Citation: Que Haifeng, Jiang Huaning, Wang Xingguo, Zhai Pengbo, Meng Lingjia, Zhang Peng, Gong Yongji. Utilization of the van der Waals Gap of 2D Materials[J]. Acta Physico-Chimica Sinica, ;2021, 37(11): 201005. doi: 10.3866/PKU.WHXB202010051 shu

Utilization of the van der Waals Gap of 2D Materials

School of Materials Science and Engineering, Beihang University, Beijing 100191, China

Corresponding author: Gong Yongji, yongjigong@buaa.edu.cn
Received Date: 23 October 2020
Revised Date: 21 November 2020
Accepted Date: 23 November 2020
Available Online: 1 December 2020
Fund Project: the National Natural Science Foundation of China 51872012The project was supported by the National Natural Science Foundation of China (51872012) and the Key Technologies Research and Development Program of China (2018YFA0306900)the Key Technologies Research and Development Program of China 2018YFA0306900

Since their discovery, two-dimensional (2D) materials have attracted significant research attention owing to their excellent and controllable physical and chemical properties. These materials have emerged rapidly as important material system owing to their unique properties such as electricity, optics, quantum properties, and catalytic properties. 2D materials are mostly bonded by strong ionic or covalent bonds within the layers, and the layers are stacked together by van der Waals forces, thereby making it possible to peel off 2D materials with few or single layers. The weak interaction between the layers of 2D materials also enables the use of van der Waals gaps for regulating the electronic structure of the system and further optimizing the material properties. The introduction of guest atoms can significantly change the interlayer spacing of the original material and coupling strength between the layers. Also, interaction between the guest and host atom also has the potential to change the electronic structure of the original material, thereby affecting the material properties. For example, the electron structure of a host can be modified by interlayer guest atoms, and characteristics such as carrier concentration, optical transmittance, conductivity, and band gap can be tuned. Organic cations intercalated between the layers of 2D materials can produce stable superlattices, which have great potential for developing new electronic and optoelectronic devices. This method enables the modulation of the electrical, magnetic, and optical properties of the original materials, thereby establishing a family of 2D materials with widely adjustable electrical and optical properties. It is also possible to introduce some new properties to the 2D materials, such as magnetic properties and catalytic properties, by the intercalation of guest atoms. Interlayer storage, represented by lithium-ion batteries, is also an important application of 2D van der Waals gap utilization in energy storage, which has also attracted significant research attention. Herein, we review the studies conducted in recent years from the following aspects: (1) changing the layer spacing to change the interlayer coupling; (2) introducing the interaction between guest and host atoms to change the physico-chemical properties of raw materials; (3) introducing the guest substances to obtain new properties; and (4) interlayer energy storage. We systematically describe various interlayer optimization methods of 2D van der Waals gaps and their effects on the physical and chemical properties of synthetic materials, and suggest the direction of further development and utilization of 2D van der Waals gaps.
- Two-dimensional materials,
- van der Waals gap,
- Intercalation technology,
- Interlayer interaction,
- Performance optimization,
- Energy storage
1. [1]
  Hu, Y. J.; Jin, J.; Zhang, H.; Wu, P.; Cai, C. X. Acta Phys. -Chim. Sin. 2010, 26, 2073. doi: 10.3866/PKU.WHXB20100812
2. [2]
  Zhang, P.; Ma, L. L.; Fan, F. F.; Zeng, Z.; Peng, C.; Loya, P. E.; Liu, Z.; Gong, Y. J.; Zhang, J. N.; Zhang X. X.; et al. Nat. Commun. 2014, 5, 3782. doi: 10.1038/ncomms4782 doi: 10.1038/ncomms4782
3. [3]
  Li, J. Y.; Ding, Y.; Zhang, D. W.; Zhou, P. Acta Phys. -Chim. Sin. 2019, 35, 1058. doi: 10.3866/PKU.WHXB201812020
4. [4]
  Jiang, H. N.; Zhang, P.; Wang, X. G.; Gong, Y. J. Nano Res. 2020, doi: 10.1007/s12274-020-3020-5
5. [5]
  Wang, X. G.; Zhou, Z.; Zhang, P.; Zhang, S. Q.; Ma, Y.; Yang, W. W.; Wang, H.; Li, B. X.; Meng, L. J.; Jiang, H. N.; et al. Chem. Mater. 2020, 32, 2321. doi: 10.1021/acs.chemmater.9b04416 doi: 10.1021/acs.chemmater.9b04416
6. [6]
  Xue, Y. H.; Zhang, Q.; Wang, W. J.; Cao, H.; Yang, Q. H.; Fu, L. Adv. Energy Mater. 2017, 7, 1602684. doi: 10.1002/aenm.201602684 doi: 10.1002/aenm.201602684
7. [7]
  Wang, C.; He, Q. Y.; Halim, U.; Liu, Y. Y.; Zhu, E. B.; Lin, Z. Y.; Xiao, H.; Duan, X. D.; Feng, Z. Y.; Chen, R.; et al. Nature 2018, 555, 231. doi: 10.1038/nature25774 doi: 10.1038/nature25774
8. [8]
  Kobayashi, K.; Yamauchi, J. Phys. Rev. B: Condens. 1995, 51, 17085. doi: 10.1103/PhysRevB.51.17085 doi: 10.1103/PhysRevB.51.17085
9. [9]
  Lu, N.; Guo, H.; Wang, L.; Wu, X.; Zeng, X. C. Nanoscale 2014, 6, 4566. doi: 10.1039/C4NR00783B doi: 10.1039/C4NR00783B
10. [10]
  Conley, H. J.; Wang, B.; Ziegler, J. I.; Haglund, R. F.; Pantelides, S. T.; Bolotin, K. I. Nano Lett. 2013, 13, 3626. doi: 10.1021/nl4014748 doi: 10.1021/nl4014748
11. [11]
  Komsa, H. P.; Krasheninnikov, A. V. Phys. Rev. B 2013, 88, 085318. doi: 10.1103/physrevb.88.085318 doi: 10.1103/physrevb.88.085318
12. [12]
  Terrones, H.; Lopez-Urias, F.; Terrones, M. Sci. Rep. 2013, 3, 1549. doi: 10.1038/srep01549 doi: 10.1038/srep01549
13. [13]
  Lu, N.; Guo, H.; Li, L.; Dai, J.; Wang, L.; Mei, W. N.; Wu, X.; Zeng, X. C. Nanoscale 2014, 6, 2879. doi: 10.1039/c3nr06072a doi: 10.1039/c3nr06072a
14. [14]
  Ma, Y.; Dai, Y.; Guo, M.; Niu, C.; Huang, B. Nanoscale 2011, 3, 3883. doi: 10.1039/c1nr10577a doi: 10.1039/c1nr10577a
15. [15]
  Kośmider, K.; Fernández-Rossier, J. Phys. Rev. B 2013, 87, 075451. doi: 10.1103/physrevb.87.075451 doi: 10.1103/physrevb.87.075451
16. [16]
  Bao, W. Z.; Wan, J. Y.; Han, X. G.; Cai, X. H.; Zhu, H. L.; Kim, D. H.; Ma, D. K.; Xu, Y. L.; Munday, J. N.; Drew, H. D.; et al. Nat. Commun. 2014, 5, 4224. doi: 10.1038/ncomms5224 doi: 10.1038/ncomms5224
17. [17]
  Wan, J. Y.; Bao, W. Z.; Liu, Y.; Dai, J. Q.; Shen, F.; Zhou, L. H.; Cai, X. H.; Urban, D.; Li, Y. Y.; Jungjohann, K.; et al. Adv. Energy Mater. 2015, 5, 1401742. doi: 10.1002/aenm.201401742 doi: 10.1002/aenm.201401742
18. [18]
  Kim, N.; Kim, K. S.; Jung, N.; Brus, L.; Kim, P. Nano Lett. 2011, 11, 860. doi: 10.1021/nl104228f doi: 10.1021/nl104228f
19. [19]
  Yu, Y. J.; Yang, F. Y.; Lu, X. F.; Yan, Y. J.; Cho, Y. H.; Ma, L. G.; Niu, X. H.; Kim, S.; Son, Y. W.; Feng, D. L.; et al. Nat. Nanotechnol. 2015, 10, 270. doi: 10.1038/nnano.2014.323 doi: 10.1038/nnano.2014.323
20. [20]
  Wu, H.; Kong, D.; Ruan, Z.; Hsu, P. C.; Wang, S.; Yu, Z.; Carney, T. J.; Hu, L.; Fan, S.; Cui, Y. Nat. Nanotechnol. 2013, 8, 421. doi: 10.1038/nnano.2013.84 doi: 10.1038/nnano.2013.84
21. [21]
  Li, H. P.; Pan, W.; Zhang, W.; Huang, S. Y.; Wu, H. Adv. Funct. Mater. 2013, 23, 209. doi: 10.1002/adfm.201200996 doi: 10.1002/adfm.201200996
22. [22]
  Motter, J. P.; Koski, K. J.; Cui, Y. Chem. Mat. 2014, 26, 2313. doi: 10.1021/cm500242h doi: 10.1021/cm500242h
23. [23]
  Koski, K. J.; Cha, J. J.; Reed, B. W.; Wessells, C. D.; Kong, D.; Cui, Y. J. Am. Chem. Soc. 2012, 134, 7584. doi: 10.1021/ja300368x doi: 10.1021/ja300368x
24. [24]
  Yang, W. W.; Zhang, S. Q.; Chen, Q.; Zhang, C.; Wei, Y.; Jiang, H. N.; Lin, Y. X.; Zhao. M. T.; He, Q. Q.; Wang, X. G.; et al. Adv. Mater. 2020, 32, e2001167. doi: 10.1002/adma.202001167 doi: 10.1002/adma.202001167
25. [25]
  Friend, R. H.; Yoffe, A. D. Adv. Phys. 1987, 36, 1. doi: 10.1080/00018738700101951 doi: 10.1080/00018738700101951
26. [26]
  Kanetani, K.; Sugawara, K.; Sato, T.; Shimizu, R.; Iwaya, K.; Hitosugi, T.; Takahashi, T. Proc. Natl. Acad. Sci. U. S. A. 2012, 109, 19610. doi: 10.1073/pnas.1208889109 doi: 10.1073/pnas.1208889109
27. [27]
  Bouwmeester, H. J.; van der Lee, A.; van Smaalen, S.; Wiegers, G. A. Phys. Rev. B: Condens. 1991, 43, 9431. doi: 10.1103/physrevb.43.9431 doi: 10.1103/physrevb.43.9431
28. [28]
  Harshman, D. R.; Mills, A. P. Phys. Rev. B: Condens. 1992, 45, 10684. doi: 10.1038/nmat4251 doi: 10.1038/nmat4251
29. [29]
  Kumar, P.; Skomski, R.; Pushpa, R. ACS Omega. 2017, 2, 7985. doi: 10.1021/acsomega.7b01164 doi: 10.1021/acsomega.7b01164
30. [30]
  Xie, J.; Zhang, J.; Li, S.; Grote, F.; Zhang, X.; Zhang, H.; Wang, R.; Lei, Y.; Pan, B.; Xie, Y. J. Am. Chem. Soc. 2013, 135, 17881. doi: 10.1021/ja408329q doi: 10.1021/ja408329q
31. [31]
  Qin, S.; Lei, W.; Liu, D.; Chen, Y. Sci. Rep. 2014, 4, 7582. doi: 10.1038/srep07582 doi: 10.1038/srep07582
32. [32]
  Ye, L. J.; Chen, S. J.; Li, W. J.; Pi, M. Y.; Wu, T. L.; Zhang, D. K. J. Phys. Chem. C 2015, 119, 9560. doi: 10.1021/jp5128018 doi: 10.1021/jp5128018
33. [33]
  Wang, C.; He, Q. Y.; Halim, U.; Liu, Y. Y.; Zhu, E. B.; Lin, Z. Y.; Xiao, H.; Duan, X. D.; Feng, Z. Y.; Cheng, R.; et al. Nature 2018, 555, 231. doi: 10.1038/nature25774 doi: 10.1038/nature25774
34. [34]
  Wang, M.; Koski, K. J. ACS Nano 2015, 9, 3226. doi: 10.1021/acsnano.5b00336 doi: 10.1021/acsnano.5b00336
35. [35]
  Wang, M. J.; Al-Dhahir, I.; Appiah, J.; Koski, K. J. Chem. Mater. 2017, 29, 1650. doi: 10.1021/acs.chemmater.6b04918 doi: 10.1021/acs.chemmater.6b04918
36. [36]
  Hennig, G. R. J. Chem. Phys. 1965, 43, 1201. doi: 10.1063/1.1696905 doi: 10.1063/1.1696905
37. [37]
  Yang, W. W.; Xiao, J. W.; Ma, Y.; Cui, S. Q.; Zhang, P.; Zhai, P. B.; Meng. L. J.; Wang, X. G.; Wei, Y.; Du, Z. G.; et al. Adv. Energy Mater. 2019, 9, 1803137. doi: 10.1002/aenm.201803137 doi: 10.1002/aenm.201803137
38. [38]
  Wang, M.; Lahti, G.; Williams, D.; Koski, K. J. ACS Nano 2018, 12, 6163. doi: 10.1021/acsnano.8b02789 doi: 10.1021/acsnano.8b02789
39. [39]
  Gong, Y. J.; Yuan, H. T.; Wu, C. L.; Tang, P. Z.; Yang, S. Z.; Yang, A. K.; Li, G. D.; Liu, B. F.; Groep, J. V. D.; Brongersma, M. L.; et al. Nat. Nanotechnol. 2018, 13, 294. doi: 10.1038/s41565-018-0069-3 doi: 10.1038/s41565-018-0069-3
40. [40]
  He, Q.; Lin, Z.; Ding, M.; Yin, A.; Halim, U.; Wang, C.; Liu, Y.; Cheng, H. C.; Huang, Y.; Duan, X. Nano Lett. 2019, 19, 6819. doi: 10.1021/acs.nanolett.9b01898 doi: 10.1021/acs.nanolett.9b01898
41. [41]
  Wang, N. Z.; Tang, H. B.; Shi, M. Z.; Zhang, H.; Zhuo, W. Z.; Liu, D. Y.; Meng, F. B.; Ma, L. K.; Ying, J. J.; Zou, L. J.; et al. J. Am. Chem. Soc. 2019, 141, 17166. doi: 10.1021/jacs.9b06929 doi: 10.1021/jacs.9b06929
42. [42]
  Wang, H.; Lu, Z.; Kong, D.; Sun, J.; Hymel, T. M.; Cui, Y. ACS Nano 2014, 8, 4940. doi: 10.1021/nn500959v doi: 10.1021/nn500959v
43. [43]
  Wang, X.; Shen, X.; Wang, Z.; Yu, R.; Chen, L. ACS Nano 2014, 8, 11394. doi: 10.1021/nn505501v doi: 10.1021/nn505501v
44. [44]
  Chen, W. S.; Gu, J. J.; Liu, Q. L.; Luo, R. C.; Yao, L. L.; Sun, B. Y.; Zhang, W.; Su, H. L.; Chen, B.; Liu, P.; et al. ACS Nano 2018, 12, 308. doi: 10.1021/acsnano.7b06364 doi: 10.1021/acsnano.7b06364
45. [45]
  Meng, L. J.; Ma, Y.; Si, K. P.; Xu, S. Y.; Wang, J. L.; Gong, Y. J. Tungsten 2019, 1, 46. doi: 10.1007/s42864-019-00012-x doi: 10.1007/s42864-019-00012-x
46. [46]
  Li, J. Y.; Zhang, Z. Y.; Cui, W.; Wang, H.; Cen, W. L.; Johnson, G.; Jiang, G. M.; Zhang, S.; Dong, F. ACS Catal. 2018, 8, 8376. doi: 10.1021/acscatal.8b02459 doi: 10.1021/acscatal.8b02459
47. [47]
  O'Farrell, E. C.; Tan, J. Y.; Yeo, Y.; Koon, G. K.; Ozyilmaz, B.; Watanabe, K.; Taniguchi, T. Phys. Rev. Lett. 2016, 117, 076603. doi: 10.1103/physrevlett.117.076603 doi: 10.1103/physrevlett.117.076603
48. [48]
  Zhao, J.; Islam, S. M.; Kontsevoi, O. Y.; Tan, G.; Stoumpos, C. C.; Chen, H.; Li, R. K.; Kanatzidis, M. G. J. Am. Chem. Soc. 2017, 139, 6978. doi: 10.1021/jacs.7b02243 doi: 10.1021/jacs.7b02243
49. [49]
  Ebina, Y.; Sakai, N.; Sasaki, T. J. Phys. Chem. B 2005, 109, 17212. doi: 10.1021/jp051823j doi: 10.1021/jp051823j
50. [50]
  Hata, H.; Kubo, S.; Kobayashi, Y.; Mallouk, T. E. J. Am. Chem. Soc. 2007, 129, 3064. doi: 10.1021/ja068272a doi: 10.1021/ja068272a
51. [51]
  Hata, H.; Kobayashi, Y.; Salama, M.; Malek, R.; Mallouk, T. E. Chem. Mater. 2007, 19, 6588. doi: 10.1021/cm701936y doi: 10.1021/cm701936y
52. [52]
  Hata, H.; Kobayashi, Y.; Bojan, V.; Youngblood, W. J.; Mallouk, T. E. Nano Lett. 2008, 8, 794. doi: 10.1021/nl072571w doi: 10.1021/nl072571w
53. [53]
  Oshima, T.; Lu, D.; Ishitani, O.; Maeda, K. Angew. Chem. Int. Ed. 2015, 54, 2698. doi: 10.1002/ange.201411494 doi: 10.1002/ange.201411494
54. [54]
  Luo, Y.; Li, X.; Cai, X.; Zou, X.; Kang, F.; Cheng, H. M.; Liu, B. ACS Nano 2018, 12, 4565. doi: 10.1021/acsnano.8b00942 doi: 10.1021/acsnano.8b00942
55. [55]
  Chen, Z. X.; Liu, C. B.; Liu, J.; Li J.; Xi, S. B.; Chi, X.; Xu, H. S.; Park, I. H.; Peng, X. W.; Li, X.; et al. Adv. Mater. 2020, 32, e1906437. doi: 10.1002/adma.201906437 doi: 10.1002/adma.201906437
56. [56]
  Nair, N. L.; Maniv, E.; John, C.; Doyle, S.; Orenstein, J.; Analytis, J. G. Nat. Mater. 2020, 19, 153. doi: 10.1038/s41563-019-0518-x doi: 10.1038/s41563-019-0518-x
57. [57]
  Zhao, X. H.; Song, P.; Wang, C. C.; Anders C. Riis-Jensen; Fu, W.; Deng, Y.; Wan, D. Y.; Kang, L. X.; Ning, S. C.; Dan, J. D.; et al. Nature 2020, 581, 171. doi: 10.1038/s41586-020-2241-9 doi: 10.1038/s41586-020-2241-9
58. [58]
  Palomares, V.; Serras, P.; Villaluenga, I.; Hueso, K. B.; Carretero-Gonzalez, J.; Rojo, T. Energy Environ. Sci. 2012, 5, 5884. doi: 10.1039/c2ee02781j doi: 10.1039/c2ee02781j
59. [59]
  Kim, H.; Kim, J. C.; Bianchini, M.; Seo, D. H.; Rodriguez-Garcia, J.; Ceder, G. Adv. Energy Mater. 2018, 8, 1702384. doi: 10.1002/aenm.201702384 doi: 10.1002/aenm.201702384
60. [60]
  Song, M.; Tan, H.; Chao, D. L.; Fan, H. J. Adv. Funct. Mater. 2018, 28, 1802564. doi: 10.1002/adfm.201802564 doi: 10.1002/adfm.201802564
61. [61]
  Muldoon, J.; Bucur, C. B.; Gregory, T. Chem. Rev. 2014, 114, 11683. doi: 10.1021/cr500049y doi: 10.1021/cr500049y
62. [62]
  Zhai, P. B.; Wei, Y.; Xiao, J.; Liu, W.; Zuo, J. H.; Gu, X. K.; Yang, W. W.; Cui, S. Q.; Li, B.; Yang, S. B.; et al. Adv. Energy Mater. 2020, 10, 1903339. doi: 10.1002/aenm.201903339 doi: 10.1002/aenm.201903339
63. [63]
  Chen, K.; Sun, Z. H.; Fang, R. P.; Li, F.; Cheng, H. M. Acta Phys. -Chim. Sin. 2018, 34, 377. doi: 10.3866/PKU.WHXB201709001
64. [64]
  Lamb, A. B. Chem. Eng. News 1942, 20, 267. doi: 10.1021/cen-v020n004.p267 doi: 10.1021/cen-v020n004.p267
65. [65]
  Rüdorff, W. J. C. Chimia 1965, 19, 489.
66. [66]
  Whittingham, M. S.; Gamble, F. R. Mater. Res. Bull. 1975, 10, 363. doi: 10.1016/0025-5408(75)90006-9 doi: 10.1016/0025-5408(75)90006-9
67. [67]
  Whittingham, M. S. Science 1976, 192, 1126. doi: 10.1126/science.192.4244.1126 doi: 10.1126/science.192.4244.1126
68. [68]
  Mizushima, K.; Jones, P. C.; Wiseman, P. J.; Goodenough, J. B. Mater. Res. Bull. 1980, 15, 783. doi: 10.1016/0025-5408(80)90012-4 doi: 10.1016/0025-5408(80)90012-4
69. [69]
  Mashtalir, O.; Naguib, M.; Mochalin, V. N.; Dall'Agnese, Y.; Heon, M.; Barsoum, M. W.; Gogotsi, Y. Nat. Commun. 2013, 4, 1716. doi: 10.1038/ncomms2664 doi: 10.1038/ncomms2664
70. [70]
  Eames, C.; Islam, M. S. J. Am. Chem. Soc. 2014, 136, 16270. doi: 10.1021/ja508154e doi: 10.1021/ja508154e
71. [71]
  Muller, G. A.; Cook, J. B.; Kim, H. S.; Tolbert, S. H.; Dunn, B. Nano Lett. 2015, 15, 1911. doi: 10.1021/nl504764m doi: 10.1021/nl504764m
72. [72]
  Liu, W.; Zhai, P. B.; Qin, S. J.; Xiao, J.; Wei, Y.; Yang, W. W.; Cui, S. Q.; Chen, Q.; Jin, C. Q.; Yang, S. B.; et al. J. Energy Chem. 2021, 56, 463. doi: 10.1016/j.jechem.2020.08.019 doi: 10.1016/j.jechem.2020.08.019
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  Hailian Tang , Siyuan Chen , Qiaoyun Liu , Guoyi Bai , Botao Qiao , Fei Liu . Stabilized Rh/hydroxyapatite Catalyst for Furfuryl Alcohol Hydrogenation: Application of Oxidative Strong Metal-Support Interactions in Reducing Conditions. Acta Physico-Chimica Sinica, 2025, 41(4): 100036-. doi: 10.3866/PKU.WHXB202408004
16. [16]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
17. [17]
  Peng XU , Shasha WANG , Nannan CHEN , Ao WANG , Dongmei YU . Preparation of three-layer magnetic composite Fe₃O₄@polyacrylic acid@ZiF-8 for efficient removal of malachite green in water. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 544-554. doi: 10.11862/CJIC.20230239
18. [18]
  Zhao Lu , Hu Lv , Qinzhuang Liu , Zhongliao Wang . Modulating NH₂ Lewis Basicity in CTF-NH₂ through Donor-Acceptor Groups for Optimizing Photocatalytic Water Splitting. Acta Physico-Chimica Sinica, 2024, 40(12): 2405005-. doi: 10.3866/PKU.WHXB202405005
19. [19]
  Qianwen Han , Tenglong Zhu , Qiuqiu Lü , Mahong Yu , Qin Zhong . 氢电极支撑可逆固体氧化物电池性能及电化学不对称性优化. Acta Physico-Chimica Sinica, 2025, 41(1): 2309037-. doi: 10.3866/PKU.WHXB202309037
20. [20]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403

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沈阳化工大学材料科学与工程学院沈阳 110142

Utilization of the van der Waals Gap of 2D Materials

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

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通讯作者: 陈斌, bchen63@163.com