Citation: Wang Jiu, Wu Nanshi, Liu Tao, Cao Shaowen, Yu Jiaguo. MnCo Oxides Supported on Carbon Fibers for High-Performance Supercapacitors[J]. Acta Physico-Chimica Sinica, ;2020, 36(7): 190707. doi: 10.3866/PKU.WHXB201907072 shu

MnCo Oxides Supported on Carbon Fibers for High-Performance Supercapacitors

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, P. R. China

Corresponding author: Cao Shaowen, swcao@whut.edu.cn Yu Jiaguo, jiaguoyu@yahoo.com; yujiaguo93@whut.edu.cn
Received Date: 25 July 2019
Revised Date: 9 September 2019
Accepted Date: 11 September 2019
Available Online: 24 September 2019
Fund Project: the National Natural Science Foundation of China 51922081the National Natural Science Foundation of China U1705251the Natural Science Foundation of Hubei Province, China 2017CFA031the Fundamental Research Funds for the Central Universities, China WUT: 2019-Ⅲ-196the National Natural Science Foundation of China 21773179the National Natural Science Foundation of China 21433007The project was supported by the National Natural Science Foundation of China (51922081, 21773179, U1705251, 21433007), the Natural Science Foundation of Hubei Province, China (2017CFA031), and the Fundamental Research Funds for the Central Universities, China (WUT: 2019-Ⅲ-196)

The development of high-performance supercapacitor electrode materials is imperative to alleviate the ongoing energy crisis. Numerous transition metals (oxides) have been studied as electrode materials for supercapacitors owing to their low cost, environmental-friendliness, and excellent electrochemical performance. Among the developed binary transition metal oxides, manganese cobalt oxides typically show high theoretical capacitance and stable electrochemical performance, and are widely used in the electrode materials of supercapacitors. However, the poor conductivity and active material utilization of manganese cobalt oxide-based electrode materials limit their potential capacitance application. Cotton is mainly composed of organic carbon-containing materials, which can be transformed to carbon fibers after calcination. The resultant carbonaceous material exhibits a large specific surface area and good conductivity. Such advantages could potentially suppress the negative effects caused by the poor conductivity and small specific surface area of manganese cobalt oxides, thereby improving the electrochemical performance. Herein, we firstly deposited manganese cobalt oxides on cotton by a simple hydrothermal method, yielding a composite of manganese cobalt oxides and carbon fibers via subsequent calcination, to improve the electrochemical performance of the electrode material. X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET), thermogravimetric analysis (TGA), and electrochemical characterizations were used to investigate the physical, chemical, and electrochemical properties of the prepared samples. The fabricated manganese cobalt oxides in the composite were uniformly dispersed on the carbon fiber surface, which increased the contact between the interface of the electrode material and electrolyte, and enhanced electrode material utilization. The electrode material was confirmed to have well contacted with the electrolyte during a contact angle test. Hence, a pseudo-capacitance reaction completely occurred on the manganese cobalt oxide material. Moreover, the addition of carbon fibers reduced the resistance of the material, resulting in excellent capacitive performance. The capacitance of the prepared composite was 854 F∙g^-1 at a current density of 2 A∙g^-1. The capacitance was maintained at 72.3% after 2000 cycles at a current density of 2 A∙g^-1. These results indicate that the manganese cobalt oxide and carbon fiber composite is a promising electrode material for high-performance supercapacitors. The findings presented herein provide a strategy for coupling with carbon materials to enhance the performance of supercapacitor electrode materials based on manganese cobalt oxides. Thus, novel insights into the design of high-performance supercapacitors for energy management are provided.
- Manganese cobalt oxide,
- Carbon fiber,
- Supercapacitor,
- Composite,
- Contact
1. [1]
  Miller, J. R.; Simon, P. Science 2008, 321, 651. doi: 10.1126/science.1158736 doi: 10.1126/science.1158736
2. [2]
  Dong, X. C.; Xu, H.; Wang, X. W.; Huang, Y. X.; Chan-Park, M. B.; Zhang, H.; Wang, L. H.; Huang, W.; Chen, P. ACS Nano 2012, 6, 3206. doi: 10.1021/nn300097q doi: 10.1021/nn300097q
3. [3]
  Li, B.; Dai, F.; Xiao, Q. F.; Yang, L.; Shen, J. M.; Zhang, C. M.; Cai, M. Energy Environ. Sci. 2016, 9, 102. doi: 10.1039/C5EE03149D doi: 10.1039/C5EE03149D
4. [4]
  Liu, X. Y.; Gao, Y. Q.; Yang, G. W. Nanoscale 2016, 8, 4227. doi: 10.1039/C5NR09145D doi: 10.1039/C5NR09145D
5. [5]
  Qu, G. X.; Cheng, J. L.; Li, X. D.; Yuan, D. M.; Chen, P. N.; Chen, X. L.; Wang, B.; Peng, H. S. Adv. Mater. 2016, 28, 3646. doi: 10.1002/adma.201600689 doi: 10.1002/adma.201600689
6. [6]
  Liu, T.; Zhang, L. Y.; Cheng, B.; Yu, J. G. Adv. Energy Mater. 2019, 9, 1803900. doi: 10.1002/aenm.201803900 doi: 10.1002/aenm.201803900
7. [7]
  Yang, H. C.; Bo, Z.; Shuai, X. R.; Yan, J. H.; Cen, K. F. Acta Phys. -Chim. Sin. 2019, 35, 200. doi: 10.3866/PKU.WHXB201803083
8. [8]
  Wang, H. Y.; Shi, G. Q. Acta Phys. -Chim. Sin. 2017, 34, 22. doi: 10.3866/PKU.WHXB201706302
9. [9]
  Naoi, K.; Kisu, K.; Iwama, E.; Nakashima, S.; Sakai, Y.; Orikasa, Y.; Leone, P.; Dupré, N.; Brousse, T.; Rozier, P. Energy Environ. Sci. 2016, 9, 2143. doi: 10.1039/C6EE00829A doi: 10.1039/C6EE00829A
10. [10]
  Godillot, G.; Taberna, P. L.; Daffos, B.; Simon, P.; Delmas, C.; Guerlou-Demourgues, L. J. Power Sources 2016, 331, 277. doi: 10.1016/j.jpowsour.2016.09.035 doi: 10.1016/j.jpowsour.2016.09.035
11. [11]
  Chen, Y. Y.; Liu, T.; Zhang, L. Y.; Yu, J. G. ACS Sustain. Chem. Eng. 2019, 7, 11157. doi: 10.1021/acssuschemeng.9b00284 doi: 10.1021/acssuschemeng.9b00284
12. [12]
  Chen, Y. Y.; Liu, T.; Zhang, L. Y.; Yu, J. G. Appl. Surf. Sci. 2019, 484, 135. doi: 10.1016/j.apsusc.2019.04.074 doi: 10.1016/j.apsusc.2019.04.074
13. [13]
  Yang, K.; Shuai, X. R.; Yang, H. C.; Yan, J. H.; Cen, K. F. Acta Phys. -Chim. Sin. 2019, 35, 755. doi: 10.3866/PKU.WHXB201810009
14. [14]
  Kang, Y. J.; Chun, S. J.; Lee, S. S.; Kim, B. Y.; Kim, J. H.; Chung, H.; Lee, S. Y.; Kim, W. ACS Nano 2012, 6, 6400. doi: 10.1021/nn301971r doi: 10.1021/nn301971r
15. [15]
  Liu, T.; Jiang, C. J.; Cheng, B.; You, W.; Yu, J. G. J. Power Sources 2017, 359, 371. doi: 10.1016/j.jpowsour.2017.05.100 doi: 10.1016/j.jpowsour.2017.05.100
16. [16]
  Shen, X. Y.; He, J. N.; Wang, N.; Huang, C. S. Acta Phys.-Chim. Sin. 2018, 34, 1029. doi: 10.3866/PKU.WHXB201801122
17. [17]
  Zhang, L. Y.; Shi, D. W.; Liu, T.; Jaroniec, M.; Yu, J. G. Mater. Today 2018, 25, 35. doi: 10.1016/j.mattod.2018.11.002 doi: 10.1016/j.mattod.2018.11.002
18. [18]
  Wang, G. P.; Zhang, L.; Zhang, J. J. Chem. Soc. Rev. 2012, 41, 797. doi: 10.1039/C1CS15060J doi: 10.1039/C1CS15060J
19. [19]
  Kaewsongpol, T.; Sawangphruk, M.; Chiochan, P.; Suksomboon, M.; Suktha, P.; Srimuk, P.; Krittayavathananon, A.; Luanwuthi, S.; Iamprasertkun, P.; Wutthiprom, J. Mater. Today Commun. 2015, 4, 176. doi: 10.1016/j.mtcomm.2015.08.005 doi: 10.1016/j.mtcomm.2015.08.005
20. [20]
  Sawangphruk, M.; Suksomboon, M.; Kongsupornsak, K.; Khuntilo, J.; Srimuk, P.; Sanguansak, Y.; Klunbud, P.; Suktha, P.; Chiochan, P. J. Mater. Chem. A 2013, 1, 9630. doi: 10.1039/C3TA12194A doi: 10.1039/C3TA12194A
21. [21]
  Sawangphruk, M.; Srimuk, P.; Chiochan, P.; Krittayavathananon, A.; Luanwuthi, S.; Limtrakul, J. Carbon 2013, 60, 109. doi: 10.1016/j.carbon.2013.03.062 doi: 10.1016/j.carbon.2013.03.062
22. [22]
  Sawangphruk, M.; Pinitsoontorn, S.; Limtrakul, J. J. Solid State Electrochem. 2012, 16, 2623. doi: 10.1007/s10008-012-1691-x doi: 10.1007/s10008-012-1691-x
23. [23]
  Li, W. Y.; Xu, K. B.; Song, G. S.; Zhou, X. Y.; Zou, R. J.; Yang, J. M.; Chen, Z. G.; Hu, J. Q. CrystEngComm 2014, 16, 2335. doi: 10.1039/C3CE42581A doi: 10.1039/C3CE42581A
24. [24]
  Xu, Y. N.; Wang, X. F.; An, C. H.; Wang, Y. J.; Jiao, L. F.; Yuan, H. T. J. Mater. Chem. A 2014, 2, 16480. doi: 10.1039/C4TA03123G doi: 10.1039/C4TA03123G
25. [25]
  Chen, S.; Chen, H. C.; Li, C.; Fan, M. Q.; Lv, C. J.; Tian, G. L.; Shu, K. Y. J. Mater. Sci. 2017, 52, 6687. doi: 10.1007/s10853-017-0903-2 doi: 10.1007/s10853-017-0903-2
26. [26]
  Padmanathan, N.; Selladurai, S. Ionics 2014, 20, 479. doi: 10.1007/s11581-013-1009-8 doi: 10.1007/s11581-013-1009-8
27. [27]
  Hao, P.; Zhao, Z. H.; Li, L. Y.; Tuan, C. C.; Li, H. D.; Sang, Y. H.; Jiang, H. D.; Wong, C. P.; Liu, H. Nanoscale 2015, 7, 14401. doi: 10.1039/C5NR04421A doi: 10.1039/C5NR04421A
28. [28]
  Zhao, Y.; Hu, L. F.; Zhao, S. Y.; Wu, L. M. Adv. Funct. Mater. 2016, 26, 4085. doi: 10.1002/adfm.201600494 doi: 10.1002/adfm.201600494
29. [29]
  Liu, T.; Zhang, L. Y.; Cheng, B.; You, W.; Yu, J. G. Chem. Commun. 2018, 54, 3731. doi: 10.1039/C8CC00991K doi: 10.1039/C8CC00991K
30. [30]
  Ouyang, J. Y. Acta Phys. -Chim. Sin. 2018, 34, 1211. doi: 10.3866/PKU.WHXB201804095
31. [31]
  Wei, T. Y.; Chen, C. H.; Chien, H. C.; Lu, S. Y.; Hu, C. C. Adv. Mater. 2010, 22, 347. doi: 10.1002/adma.200902175 doi: 10.1002/adma.200902175
32. [32]
  Liu, T.; Li, L. M.; Zhang, L. Y.; Cheng, B.; Yu, J. G. J. Power Sources 2019, 426, 266. doi: 10.1016/j.jpowsour.2019.04.053 doi: 10.1016/j.jpowsour.2019.04.053
33. [33]
  Xu, L. Q. Y.; Zhang, L. Y.; Cheng, B.; Yu, J. G. Carbon 2019, 152, 652. doi: 10.1016/j.carbon.2019.06.062 doi: 10.1016/j.carbon.2019.06.062
34. [34]
  Lu, Q.; Chen, Y. P.; Li, W. F.; Chen, J. G. G.; Xiao, J. Q.; Jiao, F. J. Mater. Chem. A 2013, 1, 2331. doi: 10.1039/C2TA00921H doi: 10.1039/C2TA00921H
35. [35]
  Wang, H. L.; Gao, Q. M.; Jiang, L. Small 2011, 7, 2454. doi: 10.1002/smll.201100534 doi: 10.1002/smll.201100534
36. [36]
  Wu, N. S.; Low, J. X.; Liu, T.; Yu, J. G.; Cao, S. W. Appl. Surf. Sci. 2017, 413, 35. doi: 10.1016/j.apsusc.2017.03.297 doi: 10.1016/j.apsusc.2017.03.297
37. [37]
  Li, J. F.; Xiong, S. L.; Liu, Y. R.; Ju, Z. C.; Qian, Y. T. ACS Appl. Mater. Interfaces 2013, 5, 981. doi: 10.1021/am3026294 doi: 10.1021/am3026294
38. [38]
  Li, L.; Zhang, Y. Q.; Liu, X. Y.; Shi, S. J.; Zhao, X. Y.; Zhang, H.; Ge, X.; Cai, G. F.; Gu, C. D.; Wang, X. L. Electrochim. Acta 2014, 116, 467. doi: 10.1016/j.electacta.2013.11.081 doi: 10.1016/j.electacta.2013.11.081
39. [39]
  Gomez, J.; Kalu, E. E. J. Power Sources 2013, 230, 218. doi: 10.1016/j.jpowsour.2012.12.069 doi: 10.1016/j.jpowsour.2012.12.069
40. [40]
  Jagdale, P.; Koumoulos, E. P.; Cannavaro, I.; Khan, A.; Castellino, M.; Dragatogiannis. D. A.; Tagliaferro A.; Charitidis, C. A. Manufacturing Rev. 2017, 4, 10. doi: 10.1051/mfreview/2017008 doi: 10.1051/mfreview/2017008
41. [41]
  Yan, J.; Fan, Z. J.; Wei, T.; Cheng, J.; Shao, B.; Wang, K.; Song, L. P.; Zhang, M. L. J. Power Sources 2009, 194, 1202. doi: 10.1016/j.jpowsour.2009.06.006 doi: 10.1016/j.jpowsour.2009.06.006
42. [42]
  Lu, W. J.; Liu, M. X.; Miao, L.; Zhu, D. Z.; Wang, X.; Duan. H.; Wang, Z. W.; Li, L. C.; Xu Z. J.; Gan, L. H.; et al. Electrochim. Acta 2016, 205, 132. doi: 10.1016/j.electacta.2016.04.114 doi: 10.1016/j.electacta.2016.04.114
43. [43]
  Thommes, M.; Kaneko, K.; Neimark, A. V.; Olivier, J. P.; Rodriguez-Reinoso, F.; Rouquerol, J.; Sing, K. S. Pure Appl. Chem. 2015, 87, 1051. doi: 10.1515/pac-2014-1117 doi: 10.1515/pac-2014-1117
44. [44]
  Wu, S. S.; Chen, W. F.; Yan, L. F. J. Mater. Chem. A 2014, 2, 2765. doi: 10.1039/C3TA14387B doi: 10.1039/C3TA14387B
45. [45]
  Wang, X.; Liu, W. S.; Lu, X. H.; Lee, P. S. J. Mater. Chem. 2012, 22, 23114. doi: 10.1039/C2JM35307E doi: 10.1039/C2JM35307E
46. [46]
  Gao, H. C.; Xiao F.; Ching, C. B.; Duan H. W. ACS Appl. Mater. Inter. 2012, 4, 2801. doi: 10.1021/am300455d doi: 10.1021/am300455d
47. [47]
  Jing, M. J.; Hou, H. S.; Yang, Y. C.; Zhu, Y. R.; Wu, Z. B.; Ji, X. B. Electrochim. Acta 2015, 165, 198. doi: 10.1016/j.electacta.2015.03.032 doi: 10.1016/j.electacta.2015.03.032
48. [48]
  Sun, L.; Zhang, Y. X.; Zhang, Y.; Si, H. C.; Qin, W. P.; Zhang, Y. H. Chem. Commun. 2018, 54, 10172. doi: 10.1039/C8CC05745A doi: 10.1039/C8CC05745A
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