Citation: Zeyao Zhang, Yixi Yao, Yan Li. Modulating the Diameter of Bulk Single-Walled Carbon Nanotubes Grown by FeCo/MgO Catalyst[J]. Acta Physico-Chimica Sinica, ;2022, 38(8): 210105. doi: 10.3866/PKU.WHXB202101055 shu

Modulating the Diameter of Bulk Single-Walled Carbon Nanotubes Grown by FeCo/MgO Catalyst

Zeyao Zhang ^{1, 2, 4, 5} ,
Yixi Yao ^{2, 3} ,
Yan Li ^{2, 3, 4,,}

1.
Peking University Shenzhen Institute, Shenzhen 518057, Guangdong Province, China
2.
Beijing National Laboratory for Molecular Science, Key Laboratory for the Physics and Chemistry of Nanodevices, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
3.
Academy for Advanced Interdisciplinary Studies, Peking University, Beijing 100871, China
4.
PKU-HKUST ShenZhen-HongKong Institution, Shenzhen 518057, Guangdong Province, China
5.
College of Engineering, Peking University, Beijing 100871, China

Corresponding author: Yan Li, yanli@pku.edu.cn
Received Date: 28 January 2021
Revised Date: 2 March 2021
Accepted Date: 2 March 2021
Available Online: 4 March 2021
Fund Project: the Shenzhen Basic Research Project JCYJ20170817113121505the Shenzhen KQTD Project KQTD20180411143400981the National Science and Technology Major Project of the Ministry of Science and Technology of China 2016YFA0201904the National Natural Science Foundation of China 21631002the Beijing National Laboratory for Molecular Sciences BNLMS-CXTD-202001

The diameter-controlled growth of single-walled carbon nanotubes (SWNTs) is one of the key issues of SWNT synthesis and application. To guarantee that SWNTs grow with desired diameters, it is necessary to control catalyst size and modulate growth conditions. SWNTs with diameters of 0.9–1.2 nm are highly desirable for near-infrared fluorescence bioimaging and serving as effective single-photon sources for the development of quantum devices. Herein, we used an FeCo/MgO catalyst to grow bulk SWNTs with diameters in the range and studied the influence of catalysts and chemical vapor deposition (CVD) growth conditions on the diameter of SWNTs. The preparation of catalyst precursors is a key step in obtaining catalyst nanoparticles of small size. In the impregnation process, we used three different types of metal salts, namely, sulfates, acetates, and nitrates, to prepare the catalysts. The metal sulfates, which exhibit the weakest hydrolysis ability, were found to grow SWNTs with the smallest diameters. Lowering the immersion pH, which suppresses the hydrolysis of metal ions, was also favorable for growing smaller SWNTs. Moreover, the addition of complexing agent molecules such as ethylenediaminetetraacetic acid during the impregnation process, which inhibits the hydrolysis of metal ions as well, further confined the diameter distribution of the resultant SWNTs. During the solution drying process, metal salts hydrolyze into metal hydroxides and oxides. Under mild hydrolysis conditions, the produced hydroxide and oxide particles are smaller and more likely to be uniformly distributed on the surface of the supports. Therefore, it is more favorable to produce catalysts with controlled sizes under mild hydrolysis conditions, which are preferred for diameter control of the resultant SWNTs. In the CVD growth process, we used either ethanol or methane as the carbon source and found that, under our experimental conditions, the SWNTs grown from ethanol had smaller diameters than those from methane. The hydrogen content in the CVD process also affects diameter distribution of SWNTs. As the carbon-to-hydrogen ratio decreased, SWNTs with larger diameters disappeared, and the number of SWNTs with smaller diameters increased. During the CVD process, the carbon-to-hydrogen ratio determines the carbon feeding rate to the catalysts. At a low carbon feeding rate, catalysts of large sizes are underfed and unable to grow SWNTs, whereas smaller catalysts are in a favorable condition for growth. Therefore, the average diameter of the SWNTs decreased as the carbon-to-hydrogen ratio decreased.
- Single-walled carbon nanotube,
- Chemical vapor deposition,
- Controlled growth,
- Diameter,
- Metal catalyst,
- Precursor,
- Nano particle
1. [1]
  De Volder, M. F. L.; Tawfick, S. H.; Baughman, R. H.; Hart, A. J. Science 2013, 339, 535. doi: 10.1126/science.1222453 doi: 10.1126/science.1222453
2. [2]
  Hong, G.; Diao, S.; Antaris, A. L.; Dai, H. Chem. Rev. 2015, 115, 10816. doi: 10.1021/acs.chemrev.5b00008 doi: 10.1021/acs.chemrev.5b00008
3. [3]
  Zhang, R.; Zhang, Y.; Wei, F. Chem. Soc. Rev. 2017, 46, 3661. doi: 10.1039/C7CS00104E doi: 10.1039/C7CS00104E
4. [4]
  He, X.; Htoon, H.; Doorn, S. K.; Pernice, W. H. P.; Pyatkov, F.; Krupke, R.; Jeantet, A.; Chassagneux, Y.; Voisin, C. Nat. Mater. 2018, 17, 663. doi: 10.1038/s41563-018-0109-2 doi: 10.1038/s41563-018-0109-2
5. [5]
  Rao, R.; Pint, C. L.; Islam, A. E.; Weatherup, R. S.; Hofmann, S.; Meshot, E. R.; Wu, F.; Zhou, C.; Dee, N.; Amama, P. B.; et al. ACS Nano 2018, 12, 11756. doi: 10.1021/acsnano.8b06511 doi: 10.1021/acsnano.8b06511
6. [6]
  Zhang, S., Zhang, N., Zhang, J. Acta Phys. -Chim. Sin. 2020, 36, 54. doi: 10.3866/PKU.WHXB201907021
7. [7]
  Welsher, K.; Sherlock, S. P.; Dai, H. Proc. Natl. Acad. Sci. U. S. A. 2011, 108, 8943. doi: 10.1073/pnas.1014501108 doi: 10.1073/pnas.1014501108
8. [8]
  Li, M.; Liu, X.; Zhao, X.; Yang, F.; Wang, X.; Li, Y. Top. Curr. Chem. 2017, 375, 29. doi: 10.1007/s41061-017-0116-9 doi: 10.1007/s41061-017-0116-9
9. [9]
  He, M.; Zhang, S.; Wu, Q.; Xue, H.; Xin, B.; Wang, D.; Zhang, J. Adv. Mater. 2019, 31, 1800805. doi: 10.1002/adma.201800805 doi: 10.1002/adma.201800805
10. [10]
  Yang, F.; Wang, M.; Zhang, D.; Yang, J.; Zheng, M.; Li, Y. Chem. Rev. 2020, 120, 2693. doi: 10.1021/acs.chemrev.9b00835 doi: 10.1021/acs.chemrev.9b00835
11. [11]
  Zhang, Z.; Yao, Y.; Li, Y. Sci. China Chem. 2020, 50, 1188. doi: 10.1360/SSC-2020-0115
12. [12]
  Peng, F.; Luo, D.; Sun, H.; Wang, J.; Yang, F.; Li, R.; Yang, J.; Li, Y. Chin. Sci. Bull. 2013, 58, 433. doi: 10.1007/s11434-012-5588-y doi: 10.1007/s11434-012-5588-y
13. [13]
  He, M.; Jiang, H.; Liu, B.; Fedotov, P. V.; Chernov, A. I.; Obraztsova, E. D.; Cavalca, F.; Wagner, J. B.; Hansen, T. W.; Anoshkin, I. V.; et al. Sci. Rep. 2013, 3, 1460. doi: 10.1038/srep01460 doi: 10.1038/srep01460
14. [14]
  He, M.; Jiang, H.; Kauppi, I.; Fedotov, P. V.; Chernov, A. I.; Obraztsova, E. D.; Cavalca, F.; Wagner, J. B.; Hansen, T. W.; Sainio, J.; et al. J. Mater. Chem. A 2014, 2, 5883. doi: 10.1039/C3TA15325H doi: 10.1039/C3TA15325H
15. [15]
  Maruyama, S.; Kojima, R.; Miyauchi, Y.; Chiashi, S.; Kohno, M. Chem. Phys. Lett. 2002, 360, 229. doi: 10.1016/S0009-2614(02)00838-2 doi: 10.1016/S0009-2614(02)00838-2
16. [16]
  Miyauchi, Y.; Chiashi, S.; Murakami, Y.; Hayashida, Y.; Maruyama, S. Chem. Phys. Lett. 2004, 387, 198. doi: 10.1016/j.cplett.2004.01.116 doi: 10.1016/j.cplett.2004.01.116
17. [17]
  Lim, S.; Ciuparu, D.; Pak, C.; Dobek, F.; Chen, Y.; Harding, D.; Pfefferle, L.; Haller, G. J. Phys. Chem. B 2003, 107, 11048. doi: 10.1021/jp0304778 doi: 10.1021/jp0304778
18. [18]
  Chen, Y.; Ciuparu, D.; Lim, S.; Yang, Y.; Haller, G. L.; Pfefferle, L. J. Catal. 2004, 226, 351. doi: 10.1016/j.jcat.2004.04.022 doi: 10.1016/j.jcat.2004.04.022
19. [19]
  Wang, B.; Poa, C. H. P.; Wei, L.; Li, L.-J.; Yang, Y.; Chen, Y. J. Am. Chem. Soc. 2007, 129, 9014. doi: 10.1021/ja070808k doi: 10.1021/ja070808k
20. [20]
  He, M.; Magnin, Y.; Jiang, H.; Amara, H.; Kauppinen, E. I.; Loiseau, A.; Bichara, C. Nanoscale 2018, 10, 6744. doi: 10.1039/c7nr09539b doi: 10.1039/c7nr09539b
21. [21]
  Lu, C.; Liu, J. J Phys Chem B 2006, 110, 20254. doi: 10.1021/jp0632283 doi: 10.1021/jp0632283
22. [22]
  Wang, B.; Wei, L.; Yao, L.; Li, L.-J.; Yang, Y.; Chen, Y. J. Phys. Chem. C 2007, 111, 14612. doi: 10.1021/jp0762525 doi: 10.1021/jp0762525
23. [23]
  Zhang, G.; Mann, D.; Zhang, L.; Javey, A.; Li, Y.; Yenilmez, E.; Wang, Q.; McVittie, J. P.; Nishi, Y.; Gibbons, J.; et al. Proc. Natl. Acad. Sci. U. S. A. 2005, 102, 16141. doi: 10.1073/pnas.0507064102 doi: 10.1073/pnas.0507064102
24. [24]
  Zhang, G.; Qi, P.; Wang, X.; Lu, Y.; Mann, D.; Li, X.; Dai, H. J. Am. Chem. Soc. 2006, 128, 6026. doi: 10.1021/ja061324b doi: 10.1021/ja061324b
25. [25]
  Hardeman, D.; Esconjauregui, S.; Cartwright, R.; Bhardwaj, S.; D'Arsié, L.; Oakes, D.; Clark, J.; Cepek, C.; Ducati, C.; Robertson, J. J. Appl. Phys. 2015, 117, 044308. doi: 10.1063/1.4906846 doi: 10.1063/1.4906846
26. [26]
  Chen, Y.; Wang, B.; Li, L.-J.; Yang, Y.; Ciuparu, D.; Lim, S.; Haller, G. L.; Pfefferle, L. D. Carbon 2007, 45, 2217. doi: 10.1016/j.carbon.2007.06.022 doi: 10.1016/j.carbon.2007.06.022
27. [27]
  Araujo, P. T.; Maciel, I. O.; Pesce, P. B. C.; Pimenta, M. A.; Doorn, S. K.; Qian, H.; Hartschuh, A.; Steiner, M.; Grigorian, L.; Hata, K.; et al. Phys. Rev. B 2008, 77, 241403. doi: 10.1103/PhysRevB.77.241403 doi: 10.1103/PhysRevB.77.241403
28. [28]
  Zhang, D.; Yang, J.; Li, Y. Small 2013, 9, 1284. doi: 10.1002/smll.201202986 doi: 10.1002/smll.201202986
29. [29]
  Ding, L.; Zhou, W.; Chu, H.; Jin, Z.; Zhang, Y.; Li, Y. Chem. Mater. 2006, 18, 4109. doi: 10.1021/cm061122e doi: 10.1021/cm061122e
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
3. [3]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
4. [4]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
5. [5]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
6. [6]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
7. [7]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
8. [8]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
9. [9]
  Guimin ZHANG , Wenjuan MA , Wenqiang DING , Zhengyi FU . Synthesis and catalytic properties of hollow AgPd bimetallic nanospheres. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 963-971. doi: 10.11862/CJIC.20230293
10. [10]
  Lijuan Liu , Xionglei Wang . Preparation of Hydrogels from Waste Thermosetting Unsaturated Polyester Resin by Controllable Catalytic Degradation: A Comprehensive Chemical Experiment. University Chemistry, 2024, 39(11): 313-318. doi: 10.12461/PKU.DXHX202403060
11. [11]
  Haiyuan Wang , Yiming Tang , Haoran Guo , Guohui Chen , Yajing Sun , Chao Zhao , Zhen Zhang . Comprehensive Chemistry Experimental Teaching Design Based on the Integration of Science and Education: Preparation and Catalytic Properties of Silver Nanomaterials. University Chemistry, 2024, 39(10): 219-228. doi: 10.12461/PKU.DXHX202404067
12. [12]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
13. [13]
  Chunmei GUO , Weihan YIN , Jingyi SHI , Jianhang ZHAO , Ying CHEN , Quli FAN . Facile construction and peroxidase-like activity of single-atom platinum nanozyme. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1633-1639. doi: 10.11862/CJIC.20240162
14. [14]
  Jinyi Sun , Lin Ma , Yanjie Xi , Jing Wang . Preparation and Electrocatalytic Nitrogen Reduction Performance Study of Vanadium Nitride@Nitrogen-Doped Carbon Composite Nanomaterials: A Recommended Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(4): 184-191. doi: 10.3866/PKU.DXHX202310094
15. [15]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022
16. [16]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
17. [17]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
18. [18]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
19. [19]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
20. [20]
  Siyu HOU , Weiyao LI , Jiadong LIU , Fei WANG , Wensi LIU , Jing YANG , Ying ZHANG . Preparation and catalytic performance of magnetic nano iron oxide by oxidation co-precipitation method. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1577-1582. doi: 10.11862/CJIC.20230469

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(680)
HTML views(133)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142