Citation: Yang Shijie, Xu Xiangqun, Cheng Xinbing, Wang Xinmeng, Chen Jinxiu, Xiao Ye, Yuan Hong, Liu He, Chen Aibing, Zhu Wancheng, Huang Jiaqi, Zhang Qiang. Columnar Lithium Metal Deposits: the Role of Non-Aqueous Electrolyte Additive[J]. Acta Physico-Chimica Sinica, ;2021, 37(1): 200705. doi: 10.3866/PKU.WHXB202007058 shu

Columnar Lithium Metal Deposits: the Role of Non-Aqueous Electrolyte Additive

Yang Shijie ^1,3 ,
Xu Xiangqun ² ,
Cheng Xinbing ^2,, ,
Wang Xinmeng ^2,4 ,
Chen Jinxiu ^2,5 ,
Xiao Ye ^1,3 ,
Yuan Hong ^1,3,, ,
Liu He ^1,3 ,
Chen Aibing ⁴ ,
Zhu Wancheng ⁵ ,
Huang Jiaqi ^1,3 ,
Zhang Qiang ²

1.
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China
2.
Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
3.
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
4.
College of Chemical and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China
5.
School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, Shandong Province, China

Corresponding author: Cheng Xinbing, cxb12@mails.tsinghua.edu.cn Yuan Hong, yuanhong@bit.edu.cn
Received Date: 23 July 2020
Revised Date: 21 August 2020
Accepted Date: 31 August 2020
Available Online: 4 September 2020
Fund Project: the National Natural Science Foundation of China 21808124The project was supported by the National Key Research and Development Program of China (2016YFA0202500, 2016YFA0200102), the National Natural Science Foundation of China (21805161, 21808124, U1932220)the National Natural Science Foundation of China U1932220the National Key Research and Development Program of China 2016YFA0200102the National Key Research and Development Program of China 2016YFA0202500the National Natural Science Foundation of China 21805161

With the booming growth market of electric vehicles and portable electronics, high-energy-density rechargeable lithium ion batteries are being extensively used to advance high-end devices. Lithium-ion batteries with graphite anodes approach the ceiling in energy density, but they cannot satisfy the current demand. Among the next-generation electrodes, lithium metal anodes are strong candidates because of their high theoretical capacity and the most negative electrochemical potential. However, lithium metal batteries have been abandoned because of their poor safety resulting from the growth of lithium dendrites during lithium deposition. Although several strategies have been proposed to suppress the generation of lithium dendrites as well as the side reactions between active lithium and the electrolyte, lithium metal anodes have not been practically applied so far. Various studies have been conducted on the factors influencing lithium deposition, with the aim of understanding the growth behavior of lithium dendrites. The electrolyte plays a crucial role in the performance of the working Li metal anode. In this study, a unique battery system is proposed to realize columnar lithium deposition, which is convenient for obtaining the length and diameter of lithium deposits. The influence of different electrolytes on lithium deposition was investigated by comparing the length-diameter (L/D) ratio of the lithium deposits in two kinds of electrolytes (1.0 mol·L^-1 LiPF₆-ethylene carbonate/diethyl carbonate (EC/DEC, 1 : 1 by volume) and 1.0 mol·L^-1 LiPF₆-5% (volume fraction) fluoroethylene carbonate (FEC)-EC/DEC (1 : 1 by volume)). The morphology of the lithium deposits was strongly affected by the electrolyte composition. In the electrolyte with the FEC additive, the diameter of columnar lithium increased from 0.3-0.6 μm to 0.7-1.3 μm, while the L/D ratio decreased from 12.5 to 5.6. The small L/D ratio can reduce the reactive area between the lithium metal anode and the electrolyte, which is beneficial for achieving high lithium utilization and a long lifespan. To probe the origin of this influence, the surface chemistry of the cycled lithium metal anode was investigated by X-ray photoelectron spectroscopy. The FEC additive can increase the proportion of lithium fluoride (LiF) in the solid electrolyte interphase, which is conducive for the rapid diffusion of lithium ions. As a result, fewer nucleation sites are formed, providing more space for the growth of lithium cores with a large diameter. Therefore, the addition of FEC leads to a decrease in the L/D ratio of columnar lithium.
- Lithium metal battery,
- Columnar lithium,
- Electrolyte,
- Lithium fluoride,
- Length-diameter ratio
1. [1]
  Chen, X. R.; Yao, Y. X.; Yan, C.; Zhang, R.; Cheng, X. B.; Zhang, Q. Angew. Chem. Int. Ed. 2020, 132, 7817. doi: 10.1002/ange.202000375 doi: 10.1002/ange.202000375
2. [2]
  Fan, Y.; Wang, T.; Legut, D.; Zhang, Q. J. Energy Chem. 2019, 39, 160. doi: 10.1016/j.jechem.2019.01.021 doi: 10.1016/j.jechem.2019.01.021
3. [3]
  Liu, H.; Cheng, X. B.; Huang, J. Q.; Yuan, H.; Lu, Y.; Yan, C.; Zhu, G. L.; Xu, R.; Zhao, C. Z.; Hou, L. P.; et al. ACS Energy Lett. 2020, 5, 833. doi: 10.1021/acsenergylett.9b02660 doi: 10.1021/acsenergylett.9b02660
4. [4]
  Qiao, Y.; Li, Q.; Cheng, X. B.; Liu, F. X.; Yang, Y.; Lu, Z. S.; Zhao, J.; Wu, J. W.; Liu, H.; Yang, S. T.; et al. ACS Appl. Mater. Interfaces 2020, 12, 5767. doi: 10.1021/acsami.9b18315 doi: 10.1021/acsami.9b18315
5. [5]
  Shen, Y.; Zhang, Y.; Han, S.; Wang, J.; Peng, Z.; Chen, L. Joule 2018, 2, 1674. doi: 10.1016/j.joule.2018.06.021 doi: 10.1016/j.joule.2018.06.021
6. [6]
  Feng, Y. Q.; Zheng, Z. J.; Wang, C. Y.; Yin, Y. X.; Ye, H.; Cao, F. F.; Guo, Y. G. Nano Energy 2020, 73, 104731. doi: 10.1016/j.nanoen.2020.104731 doi: 10.1016/j.nanoen.2020.104731
7. [7]
  Wan, J.; Xie, J.; Kong, X.; Liu, Z.; Liu, K.; Shi, F.; Pei, A.; Chen, H.; Chen, W.; Chen, J.; et al. Nat. Nanotechnol. 2019, 14, 705. doi: 10.1038/s41565-019-0465-3 doi: 10.1038/s41565-019-0465-3
8. [8]
  Ma, Y. Y.; Chen, D.; Yang, Q. L.; Yin, Y. X.; Bai, X. P.; Zhen, S. Y.; Fan, C.; Sun, K. N. J. Energy Chem. 2020, 42, 49. doi: 10.1016/j.jechem.2019.06.008 doi: 10.1016/j.jechem.2019.06.008
9. [9]
  Liu, Y.; Zheng, L.; Gu, W.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2021, 37, 2004058. doi: 10.3866/PKU.WHXB202004058
10. [10]
  Liang, Y.; Zhao, C. Z.; Yuan, H.; Chen, Y.; Zhang, W.; Huang, J. Q.; Yu, D.; Liu, Y.; Titirici, M. M.; Chueh, Y. L.; et al. InfoMat. 2019, 1, 6. doi: 10.1002/inf2.12000 doi: 10.1002/inf2.12000
11. [11]
  Kong, L.; Yan, C.; Huang, J. Q.; Zhao, M. Q.; Titirici, M. M.; Xiang, R.; Zhang, Q. Energy Environ. Mater. 2018, 1, 100. doi: 10.1002/eem2.12012 doi: 10.1002/eem2.12012
12. [12]
  Yan, C.; Cheng, X. B.; Tian, Y.; Chen, X.; Zhang, X. Q.; Li, W. J.; Huang, J. Q.; Zhang, Q. Adv. Mater. 2018, 30, 1707629. doi: 10.1002/adma.201707629 doi: 10.1002/adma.201707629
13. [13]
  Shi, P.; Li, T.; Zhang, R.; Shen, X.; Cheng, X. B.; Xu, R.; Huang, J. Q.; Chen, X. R.; Liu, H.; Zhang, Q. Adv. Mater. 2019, 31, 1807131. doi: 10.1002/adma.201807131 doi: 10.1002/adma.201807131
14. [14]
  Xu, R.; Xiao, Y.; Zhang, R.; Cheng, X. B.; Zhao, C. Z.; Zhang, X. Q.; Yan, C.; Zhang, Q.; Huang, J. Q. Adv. Mater. 2019, 31, 1808392. doi: 10.1002/adma.201808392 doi: 10.1002/adma.201808392
15. [15]
  Tong, B.; Chen, X.; Chen, L.; Zhou, Z.; Peng, Z. ACS Appl. Energy Mater. 2018, 1, 4426. doi: 10.1021/acsaem.8b00821 doi: 10.1021/acsaem.8b00821
16. [16]
  Ye, H.; Zhang, Y.; Yin, Y. X.; Cao, F. F.; Guo, Y. G. ACS Cent. Sci. 2020, 6, 661. doi: 10.1021/acscentsci.0c00351 doi: 10.1021/acscentsci.0c00351
17. [17]
  Zhang, W.; Wu, Q.; Huang, J.; Fan, L.; Shen, Z.; He, Y.; Feng, Q.; Zhu, G.; Lu, Y. Adv. Mater. 2020, 32, 2001740. doi: 10.1002/adma.202001740 doi: 10.1002/adma.202001740
18. [18]
  Guo, F.; Chen, P.; Kang, T.; Wang, Y. L.; Liu, C. H.; Shen, Y. B.; Lu, W.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1365. doi: 10.3866/PKU.WHXB201903008
19. [19]
  Yue, X. Y.; Ma, C.; Bao, J.; Yang, S. Y.; Chen, D.; Wu, X. J.; Zhou, Y. N. Acta Phys. -Chim. Sin. 2021, 37, 2005012. doi: 10.3866/PKU.WHXB202005012
20. [20]
  Wang, G.; Xiong, X.; Xie, D.; Fu, X.; Ma, X.; Li, Y.; Liu, Y.; Lin, Z.; Yang, C.; Liu, M. Energy Storage Mater. 2019, 23, 701. doi: 10.1016/j.ensm.2019.02.026 doi: 10.1016/j.ensm.2019.02.026
21. [21]
  Zhang, R.; Shen, X.; Cheng, X. B.; Zhang, Q. Energy Storage Mater. 2019, 23, 556. doi: 10.1016/j.ensm.2019.03.029 doi: 10.1016/j.ensm.2019.03.029
22. [22]
  Shi, P.; Cheng, X. B.; Li, T.; Zhang, R.; Liu, H.; Yan, C.; Zhang, X. Q.; Huang, J. Q.; Zhang, Q. Adv. Mater. 2019, 31, 1902785. doi: 10.1002/adma.201902785 doi: 10.1002/adma.201902785
23. [23]
  Niu, C.; Lee, H.; Chen, S.; Li, Q.; Du, J.; Xu, W.; Zhang, J. G.; Whittingham, M. S.; Xiao, J.; Liu, J. Nat. Energy 2019, 4, 551. doi: 10.1038/s41560-019-0390-6 doi: 10.1038/s41560-019-0390-6
24. [24]
  Hobold, G. M.; Khurram, A.; Gallant, B. M. Chem. Mater. 2020, 32, 2341. doi: 10.1021/acs.chemmater.9b04550 doi: 10.1021/acs.chemmater.9b04550
25. [25]
  Chen, Y.; Luo, Y.; Zhang, H.; Qu, C.; Zhang, H.; Li, X. Small Methods 2019, 3, 1800551. doi: 10.1002/smtd.201800551 doi: 10.1002/smtd.201800551
26. [26]
  Yao, Y. X.; Zhang, X. Q.; Li, B. Q.; Yan, C.; Chen, P. Y.; Huang, J. Q.; Zhang, Q. InfoMat 2020, 2, 379. doi: 10.1002/inf2.12046 doi: 10.1002/inf2.12046
27. [27]
  Fan, H.; Gao, C.; Jiang, H.; Dong, Q.; Hong, B.; Lai, Y. J. Energy Chem. 2020, 49, 59. doi: 10.1016/j.jechem.2020.01.013 doi: 10.1016/j.jechem.2020.01.013
28. [28]
  Liu, H.; Cheng, X. B.; Huang, J. Q.; Kaskel, S.; Chou, S.; Park, H. S.; Zhang, Q. ACS Mater. Lett. 2019, 1, 217. doi: 10.1021/acsmaterialslett.9b00118 doi: 10.1021/acsmaterialslett.9b00118
29. [29]
  Zhang, X. Q.; Cheng, X. B.; Chen, X.; Yan, C.; Zhang, Q. Adv. Funct. Mater. 2017, 27, 1605989. doi: 10.1002/adfm.201605989 doi: 10.1002/adfm.201605989
30. [30]
  Chen, W. J.; Zhao, C. X.; Li, B. Q.; Jin, Q.; Zhang, X. Q.; Yuan, T. Q.; Zhang, X.; Jin, Z.; Kaskel, S.; Zhang, Q. Energy Environ. Mater. 2020, 3, 160. doi: 10.1002/eem2.12073 doi: 10.1002/eem2.12073
31. [31]
  He, Y.; Zhang, Y.; Yu, P.; Ding, F.; Li, X.; Wang, Z.; Lv, Z.; Wang, X.; Liu, Z.; Huang, X. J. Energy Chem. 2020, 45, 1. doi: 10.1016/j.jechem.2019.09.033 doi: 10.1016/j.jechem.2019.09.033
32. [32]
  Chen, J. X.; Zhang, X. Q.; Li, B. Q.; Wang, X. M.; Shi, P.; Zhu, W. C.; Chen, A. B.; Jin, Z. H.; Xiang, R.; Huang, J. Q.; Zhang, Q. J. Energy Chem. 2020, 47, 128. doi: 10.1016/j.jechem.2019.11.024 doi: 10.1016/j.jechem.2019.11.024
33. [33]
  Yang, Q. L.; Li, W. L.; Dong, C.; Ma, Y. Y.; Yin, Y. X.; Wu, Q. B.; Xu, Z. T.; Ma, W.; Fan, C.; Sun, K. N. J. Energy Chem. 2020, 42, 83. doi: 10.1016/j.jechem.2019.06.012 doi: 10.1016/j.jechem.2019.06.012
34. [34]
  Li, C.; Liu, S.; Shi, C.; Liang, G.; Lu, Z.; Fu, R.; Wu, D. Nat. Commun. 2019, 10, 1363. doi: 10.1038/s41467-019-09211-z doi: 10.1038/s41467-019-09211-z
35. [35]
  Wei, Z.; Ren, Y.; Sokolowski, J.; Zhu, X.; Wu, G. InfoMat 2020, 2, 483. doi: 10.1002/inf2.12097 doi: 10.1002/inf2.12097
36. [36]
  Liu, H.; Chen, X.; Cheng, X. B.; Li, B. Q.; Zhang, R.; Wang, B.; Chen, X.; Zhang, Q. Small Methods 2019, 3, 1800354. doi: 10.1002/smtd.201800354 doi: 10.1002/smtd.201800354
37. [37]
  Shen, X.; Cheng, X.; Shi, P.; Huang, J.; Zhang, X.; Yan, C.; Li, T.; Zhang, Q. J. Energy Chem. 2019, 37, 29. doi: 10.1016/j.jechem.2018.11.016 doi: 10.1016/j.jechem.2018.11.016
38. [38]
  Shang, Y.; Chu, T.; Shi, B.; Fu, K. Energy Environ. Mater. 2020. doi: 10.1002/eem2.12099 doi: 10.1002/eem2.12099
39. [39]
  Lu, D.; Shao, Y.; Lozano, T.; Bennett, W. D.; Graff, G. L.; Polzin, B.; Zhang, J.; Engelhard, M. H.; Saenz, N. T.; Henderson, W. A.; et al. Adv. Energy Mater. 2015, 5, 1702322. doi: 10.1002/aenm.201400993 doi: 10.1002/aenm.201400993
40. [40]
  Wood, K. N.; Kazyak, E.; Chadwick, A. F.; Chen, K. H.; Zhang, J. G.; Thornton, K.; Dasgupta, N. P. ACS Cent. Sci. 2016, 2, 790. doi: 10.1021/acscentsci.6b00260 doi: 10.1021/acscentsci.6b00260
41. [41]
  Yin, X.; Tang, W.; Jung, I. D.; Phua, K. C.; Adams, S.; Lee, S. W.; Zheng, G. W. Nano Energy 2018, 50, 659. doi: 10.1016/j.nanoen.2018.06.003 doi: 10.1016/j.nanoen.2018.06.003
42. [42]
  Yan, K.; Wang, J.; Zhao, S.; Zhou, D.; Sun, B.; Cui, Y.; Wang, G. Angew. Chem. Int. Ed. 2019, 58, 11364. doi: 10.1002/anie.201905251 doi: 10.1002/anie.201905251
43. [43]
  Rodriguez, R.; Loeffler, K. E.; Edison, R. A.; Stephens, R. M.; Dolocan, A.; Heller, A.; Mullins, C. B. ACS Appl. Energy Mater. 2018, 1, 5830. doi: 10.1021/acsaem.8b01194 doi: 10.1021/acsaem.8b01194
44. [44]
  Zhang, Y.; Qian, J.; Xu, W.; Russell, S. M.; Chen, X.; Nasybulin, E.; Bhattacharya, P.; Engelhard, M. H.; Mei, D.; Cao, R.; et al. Nano Lett. 2014, 14, 6889. doi: 10.1021/nl5039117 doi: 10.1021/nl5039117
45. [45]
  Zhang, X. Q.; Chen, X.; Xu, R.; Cheng, X. B.; Peng, H. J.; Zhang, R.; Huang, J. Q.; Zhang, Q. Angew. Chem. Int. Ed. 2017, 56, 14207. doi: 10.1002/anie.201707093 doi: 10.1002/anie.201707093
46. [46]
  Qian, J.; Xu, W.; Bhattacharya, P.; Engelhard, M.; Henderson, W. A.; Zhang, Y.; Zhang, J. G. Nano Energy 2015, 15, 135. doi: 10.1016/j.nanoen.2015.04.009 doi: 10.1016/j.nanoen.2015.04.009
47. [47]
  Cheng, X. B.; Zhao, M. Q.; Chen, C.; Pentecost, A.; Maleski, K.; Mathis, T.; Zhang, X. Q.; Zhang, Q.; Jiang, J.; Gogotsi, Y. Nat. Commun. 2017, 8, 336. doi: 10.1038/s41467-017-00519-2 doi: 10.1038/s41467-017-00519-2
48. [48]
  Michan, A. L.; Parimalam, B. S.; Leskes, M.; Kerber, R. N.; Yoon, T.; Grey, C. P.; Lucht, B. L. Chem. Mater. 2016, 28, 8149. doi: 10.1021/acs.chemmater.6b02282 doi: 10.1021/acs.chemmater.6b02282
49. [49]
  Nie, M.; Demeaux, J.; Young, B. T.; Heskett, D. R.; Chen, Y.; Bose, A.; Woicik, J. C.; Lucht, B. L. J. Electrochem. Soc. 2015, 162, A7008. doi: 10.1149/2.0021513jes doi: 10.1149/2.0021513jes
50. [50]
  Heine, J.; Hilbig, P.; Qi, X.; Niehoff, P.; Winter, M.; Bieker, P. J. Electrochem. Soc. 2015, 162, A1094. doi: 10.1149/2.0011507jes doi: 10.1149/2.0011507jes
51. [51]
  Jurng, S.; Brown, Z. L.; Kim, J.; Lucht, B. L. Energy Environ. Sci. 2018, 11, 2600. doi: 10.1039/c8ee00364e doi: 10.1039/c8ee00364e
52. [52]
  Ko, J.; Yoon, Y. S. Ceram. Int. 2019, 45, 30. doi: 10.1016/j.ceramint.2018.09.287 doi: 10.1016/j.ceramint.2018.09.287
53. [53]
  Lang, J.; Long, Y.; Qu, J.; Luo, X.; Wei, H.; Huang, K.; Zhang, H.; Qi, L.; Zhang, Q.; Li, Z.; Wu, H. Energy Storage Mater. 2019, 16, 85. doi: 10.1016/j.ensm.2018.04.024 doi: 10.1016/j.ensm.2018.04.024
54. [54]
  Shin, H.; Park, J.; Han, S.; Sastry, A. M.; Lu, W. J. Power Sources 2015, 277, 169. doi: 10.1016/j.jpowsour.2014.11.120 doi: 10.1016/j.jpowsour.2014.11.120
55. [55]
  Jones, J.; Anouti, M.; Caillon-Caravanier, M.; Willmann, P.; Lemordant, D. Fluid Phase Equilib. 2009, 285, 62. doi: 10.1016/j.fluid.2009.07.020 doi: 10.1016/j.fluid.2009.07.020
56. [56]
  He, M.; Guo, R.; Hobold, G. M.; Gao, H.; Gallant, B. M. Proc. Natl. Acad. Sci. U.S.A. 2020, 117, 73. doi: 10.1073/pnas.1911017116 doi: 10.1073/pnas.1911017116
57. [57]
  Yang, G.; Li, Y.; Liu, S.; Zhang, S.; Wang, Z.; Chen, L. Energy Storage Mater. 2019, 23, 350. doi: 10.1016/j.ensm.2019.04.041 doi: 10.1016/j.ensm.2019.04.041
58. [58]
  Lee, Y.; Lee, T. K.; Kim, S.; Lee, J.; Ahn, Y.; Kim, K.; Ma, H.; Park, G.; Lee, S. M.; Kwak, S. K.; Choi, N. S. Nano Energy 2020, 67, 104309. doi: 10.1016/j.nanoen.2019.104309 doi: 10.1016/j.nanoen.2019.104309
1. [1]
  Caiyun Jin , Zexuan Wu , Guopeng Li , Zhan Luo , Nian-Wu Li . Phosphazene-based flame-retardant artificial interphase layer for lithium metal batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100094-0. doi: 10.1016/j.actphy.2025.100094
2. [2]
  Jiahe LIU , Gan TANG , Kai CHEN , Mingda ZHANG . Effect of low-temperature electrolyte additives on low-temperature performance of lithium cobaltate batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 719-728. doi: 10.11862/CJIC.20250023
3. [3]
  Yu Peng , Jiawei Chen , Yue Yin , Yongjie Cao , Mochou Liao , Congxiao Wang , Xiaoli Dong , Yongyao Xia . Tailored cathode electrolyte interphase via ethylene carbonate-free electrolytes enabling stable and wide-temperature operation of high-voltage LiCoO₂. Acta Physico-Chimica Sinica, 2025, 41(8): 100087-0. doi: 10.1016/j.actphy.2025.100087
4. [4]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
5. [5]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
6. [6]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
7. [7]
  Qianli Ma , Tianbing Song , Tianle He , Xirong Zhang , Huanming Xiong . Sulfur-doped carbon dots: a novel bifunctional electrolyte additive for high-performance aqueous zinc-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100106-0. doi: 10.1016/j.actphy.2025.100106
8. [8]
  Liangliang Song , Haoyan Liang , Shunqing Li , Bao Qiu , Zhaoping Liu . Challenges and strategies on high-manganese Li-rich layered oxide cathodes for ultrahigh-energy-density batteries. Acta Physico-Chimica Sinica, 2025, 41(8): 100085-0. doi: 10.1016/j.actphy.2025.100085
9. [9]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
10. [10]
  Changsheng An , Tao Liu . Decoding SEI chemistry at the lithium-metal potential. Acta Physico-Chimica Sinica, 2025, 41(9): 100101-0. doi: 10.1016/j.actphy.2025.100101
11. [11]
  Xiting Zhou , Zhipeng Han , Xinlei Zhang , Shixuan Zhu , Cheng Che , Liang Xu , Zhenyu Sun , Leiduan Hao , Zhiyu Yang . Dual Modulation via Ag-Doped CuO Catalyst and Iodide-Containing Electrolyte for Enhanced Electrocatalytic CO₂ Reduction to Multi-Carbon Products: A Comprehensive Chemistry Experiment. University Chemistry, 2025, 40(7): 336-344. doi: 10.12461/PKU.DXHX202412070
12. [12]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
13. [13]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
14. [14]
  Yingtong Shi , Guotong Xu , Guizeng Liang , Di Lan , Siyuan Zhang , Yanru Wang , Daohao Li , Guanglei Wu . PEG-VN modified PP separator for high-stability and high-efficiency lithium-sulfur batteries. Acta Physico-Chimica Sinica, 2025, 41(7): 100082-0. doi: 10.1016/j.actphy.2025.100082
15. [15]
  Zhongyan Cao , Youzhi Xu , Menghua Li , Xiao Xiao , Xianqiang Kong , Deyun Qian . Electrochemically Driven Denitrative Borylation and Fluorosulfonylation of Nitroarenes. University Chemistry, 2025, 40(4): 277-281. doi: 10.12461/PKU.DXHX202407017
16. [16]
  Zhaoxuan ZHU , Lixin WANG , Xiaoning TANG , Long LI , Yan SHI , Jiaojing SHAO . Application of poly(vinyl alcohol) conductive hydrogel electrolytes in zinc ion batteries. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 893-902. doi: 10.11862/CJIC.20240368
17. [17]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
18. [18]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
19. [19]
  Yutong Dong , Huiling Xu , Yucheng Zhao , Zexin Zhang , Ying Wang . The Hidden World of Surface Tension and Droplets. University Chemistry, 2024, 39(6): 357-365. doi: 10.3866/PKU.DXHX202312022
20. [20]
  Yuanyuan JIANG , Fangfang TU , Yuhong ZHANG , Shi CHEN , Jiayuan XIANG , Xinhui XIA . Preparation and electrochemical properties of high-stability cathode prelithiation additive. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1101-1111. doi: 10.11862/CJIC.20240441

Get Citation

PDF

XML

Metrics

PDF Downloads(15)
Abstract views(2055)
HTML views(472)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142