Citation: Guan Jun, Li Nianwu, Yu Le. Artificial Interphase Layers for Lithium Metal Anode[J]. Acta Physico-Chimica Sinica, ;2021, 37(2): 200901. doi: 10.3866/PKU.WHXB202009011 shu

Artificial Interphase Layers for Lithium Metal Anode

State Key Lab of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Corresponding author: Li Nianwu, linianwu@mail.buct.edu.cn Yu Le, yule@mail.buct.edu.cn
Received Date: 2 September 2020
Revised Date: 27 September 2020
Accepted Date: 28 September 2020
Available Online: 19 October 2020
Fund Project: the National Natural Science Foundation of China 21975015the Key R&D Program of Shandong Province 2019TSLH0120the Fundamental Research Funds for the Central Universities buctrc201904The project was supported by the National Natural Science Foundation of China (21975015, 51902016, 21703010), the Fundamental Research Funds for the Central Universities (buctrc201829, buctrc201904), and the Key R&D Program of Shandong Province (2019TSLH0120)the National Natural Science Foundation of China 51902016the National Natural Science Foundation of China 21703010the Fundamental Research Funds for the Central Universities buctrc201829

Lithium (Li) metal is considered as the most promising anode material for high-energy-density batteries owing to its ultra-high theoretical capacity (3860 mAh·g^-1) and the lowest negative electrochemical potential (-3.040 V versus standard hydrogen electrode). However, the unstable solid electrolyte interphase (SEI) layers, uncontrollable dendrite growth, and huge volume changes during the plating/stripping processes significantly limit the practical applications of Li metal anodes. Since the unstable SEI layers can promote the nucleation and growth of Li dendrites, they play a crucial role in the decay process of Li metal anodes. The fracture and regeneration of SEI layers continuously consume electrolytes and Li metal anodes during plating/ stripping processes, and the accumulation of SEI layers can increase the interface impedance. Therefore, building artificial interphase layers is one of the most effective strategies to construct a stable SEI, reduce dendrite growth, accommodate large volume changes, and thus obtain excellent cycling performance. In this review, artificial interphase layers have been summarized into three parts based on the conductive properties of interphase, including artificial SEI layers (electronically insulating while ionically conducting), mixed ionic and electronic conductor interphase layers, and nanostructured interphase passivation layers (both ionically and electronically insulating). Artificial SEI layers with high ionic conductivity and low electronic conductivity can be classified into inorganic, organic, and organic/inorganic complex SEI according to the composition of artificial SEI layers. The artificial inorganic SEI layers with a high Young's modulus can suppress the dendrite growth. The artificial organic SEI layers with flexible features can accommodate large interface fluctuations and improve the interphase wettability. The artificial organic/inorganic complex SEI layers with a rigid-flexible structure can restrain dendrite growth and buffer volume change. The mixed ionic and electronic conductor layers possess high ionic conductivity and high Young's modulus, which are beneficial for enhancing the interphase stability and reducing dendrite growth. The artificial alloy mixed conductor layers can improve the Li diffusion coefficient and reduce Li nucleation overpotential, guiding uniform Li plating/stripping. Furthermore, the artificial mixed conductor layers comprising inorganic and organic matter have commendable flexibility and excellent interface compatibility, thereby enhancing the interphase stability and reducing dendrite growth. The nanostructured interphase passivation layers with high chemical stability can deliver Li ion through a confined electrolyte in a uniform porous structure, thereby achieving homogeneous Li plating/stripping. In addition, the structure-effective relationship of artificial interphase layers has been analyzed, and methods for improving the performance of artificial interphase layers, such as physical and chemical stability, ion transportation, interface strength and flexibility, and interfacial compatibility, have been discussed in this review. Finally, we present the main challenge and perspectives of artificial interphase layers.
- Li metal anode,
- Li metal battery,
- Artificial interphase,
- Solid electrolyte interphase,
- Lithium dendrite
1. [1]
  Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741 doi: 10.1126/science.1212741
2. [2]
  Grande, L.; Paillard, E.; Hassoun, J.; Park, J. B.; Lee, Y. J.; Sun, Y. K.; Passerini, S.; Scrosati, B. Adv. Mater. 2015, 27, 784. doi: 10.1002/adma.201403064 doi: 10.1002/adma.201403064
3. [3]
  Lu, Y.; Tikekar, M.; Mohanty, R.; Hendrickson, K.; Ma, L.; Archer, L. A. Adv. Energy Mater. 2015, 5, 1402073. doi: 10.1002/aenm.201402073 doi: 10.1002/aenm.201402073
4. [4]
  Yang, P.; Tarascon, J. M. Nat. Mater. 2012, 11, 560. doi: 10.1038/nmat3367 doi: 10.1038/nmat3367
5. [5]
  Li, S.; Jiang, M.; Xie, Y.; Xu, H.; Jia, J.; Li, J. Adv. Mater. 2018, 30, 1706375. doi: 10.1002/adma.201706375 doi: 10.1002/adma.201706375
6. [6]
  Choi, J. W.; Aurbach, D. Nat. Rev. Mater. 2016, 1, 16013. doi: 10.1038/natrevmats.2016.13 doi: 10.1038/natrevmats.2016.13
7. [7]
  Goodenough, J. B.; Kim, Y. Chem. Mater. 2010, 22, 587. doi: 10.1021/cm901452z doi: 10.1021/cm901452z
8. [8]
  Li, H. P.; Ji, X. Y.; Liang, J. J. Rare Met. 2020, 39, 861. doi: 10.1007/s12598-020-01456-8 doi: 10.1007/s12598-020-01456-8
9. [9]
  Zhang, F.; Shen, F.; Fan, Z. Y.; Ji, X.; Zhao, B.; Sun, Z. T.; Xuan, Y. Y.; Han, X. G. Rare Met. 2018, 37, 510. doi: 10.1007/s12598-018-1054-6 doi: 10.1007/s12598-018-1054-6
10. [10]
  Cheng, X. B.; Zhang, R.; Zhao, C. Z.; Zhang, Q. Chem. Rev. 2017, 117, 10403. doi: 10.1021/acs.chemrev.7b00115 doi: 10.1021/acs.chemrev.7b00115
11. [11]
  Cheng, X. B.; Zhang, Q. J. Mater. Chem. A 2015, 3, 7207. doi: 10.1039/c5ta00689a doi: 10.1039/c5ta00689a
12. [12]
  Wang, M. Q.; Peng, Z.; Lin, H.; Li, Z. D.; Liu, J.; Ren, Z. M.; He, H. Y.; Wang, D. Y. Acta Phys. -Chim. Sin. 2021, 37, 2007016. doi: 10.3866/PKU.WHXB202007016
13. [13]
  Xu, W.; Wang, J.; Ding, F.; Chen, X.; Nasybulin, E.; Zhang, Y.; Zhang, J. G. Energy Environ. Sci. 2014, 7, 513. doi: 10.1039/c3ee40795k doi: 10.1039/c3ee40795k
14. [14]
  Yu, X. R.; Ma, J.; Mou, C. B.; Cui, G. L. Acta Phys. -Chim. Sin. 2021, 37, 1912061. doi: 10.3866/PKU.WHXB201912061
15. [15]
  Zhang, Q. Acta Phys. -Chim. Sin. 2017, 33, 1275. doi: 10.3866/PKU.WHXB201705021
16. [16]
  Guo, Y.; Li, H.; Zhai, T. Adv. Mater. 2017, 29, 1700007. doi: 10.1002/adma.201700007 doi: 10.1002/adma.201700007
17. [17]
  Yin, Y. X.; Xin, S.; Guo, Y. G.; Wan, L. J. Angew. Chem. Int. Ed. 2013, 52, 13186. doi: 10.1002/anie.201304762 doi: 10.1002/anie.201304762
18. [18]
  Li, P.; Dong, X.; Li, C.; Liu, J.; Liu, Y.; Feng, W.; Wang, C.; Wang, Y.; Xia, Y. Angew. Chem. Int. Ed. 2019, 58, 2093. doi: 10.1002/anie.201813905 doi: 10.1002/anie.201813905
19. [19]
  Yoshio, M.; Wang, H.; Fukuda, K.; Hara, Y.; Adachi, Y. J. Electrochem. Soc. 2000, 147, 1245. doi: 10.1149/1.1393344 doi: 10.1149/1.1393344
20. [20]
  Cheng, X. B.; Hou, T. Z.; Zhang, R.; Peng, H. J.; Zhao, C. Z.; Huang, J. Q.; Zhang, Q. Adv. Mater. 2016, 28, 2888. doi: 10.1002/adma.201506124 doi: 10.1002/adma.201506124
21. [21]
  Lin, D.; Liu, Y.; Liang, Z.; Lee, H. W.; Sun, J.; Wang, H.; Yan, K.; Xie, J.; Cui, Y. Nat. Nanotechnol. 2016, 11, 626. doi: 10.1038/nnano.2016.32 doi: 10.1038/nnano.2016.32
22. [22]
  Liu, Y.; Lin, D.; Liang, Z.; Zhao, J.; Yan, K.; Cui, Y. Nat. Commun. 2016, 7, 10992. doi: 10.1038/ncomms10992 doi: 10.1038/ncomms10992
23. [23]
  Zhang, R.; Chen, X. R.; Chen, X.; Cheng, X. B.; Zhang, X. Q.; Yan, C.; Zhang, Q. Angew. Chem. Int. Ed. 2017, 56, 7764. doi: 10.1002/anie.201702099 doi: 10.1002/anie.201702099
24. [24]
  Cheng, X. B.; Peng, H. J.; Huang, J. Q.; Zhang, R.; Zhao, C. Z.; Zhang, Q. ACS Nano 2015, 9, 6373. doi: 10.1021/acsnano.5b01990 doi: 10.1021/acsnano.5b01990
25. [25]
  Zhang, R.; Cheng, X. B.; Zhao, C. Z.; Peng, H. J.; Shi, J. L.; Huang, J. Q.; Wang, J.; Wei, F.; Zhang, Q. Adv. Mater. 2016, 28, 2155. doi: 10.1002/adma.201504117 doi: 10.1002/adma.201504117
26. [26]
  Zhang, D.; Zhou, Y.; Liu, C.; Fan, S. Nanoscale 2016, 8, 11161. doi: 10.1039/c6nr00465b doi: 10.1039/c6nr00465b
27. [27]
  Zhang, Y.; Liu, B.; Hitz, E.; Luo, W.; Yao, Y.; Li, Y.; Dai, J.; Chen, C.; Wang, Y.; Yang, C.; et al. Nano Res. 2017, 10, 1356. doi: 10.1007/s12274-017-1461-2 doi: 10.1007/s12274-017-1461-2
28. [28]
  Li, Q.; Zhu, S.; Lu, Y. Adv. Funct. Mater. 2017, 27, 1606422. doi: 10.1002/adfm.201606422 doi: 10.1002/adfm.201606422
29. [29]
  Yang, C. P.; Yin, Y. X.; Zhang, S. F.; Li, N. W.; Guo, Y. G. Nat. Commun. 2015, 6, 8058. doi: 10.1038/ncomms9058 doi: 10.1038/ncomms9058
30. [30]
  Lin, D.; Liu, W.; Liu, Y.; Lee, H. R.; Hsu, P. C.; Liu, K.; Cui, Y. Nano Lett. 2016, 16, 459. doi: 10.1021/acs.nanolett.5b04117 doi: 10.1021/acs.nanolett.5b04117
31. [31]
  Murugan, R.; Thangadurai, V.; Weppner, W. Angew. Chem. Int. Ed. 2007, 46, 7778. doi: 10.1002/anie.200701144 doi: 10.1002/anie.200701144
32. [32]
  Zeng, X. X.; Yin, Y. X.; Li, N. W.; Du, W. C.; Guo, Y. G.; Wan, L. J. J. Am. Chem. Soc. 2016, 138, 15825. doi: 10.1021/jacs.6b10088 doi: 10.1021/jacs.6b10088
33. [33]
  Li, N. W.; Yin, Y. X.; Yang, C. P.; Guo, Y. G. Adv. Mater. 2016, 28, 1853. doi: 10.1002/adma.201504526 doi: 10.1002/adma.201504526
34. [34]
  Chen, H.; Pei, A.; Lin, D.; Xie, J.; Yang, A.; Xu, J.; Lin, K.; Wang, J.; Wang, H.; Shi, F.; et al. Adv. Energy Mater. 2019, 9, 1900858. doi: 10.1002/aenm.201900858 doi: 10.1002/aenm.201900858
35. [35]
  Zhai, P.; Wei, Y.; Xiao, J.; Liu, W.; Zuo, J.; Gu, X.; Yang, W.; Cui, S.; Li, B.; Yang, S.; et al. Adv. Energy Mater. 2020, 10, 1903339. doi: 10.1002/aenm.201903339 doi: 10.1002/aenm.201903339
36. [36]
  Lu, Y.; Gu, S.; Hong, X.; Rui, K.; Huang, X.; Jin, J.; Chen, C.; Yang, J.; Wen, Z. Energy Storage Mater. 2018, 11, 16. doi: 10.1016/j.ensm.2017.09.007 doi: 10.1016/j.ensm.2017.09.007
37. [37]
  Chen, K.; Pathak, R.; Gurung, A.; Adhamash, E. A.; Bahrami, B.; He, Q.; Qiao, H.; Smirnova, A. L.; Wu, J. J.; Qiao, Q.; et al. Energy Storage Mater. 2019, 18, 389. doi: 10.1016/j.ensm.2019.02.006 doi: 10.1016/j.ensm.2019.02.006
38. [38]
  Li, Y.; Sun, Y.; Pei, A.; Chen, K.; Vailionis, A.; Li, Y.; Zheng, G.; Sun, J.; Cui, Y. ACS Cent. Sci. 2018, 4, 97. doi: 10.1021/acscentsci.7b00480 doi: 10.1021/acscentsci.7b00480
39. [39]
  Ma, G.; Wen, Z.; Wu, M.; Shen, C.; Wang, Q.; Jin, J.; Wu, X. Chem. Commun. 2014, 50, 14209. doi: 10.1039/c4cc05535g doi: 10.1039/c4cc05535g
40. [40]
  Wu, M.; Wen, Z.; Liu, Y.; Wang, X.; Huang, L. J. Power Sources 2011, 196, 8091. doi: 10.1016/j.jpowsour.2011.05.035 doi: 10.1016/j.jpowsour.2011.05.035
41. [41]
  Lin, D.; Liu, Y.; Chen, W.; Zhou, G.; Liu, K.; Dunn, B.; Cui, Y. Nano Lett. 2017, 17, 3731. doi: 10.1021/acs.nanolett.7b01020 doi: 10.1021/acs.nanolett.7b01020
42. [42]
  Shen, X.; Li, Y.; Qian, T.; Liu, J.; Zhou, J.; Yan, C.; Goodenough, J. B. Nat. Commun. 2019, 10, 900. doi: 10.1038/s41467-019-08767-0 doi: 10.1038/s41467-019-08767-0
43. [43]
  Lang, J.; Long, Y.; Qu, J.; Luo, X.; Wei, H.; Huang, K.; Zhang, H.; Qi, L.; Zhang, Q.; Li, Z.; et al. Energy Storage Mater. 2019, 16, 85. doi: 10.1016/j.ensm.2018.04.024 doi: 10.1016/j.ensm.2018.04.024
44. [44]
  Fan, L.; Zhuang, H. L.; Gao, L.; Lu, Y.; Archer, L. A. J. Mater. Chem. A 2017, 5, 3483. doi: 10.1039/c6ta10204b doi: 10.1039/c6ta10204b
45. [45]
  Han, X.; Gong, Y.; Fu, K. K.; He, X.; Hitz, G. T.; Dai, J.; Pearse, A.; Liu, B.; Wang, H.; Rubloff, G. et al. Nat. Mater. 2017, 16, 572. doi: 10.1038/nmat4821 doi: 10.1038/nmat4821
46. [46]
  Kozen, A. C.; Lin, C. F.; Pearse, A. J.; Schroeder, M. A.; Han, X. G.; Hu, L. B.; Lee, S. B.; Rubloff, G. W.; Noked, M. ACS Nano 2015, 9, 5884. doi: 10.1021/acsnano.5b02166 doi: 10.1021/acsnano.5b02166
47. [47]
  Lee, J. I.; Shin, M.; Hong, D.; Park, S. Adv. Energy Mater. 2019, 9, 1803722. doi: 10.1002/aenm.201803722 doi: 10.1002/aenm.201803722
48. [48]
  Cheng, X. B.; Zhao, C. Z.; Yao, Y. X.; Liu, H.; Zhang, Q. Chem 2019, 5, 74. doi: 10.1016/j.chempr.2018.12.002 doi: 10.1016/j.chempr.2018.12.002
49. [49]
  Li, N. W.; Shi, Y.; Yin, Y. X.; Zeng, X. X.; Li, J. Y.; Li, C. J.; Wan, L. J.; Wen, R.; Guo, Y. G. Angew. Chem. Int. Ed. 2018, 57, 1505. doi: 10.1002/anie.201710806 doi: 10.1002/anie.201710806
50. [50]
  Liu, K.; Pei, A.; Lee, H. R.; Kong, B.; Liu, N.; Lin, D.; Liu, Y.; Liu, C.; Hsu, P. C.; Bao, Z.; et al. J. Am. Chem. Soc. 2017, 139, 4815. doi: 10.1021/jacs.6b13314 doi: 10.1021/jacs.6b13314
51. [51]
  Hu, Z.; Zhang, S.; Dong, S.; Li, W.; Li, H.; Cui, G.; Chen, L. Chem. Mater. 2017, 29, 4682. doi: 10.1021/acs.chemmater.7b00091 doi: 10.1021/acs.chemmater.7b00091
52. [52]
  Tu, Z.; Choudhury, S.; Zachman, M. J.; Wei, S.; Zhang, K.; Kourkoutis, L. F.; Archer, L. A. Joule 2017, 1, 394. doi: 10.1016/j.joule.2017.06.002 doi: 10.1016/j.joule.2017.06.002
53. [53]
  Ma, G.; Wen, Z.; Wang, Q.; Shen, C.; Jin, J.; Wu, X. J. Mater. Chem. A 2014, 2, 19355. doi: 10.1039/c4ta04172k doi: 10.1039/c4ta04172k
54. [54]
  Gao, Y.; Zhao, Y.; Li, Y. C.; Huang, Q.; Mallouk, T. E.; Wang, D. J. Am. Chem. Soc. 2017, 139, 15288. doi: 10.1021/jacs.7b06437 doi: 10.1021/jacs.7b06437
55. [55]
  Luo, J.; Fang, C. C.; Wu, N. L. Adv. Energy Mater. 2018, 8, 1701482. doi: 10.1002/aenm.201701482 doi: 10.1002/aenm.201701482
56. [56]
  Sun, Y.; Zhao, Y.; Wang, J.; Liang, J.; Wang, C.; Sun, Q.; Lin, X.; Adair, K. R.; Luo, J.; Wang, D.; et al. Adv. Mater. 2019, 31, e1806541. doi: 10.1002/adma.201806541 doi: 10.1002/adma.201806541
57. [57]
  Liu, J.; Qian, T.; Wang, M.; Zhou, J.; Xu, N.; Yan, C. Nano Lett. 2018, 18, 4598. doi: 10.1021/acs.nanolett.8b01882 doi: 10.1021/acs.nanolett.8b01882
58. [58]
  Kang, D.; Sardar, S.; Zhang, R.; Noam, H.; Chen, J.; Ma, L.; Liang, W.; Shi, C.; Lemmon, J. P. Energy Storage Mater. 2020, 27, 69. doi: 10.1016/j.ensm.2020.01.020 doi: 10.1016/j.ensm.2020.01.020
59. [59]
  Xu, R.; Xiao, Y.; Zhang, R.; Cheng, X. B.; Zhao, C. Z.; Zhang, X. Q.; Yan, C.; Zhang, Q.; Huang, J. Q. Adv. Mater. 2019, 31, e1808392. doi: 10.1002/adma.201808392 doi: 10.1002/adma.201808392
60. [60]
  Yang, C.; Liu, B.; Jiang, F.; Zhang, Y.; Xie, H.; Hitz, E.; Hu, L. Nano Res. 2017, 10, 4256. doi: 10.1007/s12274-017-1498-2 doi: 10.1007/s12274-017-1498-2
61. [61]
  Liu, Y.; Lin, D.; Yuen, P. Y.; Liu, K.; Xie, J.; Dauskardt, R. H.; Cui, Y. Adv. Mater. 2017, 29, 1605531. doi: 10.1002/adma.201605531 doi: 10.1002/adma.201605531
62. [62]
  Kozen, A. C.; Lin, C. F.; Zhao, O.; Lee, S. B.; Rubloff, G. W.; Noked, M. Chem. Mater. 2017, 29, 6298. doi: 10.1021/acs.chemmater.7b01496 doi: 10.1021/acs.chemmater.7b01496
63. [63]
  Liu, F.; Xiao, Q.; Wu, H. B.; Shen, L.; Xu, D.; Cai, M.; Lu, Y. Adv. Energy Mater. 2018, 8, 1701744. doi: 10.1002/aenm.201701744 doi: 10.1002/aenm.201701744
64. [64]
  Adair, K. R.; Zhao, C. T.; Banis, M. N.; Zhao, Y.; Li, R. Y.; Cai, M.; Sun, X. L. Angew. Chem. Int. Ed. 2019, 58, 15797. doi: 10.1002/anie.201907759 doi: 10.1002/anie.201907759
65. [65]
  Sun, C.; Huang, X.; Jin, J.; Lu, Y.; Wang, Q.; Yang, J.; Wen, Z. J. Power Sources 2018, 377, 36. doi: 10.1016/j.jpowsour.2017.11.063 doi: 10.1016/j.jpowsour.2017.11.063
66. [66]
  Xu, R.; Zhang, X. Q.; Cheng, X. B.; Peng, H. J.; Zhao, C. Z.; Yan, C.; Huang, J. Q. Adv. Funct. Mater. 2018, 28, 1705838. doi: 10.1002/adfm.201705838 doi: 10.1002/adfm.201705838
67. [67]
  Li, S.; Fan, L.; Lu, Y. Energy Storage Mater. 2019, 18, 205. doi: 10.1016/j.ensm.2018.09.015 doi: 10.1016/j.ensm.2018.09.015
68. [68]
  Cheng, X. B.; Yan, C.; Chen, X.; Guan, C.; Huang, J. Q.; Peng, H. J.; Zhang, R.; Yang, S. T.; Zhang, Q. Chem 2017, 2, 258. doi: 10.1016/j.chempr.2017.01.003 doi: 10.1016/j.chempr.2017.01.003
69. [69]
  Liu, Q. C.; Xu, J. J.; Yuan, S.; Chang, Z. W.; Xu, D.; Yin, Y. B.; Li, L.; Zhong, H. X.; Jiang, Y. S.; Yan, J. M.; et al. Adv. Mater. 2015, 27, 5241. doi: 10.1002/adma.201501490 doi: 10.1002/adma.201501490
70. [70]
  Liu, S.; Xia, X.; Deng, S.; Xie, D.; Yao, Z.; Zhang, L.; Zhang, S.; Wang, X.; Tu, J. Adv. Mater. 2019, 31, e1806470. doi: 10.1002/adma.201806470 doi: 10.1002/adma.201806470
71. [71]
  Yan, K.; Lu, Z.; Lee, H. W.; Xiong, F.; Hsu, P. C.; Li, Y.; Zhao, J.; Chu, S.; Cui, Y. Nat. Energy 2016, 1, 16010. doi: 10.1038/nenergy.2016.10 doi: 10.1038/nenergy.2016.10
72. [72]
  Liu, S.; Ma, Y.; Zhou, Z.; Lou, S.; Huo, H.; Zuo, P.; Wang, J.; Du, C.; Yin, G.; Gao, Y. Energy Storage Mater. 2020, 33, 423. doi: 10.1016/j.ensm.2020.08.007 doi: 10.1016/j.ensm.2020.08.007
73. [73]
  Liang, X.; Pang, Q.; Kochetkov, I. R.; Sempere, M. S.; Huang, H.; Sun, X.; Nazar, L. F. Nat. Energy 2017, 2, 17119. doi: 10.1038/nenergy.2017.119 doi: 10.1038/nenergy.2017.119
74. [74]
  Jiang, Z.; Jin, L.; Han, Z.; Hu, W.; Zeng, Z.; Sun, Y.; Xie, J. Angew. Chem. Int. Ed. 2019, 58, 11374. doi: 10.1002/anie.201905712 doi: 10.1002/anie.201905712
75. [75]
  Ma, L.; Kim, M. S.; Archer, L. A. Chem. Mater. 2017, 29, 4181. doi: 10.1021/acs.chemmater.6b03687 doi: 10.1021/acs.chemmater.6b03687
76. [76]
  Tang, W.; Yin, X.; Kang, S.; Chen, Z.; Tian, B.; Teo, S. L.; Wang, X.; Chi, X.; Loh, K. P.; Lee, H. W.; et al. Adv. Mater. 2018, e1801745. doi: 10.1002/adma.201801745 doi: 10.1002/adma.201801745
77. [77]
  Hu, Z.; Liu, F.; Gao, J.; Zhou, W.; Huo, H.; Zhou, J.; Li, L. Adv. Funct. Mater. 2020, 30, 1907020. doi: 10.1002/adfm.201907020 doi: 10.1002/adfm.201907020
78. [78]
  Liu, S.; Zhang, X.; Li, R.; Gao, L.; Luo, J. Energy Storage Mater. 2018, 14, 143. doi: 10.1016/j.ensm.2018.03.004 doi: 10.1016/j.ensm.2018.03.004
79. [79]
  Fu, K. K.; Gong, Y. H.; Liu, B. Y.; Zhu, Y. Z.; Xu, S. M.; Yao, Y. G.; Luo, W.; Wang, C. W.; Lacey, S. D.; Dai, J. Q.; et al. Sci. Adv. 2017, 3, e1601659. doi: 10.1126/sciadv.1601659 doi: 10.1126/sciadv.1601659
80. [80]
  Yan, C.; Cheng, X. B.; Yao, Y. X.; Shen, X.; Li, B. Q.; Li, W. J.; Zhang, R.; Huang, J. Q.; Li, H.; Zhang, Q. Adv. Mater. 2018, 30, 1804461. doi: 10.1002/adma.201804461 doi: 10.1002/adma.201804461
81. [81]
  Li, T.; Shi, P.; Zhang, R.; Liu, H.; Cheng, X. B.; Zhang, Q. Nano Res. 2019, 12, 2224. doi: 10.1007/s12274-019-2368-x doi: 10.1007/s12274-019-2368-x
82. [82]
  Zheng, G.; Lee, S. W.; Liang, Z.; Lee, H. W.; Yan, K.; Yao, H.; Wang, H.; Li, W.; Chu, S.; Cui, Y. Nat. Nanotechnol. 2014, 9, 618. doi: 10.1038/nnano.2014.152 doi: 10.1038/nnano.2014.152
83. [83]
  Yan, J.; Yu, J.; Ding, B. Adv. Mater. 2018, 30, 1705105. doi: 10.1002/adma.201705105 doi: 10.1002/adma.201705105
84. [84]
  Yan, M.; Liang, J. Y.; Zuo, T. T.; Yin, Y. X.; Xin, S.; Tan, S. J.; Guo, Y. G.; Wan, L. J. Adv. Funct. Mater. 2020, 30, 1908047. doi: 10.1002/adfm.201908047 doi: 10.1002/adfm.201908047
85. [85]
  Huo, H.; Chen, Y.; Li, R.; Zhao, N.; Luo, J.; da Silva, J. G. P.; Muecke, R.; Kaghazchi, P.; Guo, X.; Sun, X. Energy Environ. Sci. 2020, 13, 127. doi: 10.1039/c9ee01903k doi: 10.1039/c9ee01903k
86. [86]
  Yang, Q.; Li, W.; Dong, C.; Ma, Y.; Yin, Y.; Wu, Q.; Xu, Z.; Ma, W.; Fan, C.; Sun, K. J. Energy Chem. 2020, 42, 83. doi: 10.1016/j.jechem.2019.06.012 doi: 10.1016/j.jechem.2019.06.012
87. [87]
  Zhu, B.; Jin, Y.; Hu, X. Z.; Zheng, Q. H.; Zhang, S.; Wang, Q. J.; Zhu, J. Adv. Mater. 2017, 29, 1603755. doi: 10.1002/adma.201603755 doi: 10.1002/adma.201603755
88. [88]
  Li, Q.; Zeng, F. L.; Guan, Y. P.; Jin, Z. Q.; Huang, Y. Q.; Yao, M.; Wang, W. K.; Wang, A. B. Energy Storage Mater. 2018, 13, 151. doi: 10.1016/j.ensm.2018.01.002 doi: 10.1016/j.ensm.2018.01.002
89. [89]
  Luo, J.; Lee, R. C.; Jin, J. T.; Weng, Y. T.; Fang, C. C.; Wu, N. L. Chem. Commun. 2017, 53, 963. doi: 10.1039/c6cc09248a doi: 10.1039/c6cc09248a
90. [90]
  Yao, Y.; Zhao, X.; Razzaq, A. A.; Gu, Y.; Yuan, X.; Shah, R.; Lian, Y.; Lei, J.; Mu, Q.; Ma, Y.; et al. J. Mater. Chem. A 2019, 7, 12214. doi: 10.1039/c9ta03679b doi: 10.1039/c9ta03679b
91. [91]
  Jing, H. K.; Kong, L. L.; Liu, S.; Li, G. R.; Gao, X. P. J. Mater. Chem. A 2015, 3, 12213. doi: 10.1039/c5ta01490e doi: 10.1039/c5ta01490e
1. [1]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
2. [2]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
3. [3]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
4. [4]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
5. [5]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
6. [6]
  .
  南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积
  . CCS Chemistry, 2025, 7(0): -.
7. [7]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
8. [8]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
9. [9]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
10. [10]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
11. [11]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
12. [12]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
13. [13]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
14. [14]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
15. [15]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
16. [16]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
17. [17]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
18. [18]
  Yikai Wang , Xiaolin Jiang , Haoming Song , Nan Wei , Yifan Wang , Xinjun Xu , Cuihong Li , Hao Lu , Yahui Liu , Zhishan Bo . 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池. Acta Physico-Chimica Sinica, 2025, 41(3): 2406007-. doi: 10.3866/PKU.WHXB202406007
19. [19]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
20. [20]
  Xinlong WANG , Zhenguo CHENG , Guo WANG , Xiaokuen ZHANG , Yong XIANG , Xinquan WANG . Enhancement of the fragile interface of high voltage LiCoO₂ by surface gradient permeation of trace amounts of Mg/F. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 571-580. doi: 10.11862/CJIC.20230259

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(937)
HTML views(146)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Artificial Interphase Layers for Lithium Metal Anode

南开大学师唯/华北电力大学（保定）刘景维：二维配位聚合物中有序的亲锂冠醚位点用于无枝晶锂沉积

Metrics

通讯作者: 陈斌, bchen63@163.com