Citation: Qin Yanyan, She Pengfei, Guo Song, Huang Xiaomeng, Liu Shujuan, Zhao Qiang, Huang Wei. Structural Manipulation and Triboluminescence of Tetrahalomanganese(Ⅱ) Complexes[J]. Acta Physico-Chimica Sinica, ;2020, 36(1): 190707. doi: 10.3866/PKU.WHXB201907078 shu

Structural Manipulation and Triboluminescence of Tetrahalomanganese(Ⅱ) Complexes

Qin Yanyan ¹ ,
She Pengfei ¹ ,
Guo Song ¹ ,
Huang Xiaomeng ¹ ,
Liu Shujuan ¹ ,
Zhao Qiang ^1,, ,
Huang Wei ^1,2,,

1.
Institute of Advanced Materials, Key Laboratory for Organic Electronics and Information Displays, Nanjing University of Posts & Telecommunications, Nanjing 210023, P. R. China
2.
Shaanxi Institute of Flexible Electronics, Northwestern Polytechnical University, Xi'an 710072, P. R. China

Corresponding author: Zhao Qiang, iamqzhao@njupt.edu.cn Huang Wei, provost@nwpu.edu.cn
Received Date: 25 July 2019
Revised Date: 2 September 2019
Accepted Date: 3 September 2019
Available Online: 10 January 2019
Fund Project: the China Postdoctoral Science Foundation 2018M642282The project was supported by the National Funds for Distinguished Young Scientists, China (61825503), the China Postdoctoral Science Foundation (2018M642282), the Natural Science Foundation of Jiangsu Province, China (BK20180760) and the Jiangsu Planned Projects for Postdoctoral Research Funds, China (2018K155C)the Natural Science Foundation of Jiangsu Province, China BK20180760the National Funds for Distinguished Young Scientists, China 61825503the Jiangsu Planned Projects for Postdoctoral Research Funds, China 2018K155C

Triboluminescence is a fascinating luminescence phenomenon induced by mechanical stimuli. Triboluminescent materials have potential applications in lighting, displays, and sensing, owing to their distinctive modes of light generation. However, organic triboluminescent materials are severely limited, and their luminescence mechanism remains unclear. Herein, we found that the luminescent manganese(Ⅱ) complex [BPP]₂[MnBr₄] displayed interesting triboluminescence performance. A series of green emissive tetrahalomanganese(Ⅱ) complexes was rationally designed and synthesized. The associated single crystal structures revealed that all complexes consisted of one [MnX₄]²⁻ (X = Br or Cl) ion and two organic cationic ligands per unit cell, with a tetrahedral geometrical symmetry around the Mn(Ⅱ) ion. In addition, the photophysical properties of tetrahalomanganese(Ⅱ) complexes were easily tuned by varying the organic ligands or halogen ions, which is beneficial for these organic-inorganic hybrid structures. Under UV light irradiation, all tetrahalomanganese(Ⅱ) complexes in the solid state exhibited bright green luminescence and a broad featureless emission band at 450–650 nm. The time-resolved photoluminescent decay curves demonstrated that the emission lifetimes of the prepared tetrahalomanganese(Ⅱ) complexes ranged from 260.5 μs to 1.95 ms, which was attributed to phosphorescence. The long-lived emission was mainly due to the spin-forbidden nature of the metal center d–d (⁴T₁(G)→ ⁶A₁) radiative transition. Thermogravimetric analysis was performed to examine the thermodynamic stabilities of the tetrahalomanganese(Ⅱ) complexes. The thermal stabilities of manganese(Ⅱ) complexes with P-based ligands were higher than those of the complexes containing N-based ligands. Upon applying a force to the crystals, the tetrahalomanganese(Ⅱ) complexes all exhibited prominent triboluminescence that could be observed by the naked eye in the dark. Systematic analysis of the crystals showed that the TL activities of the manganese(Ⅱ) complexes were related to the intra- and inter-molecular C-H···X (X = Br or Cl) interactions. The intra- and inter-molecular C-H···X interactions significantly reduced the possible energy loss caused by molecular vibrations and rotations in the [MnX₄]²⁻ unit under mechanical stress, improving TL emission. Moreover, a comparison of photoluminescence and triboluminescence indicated that different excitation sources yielded two distinct luminescence processes: transition of excitons excited by illumination and recombination of electrons and holes on the surface driven by polarization charges. Overall, the results presented herein new opportunities for fundamental research based on the developed class of triboluminescent materials.
- Triboluminescence,
- Manganese(Ⅱ) complex,
- Green-light emission,
- Phosphorescence,
- Intra-/inter-molecular interaction
1. [1]
  Sage, I.; Bourhill, G. J. Mater. Chem. 2001, 11, 231. doi: 10.1039/b007029g doi: 10.1039/b007029g
2. [2]
  Olawale, D. O.; Dickens, T.; Sullivan, W. G.; Okoli, O. I.; Sobanjo, J. O.; Wang, B. J. Lumin. 2011, 131, 1407. doi: 10.1016/j.jlumin.2011.03.015 doi: 10.1016/j.jlumin.2011.03.015
3. [3]
  Eddingsaas, N. C.; Suslick, K. S. J. Am. Chem. Soc. 2007, 129, 6718. doi: 10.1021/ja0716498 doi: 10.1021/ja0716498
4. [4]
  Wang, X. D.; Zhang, H. L.; Yu, R. M.; Dong, L.; Peng, D. F.; Zhang, A. H.; Zhang, Y.; Liu, H.; Pan, C. F.; Wang, Z. L. Adv. Mater. 2015, 27, 2324. doi: 10.1002/adma.201405826 doi: 10.1002/adma.201405826
5. [5]
  Li, W. L.; Huang, Q. Y.; Mao, Z.; Li, Q.; Jiang, L.; Xie, Z. L.; Xu, R.; Yang, Z. Y.; Zhao, J.; Yu, T.; et al. Angew. Chem. Int. Ed. 2018, 57, 12727. doi: 10.1002/anie.201806861 doi: 10.1002/anie.201806861
6. [6]
  Yang, J.; Ren, Z. C.; Xie, Z. L.; Liu, Y. J.; Wang, C.; Xie, Y. J.; Peng, Q.; Xu, B.; Tian, W. J.; Zhang, F.; et al. Angew. Chem. Int. Ed. 2017, 56, 880. doi: 10.1002/anie.201610453 doi: 10.1002/anie.201610453
7. [7]
  Wong, H. Y.; Lo, W. S.; Chan, W. T. K.; Law G. L. Inorg. Chem. 2017, 56, 5135. doi: 10.1021/acs.inorgchem.7b00273 doi: 10.1021/acs.inorgchem.7b00273
8. [8]
  Hirai, Y.; Nakanishi, T.; Kitagawa, Y.; Fushimi, K.; Seki, T.; Ito, H.; Hasegawa, Y. Angew. Chem. Int. Ed. 2017, 56, 7171. doi: 10.1002/anie.201703638 doi: 10.1002/anie.201703638
9. [9]
  Hirai, Y.; da Rosa, P. P. F.; Nakanishi, T.; Kitagawa, Y.; Fushimi, K.; Seki, T.; Ito, H.; Hasegawa, Y. Inorg. Chem. 2018, 57, 14653. doi: 10.1021/acs.inorgchem.8b02367 doi: 10.1021/acs.inorgchem.8b02367
10. [10]
  Xie, Z. L.; Yu, T.; Chen, J. R.; Ubba, E.; Wang, L. Y.; Mao, Z.; Su, T. T.; Zhang, Y.; Aldred, M. P.; Chi, Z. G. Chem. Sci. 2018, 9, 5787. doi: 10.1039/c8sc01703d doi: 10.1039/c8sc01703d
11. [11]
  Wang, J. Q.; Wang, C.; Gong, Y. B.; Liao, Q. Y.; Han, M. M.; Jiang, T. J.; Dang, Q. X.; Li, Y. Q.; Li, Q. Q.; Li, Z. Angew. Chem. Int. Ed. 2018, 57, 16821. doi: 10.1002/anie.201811660 doi: 10.1002/anie.201811660
12. [12]
  Yang, J.; Gao, X. M.; Xie, Z. L.; Gong, Y. B.; Fang, M. M.; Peng, Q.; Chi, Z. G.; Li, Z. Angew. Chem. Int. Ed. 2017, 56, 15299. doi: 10.1002/anie.201708119 doi: 10.1002/anie.201708119
13. [13]
  Yang, J.; Qin, J. W.; Geng, P. Y.; Wang, J. Q.; Fang, M. M.; Li, Z. Angew. Chem. Int. Ed. 2018, 57, 14174. doi: 10.1002/anie.201809463 doi: 10.1002/anie.201809463
14. [14]
  Marchetti, F.; Nicola, D. C.; Pettinari, R.; Timokhin, I.; Pettinari, C. J. Chem. Educ. 2012, 89, 652. doi: 10.1021/ed2001494 doi: 10.1021/ed2001494
15. [15]
  Wrighton, M.; Ginley, D. Chem. Phys. 1974, 4, 295. doi: 10.1016/0301-0104(74)80097-2 doi: 10.1016/0301-0104(74)80097-2
16. [16]
  Cotton, F. A.; Goodgame, D. M. L.; Goodgame, M. J. Am. Chem. Soc. 1962, 84, 167. doi: 10.1021/ja00861a008 doi: 10.1021/ja00861a008
17. [17]
  Hardy, G. E.; Zink, J. I. Inorg. Chem. 1976, 15, 3061. doi: 10.1021/ic50166a026 doi: 10.1021/ic50166a026
18. [18]
  Pitula, S.; Mudring, A. V. Chem. Eur. J. 2010, 16, 3355. doi: 10.1002/chem.200802660 doi: 10.1002/chem.200802660
19. [19]
  Zhang, Y.; Liao, W. Q.; Fu, D. W.; Ye, H. Y.; Liu, C. M.; Chen, Z. N.; Xiong, R. G. Adv. Mater. 2015, 27, 3942. doi: 10.1002/adma.201501026 doi: 10.1002/adma.201501026
20. [20]
  Bortoluzzi, M.; Castro, J.; Enrichi, F.; Vomiero, A.; Busato, M.; Huang, W. Z. Inorg. Chem. Commun. 2018, 92, 145. doi: 10.1016/j.inoche.2018.04.023 doi: 10.1016/j.inoche.2018.04.023
21. [21]
  Hausmann, D.; Kuzmanoski A.; Feldmann, C. Dalton Trans. 2016, 45, 6541. doi: 10.1039/c6dt00458j doi: 10.1039/c6dt00458j
22. [22]
  Berezin, A. S.; Samsonenko, D. G.; Brel, V. K.; Artem'ev, A. V. Dalton Trans. 2018, 47, 7306. doi: 10.1039/c8dt01041b doi: 10.1039/c8dt01041b
23. [23]
  Wu, Y.; Zhang, X.; Xu, L. J.; Yang, M.; Chen, Z. N. Inorg. Chem. 2018, 57, 9175. doi: 10.1021/acs.inorgchem.8b01205 doi: 10.1021/acs.inorgchem.8b01205
24. [24]
  Xu, L. J.; Sun, C. Z.; Xiao, H.; Wu, Y.; Chen, Z. N. Adv. Mater. 2017, 29, 1605739. doi: 10.1002/adma.201605739 doi: 10.1002/adma.201605739
25. [25]
  Qin, Y. Y.; Tao, P.; Gao, L.; She, P. F.; Liu, S. J.; Li, X. L.; Li, F. Y.; Wang, H.; Zhao, Q.; Miao, Y. Q.; et al. Adv. Optical Mater. 2019, 7, 1801160. doi: 10.1002/adom.201801160 doi: 10.1002/adom.201801160
26. [26]
  Cotton, F. A.; Daniels, L. M.; Huang, P. L. Inorg. Chem. 2001, 40, 3576. doi: 10.1021/ic0101836 doi: 10.1021/ic0101836
27. [27]
  Balsamy, S.; Natarajan, P.; Vedalakshmi, R.; Muralidharan, S. Inorg. Chem. 2014, 53, 6054. doi: 10.1021/ic500400y doi: 10.1021/ic500400y
28. [28]
  Chen, J.; Zhang, Q.; Zheng, F. K.; Liu, Z. F.; Wang, S. H.; Wu, A. Q.; Guo, G. C. Dalton Trans. 2015, 44, 3289. doi: 10.1039/c4dt03694h doi: 10.1039/c4dt03694h
29. [29]
  Jiang, D. M.; Bo, L.; Zhu, T.; Tao, J. B.; Yang. X. P. Acta Phys. -Chim. Sin. 2018, 34, 812. doi: 10.3866/PKU.WHXB201801086
30. [30]
  Xia, H. Y.; Geng, T.; Zhao, Xu.; Li, F. F.; Wang, F. Y.; Gao, L. N. Acta Phys. -Chim. Sin. 2019, 35, 337. doi: 10.3866/PKU.WHXB201803082
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