Citation: Ya Guo, Piao Jin, Minhua Shao, Shigang Dong, Ronggui Du, Changjian Lin. Effect of an Environmentally Friendly Diisooctyl Sebacate-based Mixed Corrosion Inhibitor on Reinforcing Steel[J]. Acta Physico-Chimica Sinica, ;2022, 38(4): 200303. doi: 10.3866/PKU.WHXB202003033 shu

Effect of an Environmentally Friendly Diisooctyl Sebacate-based Mixed Corrosion Inhibitor on Reinforcing Steel

Ya Guo ^{1, 2} ,
Piao Jin ¹ ,
Minhua Shao ³ ,
Shigang Dong ⁴ ,
Ronggui Du ^1,, ,
Changjian Lin ¹

1.
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, China
2.
Department of Metallurgy and Chemical Engineering, Gansu Vocational & Technical College of Nonferrous Metallurgy, Jinchang 737100, Gansu Province, China
3.
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Klwloon, Hong Kong, China
4.
College of Energy, Xiamen University. Xiamen 361102, Fujian Province, China

Corresponding author: Ronggui Du, rgdu@xmu.edu.cn
Received Date: 14 March 2020
Revised Date: 23 April 2020
Accepted Date: 12 May 2020
Available Online: 18 May 2020
Fund Project: the National Natural Science Foundation of China 51731008the National Natural Science Foundation of China 21573182the National Natural Science Foundation of China 21073151the National Natural Science Foundation of China 21203158

Corrosion protection of reinforcing steel in concrete is an urgent task in modern society. Use of corrosion inhibitors in concrete is an effective, simple, and economical method for protecting reinforcing steel from corrosion. Mixed corrosion inhibitors usually perform better than a single inhibitor in actual reinforced concrete systems because of their synergistic inhibition effects. In recent years, environmentally friendly corrosion inhibitors have attracted increasing attention from corrosion researchers. Diisooctyl sebacate and sodium D-gluconate are environmentally friendly organic corrosion inhibitors, and ZnSO₄ is an inorganic cathodic inhibitor, they may form an innovative, nontoxic, and pollution-free mixed corrosion inhibitor to control reinforcing steel corrosion. Additionally, diisooctyl sebacate and sodium D-gluconate serve as absorption-type inhibitors, and ZnSO₄ acts as a precipitation-type inhibitor. We hypothesized that their combination might show a good synergistic corrosion inhibition effect on reinforcing steel. In this study, we developed a diisooctyl sebacate-based mixed corrosion inhibitor that includes D-gluconate and ZnSO₄ and investigated its synergistic inhibition effects on reinforcing steel (Q235 steel) corrosion in a simulated polluted concrete pore solution. The reinforcing steel corrosion behavior and the properties of the mixed corrosion inhibitor were studied by polarization curve measurements, electrochemical impedance spectroscopy tests, and surface analysis methods (scanning electron microscopy, X-ray photoelectron spectroscopy, and Raman spectroscopy). The results indicated that the reinforcing steel in the simulated polluted concrete pore solution (pH 11.00, 0.5 mol·L^-1 NaCl) was in an active dissolving state and that localized corrosion took place. The mixed corrosion inhibitor, consisting of diisooctyl sebacate (59 mmol·L^-1), sodium D-gluconate (0.5 mmol·L^-1), and ZnSO₄ (1.5 mmol·L^-1), had an obvious and powerful inhibition effect. Its inhibition efficiency reached 96.8% and 90.0% in the simulated polluted concrete pore solution and the cement mortar, respectively. The mixture of diisooctyl sebacate with sodium D-gluconate and ZnSO₄ acted as a mixed-type inhibitor and effectively controlled both anodic and cathodic reactions of the steel corrosion.
- Reinforcing steel,
- Chloride,
- Localized corrosion,
- Corrosion inhibitor,
- Simulated concrete pore solution
1. [1]
  Kumar, V. Corros. Rev. 1998, 16, 317. doi: 10.1515/CORRREV.1998.16.4.317 doi: 10.1515/CORRREV.1998.16.4.317
2. [2]
  Thangavel, K. Corros. Rev. 2004, 22, 55. doi: 10.1515/corrrev.2004.22.1.55 doi: 10.1515/corrrev.2004.22.1.55
3. [3]
  Ahmad, S. Cement Concrete. Comp. 2003, 25, 459. doi: 10.1016/S0958-9465(02)00086-0 doi: 10.1016/S0958-9465(02)00086-0
4. [4]
  Huet, B.; L'Hostis, V.; Miserque, F.; Idrissi, H. Electrochim. Acta 2005, 51, 172. doi: 10.1016/j.electacta.2005.04.014 doi: 10.1016/j.electacta.2005.04.014
5. [5]
  Xu, H.; Liu, Y.; Chen, W.; Du, R. G.; Lin, C. J. Electrochim. Acta 2009, 54, 4067. doi: 10.1016/j.electacta.2009.02.046 doi: 10.1016/j.electacta.2009.02.046
6. [6]
  Hu, R. G.; Huang, R. S.; Du, R. G.; Lin, C. J. Acta Phys. -Chim. Sin. 2003, 19, 46. doi: 10.3866/PKU.WHXB20030111
7. [7]
  Du, R. G.; Hu, R. G.; Huang, R. S.; Lin, C. J. Anal. Chem. 2006, 78, 3179. doi: 10.1021/ac0517139 doi: 10.1021/ac0517139
8. [8]
  Verbruggen, H.; Baert, K.; Terryn, H.; De Graeve, I. Surf. Coat. Technol. 2019, 361, 280. doi: 10.1016/j.surfcoat.2018.09.056 doi: 10.1016/j.surfcoat.2018.09.056
9. [9]
  Tan, Z. Q.; Hansson, C. M. Corros. Sci. 2008, 50, 2512. doi: 10.1016/j.corsci.2008.06.035 doi: 10.1016/j.corsci.2008.06.035
10. [10]
  Goyal, A.; Pouya, H. S.; Ganjian, E. Constr. Build. Mater. 2019, 223, 1083. doi: 10.1016/j.conbuildmat.2019.07.344 doi: 10.1016/j.conbuildmat.2019.07.344
11. [11]
  Shalabi, K.; Nazeer, A. A. J. Mol. Struct. 2019, 1195, 863. doi: 10.1016/j.molstruc.2019.06.033 doi: 10.1016/j.molstruc.2019.06.033
12. [12]
  Yang, R. J.; Guo, Y.; Tang, F. M.; Wang, X. P.; Du, R. G.; Lin, C. J. Acta Phys. -Chim. Sin. 2012, 28, 1923. doi: 10.3866/PKU.WHXB201205292
13. [13]
  Zheng, H. B.; Li, W. H.; Ma, F. B.; Kong, Q. L. Cem. Concr. Res. 2014, 55, 102. doi: 10.1016/j.cemconres.2013.10.005 doi: 10.1016/j.cemconres.2013.10.005
14. [14]
  Ormellese, M.; Lazzari, L.; Goidanich, S.; Fumagalli, G.; Brenna, A. Corros. Sci. 2009, 51, 2959. doi: 10.1016/j.corsci.2009.08.018 doi: 10.1016/j.corsci.2009.08.018
15. [15]
  Girčienė, O.; Ramanauskas, R.; Gudavičiūtė, L.; Martušienė, A. Corrosion 2011, 67, 125001. doi: 10.5006/1.3665355 doi: 10.5006/1.3665355
16. [16]
  Manjula, P. E J. Chem. 2009, 6, 887. doi: 10.1155/2009/859218 doi: 10.1155/2009/859218
17. [17]
  Rajendran, S.; Reenkala, S. M.; Anthony, N.; Ramaraj, R. Corros. Sci. 2002, 44, 2243. doi: 10.1016/S0010-938X(02)00052-5 doi: 10.1016/S0010-938X(02)00052-5
18. [18]
  Ashassi-Sorkhabi, H.; Asghari, E. J. Electrochem. Soc. 2012, 159, C1. doi: 10.1149/2.006201jes doi: 10.1149/2.006201jes
19. [19]
  Mohamed, K. E. M.; Ibrahim, O. H; El-Bedawy, M. E; Ali, A. H. J. Radiat. Res. Appl. Sci. 2020, 13, 276. doi: 10.1080/16878507.2020.1730603 doi: 10.1080/16878507.2020.1730603
20. [20]
  Refaey, S. Appl. Surf. Sci. 2000, 157, 199. doi: 10.1016/S0169-4332(99)00573-5 doi: 10.1016/S0169-4332(99)00573-5
21. [21]
  Otani, K.; Sakairi, M.; Islam, M. S. Corros. Rev. 2018, 36, 105. doi: 10.1515/corrrev-2017-0047 doi: 10.1515/corrrev-2017-0047
22. [22]
  Loto, R. T.; Fajobi, M.; Oluwole, O.; Loto, C. A. Cogent Engineering 2020, 7, 1712155. doi: 10.1080/23311916.2020.1712155 doi: 10.1080/23311916.2020.1712155
23. [23]
  Ivusic, F.; Lahodny-Sarc, O.; Curkovic, H. O.; Alar, V. Corros. Sci. 2015, 98, 88. doi: 10.1016/j.corsci.2015.05.017 doi: 10.1016/j.corsci.2015.05.017
24. [24]
  Wu, L. L.; Zhang, Y. J.; Yang, G. B.; Zhang, S. M.; Yu, L. G. Zhang, P. Y. RSC Adv. 2016, 6, 69836. doi: 10.1039/c6ra10042b doi: 10.1039/c6ra10042b
25. [25]
  Lu, Z. Y.; Cao, Z. Z.; Hu, E. Z.; Hu, K. H.; Hu, X. G. Tribol. Int. 2019, 130, 308. doi: 10.1016/j.triboint.2018.09.030 doi: 10.1016/j.triboint.2018.09.030
26. [26]
  Wang, X.; Zeng, H. L.; Zhao, L. X.; Lin, J. M. Talanta 2006, 70, 160. doi: 10.1016/j.talanta.2006.01.006 doi: 10.1016/j.talanta.2006.01.006
27. [27]
  Kitowski, C. J.; Wheat, H. G. Corrosion 1997, 53, 216. doi: 10.5006/1.3280463 doi: 10.5006/1.3280463
28. [28]
  Gao, Y. B.; Hu, J.; Zuo, J.; Liu, Q.; Zhang, H.; Dong, S. G.; Du, R. G.; Lin, C. J. J. Electrochem. Soc. 2015, 162, C555. doi: 10.1149/2.0641510jes doi: 10.1149/2.0641510jes
29. [29]
  Bastidas, D. M.; La Iglesia, V. M.; Criado, M.; Fajardo, S.; La Iglesia, A.; Bastidas, J. M. Constr. Build. Mater. 2010, 24, 2646. doi: 10.1016/j.conbuildmat.2010.04.060 doi: 10.1016/j.conbuildmat.2010.04.060
30. [30]
  McCarter, W. J.; Vennesland, O. Constr. Build. Mater. 2004, 18, 351. doi: 10.1016/j.conbuildmat.2004.03.008 doi: 10.1016/j.conbuildmat.2004.03.008
31. [31]
  Morris, W.; Vico, A.; Vazquez, M.; de Sanchez, S. R. Corros. Sci. 2002, 44, 81. doi: 10.1016/S0010-938X(01)00033-6 doi: 10.1016/S0010-938X(01)00033-6
32. [32]
  Hackerman, N.; Hurd, R. M. Corrosion inhibition and molecular structure. In First International Congress on Metallic Corrosion, London, April 10–15, 1961; Kenworthy, L. Ed.; Butterworths: London, 1962.
33. [33]
  Esta Abelev, D. S.; Ein-Eli, Yair. Electrochim. Acta 2007, 52, 1975. doi: 10.1016/j.electacta.2006.08.012 doi: 10.1016/j.electacta.2006.08.012
34. [34]
  Pearson, R. G. J. Am. Chem. Soc. 1963, 85, 3533. doi: 10.1021/ja00905a001 doi: 10.1021/ja00905a001
35. [35]
  Aramaki, K.; Shimura, T. Corros. Sci. 2004, 46, 2563. doi: 10.1016/j.corsci.2004.01.024 doi: 10.1016/j.corsci.2004.01.024
36. [36]
  Hamadou, L.; Kadri, A.; Benbrahim, N. Appl. Surf. Sci. 2005, 252, 1510. doi: 10.1016/j.apsusc.2005.02.135 doi: 10.1016/j.apsusc.2005.02.135
37. [37]
  Sagues, A. A.; Kranc, S. C.; Moreno, E. I. Corros. Sci. 1995, 37, 1097. doi: 10.1016/0010-938X(95)00017-E doi: 10.1016/0010-938X(95)00017-E
38. [38]
  Sagues, A. A.; Kranc, S. C.; Moreno, E. I. Electrochim. Acta 1996, 41, 1239. doi: 10.1016/0013-4686(95)00476-9 doi: 10.1016/0013-4686(95)00476-9
39. [39]
  Berthier, F.; Diard, J. P.; Michel, R. J. Electroanal. Chem. 2001, 510, 1. doi: 10.1016/S0022-0728(01)00554-X doi: 10.1016/S0022-0728(01)00554-X
40. [40]
  Neves, R. S.; De Robertis, E.; Motheo, A. J. Electrochim. Acta 2006, 51, 1215. doi: 10.1016/j.electacta.2005.06.013 doi: 10.1016/j.electacta.2005.06.013
41. [41]
  Dawson, J. L.; Ferreira, M. G. S. Corros. Sci. 1986, 26, 1009. doi: 10.1016/0010-938X(86)90130-7 doi: 10.1016/0010-938X(86)90130-7
42. [42]
  Kaesche, H. Corrosion of Metals: Physicochemical Principles and Current Problems; Springer-Verlag: Berlin, Heidelberg, 2003; pp. 98–16.
43. [43]
  Rammelt, U.; Reinhard, G. Electrochim. Acta 1990, 35, 1045. doi: 10.1016/0013-4686(90)90040-7 doi: 10.1016/0013-4686(90)90040-7
44. [44]
  Leibig, M.; Halsey, T. C. Electrochim. Acta 1993, 38, 1985. doi: 10.1016/0013-4686(93)80328-W doi: 10.1016/0013-4686(93)80328-W
45. [45]
  Benedetti, A. V.; Sumodjo, P. T. A.; Nobe, K.; Cabot, P. L.; Proud, W. G. Electrochim. Acta 1995, 40, 2657. doi: 10.1016/0013-4686(95)00108-Q doi: 10.1016/0013-4686(95)00108-Q
46. [46]
  Luo, H.; Dong, C. F.; Li, X. G.; Xiao, K. Electrochim. Acta 2012, 64, 211. doi: 10.1016/j.electacta.2012.01.025 doi: 10.1016/j.electacta.2012.01.025
47. [47]
  Della Rovere, C. A.; Alano, J. H.; Silva, R.; Nascente, P. A. P.; Otubo, J.; Kuri, S. E. Corros. Sci. 2012, 57, 154. doi: 10.1016/j.corsci.2011.12.022 doi: 10.1016/j.corsci.2011.12.022
48. [48]
  Abreu, C. M.; Cristobal, M. J.; Losada, R.; Novoa, X. R.; Pena, G.; Perez, M. C. Electrochim. Acta 2006, 51, 1881. doi: 10.1016/j.electacta.2005.06.040 doi: 10.1016/j.electacta.2005.06.040
49. [49]
  Neal, A. L.; Techkarnjanaruk, S.; Dohnalkova, A.; McCready, D.; Peyton, B. M.; Geesey, G. G. Geochim. Cosmochim. Ac. 2001, 65, 223. doi: 10.1016/S0016-7037(00)00537-8 doi: 10.1016/S0016-7037(00)00537-8
50. [50]
  Tan, B. J.; Klabunde, K. J.; Sherwood, P. M. A. Chem. Mater. 1990, 2, 186. doi: 10.1021/cm00008a021 doi: 10.1021/cm00008a021
51. [51]
  Singh, J. K.; Singh, D. D. N. Corros. Sci. 2012, 56, 129. doi: 10.1016/j.corsci.2011.11.012 doi: 10.1016/j.corsci.2011.11.012
52. [52]
  Nakayama, N.; Obuchi, A. Corros. Sci. 2003, 45, 2075. doi: 10.1016/S0010-938X(03)00032-5 doi: 10.1016/S0010-938X(03)00032-5
53. [53]
  Zhou, X.; Yang, H. Y.; Wang, F. H. Electrochim. Acta 2011, 56, 4268. doi: 10.1016/j.electacta.2011.01.081 doi: 10.1016/j.electacta.2011.01.081
54. [54]
  Aramaki, K. Corros. Sci. 2002, 44, 1621. doi: 10.1016/S0010-938X(01)00171-8 doi: 10.1016/S0010-938X(01)00171-8
55. [55]
  Nieuwoudt, M. K.; Comins, J. D.; Cukrowski, I. J. Raman Spectrosc. 2011, 42, 1335. doi: 10.1002/jrs.2837 doi: 10.1002/jrs.2837
56. [56]
  Froment, F.; Tournie, A.; Colomban, P. J. Raman Spectrosc. 2008, 39, 560. doi: 10.1002/jrs.1858 doi: 10.1002/jrs.1858
57. [57]
  Neff, D.; Bellot-Gurlet, L.; Dillmann, P.; Reguer, S.; Legrand, L. J. Raman Spectrosc. 2006, 37, 1228. doi: 10.1002/jrs.1581 doi: 10.1002/jrs.1581
58. [58]
  Reguer, S.; Neff, D.; Bellot-Gurlet, L.; Dillmann, P. J. Raman Spectrosc. 2007, 38, 389. doi: 10.1002/jrs.1659 doi: 10.1002/jrs.1659
1. [1]
  Xianzheng Zhang , Yana Chen , Zhiyong Ye , Huilin Hu , Ling Lei , Feng You , Junlong Yao , Huan Yang , Xueliang Jiang . Magnetic field-assisted microbial corrosion construction iron sulfides incorporated nickel-iron hydroxide towards efficient oxygen evolution. Chinese Journal of Structural Chemistry, 2024, 43(1): 100200-100200. doi: 10.1016/j.cjsc.2023.100200
2. [2]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224
3. [3]
  Kailong Zhang , Chao Zhang , Luanhui Wu , Qidong Yang , Jiadong Zhang , Guang Hu , Liang Song , Gaoran Li , Wenlong Cai . Chloride molten salt derived attapulgite with ground-breaking electrochemical performance. Chinese Chemical Letters, 2024, 35(10): 109618-. doi: 10.1016/j.cclet.2024.109618
4. [4]
  Wu-Jian Long , Yang Yu , Chuang He . A novel and promising engineering application of carbon dots: Enhancing the chloride binding performance of cement. Chinese Chemical Letters, 2024, 35(6): 108943-. doi: 10.1016/j.cclet.2023.108943
5. [5]
  Bo Yang , Pu-An Lin , Tingwei Zhou , Xiaojia Zheng , Bing Cai , Wen-Hua Zhang . Facile surface regulation for highly efficient and thermally stable perovskite solar cells via chlormequat chloride. Chinese Chemical Letters, 2024, 35(10): 109425-. doi: 10.1016/j.cclet.2023.109425
6. [6]
  Zhe Wang , Li-Peng Hou , Qian-Kui Zhang , Nan Yao , Aibing Chen , Jia-Qi Huang , Xue-Qiang Zhang . High-performance localized high-concentration electrolytes by diluent design for long-cycling lithium metal batteries. Chinese Chemical Letters, 2024, 35(4): 108570-. doi: 10.1016/j.cclet.2023.108570
7. [7]
  Yiran Tao , Chunlei Dai , Zhaoxiang Xie , Xinru You , Kaiwen Li , Jun Wu , Hai Huang . Redox responsive polymeric nanoparticles enhance the efficacy of cyclin dependent kinase 7 inhibitor for enhanced treatment of prostate cancer. Chinese Chemical Letters, 2024, 35(8): 109170-. doi: 10.1016/j.cclet.2023.109170
8. [8]
  Jia Chen , Yun Liu , Zerong Long , Yan Li , Hongdeng Qiu . Colorimetric detection of α-glucosidase activity using Ni-CeO₂ nanorods and its application to potential natural inhibitor screening. Chinese Chemical Letters, 2024, 35(9): 109463-. doi: 10.1016/j.cclet.2023.109463
9. [9]
  Jisheng Liu , Junli Chen , Xifeng Zhang , Yin Wu , Xin Qi , Jie Wang , Xiang Gao . Red blood cell membrane-coated FLT3 inhibitor nanoparticles to enhance FLT3-ITD acute myeloid leukemia treatment. Chinese Chemical Letters, 2024, 35(9): 109779-. doi: 10.1016/j.cclet.2024.109779
10. [10]
  Qinming Wu , Xiangju Meng . New zeolites with extra-stable extra-large-pore. Chinese Journal of Structural Chemistry, 2024, 43(6): 100310-100310. doi: 10.1016/j.cjsc.2024.100310
11. [11]
  Zhenzhen Zhao , Meichen Jiao , Jiejie Ling , Han Jiang , Yan Gao , Hao Xu , Hai-Qing Li , Jingang Jiang , Peng Wu , Le Xu . Toward the microporous zeolite family with tunable large-medium cage and pore opening. Chinese Journal of Structural Chemistry, 2024, 43(9): 100336-100336. doi: 10.1016/j.cjsc.2024.100336
12. [12]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891
13. [13]
  Xiaobo Li , Qunyan Wu , Congzhi Wang , Jianhui Lan , Meng Zhang , Weiqun Shi . Theoretical perspectives on the reduction of Pu(Ⅳ) and Np(Ⅵ) by methylhydrazine in HNO₃ solution: Implications for Np/Pu separation. Chinese Chemical Letters, 2024, 35(7): 109359-. doi: 10.1016/j.cclet.2023.109359
14. [14]
  Zheng Zhao , Ben Zhong Tang . An efficient strategy enabling solution processable thermally activated delayed fluorescence emitter with high horizontal dipole orientation. Chinese Journal of Structural Chemistry, 2024, 43(6): 100270-100270. doi: 10.1016/j.cjsc.2024.100270
15. [15]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(194)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142