Citation: Tonghui Cui, Hangyue Li, Zewei Lyu, Yige Wang, Minfang Han, Zaihong Sun, Kaihua Sun. Identification of Electrode Process in Large-Size Solid Oxide Fuel Cell[J]. Acta Physico-Chimica Sinica, ;2022, 38(8): 201100. doi: 10.3866/PKU.WHXB202011009 shu

Identification of Electrode Process in Large-Size Solid Oxide Fuel Cell

1.
Department of Energy and Power Engineering, State Key Laboratory of Control and Simulation of Power System and Generation Equipments, Tsinghua University, Beijing 100084, China
2.
Equipments, Tsinghua University, Beijing 100084, China

Corresponding author: Minfang Han, hanminfang@tsinghua.edu.cn
Received Date: 3 November 2020
Revised Date: 7 December 2020
Accepted Date: 7 December 2020
Available Online: 15 December 2020
Fund Project: the National Key R&D Program of China 2017YFB0601903the Beijing Municipal Science and Technology Commission Z191100004619009the Tsinghua University Initiative Scientific Research Program 20193080038

Solid oxide fuel cell (SOFC) with high energy conversion efficiency, low pollutant emission, and good fuel adaptability has witnessed rapid development in recent years. However, the commercialization of SOFC remains limited by constraints of performance and stability. Electrochemical impedance spectroscopy (EIS) can distinguish ohmic impedance caused by ion transport from polarization impedance related to electrode reaction; it has been widely used in the research of performance and stability as an efficient on-line characterization technology. The physical/chemical processes involved in EIS overlap significantly and can be decomposed by the distribution of relaxation times (DRT) method which does not depend on prior assumptions. Since industrial large-size SOFC is vulnerable to the influence of inductance and disturbance when testing EIS, its EIS analysis is rarely studied and mostly based on the research results of cells with smaller electrode active area. To further elucidate the impedance spectrum of industrial large-size SOFC under actual working conditions, the EIS of industrial-size (10 cm × 10 cm) anode-supported planar SOFC was systematically tested over a broad temperature and anode/cathode gas composition range. First, the quality of the impedance data was examined by performing a Kramers-Kronig test. The residuals of real and imaginary data were within the range of ±1%, indicating good data quality. Then, the DRT method was adopted to parse the EIS data. By comparing and analyzing the DRT results under different conditions, the corresponding relationships between each characteristic peak in the DRT results and the specific electrode process in the SOFC were revealed. The characteristic frequencies were separated into 0.5-1, 1-30, 10-30, 1 × 10²-1 × 10³, and 1 × 10⁴-3 × 10⁴ Hz regions, corresponding to gas conversion within the anode, gas diffusion within the anode, oxygen surface exchange reaction within the cathode, charge-transfer reaction within the anode, and oxygen ionic transport process, respectively. In this study, the identification of each electrode process in industrial large-size SOFC is realized, indicate that the gas conversion process in large-size SOFC with larger active area and smaller flows cannot be ignored compared with the cells with smaller electrode active area. The method followed and the results obtained have a universal quality and can be applied to the in situ characterization, online monitoring, and degradation mechanism research of SOFC, thus laying a foundation for the optimization of the performance and stability.
- Solid oxide fuel cell,
- Electrochemical impedance spectroscopy,
- Distribution of relaxation time,
- Large-size
1. [1]
  Hjalmarsson, P.; Sun, X.; Liu, Y. L.; Chen, M. J. Power Sources 2014, 262, 316. doi: 10.1016/j.jpowsour.2014.03.133 doi: 10.1016/j.jpowsour.2014.03.133
2. [2]
  Fang, Q.; Frey, C. E.; Menzler, N. H.; Blum, L. J. Electrochem. Soc. 2018, 165 (2), F38. doi: 10.1149/2.0541802jes doi: 10.1149/2.0541802jes
3. [3]
  Hauch, A.; Brodersen, K.; Chen, M.; Mogensen, M. B. Solid State Ionics 2016, 293, 27. doi: 10.1016/j.ssi.2016.06.003 doi: 10.1016/j.ssi.2016.06.003
4. [4]
  Lyu, Z.; Wang, Y.; Zhang, Y.; Han, M. Chem. Eng. J. 2020, 393, 124755. doi: 10.1016/j.cej.2020.124755 doi: 10.1016/j.cej.2020.124755
5. [5]
  Barfod, R.; Hagen, A.; Ramousse, S.; Hendriksen, P. V.; Mogensen, M. Fuel Cells 2006, 6 (2), 141. doi: 10.1002/fuce.200500113 doi: 10.1002/fuce.200500113
6. [6]
  Jensen, S. R. H. J.; Hauch, A.; Hendriksen, P. V.; Mogensen, M. J. Electrochem. Soc. 2009, 156 (6), B757. doi: 10.1149/1.3116247 doi: 10.1149/1.3116247
7. [7]
  Schichlein, H.; Müller, A. C.; Voigts, M.; Krügel, A.; Ivers-Tiffée, E. J. Appl. Electrochem. 2002, 32 (8), 875. doi: 10.1023/a:1020599525160 doi: 10.1023/a:1020599525160
8. [8]
  Leonide, A.; Sonn, V.; Weber, A.; Ivers-Tiffée, E. J. Electrochem. Soc. 2008, 155 (1), B36. doi: 10.1149/1.2801372 doi: 10.1149/1.2801372
9. [9]
  Endler, C.; Leonide, A.; Weber, A.; Tietz, F.; Ivers-Tiffée, E. J. Electrochem. Soc. 2010, 157 (2), B292. doi: 10.1149/1.3270047 doi: 10.1149/1.3270047
10. [10]
  Kromp, A.; Leonide, A.; Weber, A.; Ivers-Tiffée, E. J. Electrochem. Soc. 2011, 158 (8), B980. doi: 10.1149/1.3597177 doi: 10.1149/1.3597177
11. [11]
  Caliandro, P.; Nakajo, A.; Diethelm, S.; Van herle, J. J. Power Sources 2019, 436, 226838. doi: 10.1016/j.jpowsour.2019.226838 doi: 10.1016/j.jpowsour.2019.226838
12. [12]
  Shi, W. Y.; Jia, C.; Zhang, Y. L.; Lü, Z. W.; Han, M. F. Acta Phys. -Chim. Sin. 2019, 35 (5), 509. doi: 10.3866/PKU.WHXB201806071
13. [13]
  Vinke, I. C.; de Haart, L. G. J.; Eichel, R. A. ECS Trans. 2019, 91 (1), 589. doi: 10.1149/09101.0589ecst doi: 10.1149/09101.0589ecs
14. [14]
  Fang, Q.; Blum, L.; Menzler, N. H. J. Electrochem. Soc. 2015, 162 (8), F907. doi: 10.1149/2.0941508jes doi: 10.1149/2.0941508jes
15. [15]
  Sun, X.; Hendriksen, P. V.; Mogensen, M. B.; Chen, M. Fuel Cells 2019, 19 (6), 740. doi: 10.1002/fuce.201900081 doi: 10.1002/fuce.201900081
16. [16]
  Jia, C.; Chen, M.; Han, M. Int. J. Appl. Ceram. Technol. 2017, 14 (5), 1006. doi: 10.1111/ijac.12748 doi: 10.1111/ijac.12748
17. [17]
  Sonn, V.; Leonide, A.; Ivers-Tiffée, E. J. Electrochem. Soc. 2008, 155 (7), B675. doi: 10.1149/1.2908860 doi: 10.1149/1.2908860
18. [18]
  Bessler, W. G.; Gewies, S. J. Electrochem. Soc. 2007, 154 (6), B548. doi: 10.1149/1.2720639 doi: 10.1149/1.2720639
19. [19]
  Fan, H.; Keane, M.; Singh, P.; Han, M. J. Power Sources 2014, 268, 634. doi: 10.1016/j.jpowsour.2014.03.080 doi: 10.1016/j.jpowsour.2014.03.080
20. [20]
  Shi, W.; Lyu, Z.; Han, M. ECS Trans. 2019, 91 (1), 791. doi: 10.1149/09101.0791ecst doi: 10.1149/09101.0791ecst
21. [21]
  Bessler, W.; Warnatz, J.; Goodwin, D. Solid State Ionics 2007, 177 (39-40), 3371. doi: 10.1016/j.ssi.2006.10.020 doi: 10.1016/j.ssi.2006.10.020
22. [22]
  Shri Prakash, B.; Senthil Kumar, S.; Aruna, S. T. Renew. Sust. Energy Rev. 2014, 36, 149. doi: 10.1016/j.rser.2014.04.043 doi: 10.1016/j.rser.2014.04.043
23. [23]
  Simrick, N. J.; Bieberle-Hütter, A.; Ryll, T. M.; Kilner, J. A.; Atkinson, A.; Rupp, J. L. M. Solid State Ionics 2012, 206, 7. doi: 10.1016/j.ssi.2011.10.029 doi: 10.1016/j.ssi.2011.10.029
24. [24]
  Endler-Schuck, C.; Joos, J.; Niedrig, C.; Weber, A.; Ivers-Tiffée, E. Solid State Ionics 2015, 269, 67. doi: 10.1016/j.ssi.2014.11.018 doi: 10.1016/j.ssi.2014.11.018
25. [25]
  Boukamp, B. Solid State Ionics 2004, 169 (1-4), 65. doi: 10.1016/j.ssi.2003.07.002 doi: 10.1016/j.ssi.2003.07.002
26. [26]
  Schönleber, M.; Klotz, D.; Ivers-Tiffée, E. Electrochim. Acta 2014, 131, 20. doi: 10.1016/j.electacta.2014.01.034 doi: 10.1016/j.electacta.2014.01.034
27. [27]
  Dittrich, L.; Nohl, M.; Jaekel, E. E.; Foit, S.; de Haart, L. G. J.; Eichel, R. A. J. Electrochem. Soc. 2019, 166 (13), F971. doi: 10.1149/2.0581913jes doi: 10.1149/2.0581913jes
28. [28]
  Tong, X.; Ovtar, S.; Brodersen, K.; Hendriksen, P. V.; Chen, M. J. Power Sources 2020, 451, 227742. doi: 10.1016/j.jpowsour.2020.227742 doi: 10.1016/j.jpowsour.2020.227742
29. [29]
  Wang, J.; Huang, Q. A.; Li, W. H.; Wamg, J.; Zhuang, Q. C.; Zhang, J. J. J. Electrochem. 2020, 26, 607. doi: 10.13208/j.electrochem.200641
30. [30]
  Primdahl, S.; Mogensen, M. J. Electrochem. Soc. 1998, 145 (7), 2431. doi: 10.1149/1.1838654 doi: 10.1149/1.1838654
31. [31]
  Leonide, A.; Apel, Y.; Ivers-Tiffee, E. ECS Trans. 2009, 19 (20), 81. doi: 10.1149/1.3247567 doi: 10.1149/1.3247567
32. [32]
  Primdahl, S.; Mogensen, M. J. Electrochem. Soc. 1999, 146 (8), 2827. doi: 10.1149/1.1392015 doi: 10.1149/1.1392015
33. [33]
  Hong, J.; Bhardwaj, A.; Bae, H.; Kim, I. H.; Song, S. J. J. Electrochem. Soc. 2020, 167 (11), 114504. doi: 10.1149/1945-7111/aba00f doi: 10.1149/1945-7111/aba00f
34. [34]
  Gewies, S.; Bessler, W. G. J. Electrochem. Soc. 2008, 155 (9), B937. doi: 10.1149/1.2943411 doi: 10.1149/1.2943411
35. [35]
  Sumi, H.; Shimada, H.; Yamaguchi, Y.; Yamaguchi, T.; Fujishiro, Y. Electrochim. Acta 2020, 339, 135913. doi: 10.1016/j.electacta.2020.135913 doi: 10.1016/j.electacta.2020.135913
1. [1]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
2. [2]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
3. [3]
  Linbao Zhang , Weisi Guo , Shuwen Wang , Ran Song , Ming Li . Electrochemical Oxidation of Sulfides to Sulfoxides. University Chemistry, 2024, 39(11): 204-209. doi: 10.3866/PKU.DXHX202401009
4. [4]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
5. [5]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
6. [6]
  Zhihuan XU , Qing KANG , Yuzhen LONG , Qian YUAN , Cidong LIU , Xin LI , Genghuai TANG , Yuqing LIAO . Effect of graphene oxide concentration on the electrochemical properties of reduced graphene oxide/ZnS. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1329-1336. doi: 10.11862/CJIC.20230447
7. [7]
  Hongbo Zhang , Yihong Tang , Suxia Zhang , Yuanting Li . Electrochemical Monitoring of Photocatalytic Degradation of Phenol Pollutants: A Recommended Comprehensive Analytical Chemistry Experiment. University Chemistry, 2024, 39(6): 326-333. doi: 10.3866/PKU.DXHX202310013
8. [8]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
9. [9]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
10. [10]
  Yongming Zhu , Huili Hu , Yuanchun Yu , Xudong Li , Peng Gao . Construction and Practice on New Form Stereoscopic Textbook of Electrochemistry for Energy Storage Science and Engineering: Taking Basic Course of Electrochemistry as an Example. University Chemistry, 2024, 39(8): 44-47. doi: 10.3866/PKU.DXHX202312086
11. [11]
  Liangzhen Hu , Li Ni , Ziyi Liu , Xiaohui Zhang , Bo Qin , Yan Xiong . A Green Chemistry Experiment on Electrochemical Synthesis of Benzophenone. University Chemistry, 2024, 39(6): 350-356. doi: 10.3866/PKU.DXHX202312001
12. [12]
  Jinyao Du , Xingchao Zang , Ningning Xu , Yongjun Liu , Weisi Guo . Electrochemical Thiocyanation of 4-Bromoethylbenzene. University Chemistry, 2024, 39(6): 312-317. doi: 10.3866/PKU.DXHX202310039
13. [13]
  Zhengli Hu , Jia Wang , Yi-Lun Ying , Shaochuang Liu , Hui Ma , Wenwei Zhang , Jianrong Zhang , Yi-Tao Long . Exploration of Ideological and Political Elements in the Development History of Nanopore Electrochemistry. University Chemistry, 2024, 39(8): 344-350. doi: 10.3866/PKU.DXHX202401072
14. [14]
  Ping ZHANG , Chenchen ZHAO , Xiaoyun CUI , Bing XIE , Yihan LIU , Haiyu LIN , Jiale ZHANG , Yu'nan CHEN . Preparation and adsorption-photocatalytic performance of ZnAl@layered double oxides. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1965-1974. doi: 10.11862/CJIC.20240014
15. [15]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
16. [16]
  Fei Nie , Jiawei Liu , Chunxin Zhao , Hongbo Cui , Yan Li , Bin Cui . Construction of a Chemical Experimental Demonstration Center Supporting the Cultivation of Top-Notch Innovative Talents under the “Grand Ideological and Political” Framework: A Case Study of Northwest University. University Chemistry, 2024, 39(7): 32-39. doi: 10.12461/PKU.DXHX202404122
17. [17]
  Hao Wu , Zhen Liu , Dachang Bai . ¹H NMR Spectrum of Amide Compounds. University Chemistry, 2024, 39(3): 231-238. doi: 10.3866/PKU.DXHX202309020
18. [18]
  Jiahong ZHENG , Jiajun SHEN , Xin BAI . Preparation and electrochemical properties of nickel foam loaded NiMoO₄/NiMoS₄ composites. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 581-590. doi: 10.11862/CJIC.20230253
19. [19]
  Tiantian MA , Sumei LI , Chengyu ZHANG , Lu XU , Yiyan BAI , Yunlong FU , Wenjuan JI , Haiying YANG . Methyl-functionalized Cd-based metal-organic framework for highly sensitive electrochemical sensing of dopamine. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 725-735. doi: 10.11862/CJIC.20230351
20. [20]
  Qin ZHU , Jiao MA , Zhihui QIAN , Yuxu LUO , Yujiao GUO , Mingwu XIANG , Xiaofang LIU , Ping NING , Junming GUO . Morphological evolution and electrochemical properties of cathode material LiAl_0.08Mn_1.92O₄ single crystal particles. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1549-1562. doi: 10.11862/CJIC.20240022

Get Citation

PDF

XML

Metrics

PDF Downloads(45)
Abstract views(1293)
HTML views(365)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142