Citation: Meihui Jiang, Lizhi Sheng, Chao Wang, Lili Jiang, Zhuangjun Fan. Graphene Film for Supercapacitors: Preparation, Foundational Unit Structure and Surface Regulation[J]. Acta Physico-Chimica Sinica, ;2022, 38(2): 201208. doi: 10.3866/PKU.WHXB202012085 shu

Graphene Film for Supercapacitors: Preparation, Foundational Unit Structure and Surface Regulation

1.
Wood Material Science and Engineering Key Laboratory of Jilin Province, Beihua University, Jilin 132013, Jilin Province, China
2.
School of Materials Science and Engineering, Jilin Institute of Chemical Technology, Jilin 132022, Jilin Province, China
3.
School of Materials Science and Engineering, China University of Petroleum, Qingdao 266580, Shandong Province, China

Corresponding author: Lizhi Sheng, shengli_zhi@126.com Zhuangjun Fan, fanzhj666@163.com
Received Date: 30 December 2020
Revised Date: 16 January 2021
Accepted Date: 18 January 2021
Available Online: 22 January 2021
Fund Project: the National Natural Science Foundation of China 51902006the National Natural Science Foundation of China 51702117the National Natural Science Foundation of China 51672055the National Natural Science Foundation of China 51972342the Taishan Scholar Project of Shandong Province ts20190922the Key Basic Research Projects of Natural Science Foundation of Shandong Province ZR2019ZD51Department of Science and Technology of Jilin Province 20190103034JHDepartment of Science and Technology of Jilin Province 20180520014JHthe Young Elite Scientist Sponsorship Program by Jilin Province Science and Technology Association 192009

With the rapid development of the functional applications of portable and wearable electronic products (such as curved smartphones, smartwatches, laptops, and electronic skins), there is an urgent need to fabricate flexible, lightweight, and highly efficient energy storage devices that can provide sufficient power support. Flexible supercapacitors with high power density, high charging/discharging rates, wide operating temperature ranges, low maintenance consumption, and a long cycling lifespan can be integrated with smart wearable electronic products to provide power support. The conventional preparation method for the electrodes of flexible supercapacitors involves directly coating the active materials on flexible substrates. However, inactive materials such as the substrates and binders occupy a large volume and contribute notably to the weight of flexible electrodes, which is unsuitable for highly integrated flexible electronic devices. Owing to its unique characteristics, including large theoretical specific surface area, high electrical conductivity, excellent mechanical flexibility, good chemical stability, and ease of film processing, graphene has been widely used as an electrode material for flexible supercapacitors. The graphene film is a macrostructure with graphene nanosheets as the main structural units. As opposed to conventional flexible electrodes containing non-electrochemical active components such as collectors, conductive agents, and binders, graphene film electrodes are considered highly promising electrode materials for flexible supercapacitors because of their light weight and robust mechanical properties. However, the inevitable aggregation of graphene during electrode preparation creates ''dead volume'' in the film electrodes, where the electrolyte cannot reach, further limiting the specific capacitance. In this review, we review the recent research on graphene films used for flexible supercapacitors, with emphasis on the assembling methods for graphene films, regulation of the graphene units, and their electrochemical performance. First, simple preparation methods for graphene films are introduced: vacuum-assisted self-assembly, blade coating, pressing aerogel, wet spinning, and interfacial self-assembly. Second, two major strategies for structural control and surface modification of the graphene units are described in detail: (1) structural control can transform the two-dimensional graphene nanosheets into defect graphene, which not only weakens the van der Waals force and π–π bond interactions between the nanosheets, but also leads to the formation of three-dimensional conductive networks and ion transport channels during the assembly process; (2) surface modification, which can suppress the agglomeration of graphene nanosheets by introducing heteroatoms and reactive functional group molecules, while improving their electrical conductivity and wettability, and introducing pseudocapacitance. Finally, the persisting challenges and future development of the commercial applications of graphene films are discussed.
- Graphene film,
- Supercapacitor,
- Preparation method,
- Structural regulation,
- Surface modification
1. [1]
  Korkmaz, S.; Kariper, İ. A. J. Energy Storage 2020, 27, 101038. doi: 10.1016/j.est.2019.101038 doi: 10.1016/j.est.2019.101038
2. [2]
  Kumar, S.; Saeed, G.; Zhu, L.; Hui, K. N.; Kim, N. H.; Lee, J. H. Chem. Eng. J. 2021, 403, 126352. doi: 10.1016/j.cej.2020.126352 doi: 10.1016/j.cej.2020.126352
3. [3]
  Wang, J. -G.; Ren, L.; Hou, Z.; Shao, M. Chem. Eng. J. 2020, 397, 125521. doi: 10.1016/j.cej.2020.125521 doi: 10.1016/j.cej.2020.125521
4. [4]
  Tian, D.; Lu, X.; Li, W.; Li, Y.; Wang, C. Acta Phys. -Chim. Sin. 2020, 36, 1904056. [ doi: 10.3866/PKU.WHXB201904056
5. [5]
  Wang, Y.; Huo, W.; Yuan, X.; Zhang, Y. Acta Phys. -Chim. Sin. 2020, 36, 1904007. doi: 10.3866/PKU.WHXB201904007
6. [6]
  Jiang, L.; Fan, Z. Nanoscale 2014, 6, 1922. doi: 10.1039/c3nr04555b doi: 10.1039/c3nr04555b
7. [7]
  Cheng, L.; Li, X.; Li, J.; Qiu, H.; Xue, Y.; Evgenyevna, K. -I.; Kolesov, V.; Chen, C.; Yang, J. New Carbon Mater. 2020, 35, 684. doi: 10.1016/S1872-5805(20]60522-4
8. [8]
  Ma, Y.; Zhi, L. Small Methods 2019, 3, 1800199. doi: 10.1002/smtd.201800199 doi: 10.1002/smtd.201800199
9. [9]
  Li, X.; Tang, Y.; Song, J.; Yang, W.; Wang, M.; Zhu, C.; Zhao, W.; Zheng, J.; Lin, Y. Carbon 2018, 129, 236. doi: 10.1016/j.carbon.2017.11.099 doi: 10.1016/j.carbon.2017.11.099
10. [10]
  Lv, Z.; Luo, Y.; Tang, Y.; Wei, J.; Zhu, Z.; Zhou, X.; Li, W.; Zeng, Y.; Zhang, W.; Zhang, Y.; et al. Adv. Mater. 2018, 30, 1704531. doi: 10.1002/adma.201704531 doi: 10.1002/adma.201704531
11. [11]
  Jabari, E.; Ahmed, F.; Liravi, F.; Secor, E. B.; Lin, L.; Toyserkani, E. 2D Mater. 2019, 6, 042004. doi: 10.1088/2053-1583/ab29b2 doi: 10.1088/2053-1583/ab29b2
12. [12]
  Xiong, Z.; Liao, C.; Han, W.; Wang, X. Adv. Mater. 2015, 27, 4469. doi: 10.1002/adma.201501983 doi: 10.1002/adma.201501983
13. [13]
  Gao, C.; Chen, K.; Wang, Y.; Zhao, Y.; Qu, L. ChemSusChem 2020, 13, 1255. doi: 10.1002/cssc.201902707 doi: 10.1002/cssc.201902707
14. [14]
  Guo, N.; Zhang, S.; Wang, L.; Jia, D. Acta Phys. -Chim. Sin. 2020, 36, 1903055. doi: 10.3866/PKU.WHXB201903055
15. [15]
  Wang, X.; Wan, F.; Zhang, L.; Zhao, Z.; Niu, Z.; Chen, J. Adv. Funct. Mater. 2018, 28, 1707247. doi: 10.1002/adfm.201707247 doi: 10.1002/adfm.201707247
16. [16]
  Zhu, Y.; Ye, X.; Jiang, H.; Wang, L.; Zhao, P.; Yue, Z.; Wan, Z.; Jia, C. J. Power Sources 2018, 400, 605. doi: 10.1016/j.jpowsour.2018.07.075 doi: 10.1016/j.jpowsour.2018.07.075
17. [17]
  Salman, M.; Chu, X.; Huang, T.; Cai, S.; Yang, Q.; Dong, X.; Gopalsamy, K.; Gao, C. Mater. Chem. Front. 2018, 2, 2313. doi: 10.1039/c8qm00260f doi: 10.1039/c8qm00260f
18. [18]
  Meng, Q.; Du, C.; Xu, Z.; Nie, J.; Hong, M.; Zhang, X.; Chen, J. Chem. Eng. J. 2020, 393, 124684. doi: 10.1016/j.cej.2020.124684 doi: 10.1016/j.cej.2020.124684
19. [19]
  Wang, Y.; Chen, J.; Cao, J.; Liu, Y.; Zhou, Y.; Ouyang, J. -H.; Jia, D. J. Power Sources 2014, 271, 269. doi: 10.1016/j.jpowsour.2014.08.007 doi: 10.1016/j.jpowsour.2014.08.007
20. [20]
  Feng, X.; Chen, W.; Yan, L. Nanoscale 2015, 7, 3712. doi: 10.1039/c4nr06897a doi: 10.1039/c4nr06897a
21. [21]
  Hu, C.; Song, L.; Zhang, Z.; Chen, N.; Feng, Z.; Qu, L. Energy Environ. Sci. 2015, 8, 31. doi: 10.1039/c4ee02594f doi: 10.1039/c4ee02594f
22. [22]
  Lu, X.; Dou, H.; Zhang, X. Mater. Lett. 2016, 178, 304. doi: 10.1016/j.matlet.2016.05.029 doi: 10.1016/j.matlet.2016.05.029
23. [23]
  Deng, L.; Gu, Y.; Gao, Y.; Ma, Z.; Fan, G. J. Colloid Interface Sci. 2017, 494, 355. doi: 10.1016/j.jcis.2017.01.062 doi: 10.1016/j.jcis.2017.01.062
24. [24]
  Huang, C.; Hu, A.; Li, Y.; Zhou, H.; Xu, Y.; Zhang, Y.; Zhou, S.; Tang, Q.; Chen, C.; Chen, X. Nanoscale 2019, 11, 16515. doi: 10.1039/c9nr06001d doi: 10.1039/c9nr06001d
25. [25]
  Hou, M.; Xu, M.; Hu, Y.; Li, B. Electrochim. Acta 2019, 313, 245. doi: 10.1016/j.electacta.2019.05.037 doi: 10.1016/j.electacta.2019.05.037
26. [26]
  Kavinkumar, T.; Kavitha, P.; Naresh, N.; Manivannan, S.; Muneeswaran, M.; Neppolian, B. Appl. Surf. Sci. 2019, 480, 671. doi: 10.1016/j.apsusc.2019.02.231 doi: 10.1016/j.apsusc.2019.02.231
27. [27]
  Wu, D. -Y.; Zhou, W. -H.; He, L. -Y.; Tang, H. -Y.; Xu, X. -H.; Ouyang, Q. -S.; Shao, J. -J. Carbon 2020, 160, 156. doi: 10.1016/j.carbon.2020.01.019 doi: 10.1016/j.carbon.2020.01.019
28. [28]
  Yang, X.; Qiu, L.; Cheng, C.; Wu, Y.; Ma, Z. F.; Li, D. Angew. Chem. Int. Ed. 2011, 50, 7325. doi: 10.1002/anie.201100723 doi: 10.1002/anie.201100723
29. [29]
  Zhu, Y.; Ye, X.; Jiang, H.; Xia, J.; Yue, Z.; Wang, L.; Wan, Z.; Jia, C.; Yao, X. J. Power Sources 2020, 453, 227851. doi: 10.1016/j.jpowsour.2020.227851 doi: 10.1016/j.jpowsour.2020.227851
30. [30]
  Fan, Z.; Zhu, J.; Sun, X.; Cheng, Z.; Liu, Y.; Wang, Y. ACS Appl. Mater. Interfaces 2017, 9, 21763. doi: 10.1021/acsami.7b03477 doi: 10.1021/acsami.7b03477
31. [31]
  Xu, Y.; Lin, Z.; Huang, X.; Liu, Y.; Huang, Y.; Duan, X. ACS Nano 2013, 7, 4042. doi: 10.1021/nn4000836 doi: 10.1021/nn4000836
32. [32]
  Liu, F.; Song, S.; Xue, D.; Zhang, H. Adv. Mater. 2012, 24, 1089. doi: 10.1002/adma.201104691 doi: 10.1002/adma.201104691
33. [33]
  Jian, M.; Zhang, Y.; Liu, Z. Acta Phys. -Chim. Sin. 2022, 38, 2007093. doi: 10.3866/PKU.WHXB202007093
34. [34]
  Xu, Z.; Gao, C. ACS Nano 2011, 5, 2908. doi: 10.1021/nn200069w doi: 10.1021/nn200069w
35. [35]
  Xu, Z.; Gao, C. Nat. Commun. 2011, 2, 571. doi: 10.1038/ncomms1583 doi: 10.1038/ncomms1583
36. [36]
  Huang, T.; Chu, X.; Cai, S.; Yang, Q.; Chen, H.; Liu, Y.; Gopalsamy, K.; Xu, Z.; Gao, W.; Gao, C. Energy Storage Mater. 2019, 17, 349. doi: 10.1016/j.ensm.2018.07.001 doi: 10.1016/j.ensm.2018.07.001
37. [37]
  Kou, L.; Liu, Z.; Huang, T.; Zheng, B.; Tian, Z.; Deng, Z.; Gao, C. Nanoscale 2015, 7, 4080. doi: 10.1039/c4nr07038k doi: 10.1039/c4nr07038k
38. [38]
  Oksuz, M.; Erbil, H. Y. RSC Adv. 2018, 8, 17443. doi: 10.1039/c8ra02325e doi: 10.1039/c8ra02325e
39. [39]
  Kim, F.; Cote, L. J.; Huang, J. Adv. Mater. 2010, 22, 1954. doi: 10.1002/adma.200903932 doi: 10.1002/adma.200903932
40. [40]
  Loh, K. P.; Bao, Q.; Eda, G.; Chhowalla, M. Nat. Chem. 2010, 2, 1015. doi: 10.1038/nchem.907 doi: 10.1038/nchem.907
41. [41]
  Moon, I. K.; Lee, J.; Ruoff, R. S.; Lee, H. Nat. Commun. 2010, 1, 73. doi: 10.1038/ncomms1067 doi: 10.1038/ncomms1067
42. [42]
  Shao, J. J.; Lv, W.; Guo, Q.; Zhang, C.; Xu, Q.; Yang, Q. H.; Kang, F. Chem. Commun. 2012, 48, 3706. doi: 10.1039/c1cc16838j doi: 10.1039/c1cc16838j
43. [43]
  Chen, C.; Yang, Q. -H.; Yang, Y.; Lv, W.; Wen, Y.; Hou, P. -X.; Wang, M.; Cheng, H. -M. Adv. Mater. 2009, 21, 3007. doi: 10.1002/adma.200803726 doi: 10.1002/adma.200803726
44. [44]
  Oh, Y. J.; Yoo, J. J.; Kim, Y. I.; Yoon, J. K.; Yoon, H. N.; Kim, J. -H.; Park, S. B. Electrochim. Acta 2014, 116, 118. doi: 10.1016/j.electacta.2013.11.040 doi: 10.1016/j.electacta.2013.11.040
45. [45]
  Wang, H.; Sun, X.; Liu, Z.; Lei, Z. Nanoscale 2014, 6, 6577. doi: 10.1039/c4nr00538d doi: 10.1039/c4nr00538d
46. [46]
  Lei, Z.; Lu, L.; Zhao, X. S. Energy Environ. Sci. 2012, 5, 6391. doi: 10.1039/c1ee02478g doi: 10.1039/c1ee02478g
47. [47]
  Sammed, K. A.; Pan, L.; Asif, M.; Usman, M.; Cong, T.; Amjad, F.; Imran, M. A. Sci. Rep. 2020, 10, 2315. doi: 10.1038/s41598-020-58162-9 doi: 10.1038/s41598-020-58162-9
48. [48]
  Kang, L.; Zhang, G.; Bai, Y.; Wang, H.; Lei, Z.; Liu, Z. Acta Phys. -Chim. Sin. 2020, 36, 1905032. doi: 10.3866/PKU.WHXB201905032
49. [49]
  Jang, G. G.; Song, B.; Moon, K. -S.; Wong, C. -P.; Keum, J. K.; Hu, M. Z. Carbon 2017, 119, 296. doi: 10.1016/j.carbon.2017.04.023 doi: 10.1016/j.carbon.2017.04.023
50. [50]
  Xu, T.; Yang, D.; Fan, Z.; Li, X.; Liu, Y.; Guo, C.; Zhang, M.; Yu, Z. -Z. Carbon 2019, 152, 134. doi: 10.1016/j.carbon.2019.06.005 doi: 10.1016/j.carbon.2019.06.005
51. [51]
  Chao, Y.; Chen, S.; Chen, H.; Hu, X.; Ma, Y.; Gao, W.; Bai, Y. Electrochim. Acta 2018, 276, 118. doi: 10.1016/j.electacta.2018.04.156 doi: 10.1016/j.electacta.2018.04.156
52. [52]
  Wang, X.; Song, X.; Li, S.; Xu, C.; Cao, Y.; Xiao, Z.; Qi, C.; Ma, X.; Gao, J. Chem. Eng. Sci. 2020, 221, 115657. doi: 10.1016/j.ces.2020.115657 doi: 10.1016/j.ces.2020.115657
53. [53]
  Nishihara, H.; Kyotani, T. Adv. Mater. 2012, 24, 4473. doi: 10.1002/adma.201201715 doi: 10.1002/adma.201201715
54. [54]
  Liu, D.; Li, Q.; Zhao, H. J. Mater. Chem. A 2018, 6, 11471. doi: 10.1039/c8ta02580k doi: 10.1039/c8ta02580k
55. [55]
  Zhu, Y.; Murali, S.; Stoller, M. D.; Ganesh, K. J.; Cai, W.; Ferreira, P. J.; Pirkle, A.; Wallace, R. M.; Cychosz, K. A.; Thommes, M.; et al. Science 2011, 332, 1537. doi: 10.1126/science.1200770 doi: 10.1126/science.1200770
56. [56]
  Shao, Y.; Li, J.; Li, Y.; Wang, H.; Zhang, Q.; Kaner, R. B. Mater. Horiz. 2017, 4, 1145. doi: 10.1039/c7mh00441a doi: 10.1039/c7mh00441a
57. [57]
  Xu, Y.; Lin, Z.; Zhong, X.; Huang, X.; Weiss, N. O.; Huang, Y.; Duan, X. Nat. Commun. 2014, 5, 4554. doi: 10.1038/ncomms5554 doi: 10.1038/ncomms5554
58. [58]
  Xu, Y.; Chen, C. Y.; Zhao, Z.; Lin, Z.; Lee, C.; Xu, X.; Wang, C.; Huang, Y.; Shakir, M. I.; Duan, X. Nano Lett. 2015, 15, 4605. doi: 10.1021/acs.nanolett.5b01212 doi: 10.1021/acs.nanolett.5b01212
59. [59]
  Sheng, L.; Wei, T.; Liang, Y.; Jiang, L.; Qu, L.; Fan, Z. Carbon 2017, 120, 17. doi: 10.1016/j.carbon.2017.05.033 doi: 10.1016/j.carbon.2017.05.033
60. [60]
  Sheng, L.; Chang, J.; Jiang, L.; Jiang, Z.; Liu, Z.; Wei, T.; Fan, Z. Adv. Funct. Mater. 2018, 28, 1800597. doi: 10.1002/adfm.201800597 doi: 10.1002/adfm.201800597
61. [61]
  Bo, Z.; Mao, S.; Han, Z. J.; Cen, K.; Chen, J.; Ostrikov, K. K. Chem. Soc. Rev. 2015, 44, 2108. doi: 10.1039/c4cs00352g doi: 10.1039/c4cs00352g
62. [62]
  Li, M.; Liu, D.; Wei, D.; Song, X.; Wei, D.; Wee, A. T. Adv. Sci. 2016, 3, 1600003. doi: 10.1002/advs.201600003 doi: 10.1002/advs.201600003
63. [63]
  Zhang, Z.; Lee, C. -S.; Zhang, W. Adv. Energy Mater. 2017, 7, 1700678. doi: 10.1002/aenm.201700678 doi: 10.1002/aenm.201700678
64. [64]
  Zheng, S.; Li, Z.; Wu, Z. -S.; Dong, Y.; Zhou, F.; Wang, S.; Fu, Q.; Sun, C.; Guo, L.; Bao, X. ACS Nano 2017, 11, 4009. doi: 10.1021/acsnano.7b00553 doi: 10.1021/acsnano.7b00553
65. [65]
  Qi, H.; Yick, S.; Francis, O.; Murdock, A.; van der Laan, T.; Ostrikov, K.; Bo, Z.; Han, Z.; Bendavid, A. Energy Storage Mater. 2020, 26, 138. doi: 10.1016/j.ensm.2019.12.040 doi: 10.1016/j.ensm.2019.12.040
66. [66]
  Zhang, C.; Peng, Z.; Lin, J.; Zhu, Y.; Ruan, G.; Hwang, C. C.; Lu, W.; Hauge, R. H.; Tour, J. M. ACS Nano 2013, 7, 5151. doi: 10.1021/nn400750n doi: 10.1021/nn400750n
67. [67]
  Zhang, Y.; Zou, Q.; Hsu, H. S.; Raina, S.; Xu, Y.; Kang, J. B.; Chen, J.; Deng, S.; Xu, N.; Kang, W. P. ACS Appl. Mater. Interfaces 2016, 8, 7363. doi: 10.1021/acsami.5b12652 doi: 10.1021/acsami.5b12652
68. [68]
  Jang, G. G.; Song, B.; Li, L.; Keum, J. K.; Jiang, Y.; Hunt, A.; Moon, K. -S.; Wong, C. -P.; Hu, M. Z. Nano Energy 2017, 32, 88. doi: 10.1016/j.nanoen.2016.12.016 doi: 10.1016/j.nanoen.2016.12.016
69. [69]
  Zhou, Q.; Wei, T.; Yue, J.; Sheng, L.; Fan, Z. Electrochim. Acta 2018, 291, 234. doi: 10.1016/j.electacta.2018.08.104 doi: 10.1016/j.electacta.2018.08.104
70. [70]
  Hong, X.; Zhang, B.; Murphy, E.; Zou, J.; Kim, F. J. Power Sources 2017, 343, 60. doi: 10.1016/j.jpowsour.2017.01.034 doi: 10.1016/j.jpowsour.2017.01.034
71. [71]
  Li, P.; Jin, Z.; Peng, L.; Zhao, F.; Xiao, D.; Jin, Y.; Yu, G. Adv. Mater. 2018, 30, e1800124. doi: 10.1002/adma.201800124 doi: 10.1002/adma.201800124
72. [72]
  Kahriz, P. K.; Mahdavi, H.; Ehsani, A.; Heidari, A. A.; Bigdeloo, M. Electrochim. Acta 2020, 354, 136736. doi: 10.1016/j.electacta.2020.136736 doi: 10.1016/j.electacta.2020.136736
73. [73]
  Xu, L.; Jia, M.; Li, Y.; Jin, X.; Zhang, F. Sci. Rep. 2017, 7, 12857. doi: 10.1038/s41598-017-11267-0 doi: 10.1038/s41598-017-11267-0
74. [74]
  Zhou, T.; Wu, C.; Wang, Y.; Tomsia, A. P.; Li, M.; Saiz, E.; Fang, S.; Baughman, R. H.; Jiang, L.; Cheng, Q. Nat. Commun. 2020, 11, 2077. doi: 10.1038/s41467-020-15991-6 doi: 10.1038/s41467-020-15991-6
75. [75]
  Fan, Z.; Yan, J.; Zhi, L.; Zhang, Q.; Wei, T.; Feng, J.; Zhang, M.; Qian, W.; Wei, F. Adv. Mater. 2010, 22, 3723. doi: 10.1002/adma.201001029 doi: 10.1002/adma.201001029
76. [76]
  Wu, Z. S.; Zheng, Y.; Zheng, S.; Wang, S.; Sun, C.; Parvez, K.; Ikeda, T.; Bao, X.; Mullen, K.; Feng, X. Adv. Mater. 2017, 29, 1602960. doi: 10.1002/adma.201602960 doi: 10.1002/adma.201602960
77. [77]
  Huang, C.; Tang, Q.; Feng, Q.; Li, Y.; Xu, Y.; Zhang, Y.; Hu, A.; Zhang, S.; Deng, W.; Chen, X. J. Mater. Chem. A 2020, 8, 9661. doi: 10.1039/c9ta13585e doi: 10.1039/c9ta13585e
78. [78]
  Yang, X.; Zhu, J.; Qiu, L.; Li, D. Adv. Mater. 2011, 23, 2833. doi: 10.1002/adma.201100261 doi: 10.1002/adma.201100261
79. [79]
  Yang, X.; Cheng, C.; Wang, Y.; Qiu, L.; Li, D. Science 2013, 341, 534. doi: 10.1126/science.1239089 doi: 10.1126/science.1239089
80. [80]
  Li, N.; Huang, X.; Zhang, H.; Shi, Z.; Li, Y.; Wang, C. J. Mater. Chem. A 2017, 5, 14595. doi: 10.1039/c7ta03353b doi: 10.1039/c7ta03353b
81. [81]
  Li, N.; Huang, X.; Zhang, H.; Li, Y.; Wang, C. ACS Appl. Mater. Interfaces 2017, 9, 9763. doi: 10.1021/acsami.7b00487 doi: 10.1021/acsami.7b00487
82. [82]
  Li, Z.; Gadipelli, S.; Li, H.; Howard, C. A.; Brett, D. J. L.; Shearing, P. R.; Guo, Z.; Parkin, I. P.; Li, F. Nat. Energy 2020, 5, 160. doi: 10.1038/s41560-020-0560-6 doi: 10.1038/s41560-020-0560-6
83. [83]
  Zhang, L.; Huang, D.; Hu, N.; Yang, C.; Li, M.; Wei, H.; Yang, Z.; Su, Y.; Zhang, Y. J. Power Sources 2017, 342, 1. doi: 10.1016/j.jpowsour.2016.11.068 doi: 10.1016/j.jpowsour.2016.11.068
84. [84]
  Zhang, L.; Yang, C.; Hu, N.; Yang, Z.; Wei, H.; Chen, C.; Wei, L.; Xu, Z. J.; Zhang, Y. Nano Energy 2016, 26, 668. doi: 10.1016/j.nanoen.2016.06.013 doi: 10.1016/j.nanoen.2016.06.013
85. [85]
  Liu, Y.; Cai, X.; Luo, B.; Yan, M.; Jiang, J.; Shi, W. Carbon 2016, 107, 426. doi: 10.1016/j.carbon.2016.06.025 doi: 10.1016/j.carbon.2016.06.025
86. [86]
  El Rouby, W. M. A. RSC Adv. 2015, 5, 66767. doi: 10.1039/c5ra10289h doi: 10.1039/c5ra10289h
87. [87]
  Deng, S.; Berry, V. Mater. Today 2016, 19, 197. doi: 10.1016/j.mattod.2015.10.002 doi: 10.1016/j.mattod.2015.10.002
88. [88]
  Ye, X.; Zhu, Y.; Jiang, H.; Wang, L.; Zhao, P.; Yue, Z.; Wan, Z.; Jia, C. Chem. Eng. J. 2019, 361, 1437. doi: 10.1016/j.cej.2018.10.187 doi: 10.1016/j.cej.2018.10.187
89. [89]
  Lee, K.; Kim, D.; Yoon, Y.; Yang, J.; Yun, H. -G.; You, I. -K.; Lee, H. RSC Adv. 2015, 5, 60914. doi: 10.1039/c5ra10246d doi: 10.1039/c5ra10246d
90. [90]
  Yan, J.; Liu, J.; Fan, Z.; Wei, T.; Zhang, L. Carbon 2012, 50, 2179. doi: 10.1016/j.carbon.2012.01.028 doi: 10.1016/j.carbon.2012.01.028
91. [91]
  Jiang, L.; Sheng, L.; Long, C.; Fan, Z. Nano Energy 2015, 11, 471. doi: 10.1016/j.nanoen.2014.11.007 doi: 10.1016/j.nanoen.2014.11.007
92. [92]
  Ye, X.; Zhu, Y.; Jiang, H.; Yue, Z.; Wang, L.; Wan, Z.; Jia, C. J. Power Sources 2019, 441, 227167. doi: 10.1016/j.jpowsour.2019.227167 doi: 10.1016/j.jpowsour.2019.227167
93. [93]
  Kumar, R.; Sahoo, S.; Joanni, E.; Singh, R. K.; Maegawa, K.; Tan, W. K.; Kawamura, G.; Kar, K. K.; Matsuda, A. Mater. Today 2020, 39, 47. doi: 10.1016/j.mattod.2020.04.010 doi: 10.1016/j.mattod.2020.04.010
94. [94]
  Rotte, N. K.; Naresh, V.; Muduli, S.; Reddy, V.; Srikanth, V. V. S.; Martha, S. K. Electrochim. Acta 2020, 363, 137209. doi: 10.1016/j.electacta.2020.137209 doi: 10.1016/j.electacta.2020.137209
95. [95]
  Liu, Z.; Li, D.; Li, Z.; Liu, Z.; Zhang, Z. Appl. Surf. Sci. 2017, 422, 339. doi: 10.1016/j.apsusc.2017.06.046 doi: 10.1016/j.apsusc.2017.06.046
96. [96]
  Gopalsamy, K.; Balamurugan, J.; Thanh, T. D.; Kim, N. H.; Lee, J. H. Chem. Eng. J. 2017, 312, 180. doi: 10.1016/j.cej.2016.11.130 doi: 10.1016/j.cej.2016.11.130
97. [97]
  Xiao, Z.; Sheng, L.; Jiang, L.; Zhao, Y.; Jiang, M.; Zhang, X.; Zhang, M.; Shi, J.; Lin, Y.; Fan, Z. Chem. Eng. J. 2021, 408, 127269. doi: 10.1016/j.cej.2020.127269 doi: 10.1016/j.cej.2020.127269
98. [98]
  Zhang, L.; Chen, H.; Lu, X.; Wang, Y.; Tan, L.; Sui, D.; Qi, W. Appl. Surf. Sci. 2020, 529, 147022. doi: 10.1016/j.apsusc.2020.147022 doi: 10.1016/j.apsusc.2020.147022
99. [99]
  Dai, S.; Liu, Z.; Zhao, B.; Zeng, J.; Hu, H.; Zhang, Q.; Chen, D.; Qu, C.; Dang, D.; Liu, M. J. Power Sources 2018, 387, 43. doi: 10.1016/j.jpowsour.2018.03.055 doi: 10.1016/j.jpowsour.2018.03.055
100. [100]
  Enterría, M.; Pereira, M. F. R.; Martins, J. I.; Figueiredo, J. L. Carbon 2015, 95, 72. doi: 10.1016/j.carbon.2015.08.009 doi: 10.1016/j.carbon.2015.08.009
101. [101]
  Chen, H.; Lu, X.; Wang, H.; Sui, D.; Meng, F.; Qi, W. J. Energy Chem. 2020, 49, 348. doi: 10.1016/j.jechem.2020.02.043 doi: 10.1016/j.jechem.2020.02.043
102. [102]
  Jiang, H.; Ye, X.; Zhu, Y.; Yue, Z.; Wang, L.; Xie, J.; Wan, Z.; Jia, C. ACS Sustainable Chem. Eng. 2019, 7, 18844. doi: 10.1021/acssuschemeng.9b03810 doi: 10.1021/acssuschemeng.9b03810
103. [103]
  Hsiao, Y. -J.; Lin, L. -Y. ACS Sustainable Chem. Eng. 2020, 8, 2453. doi: 10.1021/acssuschemeng.9b06569 doi: 10.1021/acssuschemeng.9b06569
104. [104]
  Bakandritsos, A.; Chronopoulos, D. D.; Jakubec, P.; Pykal, M.; Čépe, K.; Steriotis, T.; Kalytchuk, S.; Petr, M.; Zbořil, R.; Otyepka, M. Adv. Funct. Mater. 2018, 28, 1801111. doi: 10.1002/adfm.201801111 doi: 10.1002/adfm.201801111
105. [105]
  Alipour, S.; Mousavi-Khoshdel, S. M. Electrochim. Acta 2019, 317, 301. doi: 10.1016/j.electacta.2019.05.029 doi: 10.1016/j.electacta.2019.05.029
106. [106]
  Ma, H.; Zhou, Q.; Wu, M.; Zhang, M.; Yao, B.; Gao, T.; Wang, H.; Li, C.; Sui, D.; Chen, Y.; Shi, G. J. Mater. Chem. A 2018, 6, 6587. doi: 10.1039/c7ta10843e doi: 10.1039/c7ta10843e
107. [107]
  Li, Y.; Zhou, M.; Xia, Z.; Gong, Q.; Liu, X.; Yang, Y.; Gao, Q. Colloids Surf. A 2020, 602, 125172. doi: 10.1016/j.colsurfa.2020.125172 doi: 10.1016/j.colsurfa.2020.125172
108. [108]
  Tian, W.; Gao, Q.; Tan, Y.; Zhang, Y.; Xu, J.; Li, Z.; Yang, K.; Zhu, L.; Liu, Z. Carbon 2015, 85, 351. doi: 10.1016/j.carbon.2015.01.001 doi: 10.1016/j.carbon.2015.01.001
109. [109]
  Jana, M.; Saha, S.; Khanra, P.; Samanta, P.; Koo, H.; Chandra Murmu, N.; Kuila, T. J. Mater. Chem. A 2015, 3, 7323. doi: 10.1039/c4ta07009g doi: 10.1039/c4ta07009g
110. [110]
  Ai, W.; Zhou, W.; Du, Z.; Du, Y.; Zhang, H.; Jia, X.; Xie, L.; Yi, M.; Yu, T.; Huang, W. J. Mater. Chem. 2012, 22, 23439. doi: 10.1039/c2jm35234f doi: 10.1039/c2jm35234f
111. [111]
  Vermisoglou, E. C.; Jakubec, P.; Bakandritsos, A.; Pykal, M.; Talande, S.; Kupka, V.; Zboril, R.; Otyepka, M. Chem. Mater. 2019, 31, 4698. doi: 10.1021/acs.chemmater.9b00655 doi: 10.1021/acs.chemmater.9b00655
112. [112]
  Jiang, L.; Sheng, L.; Long, C.; Wei, T.; Fan, Z. Adv. Energy Mater. 2015, 5, 1500771. doi: 10.1002/aenm.201500771 doi: 10.1002/aenm.201500771
113. [113]
  Zhao, G.; Zhao, F. -G.; Sun, J.; Wang, W.; Lu, Y.; Li, W. -S.; Chen, Q. -Y. Carbon 2015, 94, 114. doi: 10.1016/j.carbon.2015.06.061 doi: 10.1016/j.carbon.2015.06.061
114. [114]
  Yang, J.; Zou, L. Electrochim. Acta 2014, 130, 791. doi: 10.1016/j.electacta.2014.03.077 doi: 10.1016/j.electacta.2014.03.077
1. [1]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
2. [2]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
3. [3]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
4. [4]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
5. [5]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
6. [6]
  Zongfei YANG , Xiaosen ZHAO , Jing LI , Wenchang ZHUANG . Research advances in heteropolyoxoniobates. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 465-480. doi: 10.11862/CJIC.20230306
7. [7]
  Huan LI , Shengyan WANG , Long Zhang , Yue CAO , Xiaohan YANG , Ziliang WANG , Wenjuan ZHU , Wenlei ZHU , Yang ZHOU . Growth mechanisms and application potentials of magic-size clusters of groups Ⅱ-Ⅵ semiconductors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1425-1441. doi: 10.11862/CJIC.20240088
8. [8]
  Kuaibing Wang , Honglin Zhang , Wenjie Lu , Weihua Zhang . Experimental Design and Practice for Recycling and Nickel Content Detection from Waste Nickel-Metal Hydride Batteries. University Chemistry, 2024, 39(11): 335-341. doi: 10.12461/PKU.DXHX202403084
9. [9]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
10. [10]
  Hao BAI , Weizhi JI , Jinyan CHEN , Hongji LI , Mingji LI . Preparation of Cu₂O/Cu-vertical graphene microelectrode and detection of uric acid/electroencephalogram. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1309-1319. doi: 10.11862/CJIC.20240001
11. [11]
  Wen LUO , Lin JIN , Palanisamy Kannan , Jinle HOU , Peng HUO , Jinzhong YAO , Peng WANG . Preparation of high-performance supercapacitor based on bimetallic high nuclearity titanium-oxo-cluster based electrodes. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 782-790. doi: 10.11862/CJIC.20230418
12. [12]
  Yunting Shang , Yue Dai , Jianxin Zhang , Nan Zhu , Yan Su . Something about RGO (Reduced Graphene Oxide). University Chemistry, 2024, 39(9): 273-278. doi: 10.3866/PKU.DXHX202306050
13. [13]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
14. [14]
  Hongwei Ma , Hui Li . Three Methods for Structure Determination from Powder Diffraction Data. University Chemistry, 2024, 39(3): 94-102. doi: 10.3866/PKU.DXHX202310035
15. [15]
  Haiyu Nie , Chenhui Zhang , Fengpei Du . Ideological and Political Design for the Preparation, Characterization and Particle Size Control Experiment of Nanoemulsion. University Chemistry, 2024, 39(2): 41-46. doi: 10.3866/PKU.DXHX202306055
16. [16]
  Haiping Wang . A Streamlined Method for Drawing Lewis Structures Using the Valence State of Outer Atoms. University Chemistry, 2024, 39(8): 383-388. doi: 10.12461/PKU.DXHX202401073
17. [17]
  Zhenlin Zhou , Siyuan Chen , Yi Liu , Chengguo Hu , Faqiong Zhao . A New Program of Voltammetry Experiment Teaching Based on Laser-Scribed Graphene Electrode. University Chemistry, 2024, 39(2): 358-370. doi: 10.3866/PKU.DXHX202308049
18. [18]
  Lan Ma , Cailu He , Ziqi Liu , Yaohan Yang , Qingxia Ming , Xue Luo , Tianfeng He , Liyun Zhang . Magical Surface Chemistry: Fabrication and Application of Oil-Water Separation Membranes. University Chemistry, 2024, 39(5): 218-227. doi: 10.3866/PKU.DXHX202311046
19. [19]
  Xinyuan Shi , Chenyangjiang , Changyu Zhai , Xuemei Lu , Jia Li , Zhu Mao . Preparation and Photoelectric Performance Characterization of Perovskite CsPbBr₃ Thin Films. University Chemistry, 2024, 39(6): 383-389. doi: 10.3866/PKU.DXHX202312019
20. [20]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099

Get Citation

PDF

XML

Metrics

PDF Downloads(46)
Abstract views(1970)
HTML views(582)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142