Citation: Xiong Hui, Xie Xinwen, Wang Miao, Hou Yaqi, Hou Xu. CVD Grown Carbon Nanotubes on Reticulated Skeleton for Brine Desalination[J]. Acta Physico-Chimica Sinica, ;2020, 36(9): 191200. doi: 10.3866/PKU.WHXB201912008 shu

CVD Grown Carbon Nanotubes on Reticulated Skeleton for Brine Desalination

Xiong Hui ^1,† ,
Xie Xinwen ^2,† ,
Wang Miao ^2,†,, ,
Hou Yaqi ¹ ,
Hou Xu ^1,2,3,4,,

1.
College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
2.
College of Physical Science and Technology, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
3.
Collaborative Innovation Center of Chemistry for Energy Materials, Xiamen University, Xiamen 361005, Fujian Province, P. R. China
4.
State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Corresponding author: Wang Miao, miaowang@xmu.edu.cn Hou Xu, houx@xmu.edu.cn

^†

Received Date: 2 December 2019
Revised Date: 9 February 2020
Accepted Date: 12 February 2020
Available Online: 2 March 2020
Fund Project: the Natural Science Foundation of Fujian Province of China 2018J06003The project was supported by the National Key R & D Program of China (2018YFA0209500), the National Natural Science Foundation of China (21673197, 21621091, 21808191, 51706191), the 111 Project (B16029), the Fundamental Research Funds for the Central Universities of China (20720190037), the Natural Science Foundation of Fujian Province of China (2018J06003), the Special Project of Strategic Emerging Industries from Fujian Development and Reform Commissionthe Fundamental Research Funds for the Central Universities of China 20720190037the National Natural Science Foundation of China 21621091the National Natural Science Foundation of China 51706191the National Key R & D Program of China 2018YFA0209500the 111 Project B16029the National Natural Science Foundation of China 21808191the National Natural Science Foundation of China 21673197

Using solar energy to power evaporative processes has found various applications in desalination, wastewater treatment, and power generation among other fields. Due to its green-energy sources and energy-efficient conversions, it has gained increasing attention. However, as one of the oldest approaches, the application of solar evaporation is still limited by issues such as low evaporation efficiency, fouling, and the rapid degradation of solar absorbers. During solar evaporation processes, the solar absorbing materials are directly heated by sunlight and the generated heat is transferred to the water around the material. Within this process, in situ photo-thermal conversion is realized by absorber materials at the air-water interface. After the water is heated, it vapors continuously. Therefore, the material for solar absorption and photo-thermal conversion is key to improving the efficiency of solar evaporation processes. Currently, many approaches are being developed to achieve high-efficient solar evaporation, such as the photon management, nano-scale thermal regulation, the development of new photo-thermal conversion materials, and the design of efficient light-absorbing solar stiller. Carbon-based materials including carbon nanotubes, graphene, carbon black, graphite, etc. have broad light-absorption profiles over the entire solar spectrum, which makes them the outstanding photo-thermal conversion materials. Herein, we design a new structure and house-like solar still on the basis of carbon-based materials to achieve high light absorption, efficient photo-thermal conversion, and continuous desalination. We use the chemical vapor deposition (CVD) technique to fabricate a reticulated carbon-nanotube solar evaporation membrane. Stainless steel mesh (SSM) is used as a reticulated skeleton, providing porous structures and increasing the mechanical strength of the membrane. Then the carbon nanotubes (CNTs) are grown on the reticulated skeleton to function as solar conversion structures due to their wide range of light absorption capacities. The CVD grown CNTs reticulated membrane (CGRM) is fixed in a house-like device with a sloped ceiling to condense and collect water vapors ensuring the continuous desalination of water. Our experiments show that the fabricated CGRM is hydrophobic with an average contact angle of 133.4° for a 100.0 g·L^-1 NaCl solution, only allowing water vapors to pass through while rejecting salts. When the light intensity was 1 kW·m^-2, the surface temperature of the membrane increased rapidly and stabilized at 84.37 ℃. The salt rejection rate of the system could reach up to 99.92%.To perform a comparative study, we also prepared a mechanically-filled CNTs reticulated membrane (MFRM1, MFRM2) for solar evaporation tests, which showed an inferior performance to that of the growing structure of the CGRM. Therefore, it was determined that our system might provide a potential way to harvest freshwater readily with portable-type equipment.
- Microstructure design,
- Reticulated carbon nanotube evaporation membrane,
- Interface evaporation,
- Photo-thermal conversion,
- Solar still,
- Heavy brine
1. [1]
  Shannon, M. A.; Bohn, P. W.; Elimelech, M.; Georgiadis, J. G.; Marinas, B. J.; Mayes, A. M. Nature 2008, 452, 301. doi: 10.1038/nature06599 doi: 10.1038/nature06599
2. [2]
  Dudchenko, A. V.; Chen, C.; Cardenas, A.; Rolf, J.; Jassby, D. Nat. Nanotechnol. 2017, 12, 557. doi: 10.1038/nnano.2017.102 doi: 10.1038/nnano.2017.102
3. [3]
  Yan, K.; Jiao, L.; Lin, S.; Ji, X.; Lu, Y.; Zhang, L. Desalination 2018, 437, 26. doi: 10.1016/j.desal.2018.02.020 doi: 10.1016/j.desal.2018.02.020
4. [4]
  Zhu, L.; Chuan, F.; Gao, M.; Ghim, W. H. Adv. Mater. 2015, 27, 7713. doi: 10.1002/aenm.201702149 doi: 10.1002/aenm.201702149
5. [5]
  Huang, J.; He, Y.; Wang, L.; Huang, Y.; Jiang, B. Energ. Convers. Manage. 2017, 132, 452. doi: 10.1016/j.enconman.2016.11.053 doi: 10.1016/j.enconman.2016.11.053
6. [6]
  Lou, J.; Liu, Y.; Wang, Z.; Zhao, D.; Song, C.; Wu, J.; Dasgupta, N.; Zhang, W.; Zhang, D.; Tao, P.; et al. ACS Appl. Mater. Inter. 2016, 8, 14628. doi: 10.1021/acsami.6b04606 doi: 10.1021/acsami.6b04606
7. [7]
  Liu, Y.; Chen, J.; Guo, D.; Cao, M.; Jiang, L. ACS Appl. Mater. Inter. 2015, 7, 13645. doi: 10.1021/acsami.5b03435 doi: 10.1021/acsami.5b03435
8. [8]
  Zhu, L.; Gao, M.; Peh, C. K. N.; Wang, X.; Ho, G. W. Adv. Energy Mater. 2018, 8, 1702149. doi: 10.1002/aenm.201702149 doi: 10.1002/aenm.201702149
9. [9]
  Zhu, L.; Gao, M.; Peh, C. K. N.; Ho, G. W. Mater. Horiz. 2018, 5, 323. doi: 10.1039/C7MH01064H doi: 10.1039/C7MH01064H
10. [10]
  Zhang, P.; Li, J.; Lv, L.; Zhao, Y.; Qu, L. ACS Nano 2017, 11, 5087. doi: 10.1021/acsnano.7b01965 doi: 10.1021/acsnano.7b01965
11. [11]
  Chen, C.; Kuang, Y.; Hu, L. Joule 2019, 3, 683. doi: 10.1016/j.joule.2017.09.011 doi: 10.1016/j.joule.2017.09.011
12. [12]
  Kabeel, A. E.; El-Agouz, S. A. Desalination 2011, 276, 1. doi: 10.1016/j.desal.2011.03.042 doi: 10.1016/j.desal.2011.03.042
13. [13]
  Tao, P.; Ni, G.; Song, C.; Shang, W.; Wu, J.; Zhu, J.; Chen, G.; Deng, T. Nat. Energy 2018, 3, 1031. doi: 10.1007/BF02856901 doi: 10.1007/BF02856901
14. [14]
  Wang, Z.; Liu, Y.; Tao, P.; Shen, Q.; Yi, N.; Zhang, F.; Liu, Q.; Song, C.; Zhang, D.; Shang, W.; et al. Small 2014, 10, 3234. doi: 10.1109/tim.2011.2128710 doi: 10.1109/tim.2011.2128710
15. [15]
  Yu, F.; Chen, Y.; Liang, X.; Xu, J.; Lee, C.; Liang, Q.; Tao, P.; Deng, T. Prog. Nat. Sci-Mater. 2017, 27, 531. doi: 10.1016/j.pnsc.2017.08.010 doi: 10.1016/j.pnsc.2017.08.010
16. [16]
  Zielinski, M. S.; Choi, J. W.; La Grange, T.; Modestino, M.; Hashemi, S. M.; Pu, Y.; Birkhold, S.; Hubbell, J. A.; Psaltis, D. Nano Lett. 2016, 16, 2159. doi: 10.1021/acs.nanolett.5b03901 doi: 10.1021/acs.nanolett.5b03901
17. [17]
  Zhou., L.; Tan., Y.; Ji., D.; Zhu., B.; Zhang., P.; Xu., J.; Gan., Q.; Yu., Z.; Zhu, J. Sci. Adv. 2016, 2, e1501227. doi: 10.1364/PV.2015.PW3B.3 doi: 10.1364/PV.2015.PW3B.3
18. [18]
  Bae, K.; Kang, G.; Cho, S. K.; Park, W.; Kim, K.; Padilla, W. J. Nat. Commun. 2015, 6, 10103. doi: 10.1038/ncomms10103 doi: 10.1038/ncomms10103
19. [19]
  Zhao, F.; Zhou, X.; Shi, Y.; Qian, X.; Alexander, M.; Zhao, X.; Mendez, S.; Yang, R.; Qu, L.; Yu, G. Nat. Nanotechnol. 2018, 13, 489. doi: 10.1038/s41565-018-0097-z doi: 10.1038/s41565-018-0097-z
20. [20]
  Fujiwara., M.; Imura, T. ACS Nano 2015, 9, 5705. doi: 10.1021/nn505970n.99999j doi: 10.1021/nn505970n.99999j
21. [21]
  Ni, G.; Li, G.; Boriskina, S. V.; Li, H.; Yang, W.; Zhang, T.; Chen, G. Nat. Energy 2016, 1, 1.doi: 10.1038/nenergy.2016.126 doi: 10.1038/nenergy.2016.126
22. [22]
  Yang, Y.; Zhao, H.; Yin, Z.; Zhao, J.; Yin, X.; Li, N.; Yin, D.; Li, Y.; Lei, B.; Du, Y.; et al. Mater. Horiz. 2018, 5, 1143. doi: 10.1002/adma.201502201 doi: 10.1002/adma.201502201
23. [23]
  Zhao, J.; Yang, Y.; Yang, C.; Tian, Y.; Han, Y.; Liu, J.; Yin, X.; Que, W. J. Mater. Chem. A 2018, 6, 16196. doi: 10.1063/1.365287 doi: 10.1063/1.365287
24. [24]
  Fu, Y.; Wang, G.; Ming, X.; Liu, X.; Hou, B.; Mei, T.; Li, J.; Wang, J.; Wang, X. Carbon 2018, 130, 250. doi: 10.2307/25599220 doi: 10.2307/25599220
25. [25]
  Hao, W.; Chiou, K.; Qiao, Y.; Liu, Y.; Song, C.; Deng, T.; Huang, J. Nanoscale 2018, 10, 6306. doi: 10.1039/C7NR09556B doi: 10.1039/C7NR09556B
26. [26]
  Li, X.; Xu, W.; Tang, M.; Zhou, L.; Zhu, B.; Zhu, S.; Zhu, J. Proc. Natl. Acad. Sci. U. S. A. 2016, 113, 13953. doi: 10.1073/pnas.0813280106 doi: 10.1073/pnas.0813280106
27. [27]
  Li, Y.; Gao, T.; Yang, Z.; Chen, C.; Luo, W.; Yang, B.; Hu, L. Adv. Mater 2016, 29, 1700981. doi: 10.1002/aenm.201601122 doi: 10.1002/aenm.201601122
28. [28]
  Li, T.; Fang, Q.; Xi, X.; Chen, Y.; Liu, F. J. Mater. Chem. A 2019, 7, 586. doi: 10.1007/s13213-012-0568-7 doi: 10.1007/s13213-012-0568-7
29. [29]
  Xue, G.; Liu, K.; Chen, Q.; Yang, P.; Li, J.; Ding, T.; Duan, J.; Qi, B.; Zhou, J. ACS Appl. Mater. Inter. 2017, 9, 15052. doi: 10.1021/acsami.7b01992 doi: 10.1021/acsami.7b01992
30. [30]
  Goh, K.; Karahan, H. E.; Wei, L.; Bae, T. H.; Fane, A. G.; Wang, R.; Chen, Y. Carbon 2016, 109, 694. doi: 10.1016/j.carbon.2016.08.077 doi: 10.1016/j.carbon.2016.08.077
31. [31]
  Ghasemi, H.; Ni, G.; Marconnet, A. M.; Loomis, J.; Yerci, S.; Miljkovic, N.; Chen, G. Nat. Commun. 2014, 5, 4449. doi: 10.1038/ncomms5449 doi: 10.1038/ncomms5449
32. [32]
  Wang, Y.; Zhang, L.; Wang, P. ACS Sustain. Chem. Eng. 2016, 4, 1223. doi: 10.1021/acssuschemeng.5b01274 doi: 10.1021/acssuschemeng.5b01274
33. [33]
  Nikolaos, T. E., K.; Loukas, E. K.; Maria, B.; Evangelos, K.; Theodore, E. M.; Dimitrios, G.; Panos, P. ACS Nano 2012, 6, 10475. doi: 10.1021/nn304531k doi: 10.1021/nn304531k
34. [34]
  Yang, Z. P. J., A. B.; Shawn, Y. L.; Pulickel, M. A. Nano Lett. 2008, 8, 446. doi: 10.1021/nl072369t doi: 10.1021/nl072369t
35. [35]
  Liu, G.; Xu, J.; Wang, K. Nano Energy 2017, 41, 269. doi: 10.1016/j.nanoen.2017.09.005 doi: 10.1016/j.nanoen.2017.09.005
36. [36]
  Pendergast, M. M.; Hoek, E. M. V. Energ. Environ. Sci. 2011, 4, 1946. doi: 10.1039/C0EE00541J doi: 10.1039/C0EE00541J
37. [37]
  Shannon, M. A.; Bohn, P. W.; Elimelech, M.; Georgiadis, J. G.; Marinas, B. J.; Mayes, A. M. Nature 2008, 452, 301. doi: 10.1038/nature06599 doi: 10.1038/nature06599
38. [38]
  Wu, Z.; Jonathan, M.; Jennifer, S.; Maria, N.; Katalin, K.; John, R. R.; David, B. T.; Arthur, F. H.; Andrew, G. R. Science 2004, 305, 1273. doi: 10.1126/science.1101243 doi: 10.1126/science.1101243
39. [39]
  Cao, F.; Pan, G. X.; Xia, X. H.; Tang, P. S.; Chen, H. F. J. Power Sources 2014, 264, 161. doi: 10.1016/j.jpowsour.2014.04.103 doi: 10.1016/j.jpowsour.2014.04.103
40. [40]
  Jiang, J.; Li, Y.; Liu, J.; Huang, X.; Yuan, C.; Lou, X. W. Adv. Mater 2012, 24, 5166. doi: 10.1002/adma.201202146 doi: 10.1002/adma.201202146
41. [41]
  Li, X.; Zhu, B.; Zhu, J. Carbon 2019, 146, 320. doi: 10.1016/j.fgb.2010.08.002 doi: 10.1016/j.fgb.2010.08.002
1. [1]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
2. [2]
  Shu-Ran Xu , Fang-Xing Xiao . Metal halide perovskites quantum dots: Synthesis, and modification strategies for solar CO2 conversion. Chinese Journal of Structural Chemistry, 2023, 42(12): 100173-100173. doi: 10.1016/j.cjsc.2023.100173
3. [3]
  Jian-Rong Li , Jieying Hu , Lai-Hon Chung , Jilong Zhou , Parijat Borah , Zhiqing Lin , Yuan-Hui Zhong , Hua-Qun Zhou , Xianghua Yang , Zhengtao Xu , Jun He . Insight into stable, concentrated radicals from sulfur-functionalized alkyne-rich crystalline frameworks and application in solar-to-vapor conversion. Chinese Journal of Structural Chemistry, 2024, 43(8): 100380-100380. doi: 10.1016/j.cjsc.2024.100380
4. [4]
  Rui Cheng , Xin Huang , Tingting Zhang , Jiazhuang Guo , Jian Yu , Su Chen . Solid superacid catalysts promote high-performance carbon dots with narrow-band fluorescence emission for luminescence solar concentrators. Chinese Chemical Letters, 2024, 35(8): 109278-. doi: 10.1016/j.cclet.2023.109278
5. [5]
  Zhenyu Hu , Zhenchun Yang , Shiqi Zeng , Kun Wang , Lina Li , Chun Hu , Yubao Zhao . Cationic surface polarization centers on ionic carbon nitride for efficient solar-driven H₂O₂ production and pollutant abatement. Chinese Chemical Letters, 2024, 35(10): 109526-. doi: 10.1016/j.cclet.2024.109526
6. [6]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421
7. [7]
  Yi Herng Chan , Zhe Phak Chan , Serene Sow Mun Lock , Chung Loong Yiin , Shin Ying Foong , Mee Kee Wong , Muhammad Anwar Ishak , Ven Chian Quek , Shengbo Ge , Su Shiung Lam . Thermal pyrolysis conversion of methane to hydrogen (H₂): A review on process parameters, reaction kinetics and techno-economic analysis. Chinese Chemical Letters, 2024, 35(8): 109329-. doi: 10.1016/j.cclet.2023.109329
8. [8]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
9. [9]
  Jie XIE , Hongnan XU , Jianfeng LIAO , Ruoyu CHEN , Lin SUN , Zhong JIN . Nitrogen-doped 3D graphene-carbon nanotube network for efficient lithium storage. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1840-1849. doi: 10.11862/CJIC.20240216
10. [10]
  Shili Wang , Mamitiana Roger Razanajatovo , Xuedong Du , Shunli Wan , Xin He , Qiuming Peng , Qingrui Zhang . Recent advances on decomplexation mechanisms of heavy metal complexes in persulfate-based advanced oxidation processes. Chinese Chemical Letters, 2024, 35(6): 109140-. doi: 10.1016/j.cclet.2023.109140
11. [11]
  Ling-Ling Wu , Xiangchuan Meng , Qingyang Zhang , Xiaowan Han , Feiya Yang , Qinghua Wang , Hai-Yu Hu , Nianzeng Xing . Heavy-atom engineered hypoxia-responsive probes for precisive photoacoustic imaging and cancer therapy. Chinese Chemical Letters, 2024, 35(4): 108663-. doi: 10.1016/j.cclet.2023.108663
12. [12]
  Bharathi Natarajan , Palanisamy Kannan , Longhua Guo . Metallic nanoparticles for visual sensing: Design, mechanism, and application. Chinese Journal of Structural Chemistry, 2024, 43(9): 100349-100349. doi: 10.1016/j.cjsc.2024.100349
13. [13]
  Xiao Li , Wanqiang Yu , Yujie Wang , Ruiying Liu , Qingquan Yu , Riming Hu , Xuchuan Jiang , Qingsheng Gao , Hong Liu , Jiayuan Yu , Weijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166
14. [14]
  Xinyu Ren , Hong Liu , Jingang Wang , Jiayuan Yu . Electrospinning-derived functional carbon-based materials for energy conversion and storage. Chinese Chemical Letters, 2024, 35(6): 109282-. doi: 10.1016/j.cclet.2023.109282
15. [15]
  Yiqiao Chen , Ao Liu , Biwen Yang , Zhenzhen Li , Binggang Ye , Zhouyi Guo , Zhiming Liu , Haolin Chen . Photoluminescence and photothermal conversion in boric acid derived carbon dots for targeted microbial theranostics. Chinese Chemical Letters, 2024, 35(9): 109295-. doi: 10.1016/j.cclet.2023.109295
16. [16]
  Caixia Li , Yi Qiu , Yufeng Zhao , Wuliang Feng . Self assembled electron blocking and lithiophilic interface towards dendrite-free solid-state lithium battery. Chinese Chemical Letters, 2024, 35(4): 108846-. doi: 10.1016/j.cclet.2023.108846
17. [17]
  Lili Wang , Ya Yan , Rulin Li , Xujie Han , Jiahui Li , Ting Ran , Jialu Li , Baichuan Xiong , Xiaorong Song , Zhaohui Yin , Hong Wang , Qingjun Zhu , Bowen Cheng , Zhen Yin . Interface engineering of 2D NiFe LDH/NiFeS heterostructure for highly efficient 5-hydroxymethylfurfural electrooxidation. Chinese Chemical Letters, 2024, 35(9): 110011-. doi: 10.1016/j.cclet.2024.110011
18. [18]
  Yan Zhu , Jia Liu , Meiheng Lv , Tingting Wang , Dongxiang Zhang , Rong Shang , Xin-Dong Jiang , Jianjun Du , Guiling Wang . Heavy-atom-free orthogonal configurative dye 1,7-di-anthra-aza-BODIPY for singlet oxygen generation. Chinese Chemical Letters, 2024, 35(10): 109446-. doi: 10.1016/j.cclet.2023.109446
19. [19]
  Chen Lu , Zefeng Yu , Jing Cao . Advancement in porphyrin/phthalocyanine compounds-based perovskite solar cells. Chinese Journal of Structural Chemistry, 2024, 43(3): 100240-100240. doi: 10.1016/j.cjsc.2024.100240
20. [20]
  Chi Li , Peng Gao . Is dipole the only thing that matters for inverted perovskite solar cells?. Chinese Journal of Structural Chemistry, 2024, 43(6): 100324-100324. doi: 10.1016/j.cjsc.2024.100324

Get Citation

PDF

XML

Metrics

PDF Downloads(21)
Abstract views(712)
HTML views(93)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142