Citation: Zhu Gaolong, Zhao Chenzi, Yuan Hong, Nan Haoxiong, Zhao Bochen, Hou Lipeng, He Chuangxin, Liu Quanbing, Huang Jiaqi. Liquid Phase Therapy with Localized High-Concentration Electrolytes for Solid-State Li Metal Pouch Cells[J]. Acta Physico-Chimica Sinica, ;2021, 37(2): 200500. doi: 10.3866/PKU.WHXB202005003 shu

Liquid Phase Therapy with Localized High-Concentration Electrolytes for Solid-State Li Metal Pouch Cells

Zhu Gaolong ^1,2,3,5 ,
Zhao Chenzi ³ ,
Yuan Hong ¹ ,
Nan Haoxiong ^3,4 ,
Zhao Bochen ³ ,
Hou Lipeng ³ ,
He Chuangxin ² ,
Liu Quanbing ⁴ ,
Huang Jiaqi ^1,,

1.
Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China
2.
Shenzhen Key Laboratory of Functional Polymer, College of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518000, Guangdong Province, China
3.
Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China
4.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
5.
Key Laboratory of Optoelectronic Devices Systems of Ministry of Education and Guangdong Province, College of Optoelectronic Engineering, Shenzhen University, Shenzhen 518060, Guangdong Province, China

Corresponding author: Huang Jiaqi, jqhuang@bit.edu.cn
Received Date: 5 May 2020
Revised Date: 27 May 2020
Available Online: 18 June 2020
Fund Project: the China Postdoctoral Science Foundation 2019T120098the National Natural Science Foundation of China 21808124the National Natural Science Foundation of China 21676160The project was supported by the National Key Research and Development Program of China (2016YFA0202500, 2016YFA0200102), the National Natural Science Foundation of China (21676160, 21808124, U1801257), and the China Postdoctoral Science Foundation (2019T120098)the National Natural Science Foundation of China U1801257the National Key Research and Development Program of China 2016YFA0200102the National Key Research and Development Program of China 2016YFA0202500

Solid-state Li metal batteries are considered promising next-generation energy storage systems due to its exceptional advantages in terms of safety and high energy density. The continuous process on the development of solid-state fast ionic electrolytes enables the solid-state battery to operate at room temperature. Among these, sulfide-based solid electrolytes have attracted significant attentions due to their extremely high ionic conductivity, excellent deformability, and mild low-temperature processability. However, the full demonstration of practical batteries remains challenging due to the slow lithium-ion transport kinetics at working solid-solid interfaces. The sluggish interfacial transport kinetics mainly result from the poor solid-solid contacts, resulting in poor battery performance. Especially for solid-state pouch cells, the high local current due to the poor contact is amplified by the high working current, leading to rapid failure. Constructing fast ion transport paths between the Li metal anode and solid electrolyte interface is key for the practical application of solid-state batteries. Here a simple protocol was developed to realize fast ionic transportation by wetting the solid electrolyte/Li metal anode interface with localized high salt concentration liquid electrolyte. First, 3.5 mmol lithium trifluoroalfonylimide (LiTFSI) was added into 1, 1, 2, 2-tetrafluoroethyl-2, 2, 3, 3-tetrafluoropropyl ether (HFE) and dimethoxyethane (DME) mixed solvent, and stirred to obtain uniformly dispersed localized high-concentration liquid electrolyte, denoted as HFE-DME LiTFSI. The fluidity of liquid electrolyte ensures sufficiently conformal contacts between lithium anode and liquid electrolyte, as well as solid-state electrolyte and liquid electrolyte. Thus, fast ion transportation channels were constructed between the solid electrolyte and Li metal anode by wetting HFE-DME LiTFSI at a concentration of 3.0 μL·cm^-2. After liquid phase therapy, the interfacial resistance of solid-state Li|Li₄Ti₅O₁₂ (LTO) pouch cell rapidly reduced from 4366 to 64 Ω·cm^-2 and even lower than the cell that was pressed at 3 MPa in the assemble process (340 Ω·cm^-2). This suggests that the ion transport kinetics are significantly improved by liquid phase therapy. Therefore, the solid-state Li metal pouch cell with dimensions of 30 mm × 30 mm showed excellent cycling performances with specific capacities of 107 and 96 mAh·g^-1 at 0.1C and 0.5C, respectively. Furthermore, the solid-state Li-S pouch cell delivered capacities of 1100 and 932 mAh·g^-1 at 0.01C and 0.02C, respectively. This study demonstrates the effectiveness of the novel liquid phase therapy to construct fast ionic transportation channels, which providing an effective strategy for the practical application of solid-state Li metal pouch cells.
- Solid-state pouch cell,
- Lithium metal anode,
- Sulfide electrolyte,
- Liquid phase therapy
1. [1]
  Cheng, X. B.; Zhao, C. Z.; Yao, Y. X.; Liu, H.; Zhang, Q. Chem 2019, 5, 74. doi: 10.1016/j.chempr.2018.12.002 doi: 10.1016/j.chempr.2018.12.002
2. [2]
  Peng, H. J.; Huang, J. Q.; Cheng, X. B.; Zhang, Q. Adv. Energy Mater. 2017, 7, 1700260. doi: 10.1002/aenm.201700260 doi: 10.1002/aenm.201700260
3. [3]
  Li, B. Q.; Kong, L.; Zhao, C. X.; Jin, Q.; Chen, X.; Peng, H. J.; Qin, J. L.; Chen, J. X.; Yuan, H.; Zhang, Q.; Huang, J. Q. InfoMat 2019, 1, 533. doi: 10.1002/inf2.12056 doi: 10.1002/inf2.12056
4. [4]
  Shen, X.; Cheng, X.; Shi, P.; Huang, J.; Zhang, X.; Yan, C.; Li, T.; Zhang, Q. J. Energy Chem. 2019, 37, 29. doi: 10.1016/j.jechem.2018.11.016 doi: 10.1016/j.jechem.2018.11.016
5. [5]
  Chen, J. X.; Zhang, X. Q.; Li, B. Q.; Wang, X. M.; Shi, P.; Zhu, W.; Chen, A.; Jin, Z.; Xiang, R.; Huang, J. Q. J. Energy Chem. 2020, 47, 128. doi: 10.1016/j.jechem.2019.11.024 doi: 10.1016/j.jechem.2019.11.024
6. [6]
  Jiang, J. H.; Wang, A. B.; Wang, W. K.; Jin, Z. Q.; Fan, L. Z. J. Energy Chem. 2020, 46, 114. doi: 10.1016/j.jechem.2019.10.009 doi: 10.1016/j.jechem.2019.10.009
7. [7]
  Yan, C.; Yuan, H.; Park, H. S. Huang, J. Q. J. Energy Chem. 2020, 47, 217. doi: 10.1016/j.jechem.2019.09.034 doi: 10.1016/j.jechem.2019.09.034
8. [8]
  Guo, F.; Chen, P.; Kang, T.; Wang, Y. L.; Liu, C. H.; Shen, Y. B.; Lu, W.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1365. doi: 10.3866/PKU.WHXB201903008
9. [9]
  Chen, K.; Sun, Z. H.; Fang, R. P.; Li, F.; Cheng, H. M. Acta Phys. -Chim. Sin. 2018, 34, 377. doi: 10.3866/PKU.WHXB201709001
10. [10]
  Oh, P.; Lee, H.; Park, S.; Cha, H.; Kim, J.; Cho, J. Adv. Energy Matter. 2020, 2000904. doi: 10.1002/aenm.202000904 doi: 10.1002/aenm.202000904
11. [11]
  Cao, D.; Sun, X.; Li, Q.; Natan, A.; Xiang, P.; Zhu, H. Matter 2020, 2, 1. doi: 10.1016/j.matt.2020.03.015 doi: 10.1016/j.matt.2020.03.015
12. [12]
  Zhang, X. Q.; Zhao, C. Z.; Huang, J. Q. Zhang, Q. Engineering 2018, 4, 831. doi: 10.1016/j.eng.2018.10.008 doi: 10.1016/j.eng.2018.10.008
13. [13]
  Zhao, C. Z.; Duan, H.; Huang, J. Q.; Zhang, J.; Zhang, Q.; Guo, Y. G.; Wan, L. J. Sci. China Chem. 2019, 62, 1286. doi: 10.1007/s11426-019-9519-9 doi: 10.1007/s11426-019-9519-9
14. [14]
  Ates, T.; Keller, M.; Kulisch, J.; Adermann, T. Passerini, S. Energy Storage Mater. 2019, 17, 204. doi: 10.1016/j.ensm.2018.11.011 doi: 10.1016/j.ensm.2018.11.011
15. [15]
  Busche, M. R.; Drossel, T.; Leichtweiss, T.; Weber, D. A.; Falk, M.; Schneider, M.; Reich, M. L.; Sommer, H.; Adelhelm, P.; Janek, J. Nat. Chem. 2016, 8, 426. doi: 10.1038/nchem.2470 doi: 10.1038/nchem.2470
16. [16]
  Sakuda, A.; Sato, Y.; Hayashi, A.; Tatsumisago, M. Energy Technol. 2019, 7, 1900077. doi: 10.1002/ente.201900077 doi: 10.1002/ente.201900077
17. [17]
  Shen, Y. Q.; Zeng, F. L.; Zhou, X. Y.; Wang, A. B.; Wang, W. K.; Yuan, N. Y.; Ding, J. N. J. Energy Chem. 2020, 48, 267.doi: 10.1016/j.jechem.2020.01.016 doi: 10.1016/j.jechem.2020.01.016
18. [18]
  Wu, J. Y.; Ling, S. G.; Yang, Q.; Li, H.; Xu, X. X.; Chen, L. Q. Chin. Phys. B 2016, 25, 078204. doi: 10.1088/1674-1056/25/7/078204 doi: 10.1088/1674-1056/25/7/078204
19. [19]
  Yao, X. Y.; Huang, N.; Han, F. D.; Zhang, Q.; Wan, H. L.; Mwizerwa, J. P.; Wang, C. S.; Xu, X. X. Adv. Energy Mater. 2017, 7, 1602923. doi: 10.1002/aenm.201602923 doi: 10.1002/aenm.201602923
20. [20]
  Zhang, H.; Judez, X.; Santiago, A.; Martinez-Ibanez, M.; Munoz-Marquez, M. A.; Carrasco, J.; Li, C. M.; Eshetu, G. G.; Armand, M. Adv. Energy Mater. 2019, 9, 1900763. doi: 10.1002/aenm.201900763 doi: 10.1002/aenm.201900763
21. [21]
  Xu, R.; Zhang, S.; Wang, X.; Xia, Y.; Xia, X.; Wu, J.; Gu, C.; Tu, J. Chem. -A Eur. J. 2018, 24, 6007. doi: 10.1002/chem.201704568 doi: 10.1002/chem.201704568
22. [22]
  Zhao, C. Z.; Zhang, X. Q.; Cheng, X. B.; Zhang, R.; Xu, R.; Chen, P. Y.; Peng, H. J.; Huang, J. Q. Zhang, Q. Proc. Natl. Acad. Sci. 2017, 114, 11069. doi: 10.1073/pnas.1708489114 doi: 10.1073/pnas.1708489114
23. [23]
  Hou, L. P.; Yuan, H.; Zhao, C. Z.; Xu, L.; Zhu, G. L.; Nan, H. X.; Cheng, X. B.; Liu, Q. B.; He, C. X.; Huang, J. Q.; Zhang, Q. Energy Storage Mater. 2019, 25, 436. doi: 10.1016/j.ensm.2019.09.037 doi: 10.1016/j.ensm.2019.09.037
24. [24]
  Zhang, Q.; Cao, D. X.; Ma, Y.; Natan, A.; Aurora, P. Zhu, H. L. Adv. Mater. 2019, 31, 1901131. doi: 10.1002/adma.201901131 doi: 10.1002/adma.201901131
25. [25]
  Zhang, Y. B.; Chen, R. J.; Wang, S.; Liu, T.; Xu, B. Q.; Zhang, X.; Wang, X. Z.; Shen, Y.; Lin, Y. H.; Li, M.; et al. Energy Storage Mater. 2020, 25, 145. doi: 10.1016/j.ensm.2019.10.020 doi: 10.1016/j.ensm.2019.10.020
26. [26]
  Zhang, Y. B.; Liu, T.; Zhang, Q. H.; Zhang, X.; Wang, S.; Wang, X. Z.; Li, L. L.; Fan, L. Z.; Nan, C. W.; Shen, Y. J. Mater. Chem. A 2018, 6, 23345. doi: 10.1039/c8ta08420c doi: 10.1039/c8ta08420c
27. [27]
  Jin, C. Q.; Xie, K.; Hong, X. B. Acta Chim. Sin. 2014, 72, 11. doi: 10.6023/A13101097 doi: 10.6023/A13101097
28. [28]
  Cheng, X. B.; Zhang, R.; Zhao, C. Z.; Zhang, Q. Chem. Rev. 2017, 117, 10403. doi: 10.1021/acs.chemrev.7b00115 doi: 10.1021/acs.chemrev.7b00115
29. [29]
  Yan, M.; Liang, J. Y.; Zuo, T. T.; Yin, Y. X.; Xin, S.; Tan, S. J.; Guo, Y. G.; Wan, L. J. Adv. Funct. Mater. 2020, 30, 1908047. doi: 10.1002/adfm.201908047 doi: 10.1002/adfm.201908047
30. [30]
  Oh, D. Y.; Kim, D. H.; Jung, S. H.; Han, J. G.; Choi, N. S.; Jung, Y. S. J. Mater. Chem. A 2017, 5, 20771. doi: 10.1039/c7ta06873e doi: 10.1039/c7ta06873e
31. [31]
  Chen, L.; Fan, L. Z. Energy Storage Mater. 2018, 15, 37. doi: 10.1016/j.ensm.2018.03.015 doi: 10.1016/j.ensm.2018.03.015
32. [32]
  Fan, Z.; Ding, B.; Zhang, T.; Lin, Q.; Malgras, V.; Wang, J.; Dou, H.; Zhang, X.; Yamauchi, Y. Small 2019, 15, 1903952. doi: 10.1002/smll.201903952 doi: 10.1002/smll.201903952
33. [33]
  Gao, Z.; Zhang, S.; Huang, Z.; Lu, Y.; Wang, W.; Wang, K.; Li, J.; Zhou, Y.; Huang, L.; Sun, S. Chin. Chem. Lett. 2019, 30, 525. doi: 10.1016/j.cclet.2018.05.016 doi: 10.1016/j.cclet.2018.05.016
34. [34]
  Jiang, J. H.; Wang, A. B.; Wang, W. K.; Jin, Z. Q.; Fan, L. Z. J. Energy Chem. 2020, 46, 114. doi: 10.1016/j.jechem.2019.10.009 doi: 10.1016/j.jechem.2019.10.009
35. [35]
  Kato, Y.; Hori, S.; Saito, T.; Suzuki, K.; Hirayama, M.; Mitsui, A.; Yonemura, M.; Iba, H.; Kanno, R. Nat. Energy 2016, 1, 16030. doi: 10.1038/nenergy.2016.30 doi: 10.1038/nenergy.2016.30
36. [36]
  Deiseroth, H. J.; Kong, S. T.; Eckert, H.; Vannahme, J.; Reiner, C.; Zaiß, T.; Schlosser, M. Angew. Chem. Int. Ed. 2008, 47, 755. doi: 10.1002/anie.200703900 doi: 10.1002/anie.200703900
37. [37]
  Kamaya, N.; Homma, K.; Yamakawa, Y.; Hirayama, M.; Kanno, R.; Yonemura, M.; Kamiyama, T.; Kato, Y.; Hama, S.; Kawamoto, K.; Mitsui, A. Nat. Mater. 2011, 10, 682. doi: 10.1038/nmat3066 doi: 10.1038/nmat3066
38. [38]
  Manalastas, W.; Rikarte, J.; Chater, R. J.; Brugge, R.; Aguadero, A.; Buannic, L.; Llordés, A.; Aguesse, F.; Kilner, J. J. Power Sources 2019, 412, 287. doi: 10.1016/j.jpowsour.2018.11.041 doi: 10.1016/j.jpowsour.2018.11.041
39. [39]
  Xu, X. X.; Qiu, Z. J.; Guan, Y. B.; Huang, Z.; Jin, Y. Energy Storage Sci. Technology 2013, 2, 332. doi: 10.3969/j.issn.2095-4239.2013.04.001
40. [40]
  He, M.; Cui, Z.; Han, F.; Guo, X. J. Alloy. Compd. 2018, 762, 157. doi: 10.1016/j.jallcom.2018.05.255 doi: 10.1016/j.jallcom.2018.05.255
41. [41]
  Chen, W.; Lei, T.; Wu, C.; Deng, M.; Gong, C.; Hu, K.; Ma, Y.; Dai, L.; Lv, W.; He, W.; et al. Adv. Energy Mater. 2018, 8, 1702348. doi: 10.1002/aenm.201702348 doi: 10.1002/aenm.201702348
42. [42]
  Miura, A.; Rosero-Navarro, N. C.; Sakuda, A.; Tadanaga, K.; Phuc, N. H. H.; Matsuda, A.; Machida, N.; Hayashi, A. Tatsumisago, M. Nat. Rev. Chem. 2019, 3, 189. doi: 10.1038/s41570-019-0078-2 doi: 10.1038/s41570-019-0078-2
43. [43]
  Liang, Y.; Zhang, W.; Wu, D.; Ni, Q. Q.; Zhang, M. Q. Adv. Mater. Interfaces 2018, 5, 1800430. doi: 10.1002/admi.201800430 doi: 10.1002/admi.201800430
44. [44]
  Zhang, Q.; Ding, Z.; Liu, G.; Wan, H.; Mwizerwa, J. P.; Wu, J.; Yao, X. Energy Storage Mater. 2019, 23, 168. doi: 10.1016/j.ensm.2019.05.015 doi: 10.1016/j.ensm.2019.05.015
45. [45]
  Chen, R.; Li, Q.; Yu, X.; Chen, L.; Li, H. Chem. Rev. 2019, doi: 10.1021/acs.chemrev.9b00268 doi: 10.1021/acs.chemrev.9b00268
46. [46]
  Teragawa, S.; Aso, K.; Tadanaga, K.; Hayashi, A.; Tatsumisago, M.J. Power Sources 2014, 248, 939. doi: 10.1016/j.jpowsour.2013.09.117 doi: 10.1016/j.jpowsour.2013.09.117
47. [47]
  Tsukasaki, H.; Mori, Y.; Otoyama, M.; Yubuchi, S.; Asano, T.; Tanaka, Y.; Ohno, T.; Mori, S.; Hayashi, A.; Tatsumisago, M. Sci. Rep. 2018, 8, 6214. doi: 10.1038/s41598-018-24524-7 doi: 10.1038/s41598-018-24524-7
48. [48]
  Hayashi, A.; Noi, K.; Sakuda, A.; Tatsumisago, M. Nat. Commun. 2012, 3, 856. doi: 10.1038/ncomms1843 doi: 10.1038/ncomms1843
49. [49]
  Jin, F., Li. J.; Hu, C. J.; Dong, H. C.; Chen, P.; Shen, Y. B.; Chen, L. W. Acta Phys. -Chim. Sin. 2019, 35, 1399. doi: 10.3866/PKU.WHXB201904085
50. [50]
  Fei, H. F.; Liu, Y. P.; Wei, C. L.; Zhang, Y. C.; Feng, J. K.; Chen, C. Z.; Yu, H. J. Acta Phys. -Chim. Sin. 2020, 36, 1905015. doi: 10.3866/PKU.WHXB201905015
51. [51]
  Yuan, H.; Nan, H. X.; Zhao, C. Z.; Zhu, G. L.; Lu, Y.; Cheng, X. B.; Liu, Q. B.; He, C. X.; Huang, J. Q.; Zhang, Q. Batteries & Supercaps 2020. doi: 10.1002/batt.202000051
52. [52]
  Zhu, G. L.; Zhao, C. Z.; Huang, J. Q.; He, C.; Zhang, J.; Chen, S.; Xu, L.; Yuan, H.; Zhang, Q. Small 2019, 15, 1805389. doi: 10.1002/smll.201805389 doi: 10.1002/smll.201805389
53. [53]
  Xu, L.; Tang, S.; Cheng, Y.; Wang, K.; Liang, J.; Liu, C.; Cao, Y. C.; Wei, F.; Mai, L. Joule 2018, 2, 1991. doi: 10.1016/j.joule.2018.07.009 doi: 10.1016/j.joule.2018.07.009
54. [54]
  Wenzel, S.; Weber, D. A.; Leichtweiss, T.; Busche, M. R.; Sann, J.; Janek, J. Solid State Ionics 2016, 286, 24. doi: 10.1016/j.ssi.2015.11.034 doi: 10.1016/j.ssi.2015.11.034
55. [55]
  Wenzel, S.; Leichtweiss, T.; Krüger, D.; Sann, J.; Janek, J. Solid State Ionics 2015, 278, 98. doi: 10.1016/j.ssi.2015.06.001 doi: 10.1016/j.ssi.2015.06.001
56. [56]
  Swamy, T.; Chen, X.; Chiang, Y. M. Chem. Mater. 2019, 31, 707. doi: 10.1021/acs.chemmater.8b03420 doi: 10.1021/acs.chemmater.8b03420
57. [57]
  Zhang, Q.; Huang, N.; Huang, Z.; Cai, L.; Wu, J.; Yao, X. J. Energy Chem. 2020, 40, 151. doi: 10.1016/j.jechem.2019.03.006 doi: 10.1016/j.jechem.2019.03.006
58. [58]
  Tan, D. H. S.; Wu, E. A.; Nguyen, H.; Chen, Z.; Marple, M. A. T.; Doux, J. M.; Wang, X.; Yang, H.; Banerjee, A. Meng, Y. S. ACS Energy Lett. 2019, 4, 2418. doi: 10.1021/acsenergylett.9b01693 doi: 10.1021/acsenergylett.9b01693
59. [59]
  Sang, L.; Haasch, R. T.; Gewirth, A. A.; Nuzzo, R. G. Chem. Mater. 2017, 29, 3029. doi: 10.1021/acs.chemmater.7b00034 doi: 10.1021/acs.chemmater.7b00034
60. [60]
  Zhang, W.; Leichtweiß, T.; Culver, S. P.; Koerver, R.; Das, D.; Weber, D. A.; Zeier, W. G.; Janek, J. ACS Appl. Mater. Interfaces 2017, 9, 35888. doi: 10.1021/acsami.7b11530 doi: 10.1021/acsami.7b11530
61. [61]
  Doux, J. M.; Nguyen, H.; Tan, D. H. S.; Banerjee, A.; Wang, X.; Wu, E. A.; Jo, C.; Yang, H.; Meng, Y. S. Adv. Energy Mater. 2019, 10, 1903253. doi: 10.1002/aenm.201903253 doi: 10.1002/aenm.201903253
62. [62]
  Zhao, C. Z.; Zhao, B. C.; Yan, C.; Zhang, X.Q.; Huang, J. Q.; Mo, Y.; Xu, X.; Li, H.; Zhang, Q. Energy Storage Mater. 2019, 24, 75. doi: 10.1016/j.ensm.2019.07.026 doi: 10.1016/j.ensm.2019.07.026
63. [63]
  Liu, H.; Cheng, X. B.; Huang, J. Q.; Yuan, H.; Lu, Y.; Yan, C.; Zhu, G. L.; Xu, R.; Zhao, C. Z.; Hou, L.P.; et al. ACS Energy Lett. 2020, 5, 833. doi: 10.1021/acsenergylett.9b02660 doi: 10.1021/acsenergylett.9b02660
1. [1]
  Mingyang Men , Jinghua Wu , Gaozhan Liu , Jing Zhang , Nini Zhang , Xiayin Yao . 液相法制备硫化物固体电解质及其在全固态锂电池中的应用. Acta Physico-Chimica Sinica, 2025, 41(1): 2309019-. doi: 10.3866/PKU.WHXB202309019
2. [2]
  Jiandong Liu , Zhijia Zhang , Mikhail Kamenskii , Filipp Volkov , Svetlana Eliseeva , Jianmin Ma . Research Progress on Cathode Electrolyte Interphase in High-Voltage Lithium Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100011-. doi: 10.3866/PKU.WHXB202308048
3. [3]
  Xueyu Lin , Ruiqi Wang , Wujie Dong , Fuqiang Huang . 高性能双金属氧化物负极的理性设计及储锂特性. Acta Physico-Chimica Sinica, 2025, 41(3): 2311005-. doi: 10.3866/PKU.WHXB202311005
4. [4]
  Tao Jiang , Yuting Wang , Lüjin Gao , Yi Zou , Bowen Zhu , Li Chen , Xianzeng Li . Experimental Design for the Preparation of Composite Solid Electrolytes for Application in All-Solid-State Batteries: Exploration of Comprehensive Chemistry Laboratory Teaching. University Chemistry, 2024, 39(2): 371-378. doi: 10.3866/PKU.DXHX202308057
5. [5]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
6. [6]
  Qiangqiang SUN , Pengcheng ZHAO , Ruoyu WU , Baoyue CAO . Multistage microporous bifunctional catalyst constructed by P-doped nickel-based sulfide ultra-thin nanosheets for energy-efficient hydrogen production from water electrolysis. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1151-1161. doi: 10.11862/CJIC.20230454
7. [7]
  Zhiyuan TONG , Ziyuan LI , Ke ZHANG . Three-dimensional porous collector based on Cu-Li_6.4La₃Zr_1.4Ta_0.6O₁₂ composite layer for the construction of stable lithium metal anode. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 499-508. doi: 10.11862/CJIC.20240238
8. [8]
  Xiaotian ZHU , Fangding HUANG , Wenchang ZHU , Jianqing ZHAO . Layered oxide cathode for sodium-ion batteries: Surface and interface modification and suppressed gas generation effect. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 254-266. doi: 10.11862/CJIC.20240260
9. [9]
  Aoyu Huang , Jun Xu , Yu Huang , Gui Chu , Mao Wang , Lili Wang , Yongqi Sun , Zhen Jiang , Xiaobo Zhu . Tailoring Electrode-Electrolyte Interfaces via a Simple Slurry Additive for Stable High-Voltage Lithium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100037-. doi: 10.3866/PKU.WHXB202408007
10. [10]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . 钠离子电池中铁基异质结构负极材料的最新研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-. doi: 10.3866/PKU.WHXB202311015
11. [11]
  Pengyu Dong , Yue Jiang , Zhengchi Yang , Licheng Liu , Gu Li , Xinyang Wen , Zhen Wang , Xinbo Shi , Guofu Zhou , Jun-Ming Liu , Jinwei Gao . NbSe₂纳米片优化钙钛矿太阳能电池的埋底界面. Acta Physico-Chimica Sinica, 2025, 41(3): 2407025-. doi: 10.3866/PKU.WHXB202407025
12. [12]
  Junke LIU , Kungui ZHENG , Wenjing SUN , Gaoyang BAI , Guodong BAI , Zuwei YIN , Yao ZHOU , Juntao LI . Preparation of modified high-nickel layered cathode with LiAlO₂/cyclopolyacrylonitrile dual-functional coating. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1461-1473. doi: 10.11862/CJIC.20240189
13. [13]
  Wenqi Gao , Xiaoyan Fan , Feixiang Wang , Zhuojun Fu , Jing Zhang , Enlai Hu , Peijun Gong . Exploring Nernst Equation Factors and Applications of Solid Zinc-Air Battery. University Chemistry, 2024, 39(5): 98-107. doi: 10.3866/PKU.DXHX202310026
14. [14]
  Bowen Yang , Rui Wang , Benjian Xin , Lili Liu , Zhiqiang Niu . C-SnO₂/MWCNTs Composite with Stable Conductive Network for Lithium-based Semi-Solid Flow Batteries. Acta Physico-Chimica Sinica, 2025, 41(2): 100015-. doi: 10.3866/PKU.WHXB202310024
15. [15]
  Zeyuan WANG , Songzhi ZHENG , Hao LI , Jingbo WENG , Wei WANG , Yang WANG , Weihai SUN . Effect of I₂ interface modification engineering on the performance of all-inorganic CsPbBr₃ perovskite solar cells. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1290-1300. doi: 10.11862/CJIC.20240021
16. [16]
  Jizhou Liu , Chenbin Ai , Chenrui Hu , Bei Cheng , Jianjun Zhang . 六氯锡酸铵促进钙钛矿太阳能电池界面电子转移及其飞秒瞬态吸收光谱研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2402006-. doi: 10.3866/PKU.WHXB202402006
17. [17]
  Xiaoyao YIN , Wenhao ZHU , Puyao SHI , Zongsheng LI , Yichao WANG , Nengmin ZHU , Yang WANG , Weihai SUN . Fabrication of all-inorganic CsPbBr₃ perovskite solar cells with SnCl₂ interface modification. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 469-479. doi: 10.11862/CJIC.20240309
18. [18]
  Qiuyang LUO , Xiaoning TANG , Shu XIA , Junnan LIU , Xingfu YANG , Jie LEI . Application of a densely hydrophobic copper metal layer in-situ prepared with organic solvents for protecting zinc anodes. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1243-1253. doi: 10.11862/CJIC.20240110
19. [19]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
20. [20]
  Junli Liu . Practice and Exploration of Research-Oriented Classroom Teaching in the Integration of Science and Education: a Case Study on the Synthesis of Sub-Nanometer Metal Oxide Materials and Their Application in Battery Energy Storage. University Chemistry, 2024, 39(10): 249-254. doi: 10.12461/PKU.DXHX202404023

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(650)
HTML views(134)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142