Citation: Hao Leiduan, Sun Zhenyu. Metal Oxide-Based Materials for Electrochemical CO₂ Reduction[J]. Acta Physico-Chimica Sinica, ;2021, 37(7): 200903. doi: 10.3866/PKU.WHXB202009033 shu

Metal Oxide-Based Materials for Electrochemical CO₂ Reduction

Hao Leiduan ,
Sun Zhenyu ^,

State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Author Bio:
Zhenyu Sun was born in April 1977. He is currently a full professor in the College of Chemical Engineering at Beijing University of Chemical Technology (China). He completed his Ph.D. at Institute of Chemistry, Chinese Academy of Sciences in 2006. He did postdoctoral research in Trinity College Dublin (Ireland) from 2006 to 2008, at Ruhr University, Bochum (Germany) from 2011 to 2014, and University of Oxford from 2014 to 2015. He has obtained a Humboldt Research Fellowship for Experienced Researchers (Germany). His current research focuses on energy conversion reactions using two-dimensional materials
Corresponding author: Sun Zhenyu, sunzy@mail.buct.edu.cn
Received Date: 9 September 2020
Revised Date: 24 October 2020
Accepted Date: 5 November 2020
Available Online: 16 November 2020
Fund Project: This work was supported by National Natural Science Foundation of China (21972010) and Beijing Natural Science Foundation, China (2192039)Beijing Natural Science Foundation, China 2192039National Natural Science Foundation of China 21972010

The CO₂ level in the atmosphere has been increasing since the industrial revolution owing to anthropogenic activities. The increased CO₂ level has led to global warming and also has detrimental effects on human beings. Reducing the CO₂ level in the atmosphere is urgent for balancing the carbon cycle. In this regard, reduction in CO₂ emission and CO₂ storage and usage are the main strategies. Among these, CO₂ usage has been extensively explored, because it can reduce the CO₂ level and simultaneously provide opportunities for the development in catalysts and industries to convert CO₂ as a carbon source for preparing valuable products. However, transformation of CO₂ to other chemicals is challenging owing to its thermodynamic and kinetic stabilities. Among the CO₂ utilization techniques, electrochemical CO₂ reduction (ECR) is a promising alternative because it is generally conducted under ambient conditions, and water is used as the economical hydrogen source. Moreover, ECR offers a potential route to store electrical energy from renewable sources in the form of chemical energy, through generation of CO₂ reduction products. To improve the energy efficiency and viability of ECR, it is important to decrease the operational overpotential and maintain large current densities and high product selectivities; the development of efficient electrocatalysts is a critical aspect in this regard. To date, many kinds of materials have been designed and studied for application in ECR. Among these materials, metal oxide-based materials exhibit excellent performance as electrocatalysts for ECR and are attracting increasing attention in recent years. Investigation of the mechanism of reactions that involve metallic electrocatalysts has revealed the function of trace amount of oxidized metal species—it has been suggested that the presence of metal oxides and metal-oxygen bonds facilitates the activation of CO₂ and the subsequent formation and stabilization of the reaction intermediates, thereby resulting in high efficiency and selectivity of the ECR. Although the stability of metal oxides is a concern as they are prone to reduction under a cathodic potential, the catalytic performance of metal oxide-based catalysts can be maintained through careful designing of the morphology and structure of the materials. In addition, introducing other metal species to metal oxides and fabricating composites of metal oxides and other materials are effective strategies to achieve enhanced performance in ECR. In this review, we summarize the recent progress in the use of metal oxide-based materials as electrocatalysts and their application in ECR. The critical role, stability, and structure-performance relationship of the metal oxide-based materials for ECR are highlighted in the discussion. In the final part, we propose the future prospects for the development of metal oxide-based electrocatalysts for ECR.
- Electrochemical CO₂ reduction,
- Metal oxides,
- Electrocatalysts,
- Selectivity,
- Stability
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Metal Oxide-Based Materials for Electrochemical CO2 Reduction

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Metal Oxide-Based Materials for Electrochemical CO₂ Reduction