Citation: He Yucheng, Xie Kefeng, Wang Youhao, Zhou Dongshan, Hu Wenbing. Characterization of Polymer Crystallization Kinetics via Fast-Scanning Chip-Calorimetry[J]. Acta Physico-Chimica Sinica, ;2020, 36(6): 190508. doi: 10.3866/PKU.WHXB201905081 shu

Characterization of Polymer Crystallization Kinetics via Fast-Scanning Chip-Calorimetry

State Key Laboratory of Coordinate Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, P. R. China

Corresponding author: Hu Wenbing, wbhu@nju.edu.cn
Received Date: 29 May 2019
Revised Date: 2 August 2019
Accepted Date: 2 August 2019
Available Online: 16 June 2019
Fund Project: Program for Changjiang Scholars and Innovative Research Team in University IRT1252the National Natural Science Foundation of China 21734005The project was supported by the National Natural Science Foundation of China (21474050, 21734005), Program for Changjiang Scholars and Innovative Research Team in University (IRT1252), and CAS Interdisciplinary Team, Chinathe National Natural Science Foundation of China 21474050

Biological systems can be regarded as complex and open thermodynamic systems. All processes involved in biological growth and metabolism are accompanied by material and energy exchange. During metabolism, energy in the organisms is released in the form of heat, i.e., metabolic heat, which is the basis for development in the field of biothermochemistry. The calorimetric method considers the thermal effects produced by the various forms of action as the research object, to reveal the law of energy change and quantitative energy conversion. Studying the thermodynamic processes of complex biological systems and related reactions through microcalorimetry and thermodynamic methods reflects the intrinsic laws of life-related processes macroscopically and intrinsically. With the tremendous development and progress in microcalorimetry in terms of the temperature measurement accuracy, stability of temperature control, automation, and multi-functionalization, calorimetry has been widely used in life sciences. It can be used to describe macroscopic processes such as ecosystems and biological evolution, observe organismal and cell growth, examine mitochondrial metabolism, and study problems at the molecular level, including enzymatic reactions and interactions between small molecules and biomacromolecules. Herein, the application of biomass calorimetry in the life sciences is reviewed. The status and progress of biomass calorimetry at different biological and structural levels, such as the ecosystem, biological, organ, cellular, subcellular, and molecular levels are introduced. For example, soil microbial metabolic activity is a universal index for evaluating soil quality. The growth and metabolism of organisms as well as the physical and chemical processes of substances in soil are often accompanied by heat release, which is usually a non-selective signal. The use of isothermal microcalorimetry to nonspecifically monitor and record soil microbial metabolic characteristics has promoted the study of microbial metabolism in complex soil systems. The application of calorimetry to the study of tissues and organs mainly involves the calorimetric study of isolated animal and plant tissues and organs. Calorimetry of animal and microbial cells is considered the most common application of calorimetry in life sciences research. It mainly involves the classification and identification of bacteria, their growth and metabolism, inhibition mechanisms of drugs on microbial growth, principles of kinetics, and the thermodynamic characteristics of microbial growth and metabolism. However, owing to the lack of specificity of biomass calorimetry and the lack of direct access to information at the molecular level, more applications of calorimetry combined with other analytical techniques (especially in biology, medicine, and pharmacy) are needed in the future.
- Flash DSC,
- Polymer,
- Crystallization kinetics
1. [1]
  Hu W., Principles of Polymer Crystallization; Chemical Industry Press: Beijing, China, 2013.
2. [2]
  Wunderlich B., Thermal Analysis of Polymeric Materials; Springer: Berlin, Germany, 2005.
3. [3]
  Wunderlich B., Prog. in Polym. Sci. 2003, 28(3), 383. doi: 10.1016/S0079-6700(02)00085-0 doi: 10.1016/S0079-6700(02)00085-0
4. [4]
  Schick C., Anal. Bioanal. Chem. 2009, 395(6), 1589. doi: 10.1007/s00216-009-3169-y doi: 10.1007/s00216-009-3169-y
5. [5]
  Kamal M. R., Chu E., Polym. Eng. Sci. 1983, 23(1), 27. doi: 10.1002/pen.760230107 doi: 10.1002/pen.760230107
6. [6]
  Toda A., Androsch R., Schick C., Polymer 2016, 91, 239. doi: 10.1016/j.polymer.2016.03.038 doi: 10.1016/j.polymer.2016.03.038
7. [7]
  Li Z., Zhou D., Hu W., Acta Polym. Sin. 2016, 9, 1179. doi: 10.11777/j.issn1000-3304.2016.16058
8. [8]
  Di Lorenzo M. L., Androsch R., Rhoades A. M., Righetti M. C., Analysis of Polymer Crystallization by Calorimetry. In Handbook of Thermal Analysis and Calorimetry, Vyazovkin S., Koga N., Schick C., Eds.; Elsevier Science B.V.: Amsterdam, Netherlands, 2018; Vol. 6, p. 253.
9. [9]
  Gao Y., Zhao B., Vlassak J. J., Schick C., Prog. Mater. Sci. 2019, 104, 53. doi: 10.1016/j.pmatsci.2019.04.001 doi: 10.1016/j.pmatsci.2019.04.001
10. [10]
  Mathot V. B. F., Polym. Int. 2019, 68(2), 179. doi: 10.1002/pi.5671 doi: 10.1002/pi.5671
11. [11]
  Santos de Souza F., Gomes Barreto A. P., Macêdo R. O., J. Therm. Anal. Calorim. 2001, 64(2), 739. doi: 10.1023/A:1011548512655 doi: 10.1023/A:1011548512655
12. [12]
  Becker R., Döring W., Ann. Phys. 1935, 416(8), 719. doi: 10.1002/andp.19354160806 doi: 10.1002/andp.19354160806
13. [13]
  Umemoto S., Kobayashi N., Okui N., J. Macromol. Sci. Phys. 2002, B41(4–6), 923. doi: 10.1081/mb-120013074 doi: 10.1081/mb-120013074
14. [14]
  Denlinger D. W., Abarra E. N., Allen K., Rooney P. W., Messer M. T., Watson S. K., Hellman F., Rev.Sci. Instrum. 1994, 65(4), 946. doi: 10.1063/1.1144925 doi: 10.1063/1.1144925
15. [15]
  Allen L. H., Ramanath G., Lai S. L., Ma Z., Lee S., Allman D. D. J., Fuchs K. P., Appl. Phys. Lett. 1994, 64(4), 417. doi: 10.1063/1.111116 doi: 10.1063/1.111116
16. [16]
  Lai S. L., Ramanath G., Allen L. H., Infante P., Ma Z., Appl. Phys. Lett. 1995, 67(9), 1229. doi: 10.1063/1.115016 doi: 10.1063/1.115016
17. [17]
  Lai S. L., Guo J. Y., Petrova V., Ramanath G., Allen L. H., Phys. Rev. Lett. 1996, 77(1), 99. doi: 10.1103/PhysRevLett.77.99 doi: 10.1103/PhysRevLett.77.99
18. [18]
  Efremov M. Y., Schiettekatte F., Zhang M., Olson E. A., Kwan A. T., Berry R. S., Allen L. H., Phys. Rev. Lett. 2000, 85(17), 3560. doi: 10.1103/PhysRevLett.85.3560 doi: 10.1103/PhysRevLett.85.3560
19. [19]
  Efremov M. Y., Olson E. A., Zhang M., Lai S. L., Schiettekatte F., Zhang Z. S., Allen L. H., Thermochim. Acta 2004, 412(1), 13. doi: 10.1016/j.tca.2003.08.019 doi: 10.1016/j.tca.2003.08.019
20. [20]
  Efremov M. Y., Olson E. A., Zhang M., Schiettekatte F., Zhang Z., Allen L. H., Rev. Sci. Instrum. 2004, 75(1), 179. doi: 10.1063/1.1633000 doi: 10.1063/1.1633000
21. [21]
  de la Rama L. P., Hu L., Ye Z., Efremov M. Y., Allen L. H., J. Am. Chem. Soc. 2013, 135(38), 14286. doi: 10.1021/ja4059958 doi: 10.1021/ja4059958
22. [22]
  Lopeandia A. F., Cerdo L. I., Clavaguera-Mora M. T., Arana L. R., Jensen K. F., Munoz F. J., Rodriguez-Viejo J., Rev. Sci. Instru. 2005, 76(6), 3959. doi: 10.1063/1.1921567 doi: 10.1063/1.1921567
23. [23]
  Adamovsky S. A., Minakov A. A., Schick C., Thermochim. Acta 2003, 403(1), 55. doi: 10.1016/S0040-6031(03)00182-5 doi: 10.1016/S0040-6031(03)00182-5
24. [24]
  Adamovsky S., Schick C., Thermochim. Acta 2004, 415(1), 1. doi: 10.1016/j.tca.2003.07.015 doi: 10.1016/j.tca.2003.07.015
25. [25]
  Yu J., Tang Z., Zhang F., Wei G., Wang L., Chin. Phy. Lett. 2005, 22(9), 2429. doi: 10.1088/0256-307x/22/9/080 doi: 10.1088/0256-307X/22/9/080
26. [26]
  Chen M., Du M., Jiang J., Li D., Jiang W., Zhuravlev E., Zhou D., Schick C., Xue G., Thermochim. Acta 2011, 526(1), 58. doi: 10.1016/j.tca.2011.08.020
27. [27]
  Jiang J., Zhuravlev E., Huang Z., Wei L., Xu Q., Shan M., Xue G., Zhou D., Schick C., Jiang W., Soft Matter 2013, 9(5), 1488. doi: 10.1039/C2SM27012A doi: 10.1039/C2SM27012A
28. [28]
  Wei L., Jiang J., Shan M., Chen W., Deng Y., Xue G., Zhou D., Rev. Sci. Instrum. 2014, 85(7), 074901. doi: 10.1063/1.4889882 doi: 10.1063/1.4889882
29. [29]
  Jiang J., Wei L., Zhou D., Integration of Fast Scanning Calorimetry(FSC) with Microstructural Analysis Techniques. In Fast Scanning Calorimetry, Schick C., Mathot V., Eds.; Springer International Publishing: Cham, Switzerland, 2016; p. 361.
30. [30]
  van Herwaardena S., Procedia Eng. 2010, 5, 464. doi: 10.1016/j.proeng.2010.09.147 doi: 10.1016/j.proeng.2010.09.147
31. [31]
  Iervolino E., van Herwaarden A. W., van Herwaarden F. G., van de Kerkhof E., van Grinsven P. P. W., Leenaers A. C. H. I., Mathot V. B. F., Sarro P. M., Thermochim. Acta 2011, 522(1), 53. doi: 10.1016/j.tca.2011.01.023 doi: 10.1016/j.tca.2011.01.023
32. [32]
  Mathot V., Pyda M., Pijpers T., Vanden Poel G., van de Kerkhof E., van Herwaarden S., van Herwaarden F., Leenaers A., Thermochim. Acta 2011, 522(1), 36. doi: 10.1016/j.tca.2011.02.031 doi: 10.1016/j.tca.2011.02.031
33. [33]
  van Herwaarden S., Iervolino E., van Herwaarden F., Wijffels T., Leenaers A., Mathot V., Thermochim. Acta 2011, 522(1), 46. doi: 10.1016/j.tca.2011.05.025 doi: 10.1016/j.tca.2011.05.025
34. [34]
  De Santis F., Adamovsky S., Titomanlio G., Schick C., Macromolecules 2006, 39(7), 2562. doi: 10.1021/ma052525n doi: 10.1021/ma052525n
35. [35]
  De Santis F., Adamovsky S., Titomanlio G., Schick C., Macromolecules 2007, 40(25), 9026. doi: 10.1021/ma071491b doi: 10.1021/ma071491b
36. [36]
  Kalapat D., Tang Q., Zhang X., Hu W., J. Therm. Anal. Calorim. 2017, 128(3), 1859. doi: 10.1007/s10973-017-6095-9 doi: 10.1007/s10973-017-6095-9
37. [37]
  Zhuravlev E., Schmelzer J. W. P., Wunderlich B., Schick C., Polymer 2011, 52(9), 1983. doi: 10.1016/j.polymer.2011.03.013 doi: 10.1016/j.polymer.2011.03.013
38. [38]
  Wang J., Li Z., Perez R. A., Mueller A. J., Zhang B., Grayson S. M., Hu W., Polymer 2015, 63, 34. doi: 10.1016/j.polymer.2015.02.039 doi: 10.1016/j.polymer.2015.02.039
39. [39]
  Androsch R., Schick C., Di Lorenzo M. L., Kinetics of Nucleation and Growth of Crystals of Poly(L-lactic acid). In Advances in Polymer Science, Springer: New York, USA, 2017; Vol. 279, p. 235.
40. [40]
  Schawe J. E. K., Pogatscher S., Material Characterization by Fast Scanning Calorimetry: Practice and Applications. In Fast Scanning Calorimetry; Schick C., Mathot V., Eds.; Springer International Publishing: Cham, Switzerland, 2016; p. 3.
41. [41]
  Gaur U., Wunderlich B., Advanced Thermal Analysis System(ATHAS) Polymer Heat Capacity Data Bank. In Computer Applications in Applied Polymer Science, American Chemical Society: New York, USA, 1982; Vol. 197, p. 355.
42. [42]
  He Y., Luo R., Li Z., Lv R., Zhou D., Lim S., Ren X., Gao H., Hu W., Macromol. Chem. Phys. 2018, 219(3), 1700385. doi: 10.1002/macp.201700385 doi: 10.1002/macp.201700385
43. [43]
  Androsch R., Schick C., Adv. Polym. Sci. 2015, 276, 257. doi: 10.1007/12_2015_325. doi: 10.1007/12_2015_325
44. [44]
  Jiang X., Reiter G., Hu W., J. Phys. Chem. B 2016, 120(3), 566. doi: 10.1021/acs.jpcb.5b09324 doi: 10.1021/acs.jpcb.5b09324
45. [45]
  Schick C., Androsch R., New Insights into Polymer Crystallization by Fast Scanning Chip Calorimetry. In Fast Scanning Calorimetry, Springer International Publishing: Cham, Switzerland, 2016; pp. 463–535.
46. [46]
  Androsch R., Schick C., Crystal Nucleation of Polymers at High Supercooling of the Melt. In Advances in Polymer Science, Springer: New York, USA, 2017; Vol. 276, p. 257.
47. [47]
  Schick C., Androsch R., Schmelzer J. W. P., J. Phys. Condens. Matter 2017, 29(35), 453002. doi: 10.1088/1361-648X/aa7fe0, doi: 10.1088/1361-648X/aa7fe0
48. [48]
  Pyda M., Nowak-Pyda E., Heeg J., Huth H., Minakov A. A., Di Lorenzo M. L., Schick C., Wunderlich B., J. Polym. Sci. Part B: Polym. Phys. 2006, 44(9), 1364. doi: 10.1002/polb.20789 doi: 10.1002/polb.20789
49. [49]
  Schawe J. E. K., J. Therm. Anal. Calorim. 2014, 116(3), 1165. doi: 10.1007/s10973-013-3563-8 doi: 10.1007/s10973-013-3563-8
50. [50]
  Androsch R., Rhoades A. M., Stolte I., Schick C., Eur. Polym. J. 2015, 66, 180. doi: 10.1016/j.eurpolymj.2015.02.013 doi: 10.1016/j.eurpolymj.2015.02.013
51. [51]
  Van Drongelen M., Meijer-Vissers T., Cavallo D., Portale G., Poel G. V., Androsch R., Thermochim. Acta 2013, 563, 33. doi: 10.1016/j.tca.2013.04.007 doi: 10.1016/j.tca.2013.04.007
52. [52]
  Rhoades A. M., Williams J. L., Androsch R., Thermochim. Acta 2015, 603, 103. doi: 10.1016/j.tca.2014.10.020 doi: 10.1016/j.tca.2014.10.020
53. [53]
  Cavallo D., Gardella L., Alfonso G. C., Mileva D., Androsch R., Polymer 2012, 53(20), 4429. doi: 10.1016/j.polymer.2012.08.001 doi: 10.1016/j.polymer.2012.08.001
54. [54]
  Mileva D., Androsch R., Cavallo D., Alfonso G. C., Eur. Polym. J. 2012, 48(6), 1082. doi: 10.1016/j.eurpolymj.2012.03.009 doi: 10.1016/j.eurpolymj.2012.03.009
55. [55]
  Cai J., Luo R., Lv R., He Y., Zhou D., Hu W., Eur. Polym. J. 2017, 96, 79. doi: 10.1016/j.eurpolymj.2017.09.003 doi: 10.1016/j.eurpolymj.2017.09.003
56. [56]
  Chen Y., Chen X., Zhou D., Shen Q., -D.; Hu W., Polymer 2016, 84, 319. doi: 10.1016/j.polymer.2016.01.003 doi: 10.1016/j.polymer.2016.01.003
57. [57]
  Gradys A., Sajkiewicz P., Zhuravlev E., Schick C., Polymer 2016, 82, 40. doi: 10.1016/j.polymer.2015.11.020 doi: 10.1016/j.polymer.2015.11.020
58. [58]
  Chen Y., Shen Q., -D.; Hu W., Polym. Int. 2016, 65(4), 387. doi: 10.1002/pi.5066 doi: 10.1002/pi.5066
59. [59]
  Wunderlich B., Crystal Nucleation, Growth, Annealing. in Macromolecular Physics. Academic Press: New York, NY, USA, 1976; Vol. 2.
60. [60]
  Long Y., Shanks R. A., Stachurski Z. H., Prog. Polym. Sci. 1995, 20(4), 651. doi: 10.1016/0079-6700(95)00002-W doi: 10.1016/0079-6700(95)00002-W
61. [61]
  Tammann G., Z. Phys. Chem. 1898, 25(3), 441.
62. [62]
  Zhuravlev E., Schmelzer J. W. P., Abyzov A. S., Fokin V. M., Androsch R., Schick C., Cryst. Growth Des. 2015, 15(2), 786. doi: 10.1021/cg501600s doi: 10.1021/cg501600s
63. [63]
  Androsch R., Schick C., Rhoades A. M., Macromolecules 2015, 48(22), 8082. doi: 10.1021/acs.macromol.5b01912 doi: 10.1021/acs.macromol.5b01912
64. [64]
  Okamoto N., Oguni M., Solid State Commun. 1996, 99(1), 53. doi: 10.1016/0038-1098(96)00139-1 doi: 10.1016/0038-1098(96)00139-1
65. [65]
  Wurm A., Zhuravlev E., Eckstein K., Jehnichen D., Pospiech D., Androsch R., Wunderlich B., Schick C., Macromolecules 2012, 45(9), 3816. doi: 10.1021/ma300363b doi: 10.1021/ma300363b
66. [66]
  Sánchez M. S., Mathot V. B. F., Poel G. V., Ribelles J. L. G., Macromolecules 2007, 40(22), 7989. doi: 10.1021/ma0712706 doi: 10.1021/ma0712706
67. [67]
  Androsch R., Zhuravlev E., Schmelzer J. W. P., Schick C., Eur. Polym. J. 2018, 102, 195. doi: 10.1016/j.eurpolymj.2018.03.026 doi: 10.1016/j.eurpolymj.2018.03.026
68. [68]
  Schmelzer J. W. P., Glass: Selected Properties and Crystallization. Walter de Gruyter: Berlin, Germany, 2014; p. 1.
69. [69]
  Androsch R., Schick C., Schmelzer J. W. P., Eur.Polym. J.2014, 53(1), 100. doi: 10.1016/j.eurpolymj.2014.01.012 doi: 10.1016/j.eurpolymj.2014.01.012
70. [70]
  Stolte I., Androsch R., Di Lorenzo M. L., Schick C., J. Phys. Chem. B 2013, 117(48), 15196. doi: 10.1021/jp4093404 doi: 10.1021/jp4093404
71. [71]
  Hoffman J. D., Davis G. T., Lauritzen J. I., The Rate of Crystallization of Linear Polymers with Chain Folding. In Treatise on Solid State Chemistry: Volume 3 Crystalline and Noncrystalline Solids, Hannay N. B., Ed.; Springer US: Boston, MA, USA, 1976; p. 497.
72. [72]
  Donth E., J. Non. Cryst. Solids 1982, 53(3), 325. doi: 10.1016/0022-3093(82)90089-8 doi: 10.1016/0022-3093(82)90089-8
73. [73]
  Donth E., The Glass Transition: Relaxation Dynamics in Liquids and Disordered Materials; Springer Science & Business Media: Berlin, Germany, 2013; Vol.48.
74. [74]
  Chua Y. Z., Zorn R., Holderer O., Schmelzer J. W. P., Schick C., Donth E., J. Chem. Phys. 2017, 146(10), 104501. doi: 10.1063/1.4977737 doi: 10.1063/1.4977737
75. [75]
  Rhoades A. M., Williams J. L., Wonderling N., Androsch R., Guo J., J. Therm. Anal. Calorim. 2017, 127(1), 939. doi: 10.1007/s10973-016-5793-z doi: 10.1007/s10973-016-5793-z
76. [76]
  Rhoades A. M., Wonderling N., Schick C., Androsch R., Polymer 2016, 106, 29. doi: 10.1016/j.polymer.2016.10.050 doi: 10.1016/j.polymer.2016.10.050
77. [77]
  Baeten D., Cavallo D., Portale G., Androsch R., Mathot V., Goderis B., Combining Fast Scanning Chip Calorimetry with Structural and Morphological Characterization Techniques. In Fast Scanning Calorimetry, Schick C., Mathot V., Eds.; Springer International Publishing: Cham, Switzerland, 2016; p. 327.
78. [78]
  Mollova A., Androsch R., Mileva D., Schick C., Benhamida A., Macromolecules 2013, 46(3), 828. doi: 10.1021/ma302238r doi: 10.1021/ma302238r
79. [79]
  Mileva D., Androsch R., Zhuravlev E., Schick C., Polymer 2012, 53(18), 3994. doi: 10.1016/j.polymer.2012.06.045 doi: 10.1016/j.polymer.2012.06.045
80. [80]
  Lv R., He Y., Wang J., Wang J., Hu J., Zhang J., Hu W., Polymer 2019, 174, 123. doi:10.1016/j.polymer.2019.04.061 doi: 10.1016/j.polymer.2019.04.061
81. [81]
  Androsch R., Di Lorenzo M. L., Schick, C. Macromol. Chem. Phys. 2017, 219(3), 1700479. doi: 10.1002/macp.201700479 doi: 10.1002/macp.201700479
82. [82]
  Schick C., Androsch R., Polym. Cryst. 2018, 1(4), e10036. doi: 10.1002/pcr2.10036 doi: 10.1002/pcr2.10036
83. [83]
  Janssens V., Block C., Van Assche G., Van Mele B., Van Puyvelde P., J. Therm. Anal. Calorim. 2009, 98(3), 675. doi: 10.1007/s10973-009-0518-1 doi: 10.1007/s10973-009-0518-1
84. [84]
  Roozemond P. C., van Drongelen M., Verbelen L., Van Puyvelde P., Peters G. W. M., Rheol. Acta 2015, 54(1), 1. doi: 10.1007/s00397-014-0820ol-0 doi: 10.1007/s00397-014-0820-0
85. [85]
  Rhoades A. M., Gohn A. M., Seo J., Androsch R., Colby R. H., Macromolecules 2018, 51(8), 2785. doi: 10.1021/acs.macromol.8b00195 doi: 10.1021/acs.macromol.8b00195
86. [86]
  Cebe P., Hu X., Kaplan D. L., Zhuravlev E., Wurm A., Arbeiter D., Schick C., Sci. Rep. 2013, 3, 1130. doi: 10.1038/srep01130 doi: 10.1038/srep01130
87. [87]
  Gao H., Wang J., Schick C., Toda A., Zhou D., Hu W., Polymer 2014, 55(16), 4307. doi: 10.1016/j.polymer.2014.06.048 doi: 10.1016/j.polymer.2014.06.048
88. [88]
  Jiang X., Li Z., Wang J., Gao H., Zhou D., Tang Y., Hu W., Thermochim. Acta 2015, 603, 79. doi: 10.1016/j.tca.2014.04.002 doi: 10.1016/j.tca.2014.04.002
89. [89]
  Jiang X., Li Z., Gao H., Hu W., Combining Fast-Scan Chip Calorimetry with Molecular Simulations to Investigate Polymer Crystal Melting. In Fast Scanning Calorimetry, Schick C., Mathot V., Eds.; Springer International Publishing: Cham, Switzerland, 2016; p. 379.
1. [1]
  Shule Liu . Application of SPC/E Water Model in Molecular Dynamics Teaching Experiments. University Chemistry, 2024, 39(4): 338-342. doi: 10.3866/PKU.DXHX202310029
2. [2]
  Shanghua Li , Malin Li , Xiwen Chi , Xin Yin , Zhaodi Luo , Jihong Yu . 基于高离子迁移动力学的取向ZnQ分子筛保护层实现高稳定水系锌金属负极的构筑. Acta Physico-Chimica Sinica, 2025, 41(1): 2309003-. doi: 10.3866/PKU.WHXB202309003
3. [3]
  Laiying Zhang , Yinghuan Wu , Yazi Yu , Yecheng Xu , Haojie Zhang , Weitai Wu . Innovation and Practice of Polymer Chemistry Experiment Teaching for Non-Polymer Major Students of Chemistry: Taking the Synthesis, Solution Property, Optical Performance and Application of Thermo-Sensitive Polymers as an Example. University Chemistry, 2024, 39(4): 213-220. doi: 10.3866/PKU.DXHX202310126
4. [4]
  Wenbing Hu , Jin Zhu . Flipped Classroom Approach in Teaching Professional English Reading and Writing to Polymer Graduates. University Chemistry, 2024, 39(6): 128-131. doi: 10.3866/PKU.DXHX202310015
5. [5]
  Kai Yang , Gehua Bi , Yong Zhang , Delin Jin , Ziwei Xu , Qian Wang , Lingbao Xing . Comprehensive Polymer Chemistry Experiment Design: Preparation and Characterization of Rigid Polyurethane Foam Materials. University Chemistry, 2024, 39(4): 206-212. doi: 10.3866/PKU.DXHX202308045
6. [6]
  Lijun Huo , Mingcun Wang , Tianyi Zhao , Mingjie Liu . Exploration of Undergraduate and Graduate Integrated Teaching in Polymer Chemistry with Aerospace Characteristics. University Chemistry, 2024, 39(6): 103-111. doi: 10.3866/PKU.DXHX202312059
7. [7]
  Feng Zheng , Ruxun Yuan , Xiaogang Wang . “Research-Oriented” Comprehensive Experimental Design in Polymer Chemistry: the Case of Polyimide Aerogels. University Chemistry, 2024, 39(10): 210-218. doi: 10.12461/PKU.DXHX202404027
8. [8]
  Qi Wang , Yicong Gao , Feng Lu , Quli Fan . Preparation and Performance Characterization of the Second Near-Infrared Phototheranostic Probe: A New Design and Teaching Practice of Polymer Chemistry Comprehensive Experiment. University Chemistry, 2024, 39(11): 342-349. doi: 10.12461/PKU.DXHX202404141
9. [9]
  Wenjun Yang , Qiaoling Tan , Wenjiao Xie , Xiaoyu Pan , Youyong Yuan . Construction and Characterization of Calcium Alginate Microparticle Drug Delivery System: A Novel Design and Teaching Practice in Polymer Experiments. University Chemistry, 2025, 40(3): 371-380. doi: 10.12461/PKU.DXHX202405150
10. [10]
  Yaling Chen . Basic Theory and Competitive Exam Analysis of Dynamic Isotope Effect. University Chemistry, 2024, 39(8): 403-410. doi: 10.3866/PKU.DXHX202311093
11. [11]
  Pingping Zhu , Yongjun Xie , Yuanping Yi , Yu Huang , Qiang Zhou , Shiyan Xiao , Haiyang Yang , Pingsheng He . Excavation and Extraction of Ideological and Political Elements for the Virtual Simulation Experiments at Molecular Level: Taking the Project “the Simulation and Computation of Conformation, Morphology and Dimensions of Polymer Chains” as an Example. University Chemistry, 2024, 39(2): 83-88. doi: 10.3866/PKU.DXHX202309063
12. [12]
  Jinfu Ma , Hui Lu , Jiandong Wu , Zhongli Zou . Teaching Design of Electrochemical Principles Course Based on “Cognitive Laws”: Kinetics of Electron Transfer Steps. University Chemistry, 2024, 39(3): 174-177. doi: 10.3866/PKU.DXHX202309052
13. [13]
  Yeyun Zhang , Ling Fan , Yanmei Wang , Zhenfeng Shang . Development and Application of Kinetic Reaction Flasks in Physical Chemistry Experimental Teaching. University Chemistry, 2024, 39(4): 100-106. doi: 10.3866/PKU.DXHX202308044
14. [14]
  Xuzhen Wang , Xinkui Wang , Dongxu Tian , Wei Liu . Enhancing the Comprehensive Quality and Innovation Abilities of Graduate Students through a “Student-Centered, Dual Integration and Dual Drive” Teaching Model: A Case Study in the Course of Chemical Reaction Kinetics. University Chemistry, 2024, 39(6): 160-165. doi: 10.3866/PKU.DXHX202401074
15. [15]
  Dexin Tan , Limin Liang , Baoyi Lv , Huiwen Guan , Haicheng Chen , Yanli Wang . Exploring Reverse Teaching Practices in Physical Chemistry Experiment Courses: A Case Study on Chemical Reaction Kinetics. University Chemistry, 2024, 39(11): 79-86. doi: 10.12461/PKU.DXHX202403048
16. [16]
  Yiying Yang , Dongju Zhang . Elucidating the Concepts of Thermodynamic Control and Kinetic Control in Chemical Reactions through Theoretical Chemistry Calculations: A Computational Chemistry Experiment on the Diels-Alder Reaction. University Chemistry, 2024, 39(3): 327-335. doi: 10.3866/PKU.DXHX202309074
17. [17]
  Yue Wu , Jun Li , Bo Zhang , Yan Yang , Haibo Li , Xian-Xi Zhang . Research on Kinetic and Thermodynamic Transformations of Organic-Inorganic Hybrid Materials for Fluorescent Anti-Counterfeiting Application information: Introducing a Comprehensive Chemistry Experiment. University Chemistry, 2024, 39(6): 390-399. doi: 10.3866/PKU.DXHX202403028
18. [18]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
19. [19]
  Yan Li , Xinze Wang , Xue Yao , Shouyun Yu . 基于激发态手性铜催化的烯烃E→Z异构的动力学拆分——推荐一个本科生综合化学实验. University Chemistry, 2024, 39(5): 1-10. doi: 10.3866/PKU.DXHX202309053
20. [20]
  Feng Cui , Fangman Chen , Xiaochun Xie , Chenyang Guo , Kai Xiao , Ziping Wu , Yinglu Chen , Junna Lu , Feixia Ruan , Chuanxu Cheng , Chao Yang , Dan Shao . Scalable production of mesoporous titanium nanoparticles through sequential flash nanocomplexation. Chinese Chemical Letters, 2024, 35(4): 108681-. doi: 10.1016/j.cclet.2023.108681

Get Citation

PDF

XML

Metrics

PDF Downloads(31)
Abstract views(2111)
HTML views(690)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142