Citation: Li Lin, Shen Shuiyun, Wei Guanghua, Zhang Junliang. Electrocatalytic Activity of Hemin-Derived Hollow Non-Precious Metal Catalyst for Oxygen Reduction Reaction[J]. Acta Physico-Chimica Sinica, ;2021, 37(3): 191101. doi: 10.3866/PKU.WHXB201911011 shu

Electrocatalytic Activity of Hemin-Derived Hollow Non-Precious Metal Catalyst for Oxygen Reduction Reaction

1.
Institute of Fuel Cells, School of Mechanical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
2.
SJTU-Paris Tech Elite Institute of Technology, Shanghai Jiao Tong University, Shanghai 200240, China
3.
MOE Key Laboratory of Power & Machinery Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Zhang Junliang, junliang.zhang@sjtu.edu.cn
Received Date: 6 November 2019
Revised Date: 25 November 2019
Accepted Date: 25 November 2019
Available Online: 29 November 2019
Fund Project: the National Key Research and Development Program of China 2016YFB0101200the National Natural Science Foundation of China 21533005The project was supported by the National Natural Science Foundation of China (21533005) and the National Key Research and Development Program of China (2016YFB0101200)

In recent years, increasing efforts have been undertaken to develop non-precious metal (NPM) catalysts with both high activity and stability toward the oxygen reduction reaction (ORR), since they are much less expensive than commercially available Pt-based electrocatalysts. Transition metal macrocyclic compounds contain transition metal, nitrogen, and carbon species, hence becoming promising precursors for the synthesis of NPM catalysts. Hemin, a natural transition-metal-based macrocyclic compound, is widely applied to the synthesis of NPM electrocatalysts. However, the ORR activity of hemin-derived electrocatalysts must be improved considerably as compared with that of state-of-the-art NPM electrocatalysts. Morphology control is an efficient method to increase the exposure of active sites, thus enhancing the ORR activity. Here, we fabricated a hollow NPM electrocatalyst (hemin hollow derivative, Hemin-HD) using hemin as the precursor and NaCl as the template. First, hemin and NaCl were dispersed and mixed in solution. With an increase in the temperature, the solution was vapored and NaCl began to crystallize. Hemin wrapped the outer surface of NaCl because of the ionic interaction between these two compounds. The as-obtained powders were collected and carbonized at high temperature under a nitrogen atmosphere. Then, the NaCl template was removed by washing, and the hollow material Hemin-HD was obtained. Physicochemical characterization by transmission electron microscopy (TEM), X-ray diffraction (XRD), surface area measurements and X-ray photoelectron spectroscopy (XPS) confirmed that the surface area and pore volume of the as-obtained Hemin-HD electrocatalyst increased by a factor of 6.5 and 3.8, respectively, relative to those of the Hemin-D (hemin derivative) sample without the NaCl template. Owing to the hollow structure and increased surface area, the Fe and N content on the Hemin-HD surface were higher than those on the Hemin-D surface. Consequently, Hemin-HD showed better ORR activity in alkali solution than Hemin-D did, this was confirmed by the fact that the half-wave potential of Hemin-HD was greater than that of Hemin-D by 20 mV, and faster kinetics were observed for the former, as calculated by the Tafel slope. The performance of Hemin-HD was comparable to that of commercial Pt/C catalysts for the ORR in alkali solution. It is believed that the hollow structure allows the dispersion of active sites on both the inner and outer surfaces, thus facilitating the exposure of a great number of active sites. Besides, the pore structure of the electrocatalyst is expected to boost mass transfer and improve the contact between the active sites and reactants, thus enhancing the ORR activity.
- Oxygen reduction reaction,
- Non-precious metal electrocatalyst,
- Hemin,
- NaCl template,
- Hollow
1. [1]
  Gasteiger, H. A.; Yan, S. G. J. Power Sources 2004, 127 (1–2), 162. doi: 10.1016/j.jpowsour.2003.09.013 doi: 10.1016/j.jpowsour.2003.09.013
2. [2]
  Chen, C.; Zhang, X.; Zhou, Z.; Zhang, X.; Sun, S. Acta Phys. -Chim. Sin. 2017, 33 (9), 1875. doi: 10.3866/PKU.WHXB201705088
3. [3]
  Ding, W.; Li, L.; Xiong, K.; Wang, Y.; Li, W.; Nie, Y.; Chen, S.; Qi, X.; Wei, Z. J. Am. Chem. Soc. 2015, 137 (16), 5414. doi: 10.1021/jacs.5b00292 doi: 10.1021/jacs.5b00292
4. [4]
  Wang, Q.; Liu, D.; He, X. Acta Phys. -Chim. Sin. 2019, 35 (7), 740. doi: 10.3866/PKU.WHXB201809003
5. [5]
  Jasinski, R. Nature 1964, 201, 1212. doi: 10.1038/2011212a0 doi: 10.1038/2011212a0
6. [6]
  Lalande, G.; Côté, R.; Tamizhmani, G.; Guay, D.; Dodelet, J. P.; Dignard-Bailey, L.; Weng, L. T.; Bertrand, P. Electrochim. Acta 1995, 40 (16), 2635. doi: 10.1016/0013-4686(95)00104-M doi: 10.1016/0013-4686(95)00104-M
7. [7]
  Charreteur, F.; Jaouen, F.; Dodelet, J. P. Electrochim. Acta 2009, 54 (26), 6622. doi: 10.1016/j.electacta.2009.06.058 doi: 10.1016/j.electacta.2009.06.058
8. [8]
  Jaouen, F.; Herranz, J.; Lefevre, M.; Dodelet, J. P.; Kramm, U. I.; Herrmann, I.; Bogdanoff, P.; Maruyama, J.; Nagaoka, T.; Garsuch, A.; et al. ACS Appl. Mater. Interfaces 2009, 1 (8), 1623. doi: 10.1021/am900219g doi: 10.1021/am900219g
9. [9]
  Huang, H. C.; Shown, I.; Chang, S. T.; Hsu, H. C.; Du, H. Y.; Kuo, M. C.; Wong, K. T.; Wang, S. F.; Wang, C. H.; Chen, L. C.; et al. Adv. Funct. Mater. 2012, 22 (16), 3500. doi: 10.1002/adfm.201200264 doi: 10.1002/adfm.201200264
10. [10]
  Pylypenko, S.; Mukherjee, S.; Olson, T. S.; Atanassov, P. Electrochim. Acta 2008, 53 (27), 7875. doi: 10.1016/j.electacta.2008.05.047 doi: 10.1016/j.electacta.2008.05.047
11. [11]
  He, Q. G.; Yang, X. F.; Ren, X. M.; Koel, B. E.; Ramaswamy, N.; Mukerjee, S.; Kostecki, R. J. Power Sources 2011, 196 (18), 7404. doi: 10.1016/j.jpowsour.2011.04.016 doi: 10.1016/j.jpowsour.2011.04.016
12. [12]
  Yang, Q.; Gao, G.; Wang, X. Acta Phys. -Chim. Sin. 2000, 16 (8), 741. doi: 10.3866/PKU.WHXB20000813
13. [13]
  Mo, Z.; Zheng, R.; Peng, H.; Liang, H.; Liao, S. J. Power Sources 2014, 245, 801. doi: 10.1016/j.jpowsour.2013.07.038 doi: 10.1016/j.jpowsour.2013.07.038
14. [14]
  Jiang, R.; Tran, D. T.; McClure, J.; Chu, D. Electrochem. Commun. 2012, 19, 73. doi: 10.1016/j.elecom.2012.03.013 doi: 10.1016/j.elecom.2012.03.013
15. [15]
  Xi, P. B.; Liang, Z. X.; Liao, S. J. Int. J. Hydrogen Energy 2012, 37 (5), 4606. doi: 10.1016/j.ijhydene.2011.05.102 doi: 10.1016/j.ijhydene.2011.05.102
16. [16]
  Jiang, R.; Chu, D. J. Power Sources 2014, 245, 352. doi: 10.1016/j.jpowsour.2013.06.123 doi: 10.1016/j.jpowsour.2013.06.123
17. [17]
  Jiang, R.; Tran, D. T.; McClure, J. P.; Chu, D. Electrochim. Acta 2012, 75, 185. doi: 10.1016/j.electacta.2012.04.098 doi: 10.1016/j.electacta.2012.04.098
18. [18]
  Xie, Y.; Tang, C.; Hao, Z.; Lv, Y.; Yang, R.; Wei, X.; Deng, W.; Wang, A.; Yi, B.; Song, Y. Faraday Discuss. 2014, 176, 393. doi: 10.1039/c4fd00121d doi: 10.1039/c4fd00121d
19. [19]
  Wang, J. Wei, Z. D. Acta Phys. -Chim. Sin. 2017, 33 (5), 886. doi: 10.3866/PKU.WHXB201702092
20. [20]
  Zhai, X., Ding, Y. Acta Phys. -Chim. Sin. 2017, 33 (7), 1366. doi: 10.3866/PKU.WHXB201704173
21. [21]
  Silva, R.; Voiry, D.; Chhowalla, M.; Asefa, T. J. Am. Chem. Soc. 2013, 135 (21), 7823. doi: 10.1021/ja402450a doi: 10.1021/ja402450a
22. [22]
  Yuan, X.; Li, L.; Ma, Z.; Yu, X.; Wen, X.; Ma, Z. F.; Zhang, L.; Wilkinson, D. P.; Zhang, J. Sci. Rep. 2016, 6, 20005. doi: 10.1038/srep20005 doi: 10.1038/srep20005
23. [23]
  Wu, J.; Jin, C.; Yang, Z.; Tian, J.; Yang, R. Carbon 2015, 82, 562. doi: 10.1016/j.carbon.2014.11.008 doi: 10.1016/j.carbon.2014.11.008
24. [24]
  Yan, J.; Meng, H.; Xie, F.; Yuan, X.; Yu, W.; Lin, W.; Ouyang, W.; Yuan, D. J. Power Sources 2014, 245, 772. doi: 10.1016/j.jpowsour.2013.07.003 doi: 10.1016/j.jpowsour.2013.07.003
25. [25]
  Cheon, J. Y.; Kim, T.; Choi, Y.; Jeong, H. Y.; Kim, M. G.; Sa, Y. J.; Kim, J.; Lee, Z.; Yang, T. H.; Kwon, K.; et al. Sci. Rep. 2013, 3, 2715. doi: 10.1038/srep02715 doi: 10.1038/srep02715
26. [26]
  Tan, Y.; Xu, C.; Chen, G.; Fang, X.; Zheng, N.; Xie, Q. Adv. Funct. Mater. 2012, 22 (21), 4584. doi: 10.1002/adfm.201201244 doi: 10.1002/adfm.201201244
27. [27]
  Zheng, X.; Cao, X.; Li, X.; Tian, J.; Jin, C.; Yang, R. Nanoscale 2017, 9 (3), 1059. doi: 10.1039/c6nr07380h doi: 10.1039/c6nr07380h
28. [28]
  Xu, Z.; Zhuang, X.; Yang, C.; Cao, J.; Yao, Z.; Tang, Y.; Jiang, J.; Wu, D.; Feng, X. Adv. Mater. 2016, 28 (10), 1981. doi: 10.1002/adma.201505131 doi: 10.1002/adma.201505131
29. [29]
  Liang, H. W.; Zhuang, X.; Bruller, S.; Feng, X.; Mullen, K. Nat. Commun. 2014, 5, 4973. doi: 10.1038/ncomms5973 doi: 10.1038/ncomms5973
30. [30]
  Yang, J.; Liu, D. J.; Kariuki, N. N.; Chen, L. X. Chem. Commun. 2008, No. 3, 329. doi: 10.1039/b713096a doi: 10.1039/b713096a
31. [31]
  Malko, D.; Kucernak, A.; Lopes, T. J. Am. Chem. Soc. 2016, 138 (49), 16056. doi: 10.1021/jacs.6b09622 doi: 10.1021/jacs.6b09622
32. [32]
  Li, L.; Shen, S.; Wei, G.; Li, X.; Yang, K.; Feng, Q.; Zhang, J. ACS Appl. Mater. Interfaces 2019, 11 (15), 14126. doi: 10.1021/acsami.8b22494 doi: 10.1021/acsami.8b22494
33. [33]
  Zhou, Y.; Cheng, Q.; Huang, Q.; Zou, Z.; Yan, L.; Yang, H. Acta Phys. -Chim. Sin. 2017, 33 (7), 1429. doi: 10.3866/PKU.WHXB201704131
34. [34]
  Lin, L.; Zhu, Q.; Xu, A. W. J. Am. Chem. Soc. 2014, 136 (31), 11027. doi: 10.1021/ja504696r doi: 10.1021/ja504696r
35. [35]
  Li, L.; Yuan, X.; Ma, Z.; Ma, Z. F. J. Electrochem. Soc. 2015, 162 (4), F359. doi: 10.1149/2.0081504jes doi: 10.1149/2.0081504jes
1. [1]
  Hailang JIA , Hongcheng LI , Pengcheng JI , Yang TENG , Mingyun GUAN . Preparation and performance of N-doped carbon nanotubes composite Co₃O₄ as oxygen reduction reaction electrocatalysts. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 693-700. doi: 10.11862/CJIC.20230402
2. [2]
  Xiaofeng Zhu , Bingbing Xiao , Jiaxin Su , Shuai Wang , Qingran Zhang , Jun Wang . Transition Metal Oxides/Chalcogenides for Electrochemical Oxygen Reduction into Hydrogen Peroxides. Acta Physico-Chimica Sinica, 2024, 40(12): 2407005-. doi: 10.3866/PKU.WHXB202407005
3. [3]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
4. [4]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
5. [5]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
6. [6]
  Yi YANG , Shuang WANG , Wendan WANG , Limiao CHEN . Photocatalytic CO₂ reduction performance of Z-scheme Ag-Cu₂O/BiVO₄ photocatalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 895-906. doi: 10.11862/CJIC.20230434
7. [7]
  Jiapei Zou , Junyang Zhang , Xuming Wu , Cong Wei , Simin Fang , Yuxi Wang . A Comprehensive Experiment Based on Electrocatalytic Nitrate Reduction into Ammonia: Synthesis, Characterization, Performance Exploration, and Applicable Design of Copper-based Catalysts. University Chemistry, 2024, 39(6): 373-382. doi: 10.3866/PKU.DXHX202312081
8. [8]
  Yanan Liu , Yufei He , Dianqing Li . Preparation of Highly Dispersed LDHs-based Catalysts and Testing of Nitro Compound Reduction Performance: A Comprehensive Chemical Experiment for Research Transformation. University Chemistry, 2024, 39(8): 306-313. doi: 10.3866/PKU.DXHX202401081
9. [9]
  Jiahong ZHENG , Jingyun YANG . Preparation and electrochemical properties of hollow dodecahedral CoNi₂S₄ supported by MnO₂ nanowires. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1881-1891. doi: 10.11862/CJIC.20240170
10. [10]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
11. [11]
  Tong Zhou , Jun Li , Zitian Wen , Yitian Chen , Hailing Li , Zhonghong Gao , Wenyun Wang , Fang Liu , Qing Feng , Zhen Li , Jinyi Yang , Min Liu , Wei Qi . Experiment Improvement of “Redox Reaction and Electrode Potential” Based on the New Medical Concept. University Chemistry, 2024, 39(8): 276-281. doi: 10.3866/PKU.DXHX202401005
12. [12]
  Ji-Quan Liu , Huilin Guo , Ying Yang , Xiaohui Guo . Calculation and Discussion of Electrode Potentials in Redox Reactions of Water. University Chemistry, 2024, 39(8): 351-358. doi: 10.3866/PKU.DXHX202401031
13. [13]
  Rong Tian , Yadi Yang , Naihao Lu . Comprehensive Experimental Design of Undergraduate Students Based on Interdisciplinarity: Study on the Effect of Quercetin on Chlorination Activity of Myeloperoxidase. University Chemistry, 2024, 39(8): 247-254. doi: 10.3866/PKU.DXHX202312064
14. [14]
  Wenlong LI , Xinyu JIA , Jie LING , Mengdan MA , Anning ZHOU . Photothermal catalytic CO₂ hydrogenation over a Mg-doped In₂O_3-x catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 919-929. doi: 10.11862/CJIC.20230421
15. [15]
  Juntao Yan , Liang Wei . 2D S-Scheme Heterojunction Photocatalyst. Acta Physico-Chimica Sinica, 2024, 40(10): 2312024-. doi: 10.3866/PKU.WHXB202312024
16. [16]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
17. [17]
  Dan Li , Hui Xin , Xiaofeng Yi . Comprehensive Experimental Design on Ni-based Catalyst for Biofuel Production. University Chemistry, 2024, 39(8): 204-211. doi: 10.3866/PKU.DXHX202312046
18. [18]
  Zhanggui DUAN , Yi PEI , Shanshan ZHENG , Zhaoyang WANG , Yongguang WANG , Junjie WANG , Yang HU , Chunxin LÜ , Wei ZHONG . Preparation of UiO-66-NH₂ supported copper catalyst and its catalytic activity on alcohol oxidation. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 496-506. doi: 10.11862/CJIC.20230317
19. [19]
  Juan WANG , Zhongqiu WANG , Qin SHANG , Guohong WANG , Jinmao LI . NiS and Pt as dual co-catalysts for the enhanced photocatalytic H₂ production activity of BaTiO₃ nanofibers. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1719-1730. doi: 10.11862/CJIC.20240102
20. [20]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431

Get Citation

PDF

XML

Metrics

PDF Downloads(13)
Abstract views(837)
HTML views(147)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142