Citation: Yang Tianyi, Cui Cheng, Rong Hongpan, Zhang Jiatao, Wang Dingsheng. Recent Advances in Platinum-based Intermetallic Nanocrystals: Controlled Synthesis and Electrocatalytic Applications[J]. Acta Physico-Chimica Sinica, ;2020, 36(9): 200304. doi: 10.3866/PKU.WHXB202003047 shu

Recent Advances in Platinum-based Intermetallic Nanocrystals: Controlled Synthesis and Electrocatalytic Applications

1.
Beijing Key Laboratory of Construction-Tailorable Advanced Functional Materials and Green Applications, School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China
2.
Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China

Corresponding author: Rong Hongpan, rhp@bit.edu.cn Wang Dingsheng, wangdingsheng@mail.tsinghua.edu.cn
Received Date: 19 March 2020
Revised Date: 15 April 2020
Accepted Date: 17 April 2020
Available Online: 24 April 2020
Fund Project: the Beijing Municipal Science & Technology Commission, China Z191100007219003the National Natural Science Foundation of China 51902023the National Natural Science Foundation of China 51631001the National Natural Science Foundation of China 21671117the National Key R&D Program of China 2018YFA0702003the National Natural Science Foundation of China 51872030The project was supported by the Beijing Institute of Technology Research Fund Program for Young Scholars, China, the National Key R&D Program of China (2018YFA0702003, 2016YFA0202801), the National Natural Science Foundation of China (51631001, 51872030, 51702016, 51902023, 21801015, 21890383, 21671117, 21871159), and the Beijing Municipal Science & Technology Commission, China (Z191100007219003)the National Natural Science Foundation of China 21801015the National Natural Science Foundation of China 51702016the National Natural Science Foundation of China 21871159the National Key R&D Program of China 2016YFA0202801the National Natural Science Foundation of China 21890383

Fuel cells, whose energy source can be hydrogen, formic acid, methanol, or ethanol, have received considerable attention in recent years because of their environmentally friendly characteristics. A high Pt loading is often required to achieve a practical power density in fuel cells, thus leading to high costs and limited applications. Meanwhile, the high Pt loading promotes aggregation during cycling under harsh electrocatalytic conditions, which reduces the surface area of the catalyst and leads to a decrease in catalytic activity. The formation of alloy or intermetallic nanocrystals via the addition of non-precious metals along with precious metals is one strategy to effectively reduce the cost. Due to the electronic and geometric effects introduced by the non-precious metals, the catalytic performance of these bimetallic nanocrystals can be retained or even improved. Compared to the metallic alloy nanocrystals, the intermetallic ones are more stable in critical catalytic conditions. Due to their highly ordered structures, Pt-based intermetallic nanocrystals are widely used as electrode materials for various electrocatalytic reactions in fuel cells, and they show high stability against oxidation and etching. PtCo intermetallic nanocrystals have attained performances that exceed the 2020 target of the U.S. Department of Energy (DOE) for Pt activity and stability for the cathode reaction of fuel cells (oxygen reduction reaction). Decreasing the size of intermetallic compounds to the nanometer scale can significantly increase their active site densities due to the large specific surface area. However, the preparation of intermetallic nanocrystals is more complicated than that of alloys. Therefore, to further improve the electrocatalytic properties of intermetallic nanocrystals, an in-depth study of the factors affecting the electrocatalytic properties of nanocrystals is necessary. This review summarizes recent advances in Pt-based intermetallic nanocrystals. First, we highlight the controlled synthesis strategies, including direct liquid-phase synthesis, the thermal annealing approach, and chemical vapor deposition. Of these strategies, direct liquid-phase synthesis is the most common approach to prepare the intermetallic nanocrystals. Second, the diverse potential applications of different electrocatalytic reactions are summarized. The reactions include the hydrogen evolution reaction (HER), oxygen reduction reaction (ORR), and hydrogen oxidation reaction (HOR), as well as the oxidation reactions of formic acid (FAOR), methanol (MOR), and ethanol (EtOR). Of these reactions, ORR is the most important, and it has been widely studied. Some advanced characterization techniques and machine learning research based on density functional theory (DFT) are also mentioned. Finally, the challenges and the future perspectives of intermetallic nanocrystals are outlined.
- Platinum-based intermetallic compounds,
- Nanocrystals,
- Controlled synthesis,
- Structure-ordered,
- Electrocatalytic reactions
1. [1]
  Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741 doi: 10.1126/science.1212741
2. [2]
  Xu, Q.; Guo, C.; Tian, S.; Zhang, J.; Chen, W.; Cheong, W.; Gu, L.; Zheng, L.; Xiao, J.; Liu, Q.; et al. Sci. China Mater. 2020, doi: 10.1007/s40843-020-1334-6 doi: 10.1007/s40843-020-1334-6
3. [3]
  Xiong, Y.; Dong, J.; Zheng, Q.; Xin, P.; Chen, W.; Wang, Y.; Li, Z.; Jin, Z.; Xing, W.; Zhuang, Z.; et al. Nat. Nanotechnol. 2020, doi: 10.1038/s41565-020-0665-x doi: 10.1038/s41565-020-0665-x
4. [4]
  Li, X.; Rong, H.; Zhang, J.; Wang, D.; Li, Y. Nano Res. 2020, doi: 10.1007/s12274-020-2755-3 doi: 10.1007/s12274-020-2755-3
5. [5]
  Sun, T.; Xu, L.; Wang, D.; Li, Y. Nano Res. 2019, 12, 2067. doi: 10.1007/s12274-019-2345-4 doi: 10.1007/s12274-019-2345-4
6. [6]
  Huang, L.; Jiang, Z.; Gong, W.; Shen, P. K. Appl. Nano Mater. 2018, 1, 5019. doi: 10.1021/acsanm.8b01113 doi: 10.1021/acsanm.8b01113
7. [7]
  Huang, L.; Zhang, X.; Wang, Q.; Han, Y.; Fang, Y.; Dong, S. J. Am. Chem. Soc. 2018, 140, 1142. doi: 10.1021/jacs.7b12353 doi: 10.1021/jacs.7b12353
8. [8]
  Xue, S.; Deng, W.; Yang, F.; Yang, J.; Amiinu, I. S.; He, D.; Tang, H.; Mu, S. ACS Catal. 2018, 8, 7578. doi: 10.1021/acscatal.8b00366 doi: 10.1021/acscatal.8b00366
9. [9]
  US Department of Energy. (2018). DOE technical targets for polymer electrolyte membrane fuel cell components. https://www.energy.gov/eere/fuelcells/doe-technicaltargets-polymer-electrolyte-membrane-fuelcell-components
10. [10]
  Fu, K.; Zeng, L.; Liu, J.; Liu, M.; Li, S.; Guo, W.; Gao, Y.; Pan, M. J. Alloys Compd. 2020, 815, 152374. doi: 10.1016/j.jallcom.2019.152374 doi: 10.1016/j.jallcom.2019.152374
11. [11]
  Liu, L.; Corma, A. Chem. Rev. 2018, 118, 4981. doi: 10.1021/acs.chemrev.7b00776 doi: 10.1021/acs.chemrev.7b00776
12. [12]
  Robinson, J. E.; Labrador, N. Y.; Chen, H.; Sartor, B. E.; Esposito, D. V. ACS Catal. 2018, 8, 11423. doi: 10.1021/acscatal.8b03626 doi: 10.1021/acscatal.8b03626
13. [13]
  Wu, Z.; Bukowski, B. C.; Li, Z.; Milligan, C.; Zhou, L.; Ma, T.; Wu, Y.; Ren, Y.; Ribeiro, F. H.; Delgass, W. N.; et al. J. Am. Chem. Soc. 2018, 140, 14870. doi: 10.1021/jacs.8b08162
14. [14]
  Zhao, X.; Liu, X.; Huang, B.; Wang, P.; Pei, Y. J. Mater. Chem. A 2019, 7, 24583. doi: 10.1039/c9ta08661g doi: 10.1039/c9ta08661g
15. [15]
  Xiao, W.; Lei, W.; Gong, M.; Xin, H. L.; Wang, D. ACS Catal. 2018, 8, 3237. doi: 10.1021/acscatal.7b04420 doi: 10.1021/acscatal.7b04420
16. [16]
  Li, J.; Sun, S. Acc. Chem. Res. 2019, 52, 2015. doi: 10.1021/acs.accounts.9b00172 doi: 10.1021/acs.accounts.9b00172
17. [17]
  Karamad, M.; Tripkovic, V.; Rossmeisl, J. ACS Catal. 2014, 4, 2268. doi: 10.1021/cs500328c doi: 10.1021/cs500328c
18. [18]
  Zhu, Y.; Yuan, M.; Deng, L.; Ming, R.; Zhang, A.; Yang, M.; Chai, B.; Ren, Z. RSC Adv. 2017, 7, 1553. doi: 10.1039/c6ra24754g doi: 10.1039/c6ra24754g
19. [19]
  Magno, L. M.; Sigle, W.; van Aken, P. A.; Angelescu, D.; Stubenrauch, C. Phys. Chem. Chem. Phys. 2011, 13, 9134. doi: 10.1039/c1cp20159j doi: 10.1039/c1cp20159j
20. [20]
  Wang, C.; Sang, X.; Gamler, J. T. L.; Chen, D. P.; Unocic, R. R.; Skrabalak, S. E. Nano Lett. 2017, 17, 5526. doi: 10.1021/acs.nanolett.7b02239 doi: 10.1021/acs.nanolett.7b02239
21. [21]
  Thompson, S. T.; James, B. D.; Huya-Kouadio, J. M.; Houchins, C.; DeSantis, D. A.; Ahluwalia, R.; Wilson, A. R.; Kleen, G.; Papageorgopoulos, D. J. Power Sources 2018, 399, 304. doi: 10.1016/j.jpowsour.2018.07.100 doi: 10.1016/j.jpowsour.2018.07.100
22. [22]
  Li, J.; Sharma, S.; Liu, X.; Pan, Y.; Spendelow, J. S.; Chi, M.; Jia, Y.; Zhang, P.; Cullen, D. A.; Cullen, D. A.; Xi, Z.; et al. Joule 2019, 3, 124. doi: 10.1016/j.joule.2018.09.016 doi: 10.1016/j.joule.2018.09.016
23. [23]
  Wang, X. X.; Swihart, M. T.; Wu, G. Nat. Catal. 2019, 2, 578. doi: 10.1038/s41929-019-0304-9 doi: 10.1038/s41929-019-0304-9
24. [24]
  Bortoloti, F.; Garcia, A. C.; Angelo, A. C. D. Int. J. Int. J. Hydrogen Energy 2015, 40, 10816. doi: 10.1016/j.ijhydene.2015.06.145 doi: 10.1016/j.ijhydene.2015.06.145
25. [25]
  Santos, E.; Pinto, L. M. C.; Soldano, G.; Innocente, A. F.; Ângelo, A. C. D.; Schmickler, W. Catal. Today 2013, 202, 191. doi: 10.1016/j.cattod.2012.07.044 doi: 10.1016/j.cattod.2012.07.044
26. [26]
  Rong, H.; Mao, J.; Xin, P.; He, D.; Chen, Y.; Wang, D.; Niu, Z.; Wu, Y.; Li, Y. Adv. Mater. 2016, 28, 2540. doi: 10.1002/adma.201504831 doi: 10.1002/adma.201504831
27. [27]
  Russell, A. E. Faraday Discuss. 2008, 140, 9. doi: 10.1039/b814058h doi: 10.1039/b814058h
28. [28]
  You, G.; Jiang, J.; Li, M.; Li, L.; Tang, D.; Zhang, J.; Zeng, X. C.; He, R. ACS Catal. 2017, 8, 132. doi: 10.1021/acscatal.7b02698 doi: 10.1021/acscatal.7b02698
29. [29]
  Cui, Z.; Chen, H.; Zhao, M.; Marshall, D.; Yu, Y.; Abruna, H.; DiSalvo, F. J. J. Am. Chem. Soc. 2014, 136, 29. doi: 10.1021/ja504573a doi: 10.1021/ja504573a
30. [30]
  Liao, H.; Zhu, J.; Hou, Y. Nanoscale 2014, 6, 1049. doi: 10.1039/c3nr05590f doi: 10.1039/c3nr05590f
31. [31]
  Qi, Z.; Xiao, C.; Liu, C.; Goh, T. W.; Zhou, L.; Maligal-Ganesh, R.; Pei, Y.; Li, X.; Curtiss, L. A.; Huang, W. J. Am. Chem. Soc. 2017, 139, 4762. doi: 10.1021/jacs.6b12780 doi: 10.1021/jacs.6b12780
32. [32]
  Yuan, X.; Jiang, X.; Cao, M.; Chen, L.; Nie, K.; Zhang, Y.; Xu, Y.; Sun, X.; Li, Y.; Zhang, Q. Nano Res. 2018, 12, 429. doi: 10.1007/s12274-018-2234-2 doi: 10.1007/s12274-018-2234-2
33. [33]
  Wang, Q.; Chen, S.; Li, P.; Ibraheem, S.; Li, J.; Deng, J.; Wei, Z. Appl. Catal., B 2019, 252, 120. doi: 10.1016/j.apcatb.2019.04.023 doi: 10.1016/j.apcatb.2019.04.023
34. [34]
  Furukawa, S.; Komatsu, T. ACS Catal. 2017, 7, 735. doi: 10.1021/acscatal.6b02603 doi: 10.1021/acscatal.6b02603
35. [35]
  Abe, H.; Matsumoto, F.; Alden, L. R.; Warren, S. C.; Abruña, H. D.; DiSalvo, F. J. J. Am. Chem. Soc. 2008, 130, 5452. doi: 10.1021/ja075061c doi: 10.1021/ja075061c
36. [36]
  Yan, Y.; Du, J. S.; Gilroy, K. D.; Yang, D.; Xia, Y.; Zhang, H. Adv. Mater. 2017, 29, 1605997. doi: 10.1002/adma.201605997 doi: 10.1002/adma.201605997
37. [37]
  Wang, D.; Peng, Q.; Li, Y. Nano Res. 2010, 3, 574. doi: 10.1007/s12274-010-0018-4 doi: 10.1007/s12274-010-0018-4
38. [38]
  Chen, Q. L.; Zhang, J. W.; Jia, Y. Y.; Jiang, Z. Y.; Xie, Z. X.; Zheng, L. S. Nanoscale 2014, 6, 7019. doi: 10.1039/c4nr00313f doi: 10.1039/c4nr00313f
39. [39]
  Dong, H.; Chen, Y. C.; Feldmann, C. Green Chem. 2015, 17, 4107. doi: 10.1039/c5gc00943j doi: 10.1039/c5gc00943j
40. [40]
  Teichert, J.; Heise, M.; Chang, J. H.; Ruck, M. Eur. J. Inorg. Chem. 2017, 42, 4930. doi: 10.1002/ejic.201700966 doi: 10.1002/ejic.201700966
41. [41]
  Chen, W.; Lei, Z.; Zeng, T.; Wang, L.; Cheng, N. C.; Tan, Y. Y.; Mu, S. C. Nanoscale 2019, 11, 19895. doi: 10.1039/c9nr07245d doi: 10.1039/c9nr07245d
42. [42]
  Bauer, J. C.; Chen, X.; Liu, Q. S.; Phan, T. H.; Schaak, R. E. J. Mater. Chem. 2008, 18, 275. doi: 10.1039/b712035d doi: 10.1039/b712035d
43. [43]
  Bu, L.; Zhang, N.; Guo, S; Zhang, X.; Li, J; Yao, J.; Wu, T.; Lu, G.; Ma, J.; Su, D.; et al. Science 2016, 354, 1410. doi: 10.1126/science.aah6133 doi: 10.1126/science.aah6133
44. [44]
  Feng, Q.; Zhao, S.; He, D.; Tian, S.; Gu, L.; Wen, X.; Chen, C.; Peng, Q.; Wang, D.; Li, Y. J. Am. Chem. Soc. 2018, 140, 2773. doi: 10.1021/jacs.7b13612 doi: 10.1021/jacs.7b13612
45. [45]
  Luo, S.; Chen, W.; Cheng, Y.; Song, X.; Wu, Q; Li, L.; Wu, X.; Wu, T.; Li, M.; Yang, Q.; et al. Adv. Mater. 2019, 31, 1903683. doi: 10.1002/adma.201903683 doi: 10.1002/adma.201903683
46. [46]
  Kim, J.; Lee, Y.; Sun, S. H. J. Am. Chem. Soc. 2010, 132, 14. doi: 10.1021/ja1009629 doi: 10.1021/ja1009629
47. [47]
  Gamler, J. T. L.; Ashberry, H. M.; Skrabalak, S. E.; Koczkur, K. M. Adv. Mater. 2018, 30, 40. doi: 10.1002/adma.201801563 doi: 10.1002/adma.201801563
48. [48]
  Li, J.; Xi, Z.; Pan, Y.; Spendelow, Jacob S.; Duchesne, Paul N.; Su, D.; Li, Q.; Yu, C.; Yin, Z.; Shen, B.; et al. J. Am. Chem. Soc. 2018, 140, 2926. doi: 10.1021/jacs.7b12829 doi: 10.1021/jacs.7b12829
49. [49]
  Wang, D.; Xin, H. L.; Hovden, R.; Wang, H.; Yu, Y.; Muller, D. A.; DiSalvo, F. J.; Abruña, H. D. Nat. Mater. 2012, 12, 81. doi: 10.1038/nmat3458 doi: 10.1038/nmat3458
50. [50]
  Shim, J.; Lee, J.; Ye, Y.; Hwang, J.; Kim, S. K.; Lim, T. H.; Wiesner, U.; Lee, J. ACS Nano 2012, 6, 8. doi: 10.1021/nn301692y doi: 10.1021/nn301692y
51. [51]
  Zhang, B. -W.; Jiang, Y. -X.; Ren, J.; Qu, X. -M.; Xu, G. -L.; Sun, S. -G. Electrochim. Acta 2015, 162, 254. doi: 10.1016/j.electacta.2014.09.159 doi: 10.1016/j.electacta.2014.09.159
52. [52]
  Zhang, G.; Yang, Z.; Zhang, W.; Hu, H.; Wang, C.; Huang, C.; Wang, Y. Nanoscale 2016, 8, 3075. doi: 10.1039/c5nr08013d doi: 10.1039/c5nr08013d
53. [53]
  Kim, J.; Rong, C.; Liu, J. P.; Sun, S. Adv. Mater. 2009, 21, 906. doi: 10.1002/adma.200801620 doi: 10.1002/adma.200801620
54. [54]
  Kim, J.; Rong, C.; Lee, Y.; Liu, J. P.; Sun, S. Chem. Mater. 2008, 20, 7242. doi: 10.1021/cm8024878 doi: 10.1021/cm8024878
55. [55]
  Yu, J.; Gao, W.; Liu, F.; Ju, Y.; Zhao, F.; Yang, Z.; Chu, X.; Che, S.; Hou, Y. Sci. China Mater. 2018, 61, 961. doi: 10.1007/s40843-017-9203-9 doi: 10.1007/s40843-017-9203-9
56. [56]
  Han, A.; Zhang, J.; Sun, W.; Chen, W.; Zhang, S.; Hang, Y.; Feng, Q.; Zheng, L.; Gu, L.; Chen, C.; et al. Nat. Commun. 2019, 10, 3787. doi: 10.1038/s41467-019-11794-6 doi: 10.1038/s41467-019-11794-6
57. [57]
  Li, Q.; Wu, L.; Wu, G.; Su, D.; Lu, H.; Zhang, S.; Zhu, W.; Casimir, A.; Zhu, H.; Mendoza-Garcia, A.; et al. Nano Lett. 2015, 15, 2468. doi: 10.1021/acs.nanolett.5b00320 doi: 10.1021/acs.nanolett.5b00320
58. [58]
  Zhang, S.; Guo, S.; Zhu, H.; Su, D.; Sun, S. J. Am. Chem. Soc. 2012, 134, 5060. doi: 10.1021/ja300708j doi: 10.1021/ja300708j
59. [59]
  Zhang, S.; Zhang, X.; Jiang, G.; Zhu, H.; Guo, S.; Su, D.; Lu, G.; Sun, S. J. Am. Chem. Soc. 2014, 136, 7734. doi: 10.1021/ja5030172 doi: 10.1021/ja5030172
60. [60]
  Bernal, S.; Calvino, J. J.; Gatica, J. M.; Larese, C.; López-Cartes, C.; Pérez-Omil, J. A. J. Catal. 1997, 169, 510. doi: 10.1006/jcat.1997.1707 doi: 10.1006/jcat.1997.1707
61. [61]
  Li, Z.; Qi, Z.; Wang, S.; Ma, T.; Zhou, L.; Wu, Z.; Luan, X.; Lin, F.; Chen, M.; Miller, J.; et al. Nano Lett. 2019, 19, 5102. doi: 10.1021/acs.nanolett.9b01381 doi: 10.1021/acs.nanolett.9b01381
62. [62]
  Huang, L. L.; Liu, M.; Lin, H. X.; Xu, Y. B.; Wu, J. S.; Dravid, V. P.; Wolverton, C.; Mirkin, C. A. Science 2019, 365, 1159. doi: 10.1126/science.aax5843 doi: 10.1126/science.aax5843
63. [63]
  Komatsu, T.; Mesuda, M.; Yashima, T. Appl. Catal. A 2000, 194, 333. doi: 10.1016/S0926-860X(99)00379-8 doi: 10.1016/S0926-860X(99)00379-8
64. [64]
  Saedy, S.; Palagin, D.; Safonova, O.; van Bokhoven, J. A.; Khodadadi, A. A.; Mortazavi, Y. J. Mater. Chem. A 2017, 5, 24396. doi: 10.1039/C7TA06737B doi: 10.1039/C7TA06737B
65. [65]
  Geisler, A. H.; Martin, D. L. J. Appl. Phys. 1952, 23, 375. doi: 10.1063/1.1702216 doi: 10.1063/1.1702216
66. [66]
  Na, H.; Choi, H.; Oh, J. W.; Jung, Y. S.; Cho, Y. S. ACS Appl. Mater. Interfaces 2019, 11, 25179. doi: 10.1021/acsami.9b06159 doi: 10.1021/acsami.9b06159
67. [67]
  Chung, D.; Jun, S.; Yoon, G.; Kwon, S.; Shin, D.; Seo, P; Yoo, J.; Shin, H.; Chung, Y.; Kim, H.; et al. J. Am. Chem. Soc. 2015, 137, 15478. doi: 10.1021/jacs.5b09653 doi: 10.1021/jacs.5b09653
68. [68]
  Lim, S. C.; Chan, C. Y.; Chen, K. T.; Tuan, H. Y. Electrochim. Acta 2019, 297, 288. doi: 10.1016/j.electacta.2018.11.152 doi: 10.1016/j.electacta.2018.11.152
69. [69]
  Lim, S. C.; Hsiao, M. C.; Lu, M. D.; Tung, Y. L.; Tuan, H. Y. Nanoscale 2018, 10, 16657. doi: 10.1039/c8nr03983f doi: 10.1039/c8nr03983f
70. [70]
  Maccio, D.; Rosalbino, F.; Saccone, A.; Delfino, S. J. Alloys Compd. 2005, 391, 60. doi: 10.1016/j.jallcom.2004.08.050 doi: 10.1016/j.jallcom.2004.08.050
71. [71]
  Strasser, P.; Kuhl, S. Nano Energy 2016, 29, 166. doi: 10.1016/j.nanoen.2016.04.047 doi: 10.1016/j.nanoen.2016.04.047
72. [72]
  Rößner, L.; Armbrüster, M. ACS Catal. 2019, 9, 2018. doi: 10.1021/acscatal.8b04566 doi: 10.1021/acscatal.8b04566
73. [73]
  Leidheiser, H. J. Am. Chem. Soc. 1949, 71, 3634. doi: 10.1021/ja01179a015 doi: 10.1021/ja01179a015
74. [74]
  Wang, X. X.; Hwang, S.; Pan, Y. T.; Chen, K.; He, Y. H.; Karakalos, S.; Zhang, H. G.; Spendelow, J. S.; Su, D.; Wu, G. Nano Lett. 2018, 18, 4163. doi: 10.1021/acs.nanolett.8b00978 doi: 10.1021/acs.nanolett.8b00978
75. [75]
  Gokhale, R.; Chen, Y. C.; Serov, A.; Artyushkova, K.; Atanassov, P. Electrochim. Acta 2017, 224, 49. doi: 10.1016/j.electacta.2016.12.052 doi: 10.1016/j.electacta.2016.12.052
76. [76]
  Xiong, Y.; Xiao, L.; Yang, Y.; DiSalvo, F. J.; Abruna, H. D. Chem. Mater. 2018, 30, 1532. doi: 10.1021/acs.chemmater.7b04201 doi: 10.1021/acs.chemmater.7b04201
77. [77]
  Zhu, H.; Luo, M. C.; Cai, Y. Z.; Sun, Z. N. Acta Phys. -Chim. Sin. 2016, 32, 2462. doi: 10.3866/PKU.WHXB201606293
78. [78]
  Kuttiyiel, K.; Kattel, S.; Cheng, S.; Lee, J.; Wu, L.; Zhu, Y.; Park, G.; Liu, P.; Sasaki, K.; Chen, J.; et al. ACS Appl. Energy Mater. 2018, 1, 3771. doi: 10.1021/acsaem.8b00555 doi: 10.1021/acsaem.8b00555
79. [79]
  Wang, G. W.; Huang, B.; Xiao, L.; Ren, Z. D.; Chen, H.; Wang, D. L.; Abruna, H. D.; Lu, J. T.; Zhuang, L. J. Am. Chem. Soc. 2014, 136, 9643. doi: 10.1021/ja503315s doi: 10.1021/ja503315s
80. [80]
  Xiao, W.; Cordeiro, M.; Gao, G.; Zheng, A.; Wang, J.; Lei, W.; Gong, M.; Lin, R.; Stavitski, E.; Xin, H.; et al. Nano Energy 2018, 50, 70. doi: 10.1016/j.nanoen.2018.05.032 doi: 10.1016/j.nanoen.2018.05.032
81. [81]
  Masuda, T.; Fukumitsu, H.; Fugane, K.; Togasaki, H.; Matsumura, D.; Tamura, K.; Matsumura, D.; Tamura, K.; Nishihata, Y.; Yoshikawa, H.; Kobayashi, K.; Mori, T.; et al. J. Phys. Chem. C 2012, 116, 10098. doi: 10.1021/jp301509t doi: 10.1021/jp301509t
82. [82]
  Sasaki, K.; Zhang, L.; Adzic, R. R. Phys. Chem. Chem. Phys. 2008, 10, 159. doi: 10.1039/b709893f doi: 10.1039/b709893f
83. [83]
  Wang, Y. -J.; Zhao, N.; Fang, B.; Li, H.; Bi, X. T.; Wang, H. Chem. Rev. 2015, 115, 3433. doi: 10.1021/cr500519c doi: 10.1021/cr500519c
84. [84]
  Luo, M.; Sun, Y.; Wang, L.; Guo, S. Adv. Energy Mater. 2017, 7, 11. doi: 10.1002/aenm.201602073 doi: 10.1002/aenm.201602073
85. [85]
  Antolini, E. Appl. Catal. B 2017, 217, 201. doi: 10.1016/j.apcatb.2017.05.081 doi: 10.1016/j.apcatb.2017.05.081
86. [86]
  Liang, J.; Miao, Z.; Ma, F.; Pan, R.; Chen, X.; Wang, T.; Xie, H.; Li, Q. Chin. J. Catal. 2018, 39, 583. doi: 10.1016/S1872-2067(17)62989-9 doi: 10.1016/S1872-2067(17)62989-9
87. [87]
  Chen, X.; McCrum, I. T.; Schwarz, K. A.; Janik, M. J.; Koper, M. T. M. Angew. Chem. Int. Ed. 2017, 56, 15025. doi: 10.1002/anie.201709455 doi: 10.1002/anie.201709455
88. [88]
  Park, E. D.; Lee, D.; Lee, H. C. Catal. Today 2009, 139, 280. doi: 10.1016/j.cattod.2008.06.027 doi: 10.1016/j.cattod.2008.06.027
89. [89]
  Innocente, A. F.; Ângelo, A. C. D. J. Power Sources 2008, 175, 779. doi: 10.1016/j.jpowsour.2007.10.001 doi: 10.1016/j.jpowsour.2007.10.001
90. [90]
  Liu, Z.; Jackson, G. S.; Eichhorn, B. W. Energy Environ. Sci. 2011, 4, 1900. doi: 10.1039/C1EE01125A doi: 10.1039/C1EE01125A
91. [91]
  Neurock, M.; Janik, M.; Wieckowski, A. Faraday Discuss. 2009, 140, 363. doi: 10.1039/B804591G doi: 10.1039/B804591G
92. [92]
  Xu, H.; Yan, B.; Li, S.; Wang, J.; Wang, C.; Guo, J.; Du, Y. Chem. Eng. J. 2018, 334, 2638. doi: 10.1016/j.cej.2017.10.175 doi: 10.1016/j.cej.2017.10.175
93. [93]
  Zhu, J.; Zheng, X.; Wang, J.; Wu, Z.; Han, L.; Lin, R.; Xin, H. L.; Wang, D. J. Mater. Chem. A 2015, 3, 22129. doi: 10.1039/C5TA05699C doi: 10.1039/C5TA05699C
94. [94]
  Ramesh, G. V.; Kodiyath, R.; Tanabe, T.; Manikandan, M.; Fujita, T.; Umezawa, N.; Ueda, S.; Ishihara, S.; Ariga, K.; Abe, H. ACS Appl. Mater. Interfaces 2014, 6, 16124. doi: 10.1021/am504147q doi: 10.1021/am504147q
95. [95]
  Ghosh, T.; Zhou, Q.; Gregoire, J. M.; van Dover, R. B.; DiSalvo, F. J. J. Phys. Chem. C 2010, 114, 12545. doi: 10.1021/jp101175m doi: 10.1021/jp101175m
96. [96]
  Casado-Rivera, E.; Gál, Z.; Angelo, A. C. D.; Lind, C.; DiSalvo, F. J.; Abruña, H. D. ChemPhysChem 2003, 4, 193. doi: 10.1002/cphc.200390030 doi: 10.1002/cphc.200390030
97. [97]
  Ji, X.; Lee, K. T.; Holden, R.; Zhang, L.; Zhang, J.; Botton, G. A.; Couillard, M.; Nazar, L. F. Nat. Chem. 2010, 2, 286. doi: 10.1038/nchem.553 doi: 10.1038/nchem.553
98. [98]
  Casado-Rivera, E.; Volpe, D. J.; Alden, L.; Lind, C.; Downie, C.; Vázquez-Alvarez, T.; Angelo, A. C. D.; DiSalvo, F. J.; Abruña, H. D. J. Am. Chem. Soc. 2004, 126, 4043. doi: 10.1021/ja038497a doi: 10.1021/ja038497a
99. [99]
  Pan, Y. -T.; Yan, Y.; Shao, Y. -T.; Zuo, J. -M.; Yang, H. Nano Lett. 2016, 16, 6599. doi: 10.1021/acs.nanolett.6b03302 doi: 10.1021/acs.nanolett.6b03302
100. [100]
  Kang, Y.; Murray, C. B. J. Am. Chem. Soc. 2010, 132, 7568. doi: 10.1021/ja100705j doi: 10.1021/ja100705j
101. [101]
  Ghosh, T.; Leonard, B. M.; Zhou, Q.; DiSalvo, F. J. Chem. Mater. 2010, 22, 2190. doi: 10.1021/cm9018474 doi: 10.1021/cm9018474
102. [102]
  Feng, Y.; Liu, H.; Yang, J. Sci. Adv. 2017, 3, e1700580. doi: 10.1126/sciadv.1700580 doi: 10.1126/sciadv.1700580
103. [103]
  Sanetuntikul, J.; Ketpang, K.; Shanmugam, S. ACS Catal. 2015, 5, 7321. doi: 10.1021/acscatal.5b01390 doi: 10.1021/acscatal.5b01390
104. [104]
  Zhang, B.; Sheng, T.; Wang, Y.; Qu, X.; Zhang, J.; Zhang, Z.; Liao, H.; Zhu, F.; Dou, S.; Jiang, Y.; et al. ACS Catal. 2017, 7, 892. doi: 10.1021/acscatal.6b03021 doi: 10.1021/acscatal.6b03021
105. [105]
  Mikhailova, A. A.; Pasynskii, A. A.; Grinberg, V. A.; Velikodnyi, Y. A.; Khazova, O. A. Russ. J. Electrochem. 2010, 46, 26. doi: 10.1134/s1023193510010039 doi: 10.1134/s1023193510010039
106. [106]
  Herranz, T.; Ibáñez, M.; Gómez de la Fuente, J. L.; Pérez-Alonso, F. J.; Peña, M. A.; Cabot, A.; Rojas, S. ChemElectroChem 2014, 1, 885. doi: 10.1002/celc.201300254 doi: 10.1002/celc.201300254
107. [107]
  Kwak, D. -H.; Lee, Y. -W.; Han, S. -B.; Hwang, E. -T.; Park, H. -C.; Kim, M. -C.; Park, K. -W. J. Power Sources 2015, 275, 557. doi: 10.1016/j.jpowsour.2014.11.050 doi: 10.1016/j.jpowsour.2014.11.050
108. [108]
  Ramesh, G.; Kodiyath, R.; Tanabe, T.; Manikandan, M.; Fujita, T.; Matsumoto, F.; Ishihara, S.; Ueda, S.; Yamashita, Y.; Ariga, K.; et al. ChemElectroChem 2014, 1, 728. doi: 10.1002/celc.201300240 doi: 10.1002/celc.201300240
109. [109]
  Sun, Y.; Liang, Y.; Luo, M.; Lv, F.; Qin, Y.; Wang, L.; Xu, C.; Fu, E.; Guo, S. Small 2018, 14, 1702259. doi: 10.1002/smll.201702259 doi: 10.1002/smll.201702259
110. [110]
  Gunji, T.; Tanabe, T.; Jeevagan, A. J.; Usui, S.; Tsuda, T.; Kaneko, S.; Saravanan, G.; Abe, H.; Matsumoto, F. J. Power Sources 2015, 273, 990. doi: 10.1016/j.jpowsour.2014.09.182 doi: 10.1016/j.jpowsour.2014.09.182
111. [111]
  Kodiyath, R.; Ramesh, G.; Koudelkova, E.; Tanabe, T.; Ito, M.; Manikandan, M.; Ueda, S.; Fujita, T.; Umezawa, N.; Noguchi, H.; et al. Energy Environ. Sci. 2015, 8, 1685. doi: 10.1039/C4EE03746D doi: 10.1039/C4EE03746D
112. [112]
  Nia, N. S.; Guillen-Villafuerte, O.; Griesser, C.; Manning, G.; Kunze-Liebhauser, J.; Arevalo, C.; Pastor, E.; Garcia, G. ACS Catal. 2020, 10, 1113. doi: 10.1021/acscatal.9b04348 doi: 10.1021/acscatal.9b04348
113. [113]
  Xue, X. Z.; Ge, J. J.; Tian, T.; Liu, C. P.; Xing, W.; Lu, T. H. J. Power Sources 2007, 172, 560. doi: 10.1016/j.jpowsour.2007.05.091 doi: 10.1016/j.jpowsour.2007.05.091
114. [114]
  Gao, Z. F.; Chen, H.; Qi, S. T.; Yin, C. H.; Yang, B. L. Acta Phys. -Chim. Sin. 2013, 29, 1900. doi: 10.3866/PKU.WHXB201307021
115. [115]
  Chen, C.; Zuo, Y. X.; Ye, W. K.; Li, X. G.; Deng, Z.; Ong, S. P. Adv. Energy Mater. 2020, 10, 1903242. doi: 10.1002/aenm.201903242 doi: 10.1002/aenm.201903242
116. [116]
  Chen, F.; Yang, Z. Y.; Wen, H.; Xu, Z. H. Acta Phys. -Chim. Sin. 1997, 13, 712. doi: 10.3866/PKU.WHXB19970807
117. [117]
  Han, M. R.; Zhou, Y. N.; Zhou, X.; Chu, W. Acta Phys. -Chim. Sin. 2019, 35, 850. doi: 10.3866/PKU.WHXB201811040
118. [118]
  Toyao, T.; Maeno, Z.; Takakusagi, S.; Kamachi, T.; Takigawa, I.; Shimizu, K. -I. ACS Catal. 2020, 10, 2260. doi: 10.1021/acscatal.9b04186 doi: 10.1021/acscatal.9b04186
119. [119]
  Li, Z.; Ma, X. F.; Xin, H. L. Catal. Today 2017, 280, 232. doi: 10.1016/j.cattod.2016.04.013 doi: 10.1016/j.cattod.2016.04.013
120. [120]
  Li, Z.; Wang, S. W.; Chin, W. S.; Achenie, L. E.; Xin, H. L. J. Mater. Chem. A 2017, 5, 24131. doi: 10.1039/c7ta01812f doi: 10.1039/c7ta01812f
121. [121]
  Tran, K.; Ulissi, Z. W. Nat. Catal. 2018, 1, 696. doi: 10.1038/s41929-018-0142-1 doi: 10.1038/s41929-018-0142-1
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