Citation: Liu Dongmei, Chen Xiumei, Yuan Ze, Lu Min, Yin Lisha, Xie Xiaoji, Huang Ling. Coating and Transforming the Y(OH)CO₃ Shell on Upconversion Nanoparticles[J]. Acta Physico-Chimica Sinica, ;2020, 36(7): 190701. doi: 10.3866/PKU.WHXB201907011 shu

Coating and Transforming the Y(OH)CO₃ Shell on Upconversion Nanoparticles

Institute of Advanced Materials, Nanjing Tech University, Nanjing 211816, P.R. China

Corresponding author: Yin Lisha, iamlsyin@njtech.edu.cn Xie Xiaoji, iamxjxie@njtech.edu.cn
Received Date: 1 July 2019
Revised Date: 25 July 2019
Accepted Date: 26 July 2019
Available Online: 2 August 2019
Fund Project: The project was supported by the National Key Research and Development Program of China (2017YFB1002900) and the Natural Science Foundation of Jiangsu Province, China (BK20160987)the National Key Research and Development Program of China 2017YFB1002900the Natural Science Foundation of Jiangsu Province, China BK20160987

Along with the promising applications of lanthanide doped upconversion nanomaterials in diverse fields such as biology, anti-counterfeiting, and lasering, the demand for multifunctional upconversion nanomaterials is increasing. One effective means of obtaining these nanomaterials is to fabricate upconversion nanomaterial-based heterostructures, which may provide superior properties as compared to the sum of the parts. However, obtaining heterostructured upconversion nanomaterials remains challenging mainly because of the crystal lattice mismatch between upconversion nanomaterials and other materials. Typically used strategies for synthesizing upconversion nanomaterial-based heterostructures are applicable only to limited types of materials. Alternatively, transformation of the intermediate layer is a promising strategy used to obtain these heterostructures. Nevertheless, this method remains in its infancy and, to date, only a few intermediate layers have been developed. New types of intermediate layers are therefore highly desirable. In this study, we show that amorphous Y(OH)CO₃ can be a promising candidate as an intermediate layer for fabricating upconversion nanoparticle-based heterostructures. As a proof-of-concept experiment, ligand-free NaGdF₄:Yb/Tm upconversion nanoparticles were first prepared as core nanoparticles. The Y(OH)CO₃ shell was then directly coated on the NaGdF₄:Yb/Tm upconversion nanoparticles in an aqueous solution using urea and Y(NO₃)₃, by a homogeneous precipitation approach. The thickness of the resulting Y(OH)CO₃ shell could be tuned by adjusting the amounts of either urea or Y(NO₃)₃. The as-coated Y(OH)CO₃ shell could be easily converted to YOF by heating at 300 ℃, yielding NaGdF₄:Yb/Tm@YOF core-shell heterostructured nanoparticles. In addition, we found that the NaGdF₄ core could be transformed to lanthanide oxide fluoride if the NaGdF₄:Yb/Tm@Y(OH)CO₃ core-shell nanoparticles were heated at 350 ℃. We also observed that treating the NaGdF₄:Yb/Tm@Y(OH)CO₃ core-shell nanoparticles at even higher temperatures (e.g., 400 ℃) produced aggregations of nanoparticles without regular morphologies. The transformation of the shell can be attributed to the decomposition of Y(OH)CO₃ and reactions between the Y(OH)CO₃ shell and NaGdF₄ core. Meanwhile, the transformation of the NaGdF₄ core at relatively high temperatures could be primarily due to the reactions between Y(OH)CO₃ and NaGdF₄. Notably, in this study, the core-shell structured nanoparticles, with either a Y(OH)CO₃ or YOF shell, maintained the photon upconversion properties of NaGdF₄:Yb/Tm upconversion nanoparticles. In addition, the method used here could be extended to the coating of other shells such as Tb(OH)CO₃ and Yb(OH)CO₃ on upconversion nanoparticles. Moreover, the NaGdF₄:Yb/Tm@Y(OH)CO₃ core-shell nanoparticles could be transformed to other nanoparticles with novel structures such as yolk-shell nanoparticles. These results can pave the way for preparing upconversion nanoparticle-based heterostructures and multifunctional composites, thus promoting new applications of upconversion nanoparticles.
- Lanthanide,
- Doping,
- Luminescence,
- Core-shell,
- Nanomaterials
1. [1]
  Dong, H.; Du, S. R.; Zheng, X. Y.; Lyu, G. M.; Sun, L. D.; Li, L. D.; Zhang, P. Z.; Zhang, C.; Yan, C. H. Chem. Rev. 2015, 115, 10725. doi: 10.1021/acs.chemrev.5b00091 doi: 10.1021/acs.chemrev.5b00091
2. [2]
  Chen, S.; Weitemier, A. Z.; Zeng, X.; He, L.; Wang, X.; Tao, Y.; Huang, A. J. Y.; Hashimotodani, Y.; Kano, M.; Iwasaki, H.; et al. Science 2018, 359, 679. doi: 10.1126/science.aaq1144 doi: 10.1126/science.aaq1144
3. [3]
  Feng, Y.; Yang, C.; Fang, W.; Huang, B.; Shao, Q.; Huang, X. Nano Energy 2019, 58, 234. doi: 10.1016/j.nanoen.2019.01.036 doi: 10.1016/j.nanoen.2019.01.036
4. [4]
  Bu, L.; Zhang, N.; Guo, S.; Zhang, X.; Li, J.; Yao, J.; Wu, T.; Lu, G.; Ma, J. Y.; Su, D.; et al. Science 2016, 354, 1410. doi: 10.1126/science.aah6133 doi: 10.1126/science.aah6133
5. [5]
  Yuan, Z.; Zhang, L.; Li, S.; Zhang, W.; Lu, M.; Pan, Y.; Xie, X.; Huang, L.; Huang, W. J. Am. Chem. Soc. 2018, 140, 15507. doi: 10.1021/jacs.8b10122 doi: 10.1021/jacs.8b10122
6. [6]
  Fan, Y.; Liu, L.; Zhang, F. Nano Today 2019, 25, 68. doi: 10.1016/j.nantod.2019.02.009 doi: 10.1016/j.nantod.2019.02.009
7. [7]
  Chaudhuri, G. R.; Paria, S. Chem. Rev. 2012, 112, 2373. doi: 10.1021/cr100449n doi: 10.1021/cr100449n
8. [8]
  Hudry, D.; Howard, I. A.; Popescu, R.; Gerthsen, D.; Richards, B. S. Adv. Mater. 2019, 31, 1900623. doi: 10.1002/adma.201900623 doi: 10.1002/adma.201900623
9. [9]
  Chen, G.; Ågren, H.; Ohulchanskyy, T. Y.; Prasad, P. N. Chem. Soc. Rev. 2015, 44, 1680. doi: 10.1039/C4CS00170B doi: 10.1039/C4CS00170B
10. [10]
  Chen, X.; Peng, D.; Ju, Q.; Wang, F. Chem. Soc. Rev. 2015, 44, 1318. doi: 10.1039/C4CS00151F doi: 10.1039/C4CS00151F
11. [11]
  Yu, S.; Tu, D.; Lian, W.; Xu, J.; Chen, X. Sci. China Mater. 2019, 62, 1071. doi: 10.1007/s40843-019-9414-4 doi: 10.1007/s40843-019-9414-4
12. [12]
  Zhou, B.; Shi, B.; Jin, D.; Liu, X. Nat. Nanotechnol. 2015, 10, 924. doi: 10.1038/nnano.2015.251 doi: 10.1038/nnano.2015.251
13. [13]
  Yang, D.; Ma, P.; Hou, Z.; Cheng, Z.; Li, C.; Lin, J. Chem. Soc. Rev. 2015, 44, 1416. doi: 10.1039/C4CS00155A doi: 10.1039/C4CS00155A
14. [14]
  Lyu, L.; Cheong, H.; Ai, X.; Zhang, W.; Li, J.; Yang, H. H.; Lin, J.; Xing, B. NPG Asia Mater. 2018, 10, 685. doi: 10.1038/s41427-018-0065-y doi: 10.1038/s41427-018-0065-y
15. [15]
  Zhang, Z.; Shikha, S.; Liu, J.; Zhang, J.; Mei, Q.; Zhang, Y. Anal. Chem. 2019, 91, 548. doi: 10.1021/acs.analchem.8b04049 doi: 10.1021/acs.analchem.8b04049
16. [16]
  Hirsh, D. A.; Johnson, N. J. J.; van Veggel, F. C. J. M.; Schurko, R. W. Chem. Mater. 2015, 27, 6495. doi: 10.1021/acs.chemmater.5b01986 doi: 10.1021/acs.chemmater.5b01986
17. [17]
  Bai, H. R.; Fan, H. H.; Zhang, X. B.; Chen, Z.; Tan, W. H. Acta Phys. -Chim. Sin. 2018, 34, 348. doi: 10.3866/PKU.WHXB201708311
18. [18]
  Arboleda, C.; He, S.; Stubelius, A.; Johnson, N. J. J.; Almutairi, A. Chem. Mater. 2019, 31, 3103. doi: 10.1021/acs.chemmater.8b04057 doi: 10.1021/acs.chemmater.8b04057
19. [19]
  Zhao, H.; Xia, J.; Yin, D.; Luo, M.; Yan, C.; Du, Y. Coord. Chem. Rev. 2019, 390, 32. doi: 10.1016/j.ccr.2019.03.011 doi: 10.1016/j.ccr.2019.03.011
20. [20]
  Cui, C.; Tou, M.; Li, M.; Luo, Z.; Xiao, L.; Bai, S.; Li, Z. Inorg. Chem. 2017, 56, 2328. doi: 10.1021/acs.inorgchem.6b03079 doi: 10.1021/acs.inorgchem.6b03079
21. [21]
  Tang, Y.; Di, W.; Zhai, X.; Yang, R.; Qin, W. ACS Catal. 2013, 3, 405. doi: 10.1021/cs300808r doi: 10.1021/cs300808r
22. [22]
  Li, Y.; Di, Z.; Gao, J.; Cheng, P.; Di, C.; Zhang, G.; Liu, B.; Shi, X.; Sun, L. D.; Li, L.; et al. J. Am. Chem. Soc. 2017, 139, 13804. doi: 10.1021/jacs.7b07302 doi: 10.1021/jacs.7b07302
23. [23]
  Xu, J.; Xu, L.; Wang, C.; Yang, R.; Zhuang, Q.; Han, X.; Dong, Z.; Zhu, W.; Peng, R.; Liu, Z. ACS Nano 2017, 11, 4463. doi: 10.1021/acsnano.7b00715 doi: 10.1021/acsnano.7b00715
24. [24]
  Feng, L.; He, F.; Dai, Y.; Gai, S.; Zhong, C.; Li, C.; Yang, P. Biomater. Sci. 2017, 5, 2456. doi: 10.1039/C7BM00798A doi: 10.1039/C7BM00798A
25. [25]
  Chen, J.; Zhang, D.; Zou, Y.; Wang, Z.; Hao, M.; Zheng, M.; Xue, X.; Pan, X.; Lu, Y.; Wang, J.; et al. J. Mater. Chem. B 2018, 6, 7862. doi: 10.1039/C8TB02213E doi: 10.1039/C8TB02213E
26. [26]
  Dong, H.; Sun, L. D.; Li, L. D.; Si, R.; Liu, R.; Yan, C. H. J. Am. Chem. Soc. 2017, 139, 18492. doi: 10.1021/jacs.7b11836 doi: 10.1021/jacs.7b11836
27. [27]
  Su, Q.; Feng, W.; Yang, D.; Li, F. Acc. Chem. Res. 2017, 50, 32. doi: 10.1021/acs.accounts.6b00382 doi: 10.1021/acs.accounts.6b00382
28. [28]
  Zuo, J.; Sun, D.; Tu, L.; Wu, Y.; Cao, Y.; Xue, B.; Zhang, Y.; Chang, Y.; Liu, X.; Kong, X.; et al. Angew. Chem. Int. Ed. 2018, 57, 3054. doi: 10.1002/anie.201711606 doi: 10.1002/anie.201711606
29. [29]
  Lay, A.; Siefe, C.; Fischer, S.; Mehlenbacher, R. D.; Ke, F.; Mao, W. L.; Alivisatos, A. P.; Goodman, M. B.; Dionne, J. A. Nano Lett. 2018, 18, 4454. doi: 10.1021/acs.nanolett.8b01535 doi: 10.1021/acs.nanolett.8b01535
30. [30]
  Yang, G.; Yang, D.; Yang, P.; Lv, R.; Li, C.; Zhong, C.; He, F.; Gai, S.; Lin, J. Chem. Mater. 2015, 27, 7957. doi: 10.1021/acs.chemmater.5b03136 doi: 10.1021/acs.chemmater.5b03136
31. [31]
  Tou, M.; Luo, Z.; Bai, S.; Liu, F.; Chai, Q.; Li, S.; Li, Z. Mater. Sci. Eng. C 2017, 70, 1141. doi: 10.1016/j.msec.2016.03.038 doi: 10.1016/j.msec.2016.03.038
32. [32]
  Zhang, F.; Braun, G. B.; Pallaoro, A.; Zhang, Y.; Shi, Y.; Cui, D.; Moskovits, M.; Zhao, D.; Stucky, G. D. Nano Lett. 2012, 12, 61. doi: 10.1021/nl202949y doi: 10.1021/nl202949y
33. [33]
  Wang, W.; Zhao, M.; Zhang, C.; Qian, H. Chem. Rec. 2019, 19, doi: 10.1002/tcr.201900006 doi: 10.1002/tcr.201900006
34. [34]
  Chen, G.; Qiu, H.; Prasad, P. N.; Chen, X. Chem. Rev. 2014, 114, 5161. doi: 10.1021/cr400425h doi: 10.1021/cr400425h
35. [35]
  Liu, K. C.; Zhang, Z. Y.; Shan, C. X.; Feng, Z. Q.; Li, J. S.; Song, C. L.; Bao, Y. N.; Qi, X. H.; Dong, B. Light Sci. Appl. 2016, 5, e16136.doi: 10.1038/lsa.2016.136 doi: 10.1038/lsa.2016.136
36. [36]
  Wang, Y.; Yang, G.; Wang, Y.; Zhao, Y.; Jiang, H.; Han, Y.; Yang, P. Nanoscale 2017, 9, 4759. doi: 10.1039/C6NR09030C doi: 10.1039/C6NR09030C
37. [37]
  Wang, F.; Liu, X. Acc. Chem. Res. 2014, 47, 1378. doi: 10.1021/ar5000067 doi: 10.1021/ar5000067
38. [38]
  Cheng, X.; Pan, Y.; Yuan, Z.; Wang, X.; Su, W.; Yin, L.; Xie, X.; Huang, L. Adv. Funct. Mater. 2018, 28, 1800208. doi: 10.1002/adfm.201800208 doi: 10.1002/adfm.201800208
39. [39]
  Yan, C.; Dadvand, A.; Rosei, F.; Perepichka, D. F. J. Am. Chem. Soc. 2010, 132, 8868. doi: 10.1021/ja103743t doi: 10.1021/ja103743t
40. [40]
  Zhang, F.; Wang, W.; Cong, H.; Luo, L.; Zha, Z.; Qian, H. Part. Part. Syst. Charact. 2017, 34, 1600222. doi: 10.1002/ppsc.201600222 doi: 10.1002/ppsc.201600222
41. [41]
  Ling, X.; Shi, R.; Zhang, J.; Liu, D.; Weng, M.; Zhang, C.; Lu, M.; Xie, X.; Huang, L.; Huang, W. ACS Sens. 2018, 3, 1683. doi: 10.1021/acssensors.8b00368 doi: 10.1021/acssensors.8b00368
42. [42]
  Xu, Z.; Ma, P.; Li, C.; Hou, Z.; Zhai, X.; Huang, S.; Lin, J. Biomaterials 2011, 32, 4161. doi: 10.1016/j.biomaterials.2011.02.026 doi: 10.1016/j.biomaterials.2011.02.026
43. [43]
  Lv, C.; Di, W.; Liu, Z.; Zheng, K.; Qin, W. Dalton Trans. 2014, 43, 3681. doi: 10.1039/c3dt53213e doi: 10.1039/c3dt53213e
1. [1]
  Hao Jiang , Yuan-Yuan He , Hai-Chao Liang , Meng-Jia Shang , Han-Han Lu , Chun-Hua Liu , Yin-Shan Meng , Tao Liu , Yuan-Yuan Zhu . Tuning lanthanide luminescence from bipyridine-bis(oxazoline/thiazoline) tetradentate ligands. Chinese Journal of Structural Chemistry, 2024, 43(9): 100354-100354. doi: 10.1016/j.cjsc.2024.100354
2. [2]
  Xiangshuai Li , Jian Zhao , Li Luo , Zhuohao Jiao , Ying Shi , Shengli Hou , Bin Zhao . Visual and portable detection of metronidazole realized by metal-organic framework flexible sensor and smartphone scanning. Chinese Chemical Letters, 2024, 35(10): 109407-. doi: 10.1016/j.cclet.2023.109407
3. [3]
  Wen-Jun Xia , Yong-Jiang Wang , Yun-Fei Cao , Cai Sun , Xin-Xiong Li , Yan-Qiong Sun , Shou-Tian Zheng . A luminescent folded S-shaped high-nuclearity Eu₁₉-oxo-cluster embedded polyoxoniobate for information encryption. Chinese Chemical Letters, 2025, 36(2): 110248-. doi: 10.1016/j.cclet.2024.110248
4. [4]
  Chun-Yun Ding , Ru-Yuan Zhang , Yu-Wu Zhong , Jiannian Yao . Binary and heterostructured microplates of iridium and ruthenium complexes: Preparation, characterization, and thermo-responsive emission. Chinese Journal of Structural Chemistry, 2024, 43(10): 100393-100393. doi: 10.1016/j.cjsc.2024.100393
5. [5]
  Pan Liu , Yanming Sun , Alberto J. Fernández-Carrión , Bowen Zhang , Hui Fu , Lunhua He , Xing Ming , Congling Yin , Xiaojun Kuang . Bismuth-based halide double perovskite Cs₂KBiCl₆: Disorder and luminescence. Chinese Chemical Letters, 2024, 35(5): 108641-. doi: 10.1016/j.cclet.2023.108641
6. [6]
  Yan Cheng , Hua-Peng Ruan , Yan Peng , Longhe Li , Zhenqiang Xie , Lang Liu , Shiyong Zhang , Hengyun Ye , Zhao-Bo Hu . Magnetic, dielectric and luminescence synergetic switchable effects in molecular material [Et₃NCH₂Cl]₂[MnBr₄]. Chinese Chemical Letters, 2024, 35(4): 108554-. doi: 10.1016/j.cclet.2023.108554
7. [7]
  Shuangliang Xie , Yuyue Chen , Qing He , Liang Chen , Jikun Yang , Shiqing Deng , Yimei Zhu , He Qi . Relaxor antiferroelectric-relaxor ferroelectric crossover in NaNbO₃-based lead-free ceramics for high-efficiency large-capacitive energy storage. Chinese Chemical Letters, 2024, 35(7): 108871-. doi: 10.1016/j.cclet.2023.108871
8. [8]
  Miao-Miao Chen , Min-Ling Zhang , Xiao Song , Jun Jiang , Xiaoqian Tang , Qi Zhang , Xiuhua Zhang , Peiwu Li . Smartphone-assisted electrochemiluminescence imaging test strips towards dual-signal visualized and sensitive monitoring of aflatoxin B1 in corn samples. Chinese Chemical Letters, 2025, 36(1): 109785-. doi: 10.1016/j.cclet.2024.109785
9. [9]
  Xu Luo , Jinwen Xiao , Qiming Yang , Xiaolong Lu , Qianjun Huang , Xiaojun Ai , Bo Li , Li Sun , Long Chen . Biomaterials for surgical repair of osteoporotic bone defects. Chinese Chemical Letters, 2025, 36(1): 109684-. doi: 10.1016/j.cclet.2024.109684
10. [10]
  Ping Wang , Ting Wang , Ming Xu , Ze Gao , Hongyu Li , Bowen Li , Yuqi Wang , Chaoqun Qu , Ming Feng . Keplerate polyoxomolybdate nanoball mediated controllable preparation of metal-doped molybdenum disulfide for electrocatalytic hydrogen evolution in acidic and alkaline media. Chinese Chemical Letters, 2024, 35(7): 108930-. doi: 10.1016/j.cclet.2023.108930
11. [11]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
12. [12]
  Chen Lian , Si-Han Zhao , Hai-Lou Li , Xinhua Cao . A giant Ce-containing poly(tungstobismuthate): Synthesis, structure and catalytic performance for the decontamination of a sulfur mustard simulant. Chinese Chemical Letters, 2024, 35(10): 109343-. doi: 10.1016/j.cclet.2023.109343
13. [13]
  Zhu Shu , Xin Lei , Yeye Ai , Ke Shao , Jianliang Shen , Zhegang Huang , Yongguang Li . ATP-induced supramolecular assembly based on chromophoric organic molecules and metal complexes. Chinese Chemical Letters, 2024, 35(11): 109585-. doi: 10.1016/j.cclet.2024.109585
14. [14]
  Pengfei Li , Chulin Qu , Fan Wu , Hu Gao , Chengyan Zhao , Yue Zhao , Zhen Shen . Robust free-base and metalated corrole radicals with reduction-induced emission. Chinese Chemical Letters, 2025, 36(2): 110292-. doi: 10.1016/j.cclet.2024.110292
15. [15]
  Yongjing Deng , Feiyang Li , Zijian Zhou , Mengzhu Wang , Yongkang Zhu , Jianwei Zhao , Shujuan Liu , Qiang Zhao . Chiral induction and Sb³⁺ doping in indium halides to trigger second harmonic generation and circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(8): 109085-. doi: 10.1016/j.cclet.2023.109085
16. [16]
  Min Song , Qian Zhang , Tao Shen , Guanyu Luo , Deli Wang . Surface reconstruction enabled o-PdTe@Pd core-shell electrocatalyst for efficient oxygen reduction reaction. Chinese Chemical Letters, 2024, 35(8): 109083-. doi: 10.1016/j.cclet.2023.109083
17. [17]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
18. [18]
  Yaoyin Lou , Xiaoyang Jerry Huang , Kuang-Min Zhao , Mark J. Douthwaite , Tingting Fan , Fa Lu , Ouardia Akdim , Na Tian , Shigang Sun , Graham J. Hutchings . Stable core-shell Janus BiAg bimetallic catalyst for CO₂ electrolysis into formate. Chinese Chemical Letters, 2025, 36(3): 110300-. doi: 10.1016/j.cclet.2024.110300
19. [19]
  Shaonan Tian , Yu Zhang , Qing Zeng , Junyu Zhong , Hui Liu , Lin Xu , Jun Yang . Core-shell gold-copper nanoparticles: Evolution of copper shells on gold cores at different gold/copper precursor ratios. Chinese Journal of Structural Chemistry, 2023, 42(11): 100160-100160. doi: 10.1016/j.cjsc.2023.100160
20. [20]
  Zunyuan Xie , Lijin Yang , Zixiao Wan , Xiaoyu Liu , Yushan He . Exploration of the Preparation and Characterization of Nano Barium Titanate and Its Application in Inorganic Chemistry Laboratory Teaching. University Chemistry, 2024, 39(4): 62-69. doi: 10.3866/PKU.DXHX202310137

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(642)
HTML views(94)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Coating and Transforming the Y(OH)CO3 Shell on Upconversion Nanoparticles

Metrics

通讯作者: 陈斌, bchen63@163.com

Coating and Transforming the Y(OH)CO₃ Shell on Upconversion Nanoparticles