi: 10.1002/adsu.202000197 doi: 10.1002/adsu.202000197
20. [20]
  Xiao, Y.; Tao, X.; Qiu, G.; Dai, Z.; Gao, P.; Li, B. J. Colloid Interface Sci. 2019, 550, 99. doi: 10.1016/j.jcis.2019.04.081 doi: 10.1016/j.jcis.2019.04.081
21. [21]
  Jiang, M.; Li, C.; Huang, K.; Wang, Y.; Liu, J. H.; Geng, Z.; Hou, X.; Shi, J.; Feng, S. ACS Appl. Mater. Interfaces 2020, 12, 35113. doi: 10.1021/acsami.0c11072 doi: 10.1021/acsami.0c11072
22. [22]
  Shen, C. H.; Wen, X. J.; Fei, Z. H.; Liu, Z. T.; Mu, Q. M. J. Colloid Interface Sci. 2020, 579, 297. doi: 10.1016/j.jcis.2020.06.075 doi: 10.1016/j.jcis.2020.06.075
23. [23]
  Zhang, N.; Jalil, A.; Wu, D.; Chen, S.; Liu, Y.; Gao, C.; Ye, W.; Qi, Z.; Ju, H.; Wang, C.; et al. J. Am. Chem. Soc. 2018, 140, 9434. doi: 10.1021/jacs.8b02076 doi: 10.1021/jacs.8b02076
24. [24]
  Zhang, M.; Cheng, G.; Wei, Y.; Wen, Z.; Chen, R.; Xiong, J.; Li, W.; Han, C.; Li, Z. J. Colloid Interface Sci. 2020, 572, 306. doi: 10.1016/j.jcis.2020.03.090 doi: 10.1016/j.jcis.2020.03.090
25. [25]
  Wang, B.; Chen, C.; Jiang, Y.; Ni, P.; Zhang, C.; Yang, Y.; Lu, Y.; Liu, P. Chem. Eng. J. 2021, 412, 128690. doi: 10.1016/j.cej.2021.128690 doi: 10.1016/j.cej.2021.128690
26. [26]
  Wang, K.; Li, J.; Zhang, G. ACS Appl. Mater. Interfaces 2019, 11, 27686. doi: 10.1021/acsami.9b05074 doi: 10.1021/acsami.9b05074
27. [27]
  Huo, Y.; Zhang, J.; Wang, Z.; Dai, K.; Pan, C.; Liang, C. J. Colloid Interface Sci. 2021, 585, 684. doi: 10.1016/j.jcis.2020.10.048 doi: 10.1016/j.jcis.2020.10.048
28. [28]
  Qin, D.; Xia, Y.; Li, Q.; Yang, C.; Qin, Y.; Lv, K. J. Mater. Sci. Technol. 2020, 56, 206. doi: 10.1016/j.jmst.2020.03.034 doi: 10.1016/j.jmst.2020.03.034
29. [29]
  Liu, D.; Zhang, S.; Wang, J.; Peng, T.; Li, R. ACS Appl. Mater. Interfaces 2019, 11, 27913. doi: 10.1021/acsami.9b08329 doi: 10.1021/acsami.9b08329
30. [30]
  Liang, Y.; Xu, W.; Fang, J.; Liu, Z.; Chen, D.; Pan, T.; Yu, Y.; Fang, Z. Appl. Catal. B 2021, 295, 120279. doi: 10.1016/j.apcatb.2021.120279 doi: 10.1016/j.apcatb.2021.120279
31. [31]
  Zhang, B.; Hu, X.; Liu, E.; Fan, J. Chin. J. Catal. 2021, 42, 1519. doi: 10.1016/s1872-2067(20)63765-2 doi: 10.1016/s1872-2067(20)63765-2
32. [32]
  Mei, F.; Li, Z.; Dai, K.; Zhang, J.; Liang, C. Chin. J. Catal. 2020, 41, 41. doi: 10.1016/s1872-2067(19)63389-9 doi: 10.1016/s1872-2067(19)63389-9
33. [33]
  Yang, Y.; Zhang, D.; Fan, J.; Liao, Y.; Xiang, Q. Sol. RRL 2020, 5, 2000351. doi: 10.1002/solr.202000351 doi: 10.1002/solr.202000351
34. [34]
  Li, Q.; Zhao, W.; Zhai, Z.; Ren, K.; Wang, T.; Guan, H.; Shi, H. J. Mater. Sci. Technol. 2020, 56, 216. doi: 10.1016/j.jmst.2020.03.038 doi: 10.1016/j.jmst.2020.03.038
35. [35]
  Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. Adv. Mater. 2021, 33, 2100317. doi: 10.1002/adma.202100317 doi: 10.1002/adma.202100317
36. [36]
  Liu, L.; Dai, K.; Zhang, J.; Li, L. J. Colloid Interface Sci. 2021, 604, 844. doi: 10.1016/j.jcis.2021.07.064 doi: 10.1016/j.jcis.2021.07.064
37. [37]
  He, F.; Meng, A.; Cheng, B.; Ho, W.; Yu, J. Chin. J. Catal. 2020, 41, 9. doi: 10.1016/s1872-2067(19)63382-6 doi: 10.1016/s1872-2067(19)63382-6
38. [38]
  Ke, X.; Zhang, J.; Dai, K.; Fan, K.; Liang, C. Sol. RRL 2021, 5, 2000805. doi: 10.1002/solr.202000805 doi: 10.1002/solr.202000805
39. [39]
  He, R.; Liu, H.; Liu, H.; Xu, D.; Zhang, L. J. Mater. Sci. Technol. 2020, 52, 145. doi: 10.1016/j.jmst.2020.03.027 doi: 10.1016/j.jmst.2020.03.027
40. [40]
  Chen, R.; Li, D.; Fang, Z.; Huang, Y.; Luo, B.; Shi, W. Acta Phys. -Chim. Sin. 2020, 36, 1903047. doi: 10.3866/PKU.WHXB201903047
41. [41]
  Li, X.; Mei, F.; Zhang, J.; Dai, K.; Liang, C. Appl. Surf. Sci. 2020, 507, 145213. doi: 10.1016/j.apsusc.2019.145213 doi: 10.1016/j.apsusc.2019.145213
42. [42]
  Zhuang, Y.; Liu, Y.; Meng, X. Appl. Surf. Sci. 2019, 496, 143647. doi: 10.1016/j.apsusc.2019.143647 doi: 10.1016/j.apsusc.2019.143647
43. [43]
  Peng, J.; Shen, J.; Yu, X.; Tang, H.; Zulfiqar; Liu, Q. Chin. J. Catal. 2021, 42, 87. doi: 10.1016/s1872-2067(20)63595-1 doi: 10.1016/s1872-2067(20)63595-1
44. [44]
  Li, Q.; Shi, T.; Li, X.; Lv, K.; Li, M.; Liu, F.; Li, H.; Lei, M. Appl. Catal. B 2018, 229, 8. doi: 10.1016/j.apcatb.2018.01.078 doi: 10.1016/j.apcatb.2018.01.078
45. [45]
  Vu, M. H.; Nguyen, C. C.; Do, T. O. ACS Sustain. Chem. Eng. 2020, 8, 12321. doi: 10.1021/acssuschemeng.0c04662 doi: 10.1021/acssuschemeng.0c04662
46. [46]
  Yang, Y.; Zhang, X.; Niu, C.; Feng, H.; Qin, P.; Guo, H.; Liang, C.; Zhang, L.; Liu, H.; Li, L. Appl. Catal. B 2020, 264, 118465. doi: 10.1016/j.apcatb.2019.118465 doi: 10.1016/j.apcatb.2019.118465
47. [47]
  Sun, S.; Gou, X.; Tao, S.; Cui, J.; Li, J.; Yang, Q.; Liang, S.; Yang, Z. Mater. Chem. Front. 2019, 3, 597. doi: 10.1039/c8qm00577j doi: 10.1039/c8qm00577j
48. [48]
  Yan, J.; Wang, C.; Ma, H.; Li, Y.; Liu, Y.; Suzuki, N.; Terashima, C.; Fujishima, A.; Zhang, X. Appl. Catal. B 2020, 268, 118401. doi: 10.1016/j.apcatb.2019.118401 doi: 10.1016/j.apcatb.2019.118401
49. [49]
  Li, X.; Zhang, J.; Huo, Y.; Dai, K.; Li, S.; Chen, S. Appl. Catal. B 2021, 280, 119452. doi: 10.1016/j.apcatb.2020.119452 doi: 10.1016/j.apcatb.2020.119452
50. [50]
  Xie, Y.; Zhuo, Y.; Liu, S.; Lin, Y.; Zuo, D.; Wu, X.; Li, C.; Wong, P. K. Sol. RRL 2020, 4, 1900440. doi: 10.1002/solr.201900440 doi: 10.1002/solr.201900440
51. [51]
  Hu, T.; Dai, K.; Zhang, J.; Chen, S. Appl. Catal. B 2020, 269, 118844. doi: 10.1016/j.apcatb.2020.118844 doi: 10.1016/j.apcatb.2020.118844
52. [52]
  Liu, Y.; Liu, H.; Zhou, H.; Li, T.; Zhang, L. Appl. Surf. Sci. 2019, 466, 133. doi: 10.1016/j.apsusc.2018.10.027 doi: 10.1016/j.apsusc.2018.10.027
53. [53]
  Xu, X.; Luo, F.; Tang, W.; Hu, J.; Zeng, H.; Zhou, Y. Adv. Funct. Mater. 2018, 28, 1804055. doi: 10.1002/adfm.201804055 doi: 10.1002/adfm.201804055
54. [54]
  Deng, Y.; Tang, L.; Feng, C.; Zeng, G.; Chen, Z.; Wang, J.; Feng, H.; Peng, B.; Liu, Y.; Zhou, Y. Appl. Catal. B 2018, 235, 225. doi: 10.1016/j.apcatb.2018.04.075 doi: 10.1016/j.apcatb.2018.04.075
55. [55]
  Fei, X.; Zhang, L.; Yu, J.; Zhu, B. Front. Nanotechnol. 2021, 3, 698351. doi: 10.3389/fnano.2021.698351 doi: 10.3389/fnano.2021.698351
56. [56]
  Liu, Y.; Hao, X.; Hu, H.; Jin, Z. Acta Phys. -Chim. Sin. 2021, 37, 2008030. doi: 10.3866/PKU.WHXB202008030
57. [57]
  Zhu, B.; Tan, H.; Fan, J.; Cheng, B.; Yu, J.; Ho, W. J. Materiomics 2021, 7, 988. doi: 10.1016/j.jmat.2021.02.015 doi: 10.1016/j.jmat.2021.02.015
58. [58]
  Wageh, S.; Ahmed A., A. G. a.; Rashida, J.; Xin, L.; Peng, Z. Chin. J. Catal. 2021, 42, 667. doi: 10.1016/S1872-2067(20)63705-6 doi: 10.1016/S1872-2067(20)63705-6
59. [59]
  Bao, Y.; Song, S.; Yao, G.; Jiang, S. Sol. RRL 2021, 5, 2100118. doi: 10.1002/solr.202100118 doi: 10.1002/solr.202100118
60. [60]
  Shen, R.; Lu, X.; Zheng, Q.; Chen, Q.; Ng, Y. H.; Zhang, P.; Li, X. Sol. RRL 2021, 5, 2100177. doi: 10.1002/solr.202100177 doi: 10.1002/solr.202100177
61. [61]
  Xia, P.; Cao, S.; Zhu, B.; Liu, M.; Shi, M.; Yu, J.; Zhang, Y. Angew. Chem. Int. Ed. 2020, 59, 5218. doi: 10.1002/anie.201916012 doi: 10.1002/anie.201916012
62. [62]
  Liu, L.; Hu, T.; Dai, K.; Zhang, J.; Liang, C. Chin. J. Catal. 2021, 42, 46. doi: 10.1016/s1872-2067(20)63560-4 doi: 10.1016/s1872-2067(20)63560-4
63. [63]
  Wang, R.; Shen, J.; Zhang, W.; Liu, Q.; Zhang, M.; Zulfiqar; Tang, H. Ceram. Int. 2020, 46, 23. doi: 10.1016/j.ceramint.2019.08.226 doi: 10.1016/j.ceramint.2019.08.226
64. [64]
  Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. Chem 2020, 6, 1543. doi: 10.1016/j.chempr.2020.06.010 doi: 10.1016/j.chempr.2020.06.010
65. [65]
  Wageh, S.; Al-Ghamdi, A. A.; Liu, L. Acta Phys. -Chim. Sin. 2021, 37, 2010024. Wageh, S., Al-Ghamdi, A. A.,
66. [66]
  Xiang, X.; Zhu, B.; Cheng, B.; Yu, J.; Lv, H. Small 2020, 16, 2001024. doi: 10.1002/smll.202001024 doi: 10.1002/smll.202001024
1. [1]
  Hongrui Zhang , Miaoying Cui , Yongjie Lv , Yongfang Rao , Yu Huang . A short review on research progress of ZnIn₂S₄-based S-scheme heterojunction: Improvement strategies. Chinese Chemical Letters, 2025, 36(4): 110108-. doi: 10.1016/j.cclet.2024.110108
2. [2]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
3. [3]
  Renshu Huang , Jinli Chen , Xingfa Chen , Tianqi Yu , Huyi Yu , Kaien Li , Bin Li , Shibin Yin . Synergized oxygen vacancies with Mn2O3@CeO2 heterojunction as high current density catalysts for Li–O2 batteries. Chinese Journal of Structural Chemistry, 2023, 42(11): 100171-100171. doi: 10.1016/j.cjsc.2023.100171
4. [4]
  Xiuzheng Deng , Changhai Liu , Xiaotong Yan , Jingshan Fan , Qian Liang , Zhongyu Li . Carbon dots anchored NiAl-LDH@In₂O₃ hierarchical nanotubes for promoting selective CO₂ photoreduction into CH₄. Chinese Chemical Letters, 2024, 35(6): 108942-. doi: 10.1016/j.cclet.2023.108942
5. [5]
  Xin Jiang , Han Jiang , Yimin Tang , Huizhu Zhang , Libin Yang , Xiuwen Wang , Bing Zhao . g-C₃N₄/TiO_2-X heterojunction with high-efficiency carrier separation and multiple charge transfer paths for ultrasensitive SERS sensing. Chinese Chemical Letters, 2024, 35(10): 109415-. doi: 10.1016/j.cclet.2023.109415
6. [6]
  Meijuan Chen , Liyun Zhao , Xianjin Shi , Wei Wang , Yu Huang , Lijuan Fu , Lijun Ma . Synthesis of carbon quantum dots decorating Bi₂MoO₆ microspherical heterostructure and its efficient photocatalytic degradation of antibiotic norfloxacin. Chinese Chemical Letters, 2024, 35(8): 109336-. doi: 10.1016/j.cclet.2023.109336
7. [7]
  Zheng Zhang , Lei Shi , Bin Wang , Jingyuan Qu , Xiaoling Wang , Tao Wang , Qitao Jiang , Wuhong Xue , Xiaohong Xu . Epitaxial growth of full-vdW α-In₂Se₃/MoS₂ heterostructures for all-in-one sensing and memory-computing artificial visual system. Chinese Chemical Letters, 2025, 36(3): 109687-. doi: 10.1016/j.cclet.2024.109687
8. [8]
  Qinyu Zhao , Yunchao Zhao , Songjing Zhong , Zhaoyang Yue , Zhuoheng Jiang , Shaobo Wang , Quanhong Hu , Shuncheng Yao , Kaikai Wen , Linlin Li . Urchin-like piezoelectric ZnSnO₃/Cu₃P p-n heterojunction for enhanced cancer sonodynamic therapy. Chinese Chemical Letters, 2024, 35(12): 109644-. doi: 10.1016/j.cclet.2024.109644
9. [9]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
10. [10]
  Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
11. [11]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
12. [12]
  Yihu Ke , Shuai Wang , Fei Jin , Guangbo Liu , Zhiliang Jin , Noritatsu Tsubaki . Charge transfer optimization: Role of Cu-graphdiyne/NiCoMoO4 S-scheme heterojunction and Ohmic junction. Chinese Journal of Structural Chemistry, 2024, 43(12): 100458-100458. doi: 10.1016/j.cjsc.2024.100458
13. [13]
  Kaihui Huang , Boning Feng , Xinghua Wen , Lei Hao , Difa Xu , Guijie Liang , Rongchen Shen , Xin Li . Effective photocatalytic hydrogen evolution by Ti3C2-modified CdS synergized with N-doped C-coated Cu2O in S-scheme heterojunctions. Chinese Journal of Structural Chemistry, 2023, 42(12): 100204-100204. doi: 10.1016/j.cjsc.2023.100204
14. [14]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
15. [15]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 100031-. doi: 10.3866/PKU.WHXB202402016
16. [16]
  Wenda WANG , Jinku MA , Yuzhu WEI , Shuaishuai MA . Waste biomass-derived carbon modified porous graphite carbon nitride heterojunction for efficient photodegradation of oxytetracycline in seawater. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 809-822. doi: 10.11862/CJIC.20230353
17. [17]
  Zhinan GUO , Junli WANG , Qiang ZHAO , Zhifang JIA , Zuopeng LI , Kewei WANG , Yong GUO . Cu₂O/Bi₂CrO₆ Z-scheme heterojunction: Construction and photocatalytic degradation properties for tetracycline. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 741-752. doi: 10.11862/CJIC.20240403
18. [18]
  Entian Cui , Yulian Lu , Zhaoxia Li , Zhilei Chen , Chengyan Ge , Jizhou Jiang . Interfacial B-O bonding modulated S-scheme B-doped N-deficient C₃N₄/O-doped-C₃N₅ for efficient photocatalytic overall water splitting. Chinese Chemical Letters, 2025, 36(1): 110288-. doi: 10.1016/j.cclet.2024.110288
19. [19]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
20. [20]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526

Get Citation

PDF

XML

Metrics

PDF Downloads(78)
Abstract views(1527)
HTML views(485)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Construction of 1D/2D W18O49/Porous g-C3N4 S-Scheme Heterojunction with Enhanced Photocatalytic H2 Evolution

Metrics

通讯作者: 陈斌, bchen63@163.com

Construction of 1D/2D W₁₈O₄₉/Porous g-C₃N₄ S-Scheme Heterojunction with Enhanced Photocatalytic H₂ Evolution