Citation: Qiu Xiaoguang, Liu Wei, Liu Jiuding, Li Junzhi, Zhang Kai, Cheng Fangyi. Nucleation Mechanism and Substrate Modification of Lithium Metal Anode[J]. Acta Physico-Chimica Sinica, ;2021, 37(1): 200901. doi: 10.3866/PKU.WHXB202009012 shu

Nucleation Mechanism and Substrate Modification of Lithium Metal Anode

Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Renewable Energy Conversion and Storage Center, College of Chemistry, Nankai University, Tianjin 300071, China

Corresponding author: Cheng Fangyi, fycheng@nankai.edu.cn
Received Date: 2 September 2020
Revised Date: 22 September 2020
Accepted Date: 23 September 2020
Available Online: 9 October 2020
Fund Project: the Ministry of Science and Technology 2016YFA0202500Young Elite Scientists Sponsorship Program by CAST 2019QNRC001the Ministry of Science and Technology 2017YFA0206702the National Natural Science Foundation of China 21835004The project was supported by the Ministry of Science and Technology (2017YFA0206702, 2016YFA0202500), the National Natural Science Foundation of China (21925503, 21835004), and Young Elite Scientists Sponsorship Program by CAST (2019QNRC001)the National Natural Science Foundation of China 21925503

Li is highly attractive anode material for next-generation high-energy-density batteries, such as Li-air, Li-sulfur, and solid-state Li-based systems because of its exceedingly low electrode potential (-3.04 V vs the standard hydrogen electrode) and ultra-high theoretical capacity (3860 mAh-g^-1). However, Li metal anodes and Li-based batteries are plagued by issues, including unstable solid electrolyte interface (SEI), dead Li formation, and uncontrollable dendritic growth. These limitations result in low cycling stability and could induce short circuits, thermal runaway, and safety hazards. In recent years, a variety of efficient strategies have been proposed to alleviate the challenges faced by Li anodes. For example, the design of Li-free anodes (with Li supplied from the lithiated cathode) or Li-composite anodes has attracted significant attention. Their population can be ascribed to the use of non-excessive Li metal that could be potentially safer and easier to produce. In Li-free and Li-composite anodes, the initial nucleation sites play a crucial role in influencing the subsequent Li electroplating behavior. Stable, homogenous Li electrodeposition is crucial for improving Coulomb efficiency and inhibiting dendrite formation. Moreover, it is also desirable to explore the nucleation and growth mechanism of Li metal on substrates or current collectors. Therefore, in this article, we aim to provide an overview of the mechanism of Li nucleation and strategies to enhance Li metal batteries via substrate modification. The mechanisms of Li nucleation are discussed in terms of nucleation-driven forces and the relation between nuclei size/distribution and overpotential/current density. Heterogeneous nucleation and Chazalviel space charge models are introduced to describe the deposition behaviors of Li in the initial nucleation stage. In the heterogeneous nucleation process, the formation of Li nuclei and its kinetics depend on the nucleation barrier, which correlates with the properties of substrates, such as their crystal structure, lattice matching, facets, and defects. The space charge model can be applied to low-concentration electrolytes or rapid Li deposition, where the decrease in ion concentration on the electrode surface induces a localized space charge and polarized electric field. This subsequently affects the microstructure and morphology of the deposited Li. After discussing the nucleation mechanism and substrate effect, strategies to stabilize nucleation and suppress dendrite are highlighted, such as three-dimensional frameworks, heterogeneous crystal nuclei, Li storage buffer layers, electric field effects, and lattice matching engineering. Information gained from the perspective of Li nucleation and the substrate effect might enlighten the development of strategies to upgrade metallic Li anodes for application in Li-based batteries.
- Lithium metal battery,
- Dendrite,
- Nucleation mechanism,
- Framework modification
1. [1]
  Liu, J.; Bao, Z.; Cui, Y.; Dufek, E. J.; Goodenough, J. B.; Khalifah, P.; Li, Q.; Liaw, B. Y.; Liu, P.; Manthiram, A.; et al. Nat. Energy 2019, 4, 180. doi: 10.1038/s41560-019-0338-x doi: 10.1038/s41560-019-0338-x
2. [2]
  Liu, Y.; Zhu, Y.; Cui, Y. Nat. Energy 2019, 4, 540. doi: 10.1038/s41560-019-0405-3 doi: 10.1038/s41560-019-0405-3
3. [3]
  Wang, L.; Wu, Z.; Zou, J.; Gao, P.; Niu, X.; Li, H.; Chen, L. Joule 2019, 3, 2086. doi: 10.1016/j.Joule2019.07.011 doi: 10.1016/j.Joule2019.07.011
4. [4]
  Goodenough, J. B.; Kim, Y. Chem. Mater. 2010, 22, 587. doi: 10.1021/cm901452z doi: 10.1021/cm901452z
5. [5]
  Cheng, F.; Liang, J.; Tao, Z.; Chen, J. Adv. Mater. 2011, 23, 1695. doi: 10.1002/adma.201003587 doi: 10.1002/adma.201003587
6. [6]
  Martin, C.; Genovese, M.; Louli, A. J.; Weber, R.; Dahn, J. R. Joule 2020, 4, 1296. doi: 10.1016/j.Joule2020.04.003 doi: 10.1016/j.Joule2020.04.003
7. [7]
  Zhang, P.; Zhao, Y.; Zhang, X. Chem. Soc. Rev. 2018, 47, 2921. doi: 10.1039/c8cs00009c doi: 10.1039/c8cs00009c
8. [8]
  Qu, G.; Tan, J.; Wu, H.; Yu, Z.; Zhang, S.; Liu, G.; Zheng, G. W.; Tian, B.; Su, C. ACS Appl. Mater. Interfaces 2020, 12, 23867. doi: 10.1021/acsami.0c03621 doi: 10.1021/acsami.0c03621
9. [9]
  Zhu, G. L.; Zhao, C. Z.; Yuan, H.; Nan, H. X.; Zhao, B. C.; Hou, L. P.; He, C. X.; Liu, Q. B.; Huang, J. Q. Acta Phys. -Chim. Sin. 2021, 37, 2005003. doi: 10.3866/PKU.WHXB202005003
10. [10]
  Ghazi, Z. A.; Sun, Z.; Sun, C.; Qi, F.; An, B.; Li, F.; Cheng, H. M. Small 2019, 15, e1900687. doi: 10.1002/smll.201900687 doi: 10.1002/smll.201900687
11. [11]
  Xie, Z.; Wu, Z.; An, X.; Yue, X.; Wang, J.; Abudula, A.; Guan, G. Energy Storage Mater. 2020, 32, 386. doi: 10.1016/j.ensm.2020.07.004 doi: 10.1016/j.ensm.2020.07.004
12. [12]
  Ju, Z.; Nai, J.; Wang, Y.; Liu, T.; Zheng, J.; Yuan, H.; Sheng, O.; Jin, C.; Zhang, W.; Jin, Z.; et al. Nat. Commun. 2020, 11, 488. doi: 10.1038/s41467-020-14358-1 doi: 10.1038/s41467-020-14358-1
13. [13]
  Chen, X.; Bai, Y. K.; Zhao, C. Z.; Shen, X.; Zhang, Q. Angew. Chem. Int. Ed. 2020, 59, 11192. doi: 10.1002/anie.201915623 doi: 10.1002/anie.201915623
14. [14]
  Yue, X, Y.; Ma, C.; Bao, J.; Yang, S, Y.; Chen, D.; Wu, X, J.; Zhou, Y, N. Acta Phys. -Chim. Sin. 2021, 37, 2005012. doi: 10.3866/PKU.WHXB202005012
15. [15]
  Liu, F, F.; Zhang, Z, W.; Ye, S, F.; Yao, Y.; Yu, Y. Acta Phys. -Chim. Sin. 2021, 37, 2006021. doi: 10.3866/PKU.WHXB202006021
16. [16]
  Wang, Z.; Qi, F.; Yin, L.; Shi, Y.; Sun, C.; An, B.; Cheng, H. M.; Li, F. Adv. Energy Mater. 2020, 10, 1903843. doi: 10.1002/aenm.201903843 doi: 10.1002/aenm.201903843
17. [17]
  Liu, J.; Wang, Y.; Liu, F.; Cheng, F.; Chen, J. J. Energy Chem. 2020, 42, 1. doi: 10.1016/j.jechem.2019.05.017 doi: 10.1016/j.jechem.2019.05.017
18. [18]
  Chen, J.; Fan, X.; Li, Q.; Yang, H.; Khoshi, M. R.; Xu, Y.; Hwang, S.; Chen, L.; Ji, X.; Yang, C.; et al. Nat. Energy 2020. doi: 10.1038/s41560-020-0601-1 doi: 10.1038/s41560-020-0601-1
19. [19]
  Biswal, P.; Stalin, S.; Kludze, A.; Choudhury, S.; Archer, L. A. Nano Lett. 2019, 19, 8191. doi: 10.1021/acs.nanolett.9b03548 doi: 10.1021/acs.nanolett.9b03548
20. [20]
  Thirumalraj, B.; Hagos, T. T.; Huang, C. J.; Teshager, M. A.; Cheng, J. H.; Su, W. N.; Hwang, B. J. J. Am. Chem. Soc. 2019, 141, 18612. doi: 10.1021/jacs.9b10195 doi: 10.1021/jacs.9b10195
21. [21]
  Pei, A.; Zheng, G.; Shi, F.; Li, Y.; Cui, Y. Nano Lett. 2017, 17, 1132. doi: 10.1021/acs.nanolett.6b04755 doi: 10.1021/acs.nanolett.6b04755
22. [22]
  Xu, W.; Wang, J.; Ding, F.; Chen, X.; Nasybulin, E.; Zhang, Y.; Zhang, J. G. Energy Environ. Sci. 2014, 7, 513. doi: 10.1039/c3ee40795k doi: 10.1039/c3ee40795k
23. [23]
  Brissot, C.; Rosso, M.; Chazalviel, J. N.; Lascaud, S. J. Power Sources 1999, 81, 925. doi: 10.1016/s0378-7753(98)00242-0 doi: 10.1016/s0378-7753(98)00242-0
24. [24]
  Rosso, M.; Brissot, C.; Teyssot, A.; Dolle, M.; Sannier, L.; Tarascon, J. M.; Bouchetc, R.; Lascaud, S. Electrochim. Acta 2006, 51, 5334. doi: 10.1016/j.electacta.2006.02.004 doi: 10.1016/j.electacta.2006.02.004
25. [25]
  Ely, D. R.; García, R. E. J. Electrochem. Soc. 2013, 160, A662. doi: 10.1149/1.057304jes doi: 10.1149/1.057304jes
26. [26]
  Sun, X.; Zhang, X.; Ma, Q.; Guan, X.; Wang, W.; Luo, J. Angew. Chem. Int. Ed. 2020, 59, 6665. doi: 10.1002/anie.201912217 doi: 10.1002/anie.201912217
27. [27]
  Pande, V.; Viswanathan, V. ACS Energy Lett. 2019, 4, 2952. doi: 10.1021/acsenergylett.9b02306 doi: 10.1021/acsenergylett.9b02306
28. [28]
  Chazalviel, J. N. Phys. Rev. A 1990, 42, 7355. doi: 10.1103/PhysRevA.42.7355 doi: 10.1103/PhysRevA.42.7355
29. [29]
  Liu, Z, F. Acta Phys. -Chim. Sin. 2019, 35, 1293. doi: 10.3866/PKU.WHXB201906040
30. [30]
  Shi, Y.; Wang, Z.; Gao, H.; Niu, J.; Ma, W.; Qin, J.; Peng, Z.; Zhang, Z. J. Mater. Chem. A 2019, 7, 1092. doi: 10.1039/c8ta09384a doi: 10.1039/c8ta09384a
31. [31]
  Zhang, D.; Dai, A.; Wu, M.; Shen, K.; Xiao, T.; Hou, G.; Lu, J.; Tang, Y. ACS Energy Lett. 2019, 5, 180. doi: 10.1021/acsenergylett.9b01987 doi: 10.1021/acsenergylett.9b01987
32. [32]
  Zhai, P.; Wei, Y.; Xiao, J.; Liu, W.; Zuo, J.; Gu, X.; Yang, W.; Cui, S.; Li, B.; Yang, S.; Gong, Y. Adv. Energy Mater. 2020, 10, 1903339. doi: 10.1002/aenm.201903339 doi: 10.1002/aenm.201903339
33. [33]
  Yang, C. P.; Yin, Y. X.; Zhang, S. F.; Li, N. W.; Guo, Y. G. Nat. Commun. 2015, 6, 8058. doi: 10.1038/ncomms9058 doi: 10.1038/ncomms9058
34. [34]
  Zhang, Q. Acta Phys. -Chim. Sin. 2017, 33, 1275. doi: 10.3866/PKU.WHXB201705021
35. [35]
  Wang, H.; Wu, J.; Yuan, L.; Li, Z.; Huang, Y. ACS Appl. Mater. Interfaces 2020, 12, 28337. doi: 10.1021/acsami.0c08029 doi: 10.1021/acsami.0c08029
36. [36]
  Shi, H.; Zhang, C. J.; Lu, P.; Dong, Y.; Wen, P.; Wu, Z. S. ACS Nano 2019, 13, 14308. doi: 10.1021/acsnano.9b07710 doi: 10.1021/acsnano.9b07710
37. [37]
  Meng, J. K.; Wang, W. W.; Yue, X. Y.; Xia, H. Y.; Wang, Q. C.; Wang, X. X.; Fu, Z.; Wu, X. J.; Zhou, Y. N. J. Power Sources 2020, 465, 228291. doi: 10.1016/j.jpowsour.2020.228291 doi: 10.1016/j.jpowsour.2020.228291
38. [38]
  Hwang, C.; Song, W. J.; Song, G.; Wu, Y.; Lee, S.; Son, H. B.; Kim, J.; Liu, N.; Park, S.; Song, H. K. ACS Appl. Mater. Interfaces 2020, 12, 29235. doi: 10.1021/acsami.0c05065 doi: 10.1021/acsami.0c05065
39. [39]
  Zhang, R.; Wang, N.; Shi, C.; Liu, E.; He, C.; Zhao, N. Carbon 2020, 161, 198. doi: 10.1016/j.carbon.2020.01.077 doi: 10.1016/j.carbon.2020.01.077
40. [40]
  Yun, Q.; He, Y. B.; Lv, W.; Zhao, Y.; Li, B.; Kang, F.; Yang, Q. H. Adv. Mater. 2016, 28, 6932. doi: 10.1002/adma.201601409 doi: 10.1002/adma.201601409
41. [41]
  Zhang, D.; Dai, A.; Fan, B.; Li, Y.; Shen, K.; Xiao, T.; Hou, G.; Cao, H.; Tao, X.; Tang, Y. ACS Appl. Mater. Interfaces 2020, 12, 31542. doi: 10.1021/acsami.0c09503 doi: 10.1021/acsami.0c09503
42. [42]
  Yan, K.; Lu, Z.; Lee, H. W.; Xiong, F.; Hsu, P. C.; Li, Y.; Zhao, J.; Chu, S.; Cui, Y. Nat. Energy 2016, 1, 16010. doi: 10.1038/nenergy.2016.10 doi: 10.1038/nenergy.2016.10
43. [43]
  Cui, Y. Acta Phys. -Chim. Sin. 2019, 35, 661. doi: 10.3866/PKU.WHXB201809053
44. [44]
  Yang, G.; Chen, J.; Xiao, P.; Agboola, P. O.; Shakir, I.; Xu, Y. J. Mater. Chem. A 2018, 6, 9899. doi: 10.1039/c8ta02810a doi: 10.1039/c8ta02810a
45. [45]
  Guo, H.; Yao, Y.; Cheng, J.; Chen, L.; Dai, L.; Zhang, L.; Si, P.; Ci, L. ACS Appl. Energy Mater. 2020. doi: 10.1021/acsaem.0c01316 doi: 10.1021/acsaem.0c01316
46. [46]
  Meng, Q.; Deng, B.; Zhang, H.; Wang, B.; Zhang, W.; Wen, Y.; Ming, H.; Zhu, X.; Guan, Y.; Xiang, Y.; et al. Energy Storage Mater. 2019, 16, 419. doi: 10.1016/j.ensm.2018.06.024 doi: 10.1016/j.ensm.2018.06.024
47. [47]
  Liu, H.; Chen, X.; Cheng, X. B.; Li, B. Q.; Zhang, R.; Wang, B.; Chen, X.; Zhang, Q. Small Methods 2019, 3, 2366. doi: 10.1002/smtd.201800354 doi: 10.1002/smtd.201800354
48. [48]
  Shin, W. K.; Kannan, A. G.; Kim, D. W. ACS Appl. Mater. Interfaces 2015, 7, 23700. doi: 10.1021/acsami.5b07730 doi: 10.1021/acsami.5b07730
49. [49]
  Wang, T.; Zhai, P.; Legut, D.; Wang, L.; Liu, X.; Li, B.; Dong, C.; Fan, Y.; Gong, Y.; Zhang, Q. Adv. Energy Mater. 2019, 9, 1804000. doi: 10.1002/aenm.201804000 doi: 10.1002/aenm.201804000
50. [50]
  Li, K.; Hu, Z.; Ma, J.; Chen, S.; Mu, D.; Zhang, J. Adv. Mater. 2019, 31, e1902399. doi: 10.1002/adma.201902399 doi: 10.1002/adma.201902399
51. [51]
  Liu, Y.; Zhang, S.; Qin, X.; Kang, F.; Chen, G.; Li, B. Nano Lett. 2019, 19, 4601. doi: 10.1021/acs.nanolett.9b01567 doi: 10.1021/acs.nanolett.9b01567
52. [52]
  Zhang, N.; Yu, S. H.; Abruña, H. D. Nano Res. 2019, 13, 45. doi: 10.1007/s12274-019-2567-7 doi: 10.1007/s12274-019-2567-7
53. [53]
  Feng, W.; Dong, X.; Li, P.; Wang, Y.; Xia, Y. J. Power Sources 2019, 419, 91. doi: 10.1016/j.jpowsour.2019.02.066 doi: 10.1016/j.jpowsour.2019.02.066
54. [54]
  Zhang, R.; Chen, X.; Shen, X.; Zhang, X. Q.; Chen, X. R.; Cheng, X. B.; Yan, C.; Zhao, C. Z.; Zhang, Q. Joule 2018, 2, 764. doi: 10.1016/j.Joule2018.02.001 doi: 10.1016/j.Joule2018.02.001
55. [55]
  Ke, X.; Liang, Y.; Ou, L.; Liu, H.; Chen, Y.; Wu, W.; Cheng, Y.; Guo, Z.; Lai, Y.; Liu, P.; Shi, Z. Energy Storage Mater. 2019, 23, 547. doi: 10.1016/j.ensm.2019.04.003 doi: 10.1016/j.ensm.2019.04.003
56. [56]
  Kang, H.; Boyer, M.; Hwang, G. S.; Lee, J. W. Electrochim. Acta 2019, 303, 78. doi: 10.1016/j.electacta.2019.02.068 doi: 10.1016/j.electacta.2019.02.068
57. [57]
  Zhang, H.; Liao, X.; Guan, Y.; Xiang, Y.; Li, M.; Zhang, W.; Zhu, X.; Ming, H.; Lu, L.; Qiu, J.; et al. Nat. Commun. 2018, 9, 3729. doi: 10.1038/s41467-018-06126-z doi: 10.1038/s41467-018-06126-z
58. [58]
  Wang, X.; Pan, Z.; Wu, Y.; Ding, X.; Hong, X.; Xu, G.; Liu, M.; Zhang, Y.; Li, W. Nano Res. 2018, 12, 525. doi: 10.1007/s12274-018-2245-z doi: 10.1007/s12274-018-2245-z
59. [59]
  Wu, S.; Zhang, Z.; Lan, M.; Yang, S.; Cheng, J.; Cai, J.; Shen, J.; Zhu, Y.; Zhang, K.; Zhang, W. Adv. Mater. 2018, 30, 1705830. doi: 10.1002/adma.201705830 doi: 10.1002/adma.201705830
60. [60]
  Zhang, C.; Lv, W.; Zhou, G.; Huang, Z.; Zhang, Y.; Lyu, R.; Wu, H.; Yun, Q.; Kang, F.; Yang, Q. H. Adv. Energy Mater. 2018, 8, 1703404. doi: 10.1002/aenm.201703404 doi: 10.1002/aenm.201703404
61. [61]
  Li, R.; Wang, H.; Fu Q.; Tian, Z, Y.; Wang, J, X.; Ma, X, J.; Yang, J.; Qian, Y, T. J. Inorg. Mater. 2020, 8, 882. doi: 10.15541/jim20190545
62. [62]
  Liu, Y.; Zhang, S.; Qin, X.; Kang, F.; Chen, G.; Li, B. Nano Lett. 2019, 19, 4601. doi: 10.1021/acs.nanolett.9b01567 doi: 10.1021/acs.nanolett.9b01567
63. [63]
  Yi, J.; Chen, J.; Yang, Z.; Dai, Y.; Li, W.; Cui, J.; Ciucci, F.; Lu, Z.; Yang, C. Adv. Energy Mater. 2019, 9, 1901796. doi: 10.1002/aenm.201901796 doi: 10.1002/aenm.201901796
64. [64]
  Huang, G.; Chen, S.; Guo, P.; Tao, R.; Jie, K.; Liu, B.; Zhang, X.; Liang, J.; Cao, Y. C. Chem. Eng. J. 2020, 395, 125122. doi: 10.1016/j.cej.2020.125122 doi: 10.1016/j.cej.2020.125122
65. [65]
  Chen, L.; Fan, X.; Ji, X.; Chen, J.; Hou, S.; Wang, C. Joule 2019, 3, 732. doi: 10.1016/j.Joule2018.11.025 doi: 10.1016/j.Joule2018.11.025
66. [66]
  Tang, W.; Yin, X.; Kang, S.; Chen, Z.; Tian, B.; Teo, S. L.; Wang, X.; Chi, X.; Loh, K. P.; Lee, H. W.; Zheng, G. W. Adv. Mater. 2018, 30, e1801745. doi: 10.1002/adma.201801745 doi: 10.1002/adma.201801745
67. [67]
  Wang, H.; Cao, X.; Gu, H.; Liu, Y.; Li, Y.; Zhang, Z.; Huang, W.; Wang, H.; Wang, J.; et al. ACS Nano 2020, 14, 4601. doi: 10.1021/acsnano.0c00184 doi: 10.1021/acsnano.0c00184
68. [68]
  Chen, W.; Salvatierra, R. V.; Ren, M.; Chen, J.; Stanford, M. G.; Tour, J. M. Adv. Mater. 2020, e2002850. doi: 10.1002/adma.202002850 doi: 10.1002/adma.202002850
69. [69]
  Du, R.; Jie, Y.; Chen, Y.; Huang, F.; Cai, W.; Liu, Y.; Li, X.; Wang, S.; Lei, Z.; Cao, R. ACS Appl. Energy Mater. 2020, 3, 6692. doi: 10.1021/acsaem.0c00842 doi: 10.1021/acsaem.0c00842
70. [70]
  Jin, S.; Ye, Y.; Niu, Y.; Xu, Y.; Jin, H.; Wang, J.; Sun, Z.; Cao, A.; Wu, X.; Luo, Y. J. Am. Chem. Soc. 2020, 142, 8818. doi: 10.1021/jacs.0c01811 doi: 10.1021/jacs.0c01811
71. [71]
  Liu, M.; Wang, C.; Cheng, Z.; Ganapathy, S.; Haverkate, L. A.; Unnikrishnan, S.; Wagemaker, M. ACS Mater. Lett. 2020, 2, 665. doi: 10.1021/acsmaterialslett.0c00152 doi: 10.1021/acsmaterialslett.0c00152
72. [72]
  Liu, W.; Lin, D.; Pei, A.; Cui, Y. J. Am. Chem. Soc. 2016, 138, 15443. doi: 10.1021/jacs.6b08730 doi: 10.1021/jacs.6b08730
73. [73]
  Xiong, C.; Wang, Z.; Peng, X.; Guo, Y.; Xu, S.; Zhao, T. J. Mater. Chem. A 2020, 8, 14114. doi: 10.1039/d0ta04302h doi: 10.1039/d0ta04302h
74. [74]
  Cao, Z.; Li, B.; Yang, S. Adv. Mater. 2019, 31, e1901310. doi: 10.1002/adma.201901310 doi: 10.1002/adma.201901310
75. [75]
  Cao, Z.; Zhu, Q.; Wang, S.; Zhang, D.; Chen, H.; Du, Z.; Li, B.; Yang, S. Adv. Funct. Mater. 2019, 30, 1908075. doi: 10.1002/adfm.201908075 doi: 10.1002/adfm.201908075
76. [76]
  Dong, L.; Nie, L.; Liu, W. Adv. Mater. 2020, 32, e1908494. doi: 10.1002/adma.201908494 doi: 10.1002/adma.201908494
77. [77]
  Chen, Y.; Yue, M.; Liu, C.; Zhang, H.; Yu, Y.; Li, X.; Zhang, H. Adv. Funct. Mater. 2019, 29, 1806752. doi: 10.1002/adfm.201806752 doi: 10.1002/adfm.201806752
78. [78]
  Steiger, J.; Kramer, D.; Mönig, R. J. Power Sources 2014, 261, 112. doi: 10.1016/j.jpowsour.2014.03.029 doi: 10.1016/j.jpowsour.2014.03.029
79. [79]
  Lalou, I.; Gkrozou, F.; Meridis, E.; Tsonis, O.; Paschopoulos, M.; Syrrou, M. Eur. J. Obstet. Gynecol. Reprod. Biol. 2019, 236, 116. doi: 10.1016/j.ejogrb.2019.03.004 doi: 10.1016/j.ejogrb.2019.03.004
80. [80]
  Li, Y.; Li, Y.; Pei, A.; Yan, K.; Sun, Y.; Wu, C. L.; Joubert, L. M.; Chin, R.; Koh, A. L.; Yu, Y. Science 2017, 358, 506. doi: 10.1126/science.aam6014 doi: 10.1126/science.aam6014
81. [81]
  Kim, Y. J.; Kwon, S. H.; Noh, H.; Yuk, S.; Lee, H.; Jin, H. S.; Lee, J.; Zhang, J. G.; Lee, S. G.; Guim, H.; Kim, H. T. Energy Storage Mater. 2019, 19, 154. doi: 10.1016/j.ensm.2019.02.011 doi: 10.1016/j.ensm.2019.02.011
82. [82]
  Gu, Y.; Xu, H. Y.; Zhang, X. G.; Wang, W. W.; He, J. W.; Tang, S.; Yan, J. W.; Wu, D. Y.; Zheng, M. S.; Dong, Q. F.; Mao, B. W. Angew. Chem. Int. Ed. 2019, 58, 3092. doi: 10.1002/anie.201812523 doi: 10.1002/anie.201812523
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