Citation: Yuecheng Xiong, Fei Yu, Jie Ma. Research Progress in Chlorine Ion Removal Electrodes for Desalination by Capacitive Deionization[J]. Acta Physico-Chimica Sinica, ;2022, 38(5): 200603. doi: 10.3866/PKU.WHXB202006037 shu

Research Progress in Chlorine Ion Removal Electrodes for Desalination by Capacitive Deionization

Yuecheng Xiong ¹ ,
Fei Yu ² ,
Jie Ma ^{1, 3,,}

1.
Key Laboratory of Yangtze River Water Environment, Tongji University, Shanghai 200092, China
2.
College of Marine Ecology and Environment, Shanghai Ocean University, Shanghai 201306, China
3.
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China

Corresponding author: Jie Ma, jma@tongji.edu.cn
Received Date: 12 June 2020
Revised Date: 2 July 2020
Accepted Date: 7 July 2020
Available Online: 13 July 2020
Fund Project: the National Natural Science Foundation of China 21777118

Sustainable freshwater supply is a grave challenge to the society because of the severe water scarcity and global pollution. Seawater is an inexhaustible source of industrial and potable water. The relevant desalination technologies with a high market share include reverse osmosis and thermal distillation, which are energy-intensive. Capacitive deionization (CDI) is a desalination technology that is gaining extensive attention because of its low energy consumption and low chemical intensity. In CDI, charged species are removed from the aqueous environment via applying a voltage onto the anode and cathode. For desalination, Na⁺ and Cl^- ions are removed by the cathode and anode, respectively. With the boom in electrode materials for rechargeable batteries, the Na⁺ removal electrode (cathode) has evolved from a carbon-based electrode to a faradaic electrode, and the desalination performance of CDI has also been significantly enhanced. A conventional carbon-based electrode captures ions in the electrical double layer (EDL) and suffers from low charge efficiency, thus being unsuitable for use in water with high salinity. On the other hand, a faradaic electrode stores Na⁺ ions through a reversible redox process or intercalation, leading to high desalination capacity.However, the Cl^- removal electrode (anode) has not yet seen notable development. Most research groups employ activated carbon to remove Cl^-, and therefore, summarizing Cl^- storage electrodes for CDI is necessary to guide the design of electrode systems with better desalination performance. First, this review outlines the evolution of CDI configuration based on the electrode materials, suggesting that the anode and cathode are of equal importance in CDI. Second, a systematic summary of the anode materials used in CDI and a comparison of the characteristics of different electrodes, including those based on Ag/AgCl, Bi/BiOCl, 2-dimensional (2D) materials (layered double hydroxide (LDH) and MXene), redox polymers, and electrolytes, are presented. Then, the underlying mechanism for Cl^- storage is refined. Similar to the case of Na⁺ storage, traditional carbon electrodes store Cl- via electrosorption based on the EDL. Ag/AgCl and Bi/BiOCl remove Cl^- through a conversion reaction, i.e., phase transformation during the reaction with Cl^-. 2D materials store Cl^- in the space between adjacent layers, a process referred as ion intercalation, with layered double hydroxide (LDH) and MXene showing higher Cl^- storage potential. Redox polymers and electrolytes allow for Cl^- storage via redox reactions. Among all the materials mentioned above, Bi/BiOCl and LDH are the most promising for the construction of CDI anodes because of their high capacity and low cost. Finally, to spur the development of novel anodes for CDI, the electrodes applied in a chlorine ion battery are introduced. This is the first paper to comb through reports on the development of anode materials for CDI, thus laying the theoretical foundation for future materials design.
- Capacitive deionization,
- Desalination,
- Anode,
- Chlorine ion,
- Battery
1. [1]
  Hoekstra, A. Y.; Mekonnen, M. M.; Chapagain, A. K.; Mathews, R. E.; Richter, B. D. PLoS One 2012, 7, e32688. doi: 10.1371/journal.pone.0032688 doi: 10.1371/journal.pone.0032688
2. [2]
  Shannon, M. A.; Bohn, P. W.; Elimelech, M.; Georgiadis, J. G.; Marinas, B. J.; Mayes, A. M. Nature 2008, 452, 301. doi: 10.1038/nature06599 doi: 10.1038/nature06599
3. [3]
  Subramani, A.; Jacangelo, J. G. Water Res. 2015, 75, 164. doi: 10.1016/j.watres.2015.02.032 doi: 10.1016/j.watres.2015.02.032
4. [4]
  Porada, S.; Zhao, R.; van der Wal, A.; Presser, V.; Biesheuvel, P. M. Prog. Mater. Sci. 2013, 58, 1388. doi: 10.1016/j.pmatsci.2013.03.005 doi: 10.1016/j.pmatsci.2013.03.005
5. [5]
  Tan, C.; He, C.; Fletcher, J.; Waite, T. D. Water Res. 2020, 168, 115146. doi: 10.1016/j.watres.2019.115146 doi: 10.1016/j.watres.2019.115146
6. [6]
  Zhou, X.; Zhao, F.; Guo, Y.; Zhang, Y.; Yu, G. Energy Environ. Sci. 2018, 11, 1985. doi: 10.1039/c8ee00567b doi: 10.1039/c8ee00567b
7. [7]
  Liu, Y.; Jiang, Z.; Zhang, X.; Shen, P. K. J. Mater. Chem. A 2018, 6, 20037. doi: 10.1039/c8ta07587e doi: 10.1039/c8ta07587e
8. [8]
  Suss, M. E.; Porada, S.; Sun, X.; Biesheuvel, P. M.; Yoon, J.; Presser, V. Energy Environ. Sci. 2015, 8, 2296. doi: 10.1039/c5ee00519a doi: 10.1039/c5ee00519a
9. [9]
  Cao, J.; Wang, Y.; Chen, C.; Yu, F.; Ma, J. J. Colloid Interface Sci. 2018, 518, 69. doi: 10.1016/j.jcis.2018.02.019 doi: 10.1016/j.jcis.2018.02.019
10. [10]
  Ma, J.; Wang, L.; Yu, F. Electrochim. Acta 2018, 263, 40. doi: 10.1016/j.electacta.2018.01.041 doi: 10.1016/j.electacta.2018.01.041
11. [11]
  Suss, M. E.; Presser, V. Joule 2018, 2, 10. doi: 10.1016/j.joule.2017.12.010 doi: 10.1016/j.joule.2017.12.010
12. [12]
  Zhang, C.; He, D.; Ma, J.; Tang, W.; Waite, T. D. Water Res. 2018, 128, 314. doi: 10.1016/j.watres.2017.10.024 doi: 10.1016/j.watres.2017.10.024
13. [13]
  Yu, F.; Wang, L.; Wang, Y.; Shen, X.; Cheng, Y.; Ma, J. J. Mater. Chem. A 2019, 7, 15999. doi: 10.1039/c9ta01264h doi: 10.1039/c9ta01264h
14. [14]
  Ma, J.; Xiong, Y.; Dai, X.; Yu, F. Environ. Sci. Technol. Lett. 2020, 7, 118. doi: 10.1021/acs.estlett.0c00027 doi: 10.1021/acs.estlett.0c00027
15. [15]
  Pasta, M.; Wessells, C. D.; Cui, Y.; La Mantia, F. Nano Lett. 2012, 12, 839. doi: 10.1021/nl203889e doi: 10.1021/nl203889e
16. [16]
  Cao, J.; Wang, Y.; Wang, L.; Yu, F.; Ma, J. Nano Lett. 2019, 19, 823. doi: 10.1021/acs.nanolett.8b04006 doi: 10.1021/acs.nanolett.8b04006
17. [17]
  Wang, K.; Liu, Y.; Ding, Z.; Li, Y.; Lu, T.; Pan, L. J. Mater. Chem. A 2019, 7, 12126. doi: 10.1039/c9ta01106d doi: 10.1039/c9ta01106d
18. [18]
  Ma, J.; Wang, L.; Yu, F.; Dai, X. Chem. Eng. J. 2019, 370, 938. doi: 10.1016/j.cej.2019.03.243 doi: 10.1016/j.cej.2019.03.243
19. [19]
  Ding, Z.; Xu, X.; Li, Y.; Wang, K.; Lu, T.; Pan, L. Desalination 2019, 468, 114078. doi: 10.1016/j.desal.2019.114078 doi: 10.1016/j.desal.2019.114078
20. [20]
  Zhao, Y.; Liang, B.; Wei, X.; Li, K.; Lv, C.; Zhao, Y. J. Mater. Chem. A 2019, 7, 10464. doi: 10.1039/c8ta12433g doi: 10.1039/c8ta12433g
21. [21]
  Yin, H.; Zhao, S.; Wan, J.; Tang, H.; Chang, L.; He, L.; Zhao, H.; Gao, Y.; Tang, Z. Adv. Mater. 2013, 25, 6270. doi: 10.1002/adma.201302223 doi: 10.1002/adma.201302223
22. [22]
  Lee, J.; Kim, S.; Kim, C.; Yoon, J. Energy Environ. Sci. 2014, 7, 3683. doi: 10.1039/c4ee02378a doi: 10.1039/c4ee02378a
23. [23]
  Chen, F.; Huang, Y.; Guo, L.; Ding, M.; Yang, H. Y. Nanoscale 2017, 9, 10101. doi: 10.1039/c7nr01861d doi: 10.1039/c7nr01861d
24. [24]
  Nam, D. H.; Choi, K. S. J. Am. Chem. Soc. 2017, 139, 11055. doi: 10.1021/jacs.7b01119 doi: 10.1021/jacs.7b01119
25. [25]
  Chen, F.; Huang, Y.; Guo, L.; Sun, L.; Wang, Y.; Yang, H. Y. Energy Environ. Sci. 2017, 10, 2081. doi: 10.1039/c7ee00855d doi: 10.1039/c7ee00855d
26. [26]
  Biesheuvel, P. M.; van der Wal, A. J. Membr. Sci. 2010, 346, 256. doi: 10.1016/j.memsci.2009.09.043 doi: 10.1016/j.memsci.2009.09.043
27. [27]
  Wu, T.; Wang, G.; Wang, S.; Zhan, F.; Fu, Y.; Qiao, H.; Qiu, J. Environ. Sci. Technol. Let. 2018, 5, 98. doi: 10.1021/acs.estlett.7b00540 doi: 10.1021/acs.estlett.7b00540
28. [28]
  Xi, W.; Li, H. Environ. Sci. Nano 2020, 7, 764. doi: 10.1039/c9en01238a doi: 10.1039/c9en01238a
29. [29]
  Smith, K. C. Electrochim. Acta 2017, 230, 333. doi: 10.1016/j.electacta.2017.02.006 doi: 10.1016/j.electacta.2017.02.006
30. [30]
  Arulrajan, A. C.; Ramasamy, D. L.; Sillanpaa, M.; van der Wal, A.; Biesheuvel, P. M.; Porada, S.; Dykstra, J. E. Adv. Mater. 2019, 31, e1806937. doi: 10.1002/adma.201806937 doi: 10.1002/adma.201806937
31. [31]
  Huang, Z. H.; Yang, Z.; Kang, F.; Inagaki, M. J. Mater. Chem. A 2017, 5, 470. doi: 10.1039/c6ta06733f doi: 10.1039/c6ta06733f
32. [32]
  Wang, L.; Yu, F.; Ma, J. Acta Phys. -Chim. Sin. 2017, 33, 1338. doi: 10.3866/PKU.WHXB201704113
33. [33]
  Liu, Y.; Nie, C.; Liu, X.; Xu, X.; Sun, Z.; Pan, L. RSC Adv. 2015, 5, 15205. doi: 10.1039/c4ra14447c doi: 10.1039/c4ra14447c
34. [34]
  Tang, K.; Hong, T. Z. X.; You, L.; Zhou, K. J. Mater. Chem. A 2019, 7, 26693. doi: 10.1039/c9ta08663c doi: 10.1039/c9ta08663c
35. [35]
  Srimuk, P.; Su, X.; Yoon, J.; Aurbach, D.; Presser, V. Nat. Rev. Mater. 2020, 5, 517. doi: 10.1038/s41578-020-0193-1 doi: 10.1038/s41578-020-0193-1
36. [36]
  Sun, Z.; Chai, L.; Liu, M.; Shu, Y.; Li, Q.; Wang, Y.; Wang, Q.; Qiu, D. Sep. Purif. Technol. 2018, 191, 424. doi: 10.1016/j.seppur.2017.09.015 doi: 10.1016/j.seppur.2017.09.015
37. [37]
  Zhao, W.; Guo, L.; Ding, M.; Huang, Y.; Yang, H. Y. ACS Appl. Mater. Interfaces 2018, 10, 40540. doi: 10.1021/acsami.8b14014 doi: 10.1021/acsami.8b14014
38. [38]
  Zhao, W.; Ding, M.; Guo, L.; Yang, H. Y. Small 2019, 15, 1805505. doi: 10.1002/smll.201805505 doi: 10.1002/smll.201805505
39. [39]
  Yue, Z.; Ma, Y.; Zhang, J.; Li, H. J. Mater. Chem. A 2019, 7, 16892. doi: 10.1039/c9ta03570b doi: 10.1039/c9ta03570b
40. [40]
  Srimuk, P.; Husmann, S.; Presser, V. RSC Adv. 2019, 9, 14849. doi: 10.1039/c9ra02570g doi: 10.1039/c9ra02570g
41. [41]
  Ahn, J.; Lee, J.; Kim, S.; Kim, C.; Lee, J.; Biesheuvel, P. M.; Yoon, J. Desalination 2020, 476, 114216. doi: 10.1016/j.desal.2019.114216 doi: 10.1016/j.desal.2019.114216
42. [42]
  Min, X.; Zhu, M.; He, Y.; Wang, Y.; Deng, H.; Wang, S.; Jin, L.; Wang, H.; Zhang, L.; Chai, L. Chemosphere 2020, 251, 126319. doi: 10.1016/j.chemosphere.2020.126319 doi: 10.1016/j.chemosphere.2020.126319
43. [43]
  Kong, H.; Yang, M.; Miao, Y.; Zhao, X. Energy Technol. 2019, 7, 1900835. doi: 10.1002/ente.201900835 doi: 10.1002/ente.201900835
44. [44]
  Li, D.; Wang, S.; Wang, G.; Li, C.; Che, X.; Wang, S.; Zhang, Y.; Qiu, J. ACS Appl. Mater. Interfaces 2019, 11, 31200. doi: 10.1021/acsami.9b10307 doi: 10.1021/acsami.9b10307
45. [45]
  Srimuk, P.; Kaasik, F.; Krüner, B.; Tolosa, A.; Fleischmann, S.; Jäckel, N.; Tekeli, M. C.; Aslan, M.; Suss, M. E.; Presser, V. J. Mater. Chem. A 2016, 4, 18265. doi: 10.1039/c6ta07833h doi: 10.1039/c6ta07833h
46. [46]
  Khan, A. I.; O'Hare, D. J. Mater. Chem. 2002, 12, 3191. doi: 10.1039/b204076j doi: 10.1039/b204076j
47. [47]
  Long, X.; Wang, Z.; Xiao, S.; An, Y.; Yang, S. Mater. Today 2016, 19, 213. doi: 10.1016/j.mattod.2015.10.006 doi: 10.1016/j.mattod.2015.10.006
48. [48]
  Lv, L.; Yang, Z.; Chen, K.; Wang, C.; Xiong, Y. Adv. Energy Mater. 2019, 9, 1803358. doi: 10.1002/aenm.201803358 doi: 10.1002/aenm.201803358
49. [49]
  Wang, Q.; O'Hare, D. Chem. Rev. 2012, 112, 4124. doi: 10.1021/cr200434v doi: 10.1021/cr200434v
50. [50]
  Wang, L.; Wang, D.; Dong, X. Y.; Zhang, Z. J.; Pei, X. F.; Chen, X. J.; Chen, B.; Jin, J. Chem. Commun. 2011, 47, 3556. doi: 10.1039/c0cc05420h doi: 10.1039/c0cc05420h
51. [51]
  Wimalasiri, Y.; Fan, R.; Zhao, X. S.; Zou, L. Electrochim. Acta 2014, 134, 127. doi: 10.1016/j.electacta.2014.04.129 doi: 10.1016/j.electacta.2014.04.129
52. [52]
  Quan, W.; Tang, Z. L.; Wang, S. T.; Hong, Y.; Zhang, Z. T. Chem. Commun. 2016, 52, 3694. doi: 10.1039/c5cc08744a doi: 10.1039/c5cc08744a
53. [53]
  Cai, P.; Zheng, H.; Wang, C.; Ma, H.; Hu, J.; Pu, Y.; Liang, P. J. Hazard. Mater. 2012, 213-214, 100. doi: 10.1016/j.jhazmat.2012.01.069 doi: 10.1016/j.jhazmat.2012.01.069
54. [54]
  Wang, J.; Gao, F.; Du, X.; Ma, X.; Hao, X.; Ma, W.; Wang, K.; Guan, G.; Abudula, A. Electrochim. Acta 2020, 331, 135288. doi: 10.1016/j.electacta.2019.135288 doi: 10.1016/j.electacta.2019.135288
55. [55]
  Ren, Q.; Wang, G.; Wu, T.; He, X.; Wang, J.; Yang, J.; Yu, C.; Qiu, J. Ind. Eng. Chem. Res. 2018, 57, 6417. doi: 10.1021/acs.iecr.7b04983 doi: 10.1021/acs.iecr.7b04983
56. [56]
  Hu, C.; Dong, J.; Wang, T.; Liu, R.; Liu, H.; Qu, J. Chem. Eng. J. 2018, 335, 475. doi: 10.1016/j.cej.2017.10.167 doi: 10.1016/j.cej.2017.10.167
57. [57]
  Wang, X.; Kajiyama, S.; Iinuma, H.; Hosono, E.; Oro, S.; Moriguchi, I.; Okubo, M.; Yamada, A. Nat. Commun. 2015, 6, 6544. doi: 10.1038/ncomms7544 doi: 10.1038/ncomms7544
58. [58]
  Naguib, M.; Mochalin, V. N.; Barsoum, M. W.; Gogotsi, Y. Adv. Mater. 2014, 26, 992. doi: 10.1002/adma.201304138 doi: 10.1002/adma.201304138
59. [59]
  Pang, J.; Mendes, R. G.; Bachmatiuk, A.; Zhao, L.; Ta, H. Q.; Gemming, T.; Liu, H.; Liu, Z.; Rummeli, M. H. Chem. Soc. Rev. 2019, 48, 72. doi: 10.1039/c8cs00324f doi: 10.1039/c8cs00324f
60. [60]
  Ihsanullah, I. Nano-Micro Lett. 2020, 12, 72. doi: 10.1007/s40820-020-0411-9 doi: 10.1007/s40820-020-0411-9
61. [61]
  Shen, X.; Xiong, Y.; Hai, R.; Yu, F.; Ma, J. Environ. Sci. Technol. 2020, 54, 4554. doi: 10.1021/acs.est.9b05759 doi: 10.1021/acs.est.9b05759
62. [62]
  Wang, D.; Gao, Y.; Liu, Y.; Gogotsi, Y.; Meng, X.; Chen, G.; Wei, Y. J. Mater. Chem. A 2017, 5, 24720. doi: 10.1039/c7ta09057a doi: 10.1039/c7ta09057a
63. [63]
  Cui, H.; Li, Q.; Qian, Y.; Tang, R.; An, H.; Zhai, J. Water Res. 2011, 45, 5736. doi: 10.1016/j.watres.2011.08.049 doi: 10.1016/j.watres.2011.08.049
64. [64]
  Silambarasan, K.; Joseph, J. Energy Technol. 2019, 7, 1800601. doi: 10.1002/ente.201800601 doi: 10.1002/ente.201800601
65. [65]
  Li, Y.; Ding, Z.; Li, J.; Wang, K.; Lu, T.; Pan, L. Desalination 2020, 481, 114379. doi: 10.1016/j.desal.2020.114379 doi: 10.1016/j.desal.2020.114379
66. [66]
  Shi, Y.; Zhou, X.; Yu, G. Acc. Chem. Res. 2017, 50, 2642. doi: 10.1021/acs.accounts.7b00402 doi: 10.1021/acs.accounts.7b00402
67. [67]
  Wang, Z.; Xu, X.; Kim, J.; Malgras, V.; Mo, R.; Li, C.; Lin, Y.; Tan, H.; Tang, J.; Pan, L.; et al. Mater. Horiz. 2019, 6, 1433. doi: 10.1039/c9mh00306a doi: 10.1039/c9mh00306a
68. [68]
  Dai, J.; Wang, J.; Hou, X.; Ru, Q.; He, Q.; Srimuk, P.; Presser, V.; Chen, F. ChemSusChem 2020, 13, 2792. doi: 10.1002/cssc.202000188 doi: 10.1002/cssc.202000188
69. [69]
  Dai, J.; Pyae, N. L. W.; Chen, F.; Liang, M.; Wang, S.; Ramalingam, K.; Zhai, S.; Su, C.; Shi, Y.; Tan, S. C.; et al. ACS Appl. Mater. Interfaces 2020, 12, 25728. doi: 10.1021/acsami.0c02822 doi: 10.1021/acsami.0c02822
70. [70]
  Zhao, X.; Ren, S.; Bruns, M.; Fichtner, M. J. Power Sources 2014, 245, 706. doi: 10.1016/j.jpowsour.2013.07.001 doi: 10.1016/j.jpowsour.2013.07.001
71. [71]
  Gao, P.; Reddy, M. A.; Mu, X.; Diemant, T.; Zhang, L.; Zhao-Karger, Z.; Chakravadhanula, V. S.; Clemens, O.; Behm, R. J.; Fichtner, M. Angew. Chem. Int. Ed. 2016, 55, 4285. doi: 10.1002/anie.201509564 doi: 10.1002/anie.201509564
72. [72]
  Lakshmi, K. P.; Janas, K. J.; Shaijumon, M. M. J. Power Sources 2019, 433, 126685. doi: 10.1016/j.jpowsour.2019.05.091 doi: 10.1016/j.jpowsour.2019.05.091
73. [73]
  Zhao, X.; Zhao, Z.; Yang, M.; Xia, H.; Yu, T.; Shen, X. ACS Appl. Mater. Interfaces 2017, 9, 2535. doi: 10.1021/acsami.6b14755 doi: 10.1021/acsami.6b14755
74. [74]
  Zhao, Z.; Yu, T.; Miao, Y.; Zhao, X. Electrochim. Acta 2018, 270, 30. doi: 10.1016/j.electacta.2018.03.077 doi: 10.1016/j.electacta.2018.03.077
75. [75]
  Yu, T.; Yang, R.; Zhao, X.; Shen, X. ChemElectroChem 2019, 6, 1761. doi: 10.1002/celc.201801803 doi: 10.1002/celc.201801803
76. [76]
  Yang, R.; Yu, T.; Zhao, X. J. Alloys Compd. 2019, 788, 407. doi: 10.1016/j.jallcom.2019.02.234 doi: 10.1016/j.jallcom.2019.02.234
77. [77]
  Chen, F.; Leong, Z. Y.; Yang, H. Y. Energy Storage Mater. 2017, 7, 189. doi: 10.1016/j.ensm.2017.02.001 doi: 10.1016/j.ensm.2017.02.001
78. [78]
  Hu, X.; Chen, F.; Wang, S.; Ru, Q.; Chu, B.; Wei, C.; Shi, Y.; Ye, Z.; Chu, Y.; Hou, X.; et al. ACS Appl. Mater. Interfaces 2019, 11, 9144. doi: 10.1021/acsami.8b21652 doi: 10.1021/acsami.8b21652
79. [79]
  Yin, Q.; Rao, D.; Zhang, G.; Zhao, Y.; Han, J.; Lin, K.; Zheng, L.; Zhang, J.; Zhou, J.; Wei, M. Adv. Funct. Mater. 2019, 29, 1900983. doi: 10.1002/adfm.201900983 doi: 10.1002/adfm.201900983
1. [1]
  Guoze Yan , Bin Zuo , Shaoqing Liu , Tao Wang , Ruoyu Wang , Jinyang Bao , Zhongzhou Zhao , Feifei Chu , Zhengtong Li , Yusuke Yamauchi , Saad Melhi , Xingtao Xu . Opportunities and Challenges of Capacitive Deionization for Uranium Extraction from Seawater. Acta Physico-Chimica Sinica, 2025, 41(4): 100032-. doi: 10.3866/PKU.WHXB202404006
2. [2]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
3. [3]
  Ping Ye , Lingshuang Qin , Mengyao He , Fangfang Wu , Zengye Chen , Mingxing Liang , Libo Deng . 荷叶衍生多孔碳的零电荷电位调节实现废水中电化学捕集镉离子. Acta Physico-Chimica Sinica, 2025, 41(3): 2311032-. doi: 10.3866/PKU.WHXB202311032
4. [4]
  Zhuo Wang , Xue Bai , Kexin Zhang , Hongzhi Wang , Jiabao Dong , Yuan Gao , Bin Zhao . MOF模板法合成氮掺杂碳材料用于增强电化学钠离子储存和去除. Acta Physico-Chimica Sinica, 2025, 41(3): 2405002-. doi: 10.3866/PKU.WHXB202405002
5. [5]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
6. [6]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014
7. [7]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
8. [8]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
9. [9]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
10. [10]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
11. [11]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
12. [12]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
13. [13]
  Jiaxuan Zuo , Kun Zhang , Jing Wang , Xifei Li . 锂离子电池Ni-Co-Mn基正极材料前驱体的形核调控及机制. Acta Physico-Chimica Sinica, 2025, 41(1): 2404042-. doi: 10.3866/PKU.WHXB202404042
14. [14]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
15. [15]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
16. [16]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
17. [17]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
18. [18]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
19. [19]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
20. [20]
  Xinxin JING , Weiduo WANG , Hesu MO , Peng TAN , Zhigang CHEN , Zhengying WU , Linbing SUN . Research progress on photothermal materials and their application in solar desalination. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1033-1064. doi: 10.11862/CJIC.20230371

Get Citation

PDF

XML

Metrics

PDF Downloads(32)
Abstract views(1803)
HTML views(510)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142