Citation: Jianghui Zhao, Maoling Xie, Haiyang Zhang, Ruowei Yi, Chenji Hu, Tuo Kang, Lei Zheng, Ruiguang Cui, Hongwei Chen, Yanbin Shen, Liwei Chen. In Situ Modification Strategy for Development of Room-Temperature Solid-State Lithium Batteries with High Rate Capability[J]. Acta Physico-Chimica Sinica, ;2021, 37(12): 210400. doi: 10.3866/PKU.WHXB202104003 shu

In Situ Modification Strategy for Development of Room-Temperature Solid-State Lithium Batteries with High Rate Capability

Jianghui Zhao ^{1, 2, †} ,
Maoling Xie ^{3, †} ,
Haiyang Zhang ² ,
Ruowei Yi ² ,
Chenji Hu ^{2, 4} ,
Tuo Kang ² ,
Lei Zheng ^{1, 2} ,
Ruiguang Cui ² ,
Hongwei Chen ³ ,
Yanbin Shen ^{1, 2,,} ,
Liwei Chen ^{2, 4}

1.
School of Nano-Tech and Nano-Bionics, University of Science and Technology of China, Hefei 230026, China
2.
i-Lab, CAS Center for Excellence in Nanoscience, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, China
3.
College of Materials Science and Engineering, Huaqiao University, Xiamen 361021, Fujian Province, China
4.
School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, Shanghai 200240, China

Corresponding author: Yanbin Shen, ybshen2017@sinano.ac.cn

^†

Received Date: 1 April 2021
Revised Date: 23 April 2021
Accepted Date: 23 April 2021
Available Online: 28 April 2021
Fund Project: the National Natural Science Foundation of China 21625304the National Natural Science Foundation of China 21733012the National Natural Science Foundation of China 21772190the Ministry of Science and Technology of China 2016YFB0100102

The increasing development of society has resulted in the ever-growing demand for energy storage devices. To satisfy this demand, both energy density and safety performance of lithium batteries must be improved, which is challenging. Solid-state lithium batteries are promising in this regard because of their safe operation and high electrochemical performance. In recent years, intense effort has been devoted toward the exploration of materials with high ionic conductivity for room-temperature solid-state batteries. Among several types of solid-state electrolytes, Li_1.5Al_0.5Ge_1.5(PO₄)₃ (LAGP), an inorganic NASICON-type electrolyte, has drawn considerable attention because of its high ionic conductivity, wide electrochemical window, and environmental stability. However, the formation of lithium-ion-conducting networks within the electrode and between the electrode-LAGP interface is limited because of high interfacial resistance caused by the direct contact and volume expansion between the electrode and electrolyte. Thus, the application of LAGP in the fabrication of solid-state batteries is limited. Moreover, the occurrence of the unavoidable side reaction because of the direct contact of LAGP with the lithium metal anode shortens battery life. In addition, the rigid brittle nature of the LAGP electrolyte leads to the limits the facile fabrication of solid-state batteries. To overcome these limitations, herein, a novel strategy based on in situ polymerization of a vinylene carbonate solid polymer electrolyte (PVC-SPE) was proposed. The in situ formed PVC-SPE can effectively construct ion-conducting pathways within the cathode and on the interfaces of the LAGP electrolyte and electrodes. Furthermore, the PVC-SPE can significantly inhibit the side reaction between the lithium anode and LAGP electrolyte. The electrochemical performances of Li | LAGP | Li and Li | LAGP | Li with in situ PVC-SPE modified interface symmetrical solid-state batteries were compared. The in situ modified Li | LAGP | Li symmetrical solid-state battery exhibited stability toward plating and stripping for over 2700 h and a low overpotential (34 mV) at room temperature. Moreover, a Li | LAGP | LiFePO₄ solid-state battery exhibited a capacity retention of 94% at 0.2 C after 200 cycles with a capacity of 158 mAh·g^-1. In addition, high rate capability (72.4% capacity retention at 3 C) was achieved at room temperature. Therefore, the proposed in situ modification strategy was found to resolve the interface-related problem and facilitated the construction of the ion-conducting network within the electrode; thus, it can be a promising approach for the fabrication of high-performance solid batteries.
- Ion network,
- Interface,
- In situ polymerization,
- Solid-state battery
1. [1]
  Goodenough, J. B. ACS Catal. 2017, 7, 1132. doi: 10.1021/acscatal.6b03110 doi: 10.1021/acscatal.6b03110
2. [2]
  Takada, K. Acta Mater. 2013, 61, 759. doi: 10.1016/j.actamat.2012.10.034 doi: 10.1016/j.actamat.2012.10.034
3. [3]
  Janek, J.; Zeier, W. G. Nat. Energy 2016, 1, 16141. doi: 10.1038/nenergy.2016.141 doi: 10.1038/nenergy.2016.141
4. [4]
  Hu, Y. S. Nat. Energy 2016, 1, 16042. doi: 10.1038/nenergy.2016.42 doi: 10.1038/nenergy.2016.42
5. [5]
  Hu, C.; Shen, Y.; Shen, M.; Liu, X.; Chen, H.; Liu, C.; Kang, T.; Jin, F.; Li, L.; Li, J.; et al. J. Am. Chem. Soc. 2020, 142, 18035. doi: 10.1021/jacs.0c07060 doi: 10.1021/jacs.0c07060
6. [6]
  Jin, F.; Li, J.; Hu, C. J.; Dong, H. C.; Chen, P.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1399. doi: 10.3866/PKU.WHXB201904085
7. [7]
  Blanchard, D.; Nale, A.; Sveinbjornsson, D.; Eggenhuisen, T. M.; Verkuijlen, M. H. W.; Suwarno; Vegge, T.; Kentgens, A. P. M.; De Jongh, P. E. Adv. Funct. Mater. 2015, 25, 184. doi: 10.1002/adfm.201402538 doi: 10.1002/adfm.201402538
8. [8]
  Liu, Q.; Yu, Q.; Li, S.; Wang, S.; Zhang, L.; Cai, B.; Zhou, D.; Li, B. Energy Storage Mater. 2020, 25, 613. doi: 10.1016/j.ensm.2019.09.023 doi: 10.1016/j.ensm.2019.09.023
9. [9]
  Cheng, Z. J.; Mao, Y. Y.; Dong, Q. Y.; Jin, F.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 868. doi: 10.3866/PKU.WHXB201811033
10. [10]
  Augustyn, V.; McDowell, M. T.; Vojvodic, A. Joule 2018, 2, 2189. doi: 10.1016/j.joule.2018.10.014 doi: 10.1016/j.joule.2018.10.014
11. [11]
  Kerman, K.; Luntz, A.; Viswanathan, V.; Chiang, Y. M.; Chen, Z. J. Electrochem. Soc. 2017, 164, A1731. doi: 10.1149/2.1571707jes doi: 10.1149/2.1571707jes
12. [12]
  Xu, L.; Tang, S.; Cheng, Y.; Wang, K.; Liang, J.; Liu, C.; Cao, Y. C.; Wei, F.; Mai, L. Joule 2018, 2, 1991. doi: 10.1016/j.joule.2018.07.009 doi: 10.1016/j.joule.2018.07.009
13. [13]
  Wu, X. L.; Zong, J.; Xu, H.; Wang, W.; Liu, X. J. RSC Adv. 2016, 6, 57346. doi: 10.1039/c6ra08048k doi: 10.1039/c6ra08048k
14. [14]
  Liu, Q.; Geng, Z.; Han, C.; Fu, Y.; Li, S.; He, Y. B.; Kang, F.; Li, B. J. Power Sources 2018, 389, 120. doi: 10.1016/j.jpowsour.2018.04.019 doi: 10.1016/j.jpowsour.2018.04.019
15. [15]
  Hu, R.; Qiu, H.; Zhang, H.; Wang, P.; Du, X.; Ma, J.; Wu, T.; Lu, C.; Zhou, X.; Cui, G. Small 2020, 16, e1907163. doi: 10.1002/smll.201907163 doi: 10.1002/smll.201907163
16. [16]
  Li, X.; Han, X.; Zhang, H.; Hu, R.; Du, X.; Wang, P.; Zhang, B.; Cui, G. ACS Appl. Mat. Interfaces 2020, 12, 51374. doi: 10.1021/acsami.0c13520 doi: 10.1021/acsami.0c13520
17. [17]
  Han, F.; Gao, T.; Zhu, Y.; Gaskell, K. J.; Wang, C. Adv. Mater. 2015, 27, 3473. doi: 10.1002/adma.201500180 doi: 10.1002/adma.201500180
18. [18]
  Tao, X.; Liu, Y.; Liu, W.; Zhou, G.; Zhao, J.; Lin, D.; Zu, C.; Sheng, O.; Zhang, W.; Lee, H. W.; et al. Nano Lett. 2017, 17, 2967. doi: 10.1021/acs.nanolett.7b00221 doi: 10.1021/acs.nanolett.7b00221
19. [19]
  Chen, G. H.; Bai, Y.; Gao, Y. S.; Wu, F., Wu, C. Acta Phys. -Chim. Sin. 2020, 36, 1905009. doi: 10.3866/PKU.WHXB201905009
20. [20]
  Liang, J. Y.; Zeng, X. X.; Zhang, X. D.; Wang, P. F.; Ma, J. Y.; Yin, Y. X.; Wu, X. W.; Guo, Y. G.; Wan, L. J. J. Am. Chem. Soc. 2018, 140, 6767. doi: 10.1021/jacs.8b03319 doi: 10.1021/jacs.8b03319
21. [21]
  Kim, D. H.; Oh, D. Y.; Park, K. H.; Choi, Y. E.; Nam, Y. J.; Lee, H. A.; Lee, S. M.; Jung, Y. S. Nano Lett. 2017, 17, 5, 3013. doi: 10.1021/acs.nanolett.7b00330 doi: 10.1021/acs.nanolett.7b00330
22. [22]
  Fei, H. F.; Liu, Y. P.; Wei, C. L.; Zhang, Y. C.; Feng, J. K.; Chen, C. Z.; Yu, H. J. Acta Phys. -Chim. Sin. 2020, 36, 1905015. doi: 10.3866/PKU.WHXB201905015
23. [23]
  Gong, Y.; Fu, K.; Xu, S.; Dai, J.; Hamann, T. R.; Zhang, L.; Hitz, G. T.; Fu, Z.; Ma, Z.; McOwen, D. W.; et al. Mater. Today 2018, 21, 594. doi: 10.1016/j.mattod.2018.01.001 doi: 10.1016/j.mattod.2018.01.001
24. [24]
  Wu, B.; Wang, S.; Evans, W. J.; Deng, D. Z.; Yang, J.; Xiao, J. J. Mater. Chem. A 2016, 4, 15266. doi: 10.1039/c6ta05439k doi: 10.1039/c6ta05439k
25. [25]
  Xu, L. Q.; Li, J. Y.; Liu, C.; Zou, G. Q.; Hou, H. S.; Ji, X. B.; Acta Phys. -Chim. Sin. 2020, 36, 1905013. doi: 10.3866/PKU.WHXB201905013
26. [26]
  Han, X.; Gong, Y.; Fu, K.; He, X.; Hitz, G. T.; Dai, J.; Pearse, A.; Liu, B.; Wang, H.; Rubloff, G.; et al. Nat. Mater. 2017, 16, 572. doi: 10.1038/nmat4821 doi: 10.1038/nmat4821
27. [27]
  Dong, D.; Zhou, B.; Sun, Y.; Zhang, H.; Zhong, G.; Dong, Q.; Fu, F.; Qian, H.; Lin, Z.; Lu, D.; et al. Nano Lett. 2019, 19, 2343. doi: 10.1021/acs.nanolett.8b05019 doi: 10.1021/acs.nanolett.8b05019
28. [28]
  Chen, L. Q. Acta Phys. -Chim. Sin. 2020, 36, 2001035. doi: 10.3866/PKU.WHXB202001035
29. [29]
  Wei, X.; Shriver, D. F. Chem. Mater. 1998, 10, 2307. doi: 10.1021/cm980170z doi: 10.1021/cm980170z
30. [30]
  Zhang, J.; Yang, J.; Dong, T.; Zhang, M.; Chai, J.; Dong, S.; Wu, T.; Zhou, X.; Cui, G. Small 2018, 14, 1800821. doi: 10.1002/smll.201800821 doi: 10.1002/smll.201800821
31. [31]
  Chai, J.; Liu, Z.; Ma, J.; Wang, J.; Liu, X.; Liu, H.; Zhang, J.; Cui, G.; Chen, L. Adv. Sci. (Weinh) 2017, 4, 1600377. doi: 10.1002/advs.201600377 doi: 10.1002/advs.201600377
32. [32]
  Arbi, K.; Bucheli, W.; Jiménez, R.; Sanz, J. J. Eur. Ceram. Soc. 2015, 35, 1477. doi: 10.1016/j.jeurceramsoc.2014.11.023 doi: 10.1016/j.jeurceramsoc.2014.11.023
33. [33]
  Kotobuki, M.; Koishi, M. J. Asian Ceram. Soc. 2019, 7, 551. doi: 10.1080/21870764.2019.1693680 doi: 10.1080/21870764.2019.1693680
34. [34]
  Smets, G.; Hayashi, K. J. Polym. Sci. 1958, 29, 257. doi: 10.1002/pol.1958.1202911919 doi: 10.1002/pol.1958.1202911919
35. [35]
  Chen, S.; Che, H.; Feng, F.; Liao, J.; Wang, H.; Yin, Y.; Ma, Z. F. ACS Appl. Mat. Interfaces 2019, 11, 43056. doi: 10.1021/acsami.9b11259 doi: 10.1021/acsami.9b11259
36. [36]
  Huang, S.; Cui, Z.; Qiao, L.; Xu, G.; Zhang, J.; Tang, K.; Liu, X.; Wang, Q.; Zhou, X.; Zhang, B.; et al. Electrochim. Acta 2019, 299, 820. doi: 10.1016/j.electacta.2019.01.039 doi: 10.1016/j.electacta.2019.01.039
37. [37]
  Yi, J.; Liu, Y.; Qiao, Y.; He, P.; Zhou, H. ACS Energy Lett. 2017, 2, 1378. doi: 10.1021/acsenergylett.7b00292 doi: 10.1021/acsenergylett.7b00292
38. [38]
  Hiller, M. M.; Joost, M.; Gores, H. J.; Passerini, S.; Wiemhöfer, H. D. Electrochim. Acta 2013, 114, 21. doi: 10.1016/j.electacta.2013.09.138 doi: 10.1016/j.electacta.2013.09.138
39. [39]
  Liu, Y.; Li, C.; Li, B.; Song, H.; Cheng, Z.; Chen, M.; He, P.; Zhou, H. Adv. Energy Mater. 2018, 8, 1702374. doi: 10.1002/aenm.201702374 doi: 10.1002/aenm.201702374
40. [40]
  Tsai, C. L.; Roddatis, V.; Chandran, C. V.; Ma, Q.; Uhlenbruck, S.; Bram, M.; Heitjans, P.; Guillon, O. ACS Appl. Mat. Interfaces 2016, 8, 10617. doi: 10.1021/acsami.6b00831 doi: 10.1021/acsami.6b00831
41. [41]
  Chung, H.; Kang, B. Chem. Mater. 2017, 29, 8611. doi: 10.1021/acs.chemmater.7b02301 doi: 10.1021/acs.chemmater.7b02301
42. [42]
  Guo, J.; Wen, Z.; Wu, M.; Jin, J.; Liu, Y., Electrochem. Commun. 2015, 51, 59. doi: 10.1016/j.elecom.2014.12.008 doi: 10.1016/j.elecom.2014.12.008
43. [43]
  Fan, L.; Wei, S.; Li, S.; Li, Q.; Lu, Y. Adv. Energy Mater. 2018, 8, 1702657. doi: 10.1002/aenm.201702657 doi: 10.1002/aenm.201702657
44. [44]
  Huang, Q.; Turcheniuk, K.; Ren, X.; Magasinski, A.; Song, A. Y.; Xiao, Y.; Kim, D.; Yushin, G. Nat. Mater. 2019, 18, 1343. doi: 10.1038/s41563-019-0472-7 doi: 10.1038/s41563-019-0472-7
45. [45]
  Xia, S.; Lopez, J.; Liang, C.; Zhang, Z.; Bao, Z.; Cui, Y.; Liu, W. Adv. Sci. 2019, 6, 1802353. doi: 10.1002/advs.201802353 doi: 10.1002/advs.201802353
46. [46]
  Jing, B.; Evans, C. M. J. Am. Chem. Soc. 2019, 141, 18932. doi: 10.1021/jacs.9b09811 doi: 10.1021/jacs.9b09811
47. [47]
  Liu, Q.; Zhou, D.; Shanmukaraj, D.; Li, P.; Kang, F.; Li, B.; Armand, M.; Wang, G., ACS Energy Lett. 2020, 5, 1456. doi: 10.1021/acsenergylett.0c00542 doi: 10.1021/acsenergylett.0c00542
48. [48]
  Zhang, H.; Zhang, J.; Ma, J.; Xu, G.; Dong, T.; Cui, G. Electrochem. Ener. Rev. 2019, 2, 128. doi: 10.1007/s41918-018-00027-x doi: 10.1007/s41918-018-00027-x
49. [49]
  Zhou, J.; Qian, T.; Liu, J.; Wang, M.; Zhang, L.; Yan, C. Nano Lett. 2019, 19, 3066. doi: 10.1021/acs.nanolett.9b00450 doi: 10.1021/acs.nanolett.9b00450
1. [1]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
2. [2]
  Peng Jia , Yunna Guo , Dongliang Chen , Xuedong Zhang , Jingming Yao , Jianguo Lu , Liqiang Zhang . In-situ imaging electrocatalysis in a solid-state Li-O₂ battery with CuSe nanosheets as air cathode. Chinese Chemical Letters, 2024, 35(5): 108624-. doi: 10.1016/j.cclet.2023.108624
3. [3]
  Biao Fang , Runwei Mo . PVDF-based solid-state battery. Chinese Journal of Structural Chemistry, 2024, 43(8): 100347-100347. doi: 10.1016/j.cjsc.2024.100347
4. [4]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
5. [5]
  Yaping Wang , Pengcheng Yuan , Zeyuan Xu , Xiong-Xiong Liu , Shengfa Feng , Mufan Cao , Chen Cao , Xiaoqiang Wang , Long Pan , Zheng-Ming Sun . Ti₃C₂T_x MXene in-situ transformed Li₂TiO₃ interface layer enabling 4.5 V-LiCoO₂/sulfide all-solid-state lithium batteries with superior rate capability and cyclability. Chinese Chemical Letters, 2024, 35(6): 108776-. doi: 10.1016/j.cclet.2023.108776
6. [6]
  Linhui Liu , Wuwan Xiong , Mingli Fu , Junliang Wu , Zhenguo Li , Daiqi Ye , Peirong Chen . Efficient NO_x abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870
7. [7]
  Xin Li , Ling Zhang , Yunyan Fan , Shaojing Lin , Yong Lin , Yongsheng Ying , Meijiao Hu , Haiying Gao , Xianri Xu , Zhongbiao Xia , Xinchuan Lin , Junjie Lu , Xiang Han . Carbon interconnected microsized Si film toward high energy room temperature solid-state lithium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109776-. doi: 10.1016/j.cclet.2024.109776
8. [8]
  Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS₂ on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717
9. [9]
  Dong Sui , Jiayi Liu . Constriction-susceptible lithium support for fast cycling of solid-state lithium metal battery. Chinese Chemical Letters, 2025, 36(2): 110417-. doi: 10.1016/j.cclet.2024.110417
10. [10]
  Yang LIU , Lijun WANG , Hongyu WANG , Zhidong CHEN , Lin SUN . Surface and interface modification of porous silicon anodes in lithium-ion batteries by the introduction of heterogeneous atoms and hybrid encapsulation. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 773-785. doi: 10.11862/CJIC.20250015
11. [11]
  Xinzhi Ding , Chong Liu , Jing Niu , Nan Chen , Shutao Xu , Yingxu Wei , Zhongmin Liu . Solid-state NMR study of the stability of MOR framework aluminum. Chinese Journal of Structural Chemistry, 2024, 43(4): 100247-100247. doi: 10.1016/j.cjsc.2024.100247
12. [12]
  Tianyi Hou , Yunhui Huang , Henghui Xu . Interfacial engineering for advanced solid-state Li-metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100313-100313. doi: 10.1016/j.cjsc.2024.100313
13. [13]
  Han Yan , Jingming Yao , Zhangran Ye , Qiaoquan Lin , Ziqi Zhang , Shulin Li , Dawei Song , Zhenyu Wang , Chuang Yu , Long Zhang . Al-F co-doping towards enhanced electrolyte-electrodes interface properties for halide and sulfide solid electrolytes. Chinese Chemical Letters, 2025, 36(1): 109568-. doi: 10.1016/j.cclet.2024.109568
14. [14]
  Qianqian Song , Yunting Zhang , Jianli Liang , Si Liu , Jian Zhu , Xingbin Yan . Boron nitride nanofibers enhanced composite PEO-based solid-state polymer electrolytes for lithium metal batteries. Chinese Chemical Letters, 2024, 35(6): 108797-. doi: 10.1016/j.cclet.2023.108797
15. [15]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
16. [16]
  Yang Deng , Yitao Ouyang , Chao Han . Constriction-susceptible makes fast cycling of lithium metal in solid-state batteries: Silicon as an example. Chinese Journal of Structural Chemistry, 2024, 43(7): 100276-100276. doi: 10.1016/j.cjsc.2024.100276
17. [17]
  Qian Wang , Ting Gao , Xiwen Lu , Hangchao Wang , Minggui Xu , Longtao Ren , Zheng Chang , Wen Liu . Nanophase separated, grafted alternate copolymer styrene-maleic anhydride as an efficient room temperature solid state lithium ion conductor. Chinese Chemical Letters, 2024, 35(7): 108887-. doi: 10.1016/j.cclet.2023.108887
18. [18]
  Yue Zheng , Tianpeng Huang , Pengxian Han , Jun Ma , Guanglei Cui . Cathodal Li-ion interfacial transport in sulfide-based all-solid-state batteries: Challenges and improvement strategies. Chinese Journal of Structural Chemistry, 2024, 43(10): 100390-100390. doi: 10.1016/j.cjsc.2024.100390
19. [19]
  Shuai Li , Liuting Zhang , Fuying Wu , Yiqun Jiang , Xuebin Yu . Efficient catalysis of FeNiCu-based multi-site alloys on magnesium-hydride for solid-state hydrogen storage. Chinese Chemical Letters, 2025, 36(1): 109566-. doi: 10.1016/j.cclet.2024.109566
20. [20]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590

Get Citation

PDF

XML

Metrics

PDF Downloads(7)
Abstract views(319)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142