Citation: Xiaofan Shen, Xiaona Wang, Nengsheng Yu, Wei Yang, Yurong Zhou, Yanhong Shi, Yulian Wang, Lizhong Dong, Jiangtao Di, Qingwen Li. A Polypyrrole-Coated MnO₂/Carbon Nanotube Film Cathode for Rechargeable Aqueous Zn-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2022, 38(5): 200605. doi: 10.3866/PKU.WHXB202006059 shu

A Polypyrrole-Coated MnO₂/Carbon Nanotube Film Cathode for Rechargeable Aqueous Zn-Ion Batteries

Xiaofan Shen ^{1, 2} ,
Xiaona Wang ¹ ,
Nengsheng Yu ^{1, 2} ,
Wei Yang ¹ ,
Yurong Zhou ^{1, 2} ,
Yanhong Shi ¹ ,
Yulian Wang ^{1, 3} ,
Lizhong Dong ^{1, 3} ,
Jiangtao Di ^{1, 3,,} ,
Qingwen Li ^{1, 3,,}

1.
Key Laboratory of Multifunctional Nanomaterials and Smart Systems, Advanced Materials Division, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, Suzhou 215123, Jiangsu Province, China
2.
Nano Science and Technology Institute, University of Science and Technology of China, Suzhou 215123, Jiangsu Province, China
3.
School of Nano-Tech and Nano-Bionics, University of Science and Technology of China, Hefei 230026, China

Corresponding author: Jiangtao Di, jtdi2009@sinano.ac.cn Qingwen Li, qwli2007@sinano.ac.cn
Received Date: 23 June 2020
Revised Date: 28 July 2020
Accepted Date: 12 August 2020
Available Online: 17 August 2020
Fund Project: the National Natural Science Foundation of China 21975281the National Natural Science Foundation of China 21773293the National Natural Science Foundation of China 21603264the National Key Research and Development Program of China 2016YFA0203301the Jiangsu Planned Projects for Postdoctoral Research Funds, China 2019K048the Suzhou Science and Technology Plan Project, China SYG201926

Rechargeable aqueous Zinc-ion batteries (ZIBs) have emerged as potential energy storage devices due to their high energy density, low cost, and safety. To date, numerous cathodes based on manganese dioxide, vanadium dioxide, and polyanionic compounds have been reported. Among them, MnO₂ cathodes are particularly desirable candidates for commercialization owing to their tunnel structure and affordability. In particular, the parasitic reaction of Mn-based cathodes in alkaline batteries can be suppressed in mild aqueous electrolytes, resulting in enthusiasm for the development of rechargeable Zn||MnO₂ batteries. Even though various MnO₂ phases have been reported as hosts for Zn²⁺/H⁺ insertion, MnO₂ crystal structures undergo significant, irreversible transformations during cycling, which is a major challenge in Zn||MnO₂ batteries. In addition, the tunnel structure can collapse under the insertion of the hydrated cation resulting in Mn²⁺ dissolution into the electrolyte and significant loss in capacity over long cycling periods. The MnO₂ cathode also has low intrinsic electronic conductivity due to the large charge transfer resistance, which limits the diffusivity of divalent ions. Despite the achievements made in the field of ZIBs so far, designing active materials and ZIBs systems to meet commercial requirements is a significant challenge. In this study, we report the preparation of polypyrrole-wrapped MnO₂/carbon nanotubes (PPy@MnO₂/CNT) as composite cathodes for aqueous ZIBs. A combination of design strategies was used to increase structural stability and improve electronic conductivity, including increased electrode/electrolyte interaction by using nano-sized structures, shortened diffusion pathways through multistage composites, and enhanced electrical conductivity with conductive composites. The three-dimensional (3D) structured PPy/CNT network can facilitate mass and charge transport during the charge and discharge processes. The structure of MnO₂ wrapped by polypyrrole effectively prevents the dissolution of MnO₂. Thus, the assembled Zn||MnO₂ batteries, using PPy@MnO₂/CNT composite cathodes, exhibit a high capacity of 210 mAh·g^-1 at 1 A·g^-1, and achieve 85.7% capacity retention after 1000 charge/discharge cycles. Moreover, a high specific capacity of 100 mAh·g^-1 could be maintained at 2 A·g^-1, exhibiting excellent kinetic performance. The assembled quasi-solid Zn//MnO₂ battery, benefiting from the xanthan gum electrolyte and flexible CNT film, possesses intrinsic safety, bending resistance, and high potential in wearable applications.
- Zinc-ion battery,
- PPy@MnO₂,
- Carbon nanotube,
- Flexible battery,
- Long life
1. [1]
  Bruce, P. G.; Freunberger, S. A.; Hardwick, L. J.; Tarascon, J. M. Nat. Mater. 2011, 11, 19. doi: 10.1038/nmat3191 doi: 10.1038/nmat3191
2. [2]
  Jin, F.; Li, J.; Hu, C. J.; Donng, H. C.; Chen, P.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1399. doi: 10.3866/PKU.WHXB201904085
3. [3]
  Liu, Y.; Pharr, M.; Salvatore, G. A. ACS Nano 2017, 11, 9614. doi: 10.1021/acsnano.7b04898 doi: 10.1021/acsnano.7b04898
4. [4]
  Huang, S.; Zhu, J.; Tian, J.; Niu, Z. Chemistry 2019, 25, 14480. doi: 10.1002/chem.201902660 doi: 10.1002/chem.201902660
5. [5]
  Guo, Y. J.; Chen, H.; Qi, L. Acta Phys. -Chim. Sin. 2007, 23, 80. doi: 10.3866/PKU.WHXB2007Supp17
6. [6]
  Rajput, N. N.; Seguin, T. J.; Wood, B. M.; Qu, X.; Persson, K. A. Top. Curr. Chem. 2018, 376, 19. doi: 10.1007/s41061-018-0195-2 doi: 10.1007/s41061-018-0195-2
7. [7]
  Pan, H.; Shao, Y.; Yan, P.; Cheng, Y.; Han, K. S.; Nie, Z.; Wang, C.; Yang, J.; Li, X.; Bhattacharya, P.; et al. Nat. Energy 2016, 1, 16039. doi: 10.1038/nenergy.2016.39 doi: 10.1038/nenergy.2016.39
8. [8]
  Chen, W.; Li, G.; Pei, A.; Li, Y.; Liao, L.; Wang, H.; Wan, J.; Liang, Z.; Chen, G.; Zhang, H.; et al. Nat. Energy 2018, 3, 428. doi: 10.1038/s41560-018-0147-7 doi: 10.1038/s41560-018-0147-7
9. [9]
  Bai, S. L.; Li, X.; Wen, Y. H.; Cheng, J.; Cao, G. P.; Yang, Y. S.; Li, D. Q. Acta Phys. -Chim. Sin. 2016, 32, 2007. doi: 10.3866/PKU.WHXB201604261
10. [10]
  He, P.; Yan, M.; Zhang, G.; Sun, R.; Chen, L.; An, Q.; Mai, L. Adv. Energy Mater. 2017, 7, 1601920. doi: 10.1002/aenm.201601920 doi: 10.1002/aenm.201601920
11. [11]
  Kundu, D.; Adams, B. D.; Duffort, V.; Vajargah, S. H.; Nazar, L. F. Nat. Energy 2016, 1, 119. doi: 10.1038/nenergy.2016.119 doi: 10.1038/nenergy.2016.119
12. [12]
  Liu, Y.; Hu, P.; Liu, H.; Wu, X.; Zhi, C. Mater. Today Energy 2020, 17, 100431. doi: 10.1016/j.mtener.2020.100431 doi: 10.1016/j.mtener.2020.100431
13. [13]
  Paolella, A.; Faure, C.; Timoshevskii, V.; Marras, S.; Bertoni, G.; Guerfi, A.; Vijh, A.; Armand, M.; Zaghib, K. J. Mater. Chem. A 2017, 5, 1819. doi: 10.1039/c7ta05121b doi: 10.1039/c7ta05121b
14. [14]
  Hurlbutt, K.; Wheeler, S.; Capone, I.; Pasta, M. Joule 2018, 2, 1950. doi: 10.1016/j.joule.2018.07.017 doi: 10.1016/j.joule.2018.07.017
15. [15]
  Kundu, D.; Oberholzer, P.; Glaros, C.; Bouzid, A.; Tervoort, E.; Pasquarello, A.; Niederberger, M. Chem. Mater. 2018, 30, 3874. doi: 10.1021/acs.chemmater.8b01317 doi: 10.1021/acs.chemmater.8b01317
16. [16]
  Tang, B.; Shan, L.; Liang, S.; Zhou, J. Energy Environ. Sci. 2019, 12, 3288. doi: 10.1039/c9ee02526j doi: 10.1039/c9ee02526j
17. [17]
  Selvakumaran, D.; Pan, A.; Liang, S.; Cao, G. J. Mater. Chem. A 2019, 7, 18209. doi: 10.1039/c9ta05053a doi: 10.1039/c9ta05053a
18. [18]
  Liu, X.; Yi, J.; Wu, K.; Jiang, Y.; Liu, Y.; Zhao, B.; Li, W.; Zhang, J. Nanotechnology 2020, 31, 122001. doi: 10.1088/1361-6528/ab5b38 doi: 10.1088/1361-6528/ab5b38
19. [19]
  Zhao, Q.; Chen, X.; Wang, Z.; Yang, L.; Qin, R.; Yang, J.; Song, Y.; Ding, S.; Weng, M.; Huang, W.; et al. Small 2019, 15, 1904545. doi: 10.1002/smll.201904545 doi: 10.1002/smll.201904545
20. [20]
  Song, M.; Tan, H.; Chao, D.; Fan, H. J. Adv. Funct. Mater. 2018, 28, 564. doi: 10.1002/adfm.201802564 doi: 10.1002/adfm.201802564
21. [21]
  Xu, D.; Li, B.; Wei, C.; He, Y. B.; Du, H.; Chu, X.; Qin, X.; Yang, Q. H.; Kang, F. Electrochim. Acta 2014, 133, 254. doi: 10.1016/j.electacta.2014.04.001 doi: 10.1016/j.electacta.2014.04.001
22. [22]
  Guo, C.; Liu, H.; Li, J.; Hou, Z.; Liang, J.; Zhou, J.; Zhu, Y.; Qian, Y. Electrochim. Acta 2019, 304, 370. doi: 10.1016/j.electacta.2019.03.008 doi: 10.1016/j.electacta.2019.03.008
23. [23]
  Deng, Z. H.; Huang, J. D.; Liu, J.; Ren, L.; Zhu, L. Z.; Xiao, X. Y.; Tan, M. X. Mater. Lett. 2019, 248, 207. doi: 10.1016/j.matlet.2019.04.036 doi: 10.1016/j.matlet.2019.04.036
24. [24]
  Sun, W.; Wang, F.; Hou, S.; Yang, C.; Fan, X.; Ma, Z.; Gao, T.; Han, F.; Hu, R.; Zhu, M.; et al. J. Am. Chem. Soc. 2017, 139, 9775. doi: 10.1021/jacs.7b04471 doi: 10.1021/jacs.7b04471
25. [25]
  Blanc, L. E.; Kundu, D.; Nazar, L. F. Joule 2020, 4, 771. doi: 10.1016/j.joule.2020.03.002 doi: 10.1016/j.joule.2020.03.002
26. [26]
  Wu, B.; Zhang, G.; Yan, M.; Xiong, T.; He, P.; He, L.; Xu, X.; Mai, L. Small 2018, 14, 1703850. doi: 10.1002/smll.201703850 doi: 10.1002/smll.201703850
27. [27]
  Huang, J.; Wang, Z.; Hou, M.; Dong, X.; Liu, Y.; Wang, Y.; Xia, Y. Nat. Commun. 2018, 9, 2906. doi: 10.1038/s41467-018-04949-4 doi: 10.1038/s41467-018-04949-4
28. [28]
  Zhang, S.; Yu, N.; Zeng, S.; Zhou, S.; Chen, M.; Di, J.; Li, Q. J. Mater. Chem. A 2018, 6, 12237. doi: 10.1039/c8ta04298e doi: 10.1039/c8ta04298e
29. [29]
  Sadasivuni, K. K.; Ponnamma, D.; Thomas, S.; Grohens, Y. Prog. Polym. Sci. 2014, 39, 749. doi: 10.1016/j.progpolymsci.2013.08.003 doi: 10.1016/j.progpolymsci.2013.08.003
30. [30]
  Sui, Y. M.; Liu, C. F.; Zou, P. C.; Zhan, H. C.; Cui, Y. Z.; Yang, C.; Cao, G. Z. Dalton. Trans. 2020, 49, 7903. doi: 10.1039/d0dt01658f doi: 10.1039/d0dt01658f
31. [31]
  Brezesinski, T.; Wang, J.; Tolbert, S. H.; Dunn, B. Nat. Mater. 2010, 9, 146. doi: 10.1038/nmat2612 doi: 10.1038/nmat2612
32. [32]
  Wu, Y.; Wang, M.; Tao, Y.; Zhang, K.; Cai, M.; Ding, Y.; Liu, X.; Hayat, T.; Alsaedi, A.; Dai, S. Adv. Funct. Mater. 2020, 30, 1907120. doi: 10.1002/adfm.201907120 doi: 10.1002/adfm.201907120
33. [33]
  Ghodbane, O.; Ataherian, F.; Wu, N. L.; Favier, F. J. Power Sources 2012, 206, 454. doi: 10.1016/j.jpowsour.2012.01.103 doi: 10.1016/j.jpowsour.2012.01.103
1. [1]
  Haihua Yang , Minjie Zhou , Binhong He , Wenyuan Xu , Bing Chen , Enxiang Liang . Synthesis and Electrocatalytic Performance of Iron Phosphide@Carbon Nanotubes as Cathode Material for Zinc-Air Battery: a Comprehensive Undergraduate Chemical Experiment. University Chemistry, 2024, 39(10): 426-432. doi: 10.12461/PKU.DXHX202405100
2. [2]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
3. [3]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
4. [4]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
5. [5]
  Xiufang Wang , Donglin Zhao , Kehua Zhang , Xiaojie Song . “Preparation of Carbon Nanotube/SnS₂ Photoanode Materials”: A Comprehensive University Chemistry Experiment. University Chemistry, 2024, 39(4): 157-162. doi: 10.3866/PKU.DXHX202308025
6. [6]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
7. [7]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
10. [10]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
11. [11]
  Fengqiao Bi , Jun Wang , Dongmei Yang . Specialized Experimental Design for Chemistry Majors in the Context of “Dual Carbon”: Taking the Assembly and Performance Evaluation of Zinc-Air Fuel Batteries as an Example. University Chemistry, 2024, 39(4): 198-205. doi: 10.3866/PKU.DXHX202311069
12. [12]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023
13. [13]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
14. [14]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
15. [15]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
16. [16]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
17. [17]
  Caixia Lin , Zhaojiang Shi , Yi Yu , Jianfeng Yan , Keyin Ye , Yaofeng Yuan . Ideological and Political Design for the Electrochemical Synthesis of Benzoxathiazine Dioxide Experiment. University Chemistry, 2024, 39(2): 61-66. doi: 10.3866/PKU.DXHX202309005
18. [18]
  Yong Zhou , Jia Guo , Yun Xiong , Luying He , Hui Li . Comprehensive Teaching Experiment on Electrochemical Corrosion in Galvanic Cell for Chemical Safety and Environmental Protection Course. University Chemistry, 2024, 39(7): 330-336. doi: 10.3866/PKU.DXHX202310109
19. [19]
  Yu Wang , Shoulei Zhang , Tianming Lv , Yan Su , Xianyu Liu , Fuping Tian , Changgong Meng . Introduce a Comprehensive Inorganic Synthesis Experiment: Synthesis of Nano Zinc Oxide via Microemulsion Using Waste Soybean Oil. University Chemistry, 2024, 39(7): 316-321. doi: 10.3866/PKU.DXHX202311035
20. [20]
  Yixuan Gao , Lingxing Zan , Wenlin Zhang , Qingbo Wei . Comprehensive Innovation Experiment: Preparation and Characterization of Carbon-based Perovskite Solar Cells. University Chemistry, 2024, 39(4): 178-183. doi: 10.3866/PKU.DXHX202311091

Get Citation

PDF

XML

Metrics

PDF Downloads(35)
Abstract views(1814)
HTML views(444)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

A Polypyrrole-Coated MnO2/Carbon Nanotube Film Cathode for Rechargeable Aqueous Zn-Ion Batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

A Polypyrrole-Coated MnO₂/Carbon Nanotube Film Cathode for Rechargeable Aqueous Zn-Ion Batteries