Citation: Zhang Shichao, Shen Zeyu, Lu Yingying. Research Progress of Thermal Runaway and Safety for Lithium Metal Batteries[J]. Acta Physico-Chimica Sinica, ;2021, 37(1): 200806. doi: 10.3866/PKU.WHXB202008065 shu

Research Progress of Thermal Runaway and Safety for Lithium Metal Batteries

College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China

Corresponding author: Lu Yingying, yingyinglu@zju.edu.cn
Received Date: 22 August 2020
Revised Date: 15 September 2020
Accepted Date: 16 September 2020
Available Online: 21 September 2020
Fund Project: the National Key R & D Program of China 2018YFA0209600The project was supported by the National Key R & D Program of China (2018YFA0209600), the National Natural Science Foundation of China (21878268), and the Leading Innovative and Entrepreneur Team Introduction Program ofZhejiang Province (2019R01006)the Leading Innovative and Entrepreneur Team Introduction Program ofZhejiang Province 2019R01006the National Natural Science Foundation of China 21878268

Lithium ion batteries have been widely used in the fields of portable energy storage devices and electric vehicles due to their high energy density and high safety, and have a profound impact on modern society. However, the frequent occurrence of battery fire and explosion accidents has caused widespread concern of thermal runaway and thermal safety issues. Many reviews have reported the measures to mitigate thermal runaway of lithium ion batteries. Due to the use of graphite with a smaller capacity as the negative electrode material, the specific energy of lithium ion batteries has approached the theoretical limit, and there is an urgent need to develop more efficient electrode materials to meet the growing demand of the energy storage market. Lithium metal anode has smaller density, higher theoretical capacity and lower potential, which is the ideal anode material for the next generation of high energy density battery system. However, the high reactivity of lithium will cause uncontrollable lithium dendrite growth during the cycle, which may penetrate the separator and cause internal short circuit of the battery, and then cause thermal runaway, fire and even explosion. Therefore, the thermal runaway of lithium metal batteries are more complicated and serious, which hinders the commercial application of batteries. Aiming at the thermal runaway problem of lithium metal batteries, this article first introduces the causes of thermal runaway, which are mainly uncontrollable exothermic reactions caused by internal short circuits. The basic process of thermal runaway is divided into three stages. By analyzing the three characteristic temperatures and heating rate, it is proved that improving the thermal stability of electrolyte and seperator can alleviate thermal runaway. Then we investigated the influence of thermodynamics on the nucleation and growth of lithium dendrites, revealing the dual effects of temperature, and proving that a uniform thermal field is beneficial to obtain uniform lithium deposition and improve battery cycle performance and safety. Secondly, a variety of strategies to improve battery thermal safety are reviewed at the material level. In terms of liquid electrolytes, the development of non-flammable electrolyte systems includes the use of flame-retardant electrolytes and ionic liquid electrolytes with lower flammability. In addition, high-concentration electrolyte and local high-concentration electrolyte can change the solvation structure of lithium ions, and improve safety by reducing the number of free solvent molecules. In terms of separators, high thermal stability separators and thermal response separators with thermal shutdown function have been developed. The flame-retardant separators can release flame retardants to inhibit combustion. In addition, the new intelligent separators have dendrite detection, early warning and elimination functions, which effectively improve the safety and cycle life of the battery. In terms of solid electrolytes, thermally responsive polymer electrolytes have been developed to avoid thermal runaway through the strain function of polymer materials. Finally, further research on the thermal runaway of lithium metal batteries in the future is prospected.
- Thermal runaway,
- Thermal safety,
- Lithium metal anode,
- Lithium metal battery
1. [1]
  Cheng, X. B.; Zhang, R.; Zhao, C. Z.; Zhang, Q. Chem. Rev. 2017, 117, 10403. doi: 10.1021/acs.chemrev.7b00115 doi: 10.1021/acs.chemrev.7b00115
2. [2]
  Dunn, J. B.; Gaines, L.; Kelly, J. C.; James, C.; Gallagher, K. G. Energy Environ. Sci. 2015, 8, 158. doi: 10.1039/c4ee03029j doi: 10.1039/c4ee03029j
3. [3]
  Whittingham, M. S. Chem. Rev. 2014, 114, 11414. doi: 10.1021/cr5003003 doi: 10.1021/cr5003003
4. [4]
  Wang, Q. S.; Ping, P.; Zhao, X. J.; Chu, G. Q.; Sun, J. H.; Chen, C. H. J. Power Sources 2012, 208, 210. doi: 10.1016/j.jpowsour.2012.02.038 doi: 10.1016/j.jpowsour.2012.02.038
5. [5]
  Lu, L. G.; Han, X. B.; Li, J. Q.; Hua, J. F.; Ouyang, M. G. J. Power Sources 2013, 226, 272. doi: 10.1016/j.jpowsour.2012.10.060 doi: 10.1016/j.jpowsour.2012.10.060
6. [6]
  Janek, J.; Zeier, W. G. Nat. Energy 2016, 1, 16141. doi: 10.1038/nenergy.2016.141 doi: 10.1038/nenergy.2016.141
7. [7]
  Zhang, Y.; Zuo, T. T.; Popovic, J.; Lim, K.; Yin, Y. X.; Maier, J.; Guo, Y. G. Mater. Today 2020, 33, 56. doi: 10.1016/j.mattod.2019.09.018 doi: 10.1016/j.mattod.2019.09.018
8. [8]
  Gao, X.; Zhou, Y. N.; Han, D.; Zhou, J.; Zhou, D.; Tang, W.; Goodenough, J. B. Joule 2020, 4, 1864. doi: 10.1016/j.joule.2020.06.016 doi: 10.1016/j.joule.2020.06.016
9. [9]
  Liu, J.; Bao, Z. N.; Cui, Y.; Dufek, E. J.; Goodenough, J. B.; Khalifah, P.; Li, Q. Y.; Liaw, B. Y.; Liu, P.; Manthiram, A.; et al. Nat. Energy 2019, 4, 180. doi: 10.1038/s41560-019-0338-x doi: 10.1038/s41560-019-0338-x
10. [10]
  Lin, D. C.; Liu, Y. Y.; Cui, Y. Nat. Nanotech. 2017, 12, 194. doi: 10.1038/nnano.2017.16 doi: 10.1038/nnano.2017.16
11. [11]
  Liu, F. F.; Zhang, Z. W.; Ye, S. F.; Yao, Y.; Yu, Y. Acta Phys. -Chim. Sin. 2021, 37, 2006021. doi: 10.3866/PKU.WHXB202006021
12. [12]
  Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Nat. Mater. 2012, 11, 19. doi: 10.1038/nmat3191 doi: 10.1038/nmat3191
13. [13]
  Fang, R. P.; Zhao, S. Y.; Sun, Z. H.; Wang, D. W.; Cheng, H. M.; Li, F. Adv. Mater. 2017, 29, 1606823. doi: 10.1002/adma.201606823 doi: 10.1002/adma.201606823
14. [14]
  Xia, C.; Kwok, C. Y.; Nazar, L. F. Science 2018, 361, 777. doi: 10.1126/science.aas9343 doi: 10.1126/science.aas9343
15. [15]
  Yue, X. Y.; Ma, C.; Bao, J.; Yang, S. Y.; Chen, D.; Wu, X. J.; Zhou, Y. N. Acta Phys. -Chim. Sin. 2021, 37, 2005012. doi: 10.3866/PKU.WHXB202005012
16. [16]
  Koch, S.; Fill, A.; Birke, K. P. J. Power Sources 2018, 398, 106. doi: 10.1016/j.jpowsour.2018.07.051 doi: 10.1016/j.jpowsour.2018.07.051
17. [17]
  Xu, G. J.; Huang, L.; Lu, C. L.; Zhou, X. H.; Cui, G. L. Energy Storage Mater. 2020, 31, 72. doi: 10.1016/j.ensm.2020.06.004 doi: 10.1016/j.ensm.2020.06.004
18. [18]
  Lyu, P. Z.; Liu, X. J.; Qu, J.; Zhao, J. T.; Huo, Y. T.; Qu, Z. G.; Rao, Z. H. Energy Storage Mater. 2020, 31, 195. doi: 10.1016/j.ensm.2020.06.042 doi: 10.1016/j.ensm.2020.06.042
19. [19]
  Feng, X. N.; Ren, D. S.; He, X. M.; Ouyang, M. G. Joule 2020, 4, 743. doi: 10.1016/j.joule.2020.02.010 doi: 10.1016/j.joule.2020.02.010
20. [20]
  Feng, X. N.; Ouyang, M. G.; Liu, X.; Lu, L. G.; Xia, Y.; He, X. M. Energy Storage Mater. 2018, 10, 246. doi: 10.1016/j.ensm.2017.05.013 doi: 10.1016/j.ensm.2017.05.013
21. [21]
  Offer, G.; Patel, Y.; Hales, A.; Diaz, L. B.; Marzook, M. Nature 2020, 582, 485. doi: 10.1038/d41586-020-01813-8 doi: 10.1038/d41586-020-01813-8
22. [22]
  Jia, Y. K.; Uddin, M.; Li, Y. X.; Xu, J. J. Energy Storage 2020, 31, 101668. doi: 10.1016/j.est.2020.101668 doi: 10.1016/j.est.2020.101668
23. [23]
  Wang, S. J.; Rafiz, K.; Liu, J. L.; Jin, Y.; Lin, J. Y. S. Sustain Energy Fuels 2020, 4, 2342. doi: 10.1039/d0se00027b doi: 10.1039/d0se00027b
24. [24]
  Yuan, L. M.; Dubaniewicz, T.; Zlochower, I.; Thomas, R.; Rayyan, N. Proc. Saf. Environ. Prot. 2020, 144, 186. doi: 10.1016/j.psep.2020.07.028 doi: 10.1016/j.psep.2020.07.028
25. [25]
  Chen, S. C; Wang, Z. R.; Yan, W. J. Hazard. Mater. 2020, 400, 123169. doi: 10.1016/j.jhazmat.2020.123169 doi: 10.1016/j.jhazmat.2020.123169
26. [26]
  Liao, Z. H, ; Zhang, S.; Li, K.; Zhang, G. Q.; Habetler, T. G. J. Power Sources 2019, 436, 226879. doi: 10.1016/j.jpowsour.2019.226879 doi: 10.1016/j.jpowsour.2019.226879
27. [27]
  Orendorff, C. J.; Lambert, T. N.; Chavez, C. A.; Bencomo, M.; Fenton, K. R. Adv. Energy Mater. 2013, 3, 314. doi: 10.1002/aenm.201200292 doi: 10.1002/aenm.201200292
28. [28]
  Woo, J. J.; Nam, S. H.; Seo, S. J.; Yun, S. H.; Kim, W. B.; Xu, T. W.; Moon, S. H. Electrochem. Commun. 2013, 35, 68. doi: 10.1016/j.elecom.2013.08.005 doi: 10.1016/j.elecom.2013.08.005
29. [29]
  Xu, K. Chem. Rev. 2014, 114, 11503. doi: 10.1021/cr500003w doi: 10.1021/cr500003w
30. [30]
  Shen, X.; Liu, H.; Cheng, X. B.; Yan, C.; Huang, J. Q. Energy Storage Mater. 2018, 12, 161. doi: 10.1016/j.ensm.2017.12.002 doi: 10.1016/j.ensm.2017.12.002
31. [31]
  Rodrigues, M. T. F.; Babu, G.; Gullapalli, H.; Kalaga, K.; Sayed, F. N.; Kato, K.; Joyner, J.; Ajayan, P. M. Nat. Energy 2017, 2, 17108. doi: 10.1038/nenergy.2017.108 doi: 10.1038/nenergy.2017.108
32. [32]
  Geng, Z.; Lu, J. Z.; Li, Q.; Qiu, J. L.; Wang, Y.; Peng, J. Y.; Huang, J.; Li, W. J.; Yu, X. Q.; Li, H. Energy Storage Mater. 2019, 23, 646. doi: 10.1016/j.ensm.2019.03.005 doi: 10.1016/j.ensm.2019.03.005
33. [33]
  Mandal, B. K.; Padhi, A. K.; Shi, Z.; Chakraborty, S.; Filler, R. J. Power Sources 2006, 161, 1341. doi: 10.1016/j.jpowsour.2006.06.008 doi: 10.1016/j.jpowsour.2006.06.008
34. [34]
  Balakrishnan, P. G.; Ramesh, R.; Kumar, T. P. J. Power Sources 2006, 155, 401. doi: 10.1016/j.jpowsour.2005.12.002 doi: 10.1016/j.jpowsour.2005.12.002
35. [35]
  Ghazi, Z. A.; Sun, Z. H.; Sun, C. G.; Qi, F. L.; An, B. G.; Li, F.; Cheng, H. M. Small 2019, 15, 1900687. doi: 10.1002/smll.201900687 doi: 10.1002/smll.201900687
36. [36]
  Han, C. P.; He, Y. B.; Liu, M.; Li, B. H.; Yang, Q. H.; Wong, C. P.; Kang, F. Y. J. Mater. Chem. A 2017, 5, 6368. doi: 10.1039/c7ta00303j doi: 10.1039/c7ta00303j
37. [37]
  Gao, Y. L.; Guo, M. Y.; Yuan, K.; Shen, C.; Ren, Z. Y.; Zhang, K.; Zhao, H.; Qiao, F. H.; Gu, J. L.; Qi, Y. Q.; et al. Adv. Energy Mater. 2020, 10, 1903362. doi: 10.1002/aenm.201903362 doi: 10.1002/aenm.201903362
38. [38]
  Chen, R. S.; Nolan, A. M.; Lu, J. Z.; Wang, J. Y.; Yu, X. Q.; Mo, Y. F.; Chen, L. Q.; Huang, X. J.; Li, H. Joule 2020, 4, 812. doi: 10.1016/j.joule.2020.03.012 doi: 10.1016/j.joule.2020.03.012
39. [39]
  Feng, X. N.; Zheng, S. Q.; Ren, D. S.; He, X. M.; Wang, L.; Cui, H.; Liu, X.; Jin, C. Y.; Zhang, F. S.; Xu, C. S.; et al. Appl. Energy 2019, 246, 53. doi: 10.1016/j.apenergy.2019.04.009 doi: 10.1016/j.apenergy.2019.04.009
40. [40]
  Puthusseri, D.; Paramananda, M.; Mukherjee, P. P.; Pol, V. G. J. Electrochem. Soc. 2020, 167, 120513. doi: 10.1149/1945-7111/ababd2 doi: 10.1149/1945-7111/ababd2
41. [41]
  Xu, W.; Wang, J. L.; Ding, F.; Chen, X. L.; Nasybulin, E.; Zhang, Y. H.; Zhang, J. G. Energy Environ. Sci. 2014, 7, 513. doi: 10.1039/c3ee40795k doi: 10.1039/c3ee40795k
42. [42]
  Pei, A.; Zheng, G. Y.; Shi, F. F.; Li, Y. Z.; Cui, Y. Nano Lett. 2017, 17, 1132. doi: 10.1021/acs.nanolett.6b04755 doi: 10.1021/acs.nanolett.6b04755
43. [43]
  Li, L.; Basu, S.; Wang, Y. P.; Chen, Z. Z.; Hundekar, P.; Wang, B. W.; Shi, J.; Shi, Y. F.; Narayanan, S.; Koratkar, N. Science 2018, 359, 1513. doi: 10.1126/science.aap8787 doi: 10.1126/science.aap8787
44. [44]
  Hundekar, P.; Basu, S.; Pan, J. L.; Bartolucci, S. F.; Narayanan, S.; Yang, Z. Y.; Koratkar, N. Energy Storage Mater. 2019, 20, 291. doi: 10.1016/j.ensm.2019.04.013 doi: 10.1016/j.ensm.2019.04.013
45. [45]
  Ishikawa, M. J. Electrochem. Soc. 1997, 144, L90. doi: 10.1149/1.1837563 doi: 10.1149/1.1837563
46. [46]
  Mistry, A.; Fear, C.; Carter, R.; Love, C. T.; Mukherjee, P. P. ACS Energy Lett. 2019, 4, 156. doi: 10.1021/acsenergylett.8b02003 doi: 10.1021/acsenergylett.8b02003
47. [47]
  Yang, H. J.; Guo, C.; Chen, J. H.; Naveed, A.; Yang, J.; Nuli, Y.; Wang, J. L. Angew. Chem. Int. Ed. 2019, 58, 791. doi: 10.1002/anie.201811291 doi: 10.1002/anie.201811291
48. [48]
  Hong, Z.; Viswanathan, V. ACS Energy Lett. 2019, 4, 1012. doi: 10.1021/acsenergylett.9b00433 doi: 10.1021/acsenergylett.9b00433
49. [49]
  Yan, K.; Wang, J. Y.; Zhao, S. Q.; Zhou, D.; Sun, B.; Cui, Y.; Wang, G. X. Angew. Chem. Int. Ed. 2019, 58, 11364. doi: 10.1002/anie.201905251 doi: 10.1002/anie.201905251
50. [50]
  Wang, J. Y.; Huang, W.; Pei, A.; Li, Y. Z.; Shi, F. F.; Yu, X. Y.; Cui, Y. Nat. Energy 2019, 4, 664. doi: 10.1038/s41560-019-0413-3 doi: 10.1038/s41560-019-0413-3
51. [51]
  Zhu, Y. Y.; Xie, J.; Pei, A.; Liu, B. F.; Wu, Y. C.; Lin, D. C.; Li, J.; Wang, H. S.; Chen, H.; Xu, J. W.; et al. Nat. Commun. 2019, 10, 2067. doi: 10.1038/s41467-019-09924-1 doi: 10.1038/s41467-019-09924-1
52. [52]
  Golozar, M.; Paolella, A.; Demers, H.; Bessette, S.; Lagacé, M.; Bouchard, P.; Guerfi, A.; Gauvin, R.; Zaghib, K. Commun. Chem. 2019, 2, 131. doi: 10.1038/s42004-019-0234-0 doi: 10.1038/s42004-019-0234-0
53. [53]
  Vishnugopi, B. S.; Hao, F.; Verma, A.; Mukherjee, P. P. ACS Appl. Mater. Interfaces 2020, 12, 23931. doi: 10.1021/acsami.0c04355 doi: 10.1021/acsami.0c04355
54. [54]
  Deng, K. R.; Zeng, Q. G.; Wang, D.; Liu, Z.; Wang, G. X.; Qiu, Z. P.; Zhang, Y. F.; Xiao, M.; Meng, Y. Z. Energy Storage Mater. 2020, 32, 425. doi: 10.1016/j.ensm.2020.07.018 doi: 10.1016/j.ensm.2020.07.018
55. [55]
  Yao, X. L.; Xie, S.; Chen, C. H.; Wang, Q. S.; Sun, J. H.; Li, Y. L.; Lu, S. X. J. Power Sources 2005, 144, 170. doi: 10.1016/j.jpowsour.2004.11.042 doi: 10.1016/j.jpowsour.2004.11.042
56. [56]
  Yang, H. J.; Li, Q. Y.; Guo, C.; Naveed, A.; Yang, J.; Nuli, Y.; Wang, J. L. Chem. Commun. 2018, 54, 4132. doi: 10.1039/c7cc09942h doi: 10.1039/c7cc09942h
57. [57]
  Dong, Y.; Zhang, N.; Li, C. X.; Zhang, Y. F.; Jia, M.; Wang, Y. Y.; Zhao, Y. R.; Jiao, L. F.; Cheng, F. Y.; Xu, J. Z. ACS Appl. Energy Mater. 2019, 2, 2708. doi: 10.1021/acsaem.9b00027 doi: 10.1021/acsaem.9b00027
58. [58]
  Chen, S. R.; Zheng, J. M.; Yu, L.; Ren, X. D.; Engelhard, M. H.; Niu, C.; Lee, H.; Xu, W.; Xiao, J.; Liu, J.; et al. Joule 2018, 2, 1548. doi: 10.1016/j.joule.2018.05.002 doi: 10.1016/j.joule.2018.05.002
59. [59]
  Yang, G.; Song, Y. D.; Wang, Q.; Zhang, L. B.; Deng, L. J. Mater. Des. 2020, 190, 108563. doi: 10.1016/j.matdes.2020.108563 doi: 10.1016/j.matdes.2020.108563
60. [60]
  Huie, M. M.; DiLeo, R. A.; Marschilok, A. C.; Takeuchi, K. J.; Takeuchi, E. S. ACS Appl. Mater. Interfaces 2015, 7, 11724. doi: 10.1021/acsami.5b00496 doi: 10.1021/acsami.5b00496
61. [61]
  Zheng, J. M.; Gu, M.; Chen, H. H.; Meduri, P.; Engelhard, M. H.; Zhang, J. G.; Liu, J.; Xiao, J. J. Mater. Chem. A 2013, 1, 8464. doi: 10.1039/c3ta11553d doi: 10.1039/c3ta11553d
62. [62]
  Lee, S.; Park, K.; Koo, B.; Park, C.; Jang, M.; Lee, H.; Lee, H. Adv. Funct. Mater. 2020, 30, 2003132. doi: 10.1002/adfm.202003132 doi: 10.1002/adfm.202003132
63. [63]
  Suo, L. M.; Hu, Y. S.; Li, H.; Armand, M.; Chen, L. Q. Nat. Commun. 2013, 4, 1481. doi: 10.1038/ncomms2513 doi: 10.1038/ncomms2513
64. [64]
  Amine, R.; Liu, J. Z.; Acznik, I.; Sheng, T.; Lota, K.; Sun, H.; Sun, C. J.; Fic, K.; Zuo, X. B.; Ren, Y.; et al. Adv. Energy Mater. 2020, 10, 2000901. doi: 10.1002/aenm.202000901 doi: 10.1002/aenm.202000901
65. [65]
  Fan, X. L.; Chen, L.; Borodin, O.; Ji, X.; Chen, J.; Hou, S.; Deng, T.; Zheng, J.; Yang, C. Y.; Liou, S. C.; et al. Nat. Nanotechnol. 2018, 13, 715. doi: 10.1038/s41565-018-0183-2 doi: 10.1038/s41565-018-0183-2
66. [66]
  Fan, X. L.; Ji, X.; Chen, L.; Chen, J.; Deng, T.; Han, F. D.; Yue, J.; Piao, N.; Wang, R. X.; Zhou, X. Q.; et al. Nat. Energy 2019, 4, 882. doi: 10.1038/s41560-019-0474-3 doi: 10.1038/s41560-019-0474-3
67. [67]
  Liu, H. Y.; Xu, J.; Guo, B. H.; He, X. M. Ceram. Int. 2014, 40, 14105. doi: 10.1016/j.ceramint.2014.05.142 doi: 10.1016/j.ceramint.2014.05.142
68. [68]
  Peng, L. Q.; Shen, X.; Dai, J. H.; Wang, X.; Zeng, J.; Huang, B. Y.; Li, H.; Zhang, P.; Zhao, J. B. J. Electrochem. Soc. 2019, 166, A2111. doi: 10.1149/2.1141910jes doi: 10.1149/2.1141910jes
69. [69]
  Jeon, H.; Jin, S. Y.; Park, W. H.; Lee, H.; Kim, H. T.; Ryou, M. H.; Lee, Y. M. Electrochim. Acta 2016, 212, 649. doi: 10.1016/j.electacta.2016.06.172 doi: 10.1016/j.electacta.2016.06.172
70. [70]
  Deng, N. P.; Kang, W. M.; Liu, Y. B.; Ju, J. G.; Wu, D. Y.; Li, L.; Hassan, B. S.; Cheng, B. W. J. Power Sources 2016, 331, 132. doi: 10.1016/j.jpowsour.2016.09.044 doi: 10.1016/j.jpowsour.2016.09.044
71. [71]
  Lee, T.; Kim, W. K.; Lee, Y.; Ryou, M. H.; Lee, Y. M. Macromol. Res. 2014, 22, 1190. doi: 10.1007/s13233-014-2163-1 doi: 10.1007/s13233-014-2163-1
72. [72]
  Lee, T.; Lee, Y.; Ryou, M. H.; Lee, Y. M. RSC Adv. 2015, 5, 39392. doi: 10.1039/C5RA01061F doi: 10.1039/C5RA01061F
73. [73]
  Ma, L. B.; Chen, R. P; Hu, Y.; Zhang, W. J.; Zhu, G. Y; Zhao, P. Y.; Chen, T.; Wang, C. X.; Yan, W.; Wang, Y. R.; et al. Energy Storage Mater. 2018, 14, 258. doi: 10.1016/j.ensm.2018.04.016 doi: 10.1016/j.ensm.2018.04.016
74. [74]
  Song, Q. Q.; Li, A. J.; Shi, L.; Qian, C.; Feric, T. G.; Fu, Y. K.; Zhang, H. R.; Li, Z. Y.; Wang, P. Y.; Li, Z.; et al. Energy Storage Mater. 2019, 22, 48. doi: 10.1016/j.ensm.2019.06.033 doi: 10.1016/j.ensm.2019.06.033
75. [75]
  Cheng, C. L.; Wan, C. C.; Wang, Y. Y.; Wu, M. S. J. Power Sources 2005, 144, 238. doi: 10.1016/j.jpowsour.2004.12.043 doi: 10.1016/j.jpowsour.2004.12.043
76. [76]
  Shi, Q.; Ni, L.; Zhang, Y. F.; Feng, X. S.; Chang, Q. H.; Meng, J. Q. J. Mater. Chem. A 2017, 5, 13610. doi: 10.1039/C7TA02552A doi: 10.1039/C7TA02552A
77. [77]
  Zhang, X. K.; Li, N.; Hu, Z. M.; Yu, J. R.; Wang, Y.; Zhu, J. J. Membr. Sci. 2019, 581, 355. doi: 10.1016/j.memsci.2019.03.071 doi: 10.1016/j.memsci.2019.03.071
78. [78]
  He, L. Y.; Qiu, T.; Xie, C. J.; Tuo, X. L. J. Appl. Polym. Sci. 2018, 135, 46697. doi: 10.1002/app.46697 doi: 10.1002/app.46697
79. [79]
  Pan, R. J.; Xu, X. X.; Sun, R.; Wang, Z. H.; Lindh, J.; Edström, K.; Strømme, M.; Nyholm, L. Small 2018, 14, 1704371. doi: 10.1002/smll.201704371 doi: 10.1002/smll.201704371
80. [80]
  Gitina, R. M.; Oksent'yevich, L. A.; Kuznetsov, A. A.; Danilina, L. I.; Izyumnikov, A. L.; Rogozhkina, Y. D.; Bogachev, Y. S.; Kopylov, V. V.; Novikov, S. N.; Pravednikov, A. N. Polym. Sci. U.S.S.R. 1984, 26, 1184. doi: 10.1016/0032-3950(84)90339-3 doi: 10.1016/0032-3950(84)90339-3
81. [81]
  Xu, T. W.; Wu, D.; Wu, L. Prog. Polym. Sci. 2008, 33, 894. doi: 10.1016/j.progpolymsci.2008.07.002 doi: 10.1016/j.progpolymsci.2008.07.002
82. [82]
  Liu, K.; Liu, W.; Qiu, Y. C.; Kong, B. A.; Sun, Y. M.; Chen, Z.; Zhuo, D.; Lin, D. C.; Cui, Y. Sci. Adv. 2017, 3, 8. doi: 10.1126/sciadv.1601978 doi: 10.1126/sciadv.1601978
83. [83]
  Wu, H.; Zhuo, D.; Kong, D. S.; Cui, Y. Nat. Commun. 2014, 5, 5193. doi: 10.1038/ncomms6193 doi: 10.1038/ncomms6193
84. [84]
  Moon, S.; Tamwattana, O.; Park, H.; Yoon, G.; Seong, W. M.; Lee, M. H.; Park, K. Y.; Meethong, N.; Kang, K. J. Mater. Chem. A 2019, 7, 24807. doi: 10.1039/C9TA08032E doi: 10.1039/C9TA08032E
85. [85]
  Liu, K.; Zhuo, D.; Lee, H. W.; Liu, W.; Lin, D. C.; Lu, Y. Y.; Cui, Y. Adv. Mater. 2017, 29, 1603987. doi: 10.1002/adma.201603987 doi: 10.1002/adma.201603987
86. [86]
  Liu, Y. D.; Liu, Q.; Xin, L.; Liu, Y. Z.; Yang, F.; Stach, E. A.; Xie, J. Nat. Energy 2017, 2, 17083. doi: 10.1038/nenergy.2017.83 doi: 10.1038/nenergy.2017.83
87. [87]
  Tikekar, M. D.; Archer, L. A.; Koch, D. L. Sci. Adv. 2016, 2, e1600320. doi: 10.1126/sciadv.1600320 doi: 10.1126/sciadv.1600320
88. [88]
  Zhou, W. D.; Gao, H. C.; Goodenough, J. B. Adv. Energy Mater. 2016, 6, 1501802. doi: 10.1002/aenm.201501802 doi: 10.1002/aenm.201501802
89. [89]
  Pan, Q. W.; Barbash, D.; Smith, D. M.; Qi, H.; Gleeson, S. E.; Li, C. Y. Adv. Energy Mater. 2017, 7, 1701231. doi: 10.1002/aenm.201701231 doi: 10.1002/aenm.201701231
90. [90]
  Wu, N.; Shi, Y. R.; Lang, S. Y.; Zhou, J. M.; Liang, J. Y.; Wang, W.; Tan, S. J.; Yin, Y. X.; Wen, R.; Guo, Y. G. Angew. Chem. Int. Ed. 2019, 58, 18146. doi: 10.1002/anie.201910478 doi: 10.1002/anie.201910478
91. [91]
  Shi, Y.; Ha, H.; Al-Sudani, A.; Ellison, C. J.; Yu, G. H. Adv. Mater. 2016, 28, 7921. doi: 10.1002/adma.201602239 doi: 10.1002/adma.201602239
92. [92]
  Zhou, J. Q.; Qian, T.; Liu, J.; Wang, M. F.; Zhang, L.; Yan, C. L. Nano Lett. 2019, 19, 3066. doi: 10.1021/acs.nanolett.9b00450 doi: 10.1021/acs.nanolett.9b00450
93. [93]
  Li, Y. Z.; Huang, W.; Li, Y. B.; Pei, A.; Boyle, D. T.; Cui, Y. Joule 2018, 2, 2167. doi: 10.1016/j.joule.2018.08.004 doi: 10.1016/j.joule.2018.08.004
94. [94]
  Li, Y. Z.; Li, Y. B.; Pei, A. L.; Yan, K.; Sun, Y. M.; Wu, C. L.; Joubert, L. M.; Chin, R.; Koh, A. L.; Yu, Y.; et al. Science 2017, 358, 506. doi: 10.1126/science.aam6014 doi: 10.1126/science.aam6014
95. [95]
  Jin, Y.; Zheng, Z. K.; Wei, D. H.; Jiang, X.; Lu, H. F.; Sun, L.; Tao, F. B.; Guo, D. L.; Liu, Y.; Gao, J. F.; et al. Joule 2020, 4, 1714. doi: 10.1016/j.joule.2020.05.016 doi: 10.1016/j.joule.2020.05.016
96. [96]
  Shen, K.; Wang, Z.; Bi, X. X.; Ying, Y.; Zhang, D.; Jin, C. B.; Hou, G. Y.; Cao, H. Z.; Wu, L. K.; Zheng, G. Q.; et al. Adv. Energy Mater. 2019, 9, 1900260. doi: 10.1002/aenm.201900260 doi: 10.1002/aenm.201900260
97. [97]
  Chen, Y. X.; Dou, X. Y.; Wang, K.; Han, Y. S. Adv. Energy Mater. 2019, 9, 1900019. doi: 10.1002/aenm.201900019 doi: 10.1002/aenm.201900019
98. [98]
  Adair, K. R.; Banis, M. N.; Zhao, Y.; Bond, T.; Li, R. Y.; Sun, X. L. Adv. Mater. 2020, 32, 2002550. doi: 10.1002/adma.202002550 doi: 10.1002/adma.202002550
99. [99]
  Deng, Z.; Huang, Z. Y.; Shen, Y.; Huang, Y. H.; Ding, H.; Luscombe, A.; Johnson, M.; Harlow, J. E.; Gauthier, R.; Dahn, J. R. Joule 2020, 4, 2017. doi: 10.1016/j.joule.2020.07.014 doi: 10.1016/j.joule.2020.07.014
100. [100]
  Bommier, C.; Chang, W.; Lu, Y. F.; Yeung, J.; Davies, G.; Mohr, R.; Williams, M.; Steingart, D. Cell Rep. Phys. Sci. 2020, 1, 100035. doi: 10.1016/j.xcrp.2020.100035 doi: 10.1016/j.xcrp.2020.100035
101. [101]
  Deng, Z.; Lin, X.; Huang, Z. Y.; Meng, J. T.; Zhong, Y.; Ma, G. T.; Zhou, Y.; Shen, Y.; Ding, H.; Huang, Y. H. Adv. Energy Mater. 2020, 2000806. doi: 10.1002/aenm.202000806 doi: 10.1002/aenm.202000806
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