Citation: Sun Wanjun, Lin Junqi, Liang Xiangming, Yang Junyi, Ma Baochun, Ding Yong. Recent Advances in Catalysts Based on Molecular Cubanes for Visible Light-Driven Water Oxidation[J]. Acta Physico-Chimica Sinica, ;2020, 36(3): 190502. doi: 10.3866/PKU.WHXB201905025 shu

Recent Advances in Catalysts Based on Molecular Cubanes for Visible Light-Driven Water Oxidation

Sun Wanjun ^1,3 ,
Lin Junqi ¹ ,
Liang Xiangming ¹ ,
Yang Junyi ¹ ,
Ma Baochun ¹ ,
Ding Yong ^1,2,,

1.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China
2.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
3.
Department of Chemistry and Life Science, Gansu Normal University for Nationalities, Hezuo 747000, Gansu Province, P. R. China

Corresponding author: Ding Yong, dingyong1@lzu.edu.cn
Received Date: 6 May 2019
Revised Date: 11 June 2019
Accepted Date: 20 June 2019
Available Online: 24 March 2019
Fund Project: the Natural Science Foundation of China 21572084Fundamental Research Funds for the Central Universities lzujbky-2018-k08The project was supported by the Natural Science Foundation of China (21773096, 21572084), Fundamental Research Funds for the Central Universities (lzujbky-2018-k08), Natural Science Foundation of Gansu (17JR5RA186) and Higher Education Institution Research Project of Gansu Province (2018A-123)the Natural Science Foundation of China 21773096Higher Education Institution Research Project of Gansu Province 2018A-123Natural Science Foundation of Gansu 17JR5RA186

Increasing climate change and environmental pollution caused by the excessive use of fossil fuels have prompted intensive research into clean and efficient renewable sources as a substitute for traditional fossil fuels. A very promising approach is to mimic the water splitting process that occurs in plants during photosynthesis, in order to convert solar energy into chemical energy. A successful water splitting reaction, which comprises two half reactions (water oxidation and the reduction of protons), can generate H₂ and O₂ from water. Hydrogen is a promising renewable energy carrier because of its clean combustion and high calorific value. Light-driven water splitting is considered to be a feasible way to transform water and solar energy into hydrogen energy. However, water oxidation is considered to be the bottleneck process of water splitting because it advances in a thermodynamically uphill manner with the involvement of 4e⁻ and 4H⁺. Inspired by the nature of Mn₄CaO₅ in photosystem Ⅱ (PS Ⅱ), the comprehensive understanding of its key features for use in active molecular water oxidation catalysts (WOCs) remains challenging. Extensive effort has been devoted to researching and manufacturing the structure and biomimicking the catalytic activity of Mn₄CaO₅ clusters that contain the Mn₃CaO₄ cubane structure, for the construction of low-cost and robust WOCs. WOCs can be divided into heterogeneous and homogeneous catalysts. Although heterogeneous WOCs are convenient for recycling and are easily prepared on a large scale, homogeneous WOCs, especially complexes based on organic ligands or polyoxometalates (POMs), have more advantages owing to their catalytic efficiency, structural modifications, and mechanistic understanding. Thus, recently, some molecules with an M₄O₄ (M = transition metals, mainly Mn, Co, Ni, and Cu) cubic structure have been reportedly used as photocatalytic WOCs. In this review, we present an overview of the most important and recent advances based on M₄O₄ cubic WOCs that contain first-row transition metal cubanes for visible light-driven water oxidation. Our main focus is on the structure of cubane catalysts, including metal complexes, POMs, and a system containing BiVO₄ or polymeric carbon nitride (PCN) as a photosensitizer, and cubic complexes as WOCs. Results have shown that the activity and stability of the catalyst can be tuned by the ligand stability, metal center, coordination environment, and other factors. This review will be helpful for designing new cubane catalysts for photocatalytic water oxidation that are highly efficient and stable.
- Photocatalysis,
- Cubane,
- Water oxidation catalyst,
- Metal complex,
- Polyoxometalates
1. [1]
  Berardi, S.; Drouet, S.; Francàs, L.; Gimbert-Suriñach, C.; Guttentag, M.; Richmond, C.; Stoll, T.; Llobet, A. Chem. Soc. Rev. 2014, 43, 7501. doi: 10.1039/c3cs60405e doi: 10.1039/c3cs60405e
2. [2]
  Song, F.; Ding, Y.; Ma, B.; Wang, C.; Wang, Q.; Du, X.; Fu, S.; Song, J. Energy Environ. Sci. 2013, 6, 1170. doi: 10.1039/C3EE24433D doi: 10.1039/C3EE24433D
3. [3]
  Gong, J.; Li, C.; Wasielewski, M. R. Chem. Soc. Rev. 2019, 48, 1862. doi: 10.1039/c9cs90020al doi: 10.1039/c9cs90020al
4. [4]
  Wang, J. -W.; Zhong, D. -C.; Lu, T. -B. Coord. Chem. Rev. 2018, 377, 225. doi: 10.1016/j.ccr.2018.09.003 doi: 10.1016/j.ccr.2018.09.003
5. [5]
  Xiao, A.; Lu, H.; Zhao, Y.; Luo, G. G. Acta Phys. -Chim. Sin. 2016, 32 (12), 2968. doi: 10.3866/PKU.WHXB201609194
6. [6]
  Yu, L.; Ding, Y.; Zheng, M.; Chen, H.; Zhao, J. Chem. Commun. 2016, 52, 14494. doi: 10.1039/C6CC02728h doi: 10.1039/C6CC02728h
7. [7]
  Dismukes, G. C.; Brimblecombe, R.; Felton, G. A.; Pryadun, R. S.; Sheats, J. E.; Spiccia, L.; Swiegers, G. F. Acc. Chem. Res. 2009, 42, 1935. doi:10.1021/ar900249x doi: 10.1021/ar900249x
8. [8]
  Tian, T.; Gao, H.; Zhou, X.; Zheng, L.; Wu, J.; Li, K.; Ding, Y. ACS Energy Lett. 2018, 3, 2150. doi: 10.1021/acsenergylett.8b01206 doi: 10.1021/acsenergylett.8b01206
9. [9]
  Zhang, B.; Sun, L. Chem. Soc. Rev. 2019, 48, 2216. doi: 10.1039/c8cs00897c doi: 10.1039/c8cs00897c
10. [10]
  Gersten, S. W.; Samuels, G. J.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 4029. doi: 10.1021/ja00378a053 doi: 10.1021/ja00378a053
11. [11]
  Umena, Y.; Kawakami, K.; Shen, J. -R.; Kamiya, N. Nature 2011, 473, 55. doi: 10.1038/nature09913 doi: 10.1038/nature09913
12. [12]
  Zhang, C. X.; Chen, C. H.; Dong, H. X.; Shen, J. R.; Dau, H.; Zhao, J. Q. Science 2015, 348, 690. doi: 10.1126/science.aaa6550 doi: 10.1126/science.aaa6550
13. [13]
  Kok, B.; Forbush, B.; McGloin, M. Photochem. Photobiol. 1970, 11, 457. doi: 10.1111/j.1751-1097.1970.tb06017.x doi: 10.1111/j.1751-1097.1970.tb06017.x
14. [14]
  Suga, M.; Akita, F.; Sugahara, M.; Kubo, M.; Nakajima, Y.; Nakane, T.; Yamashita, K.; Umena, Y.; Nakabayashi, M.; Yamane, T.; et al. Nature 2017, 543, 131. doi: 10.1038/nature21400 doi: 10.1038/nature21400
15. [15]
  Suga, M.; Akita, F.; Hirata, K.; Ueno, G.; Murakami, H.; Nakajima, Y.; Shimizu, T.; Yamashita, K.; Yamamoto, M.; Ago, H.; et al. Nature 2015, 517, 99. doi: 10.1038/nature13991 doi: 10.1038/nature13991
16. [16]
  Chen, C.; Chen, Y.; Yao, R.; Li, Y.; Zhang, C. Angew. Chem. Int. Ed. 2019, 58, 3939. doi: 10.1002/anie.201814440 doi: 10.1002/anie.201814440
17. [17]
  Lin, J.; Han, Q.; Ding, Y. Chem. Rec. 2018, 18, 1531. doi: 10.1002/tcr.201800029 doi: 10.1002/tcr.201800029
18. [18]
  Buriak, J. M.; Kamat, P. V.; Schanze, K. S. ACS Appl. Mater. Interfaces 2014, 6, 11815. doi: 10.1021/am504389z doi: 10.1021/am504389z
19. [19]
  Lin, J.; Meng, X.; Zheng, M.; Ma, B.; Ding, Y. Appl Catal B: Environ 2019, 241, 351. doi: 10.1016/j.apcatb.2018.09.052 doi: 10.1016/j.apcatb.2018.09.052
20. [20]
  Parent, A. R.; Crabtree, R. H.; Brudvig, G. W. Chem. Soc. Rev. 2013, 42, 2247. doi: 10.1039/C2CS35225G doi: 10.1039/C2CS35225G
21. [21]
  Yamada, Y.; Yano, K.; Hong, D.; Fukuzumi, S. Phys. Chem. Chem. Phys. 2012, 14, 5753. doi: 10.1039/c2cp00022a doi: 10.1039/c2cp00022a
22. [22]
  McCool, N. S.; Robinson, D. M.; Sheats, J. E.; Dismukes, G. C. J. Am. Chem. Soc. 2011, 133, 11446. doi: 10.1021/ja203877y doi: 10.1021/ja203877y
23. [23]
  Dismukes, G. C.; Brimblecombe, R.; Felton, G. A. N.; Pryadun, R. S.; Sheats, J. E.; Spiccia, L.; Swiegers, G. F. Acc. Chem. Res. 2009, 42, 1935. doi: 10.1021/ar900249x doi: 10.1021/ar900249x
24. [24]
  Smith, P. F.; Kaplan, C.; Sheats, J. E.; Robinson, D. M.; McCool, N. S.; Mezle, N.; Dismukes, G. C. Inorg. Chem. 2014, 53, 2113. doi: 10.1021/ic402720p doi: 10.1021/ic402720p
25. [25]
  Dimitrou, K.; Folting, K.; Streib, W. E.; Christou, G. J. Am. Chem. Soc. 1993, 115, 6432. doi: 10.1021/ja00067a077 doi: 10.1021/ja00067a077
26. [26]
  Sumner, E. C. Inorg. Chem. 1988, 27, 1320. doi: 10.1021/ic00281a004 doi: 10.1021/ic00281a004
27. [27]
  La Ganga, G.; Puntoriero, F.; Campagna, S.; Bazzan, I.; Berardi, S.; Bonchio, M.; Sartorel, A.; Natali, M.; Scandola, F. Faraday Discuss. 2012, 155, 177. doi: 10.1039/c1fd00093d doi: 10.1039/c1fd00093d
28. [28]
  Berardi, S.; La Ganga, G.; Natali, M.; Bazzan, I.; Puntoriero, F.; Sartorel, A.; Scandola, F.; Campagna, S.; Bonchio, M. J. Am. Chem. Soc. 2012, 134, 11104. doi: 10.1021/ja303951z doi: 10.1021/ja303951z
29. [29]
  Zhou, X.; Li, F.; Li, H.; Zhang, B.; Yu, F.; Sun, L. ChemSusChem 2014, 7, 2453. doi: 10.1002/cssc.201402195 doi: 10.1002/cssc.201402195
30. [30]
  Ullman, A. M.; Liu, Y.; Huynh, M.; Bediako, D. K.; Wang, H.; Anderson, B. L.; Powers, D. C.; Breen, J. J.; Abruña, H. D.; Nocera, D. G. J. Am. Chem. Soc. 2014, 136, 17681. doi: 10.1021/ja5110393 doi: 10.1021/ja5110393
31. [31]
  Nguyen, A. I.; Ziegler, M. S.; Oña-Burgos, P.; Sturzbecher-Hohne, M.; Kim, W.; Bellone, D. E.; Tilley, T. D. J. Am. Chem. Soc. 2015, 137, 12865. doi: 10.1021/jacs.5b08396 doi: 10.1021/jacs.5b08396
32. [32]
  Wang, H. -Y.; Mijangos, E.; Ott, S.; Thapper, A. Angew. Chem. Int. Ed. 2014, 53, 14499. doi: 10.1002/anie.201406540 doi: 10.1002/anie.201406540
33. [33]
  Wang, J. -W.; Sahoo, P.; Lu, T. -B. ACS Catal. 2016, 6, 5062. doi: 10.1021/acscatal.6b00798 doi: 10.1021/acscatal.6b00798
34. [34]
  Evangelisti, F.; More, R.; Hodel, F.; Luber, S.; Patzke, G. R. J. Am. Chem. Soc. 2015, 137, 11076. doi: 10.1021/jacs.5b05831 doi: 10.1021/jacs.5b05831
35. [35]
  Folkman, S. J.; Soriano-Lopez, J.; Galan-Mascaros, J. R.; Finke, R. G. J. Am. Chem. Soc. 2018, 140, 12040. doi: 10.1021/jacs.8b06303 doi: 10.1021/jacs.8b06303
36. [36]
  Evangelisti, F.; Guttinger, R.; More, R.; Luber, S.; Patzke, G. R. J. Am. Chem. Soc. 2013, 135, 18734. doi: 10.1021/ja4098302 doi: 10.1021/ja4098302
37. [37]
  Song, F.; Moré, R.; Schilling, M.; Smolentsev, G.; Azzaroli, N.; Fox, T.; Luber, S.; Patzke, G. R. J. Am. Chem. Soc. 2017, 139, 14198. doi: 10.1021/jacs.7b07361 doi: 10.1021/jacs.7b07361
38. [38]
  Xie, W. -F.; Guo, L. -Y.; Xu, J. -H.; Jagodič, M.; Jagličić, Z.; Wang, W. -G.; Zhuang, G. -L.; Wang, Z.; Tung, C. -H.; Sun, D. Eur. J. Inorg. Chem. 2016, 2016, 3253. doi.10.1002/ejic.201600510
39. [39]
  Xu, J. -H.; Guo, L. -Y.; Su, H.-F.; Gao, X.; Wu, X. -F.; Wang, W. -G.; Tung, C. -H.; Sun, D. Inorg. Chem. 2017, 56, 1591. doi: 10.1021/acs.inorgchem.6b02698
40. [40]
  Zhao, Y.; Lin, J.; Liu, Y.; Ma, B.; Ding, Y.; Chen, M. Chem. Commun. 2015, 51, 17309. doi:10.1039/C5CC07448g doi: 10.1039/C5CC07448g
41. [41]
  Jiang, X.; Li, J.; Yang, B.; Wei, X. Z.; Dong, B. W.; Kao, Y.; Huang, M.; Tung, C.; Wu, L. Angew. Chem. Int. Ed. 2018, 57, 7850. doi: 10.1002/anie.201803944 doi: 10.1002/anie.201803944
42. [42]
  Lin, J.; Liang, X.; Cao, X.; Wei, N.; Ding, Y. Chem. Commun. 2018, 54, 12515. doi: 10.1039/c8cc06362a doi: 10.1039/c8cc06362a
43. [43]
  Song, F.; Ding, Y.; Zhao, C. Acta Chim Sinica 2014, 72, 133. doi: 10.6023/a13101052
44. [44]
  Lv, H.; Geletii, Y. V.; Zhao, C.; Vickers, J. W.; Zhu, G.; Luo, Z.; Song, J.; Lian, T.; Musaev, D. G.; Hill, C. L. Chem. Soc. Rev. 2012, 41, 7572. doi: 10.1039/C2CS35292C doi: 10.1039/C2CS35292C
45. [45]
  Du, X.; Zhao, J.; Mi, J.; Ding, Y.; Zhou, P.; Ma, B.; Zhao, J.; Song, J. Nano Energy 2015, 16, 247. doi: 10.1016/j.nanoen.2015.06.025 doi: 10.1016/j.nanoen.2015.06.025
46. [46]
  Yu, L.; Ding, Y.; Zheng, M. Appl. Catal. B: Environ. 2017, 209, 45. doi: 10.1016/j.apcatb.2017.02.061 doi: 10.1016/j.apcatb.2017.02.061
47. [47]
  Yu, L.; Lin, J.; Zheng, M.; Chen, M.; Ding, Y. Chem. Commun. 2018, 54, 354. doi: 10.1039/C7CC08301G doi: 10.1039/C7CC08301G
48. [48]
  Du, X.; Ding, Y.; Song, F.; Ma, B.; Zhao, J.; Song, J. Chem. Commun. 2015, 51, 13925. doi: 10.1039/c5cc04551g doi: 10.1039/c5cc04551g
49. [49]
  Yin, Q.; Tan, J. M.; Besson, C.; Geletii, Y. V.; Musaev, D. G.; Kuznetsov, A. E.; Luo, Z.; Hardcastle, K. I.; Hill, C. L. Science 2010, 328, 342. doi: 10.1126/science.1185372 doi: 10.1126/science.1185372
50. [50]
  Han, Z.; Bond, A. M.; Zhao, C. Sci. China Chem. 2011, 54, 1877. doi: 10.1007/s11426-011-4442-4 doi: 10.1007/s11426-011-4442-4
51. [51]
  Sartorel, A.; Carraro, M.; Scorrano, G.; Zorzi, R. D.; Geremia, S.; McDaniel, N. D.; Bernhard, S.; Bonchio, M. J. Am. Chem. Soc. 2008, 130, 5006. doi: 10.1021/ja077837f doi: 10.1021/ja077837f
52. [52]
  Geletii, Y. V.; Botar, B.; Kögerler, P.; Hillesheim, D. A.; Musaev, D. G.; Hill, C. L. Angew. Chem. Int. Ed. 2008, 47, 3896. doi: 10.1002/anie.200705652 doi: 10.1002/anie.200705652
53. [53]
  Geletii, Y. V.; Huang, Z.; Hou, Y.; Musaev, D. G.; Lian, T.; Hill, C. L. J. Am. Chem. Soc. 2009, 131, 7522. doi: 10.1021/ja901373m doi: 10.1021/ja901373m
54. [54]
  Han, X. -B.; Zhang, Z. -M.; Zhang, T.; Li, Y. -G.; Lin, W.; You, W.; Su, Z. -M.; Wang, E.-B. J. Am. Chem. Soc. 2014, 136, 5359. doi: 10.1021/ja412886e
55. [55]
  Du, P.; Kokhan, O.; Chapman, K. W.; Chupas, P. J.; Tiede, D. M. J. Am. Chem. Soc. 2012, 134, 11096. doi: 10.1021/ja303826a doi: 10.1021/ja303826a
56. [56]
  Wei, J.; Feng, Y.; Zhou, P.; Liu, Y.; Xu, J.; Xiang, R.; Ding, Y.; Zhao, C.; Fan, L.; Hu, C. ChemSusChem 2015, 8, 2630. doi: 10.1002/cssc.201500490 doi: 10.1002/cssc.201500490
57. [57]
  Chen, W. C.; Wang, X. L.; Qin, C.; Shao, K. Z.; Su, Z. M.; Wang, E. B. Chem. Commun. 2016, 52, 9514. doi: 10.1039/c6cc03763a doi: 10.1039/c6cc03763a
58. [58]
  Al-Oweini, R.; Sartorel, A.; Bassil, B. S.; Natali, M.; Berardi, S.; Scandola, F.; Kortz, U.; Bonchio, M. Angew. Chem. Int. Ed. 2014, 53, 11182. doi: 10.1002/anie.201404664 doi: 10.1002/anie.201404664
59. [59]
  Schwarz, B.; Forster, J.; Goetz, M. K.; Yücel, D.; Berger, C.; Jacob, T.; Streb, C. Angew. Chem. Int. Ed. 2016, 55, 6329. doi: 10.1002/anie.201601799 doi: 10.1002/anie.201601799
60. [60]
  Han, X. -B.; Li, Y. -G.; Zhang, Z. -M.; Tan, H. -Q.; Lu, Y.; Wang, E. -B. J. Am. Chem. Soc. 2015, 137, 5486. doi: 10.1021/jacs.5b01329
61. [61]
  Stewart, A. C.; Bendall, D. S. Biochem. J. 1980, 188. 351. doi: 10.1042/bj1880351 doi: 10.1042/bj1880351
62. [62]
  Xiang, R.; Ding, Y.; Zhao, J. Chem. Asian J. 2014, 9, 3228. doi: 10.1002/asia.201402483 doi: 10.1002/asia.201402483
63. [63]
  Probs, B.; Kolano, C.; Hamm, P.; Alberto, R. Inorg. Chem. 2009, 48, 1836. doi: 10.1021/ic8013255 doi: 10.1021/ic8013255
64. [64]
  Liang, X.; Lin, J.; Cao, X.; Sun, W.; Yang, J.; Ma, B.; Ding, Y. Chem. Commun. 2019, 55, 2529. doi: 10.1039/c8cc09807g doi: 10.1039/c8cc09807g
65. [65]
  Ye, C.; Wang, X. -Z.; Li, J. -X.; Li, Z. -J.; Li, X. -B.; Zhang, L. -P.; Chen, B.; Tung, C. -H.; Wu, L. -Z. ACS Catal. 2016, 6, 8336. doi: 10.1021/acscatal.6b02664
66. [66]
  Li, Y.; Kong, T.; Shen, S. Small 2019, 1900772. doi: 10.1002/smll.201900772 doi: 10.1002/smll.201900772
67. [67]
  Chang, X. X.; Gong, J. L. Acta Phys. -Chim. Sin. 2016, 32 (1), 2. doi: 10.3866/PKU.WHXB201510192
68. [68]
  Wang, Y.; Li, F.; Li, H.; Bai, L.; Sun, L. Chem. Commun. 2016, 52, 3050. doi: 10.1039/c5cc09588c doi: 10.1039/c5cc09588c
69. [69]
  Ye, S.; Chen, R.; Xu, Y.; Fan, F.; Du, P.; Zhang, F.; Zong, X.; Chen, T.; Qi, Y.; Chen, P.; et al. J. Catal. 2016, 338, 168. doi: 10.1016/j.jcat.2016.02.024 doi: 10.1016/j.jcat.2016.02.024
70. [70]
  Luo, Z. S.; Zhou, M.; Wang, X. C. Appl. Catal. B: Environ. 2018, 238, 664. doi: 10.1016/j.apcatb.2018.07.056 doi: 10.1016/j.apcatb.2018.07.056
1. [1]
  Wenxiu Yang , Jinfeng Zhang , Quanlong Xu , Yun Yang , Lijie Zhang . Bimetallic AuCu Alloy Decorated Covalent Organic Frameworks for Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312014-. doi: 10.3866/PKU.WHXB202312014
2. [2]
  Ke Li , Chuang Liu , Jingping Li , Guohong Wang , Kai Wang . 钛酸铋/氮化碳无机有机复合S型异质结纯水光催化产过氧化氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2403009-. doi: 10.3866/PKU.WHXB202403009
3. [3]
  Changjun You , Chunchun Wang , Mingjie Cai , Yanping Liu , Baikang Zhu , Shijie Li . 引入内建电场强化BiOBr/C₃N₅ S型异质结中光载流子分离以实现高效催化降解微污染物. Acta Physico-Chimica Sinica, 2024, 40(11): 2407014-. doi: 10.3866/PKU.WHXB202407014
4. [4]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
5. [5]
  Zhiquan Zhang , Baker Rhimi , Zheyang Liu , Min Zhou , Guowei Deng , Wei Wei , Liang Mao , Huaming Li , Zhifeng Jiang . Insights into the Development of Copper-based Photocatalysts for CO₂ Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2406029-. doi: 10.3866/PKU.WHXB202406029
6. [6]
  Yuanyin Cui , Jinfeng Zhang , Hailiang Chu , Lixian Sun , Kai Dai . Rational Design of Bismuth Based Photocatalysts for Solar Energy Conversion. Acta Physico-Chimica Sinica, 2024, 40(12): 2405016-. doi: 10.3866/PKU.WHXB202405016
7. [7]
  Ruolin CHENG , Haoran WANG , Jing REN , Yingying MA , Huagen LIANG . Efficient photocatalytic CO₂ cycloaddition over W₁₈O₄₉/NH₂-UiO-66 composite catalyst. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 523-532. doi: 10.11862/CJIC.20230349
8. [8]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067
9. [9]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
10. [10]
  Jianyin He , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . ZnCoP/CdLa₂S₄肖特基异质结的构建促进光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2404030-. doi: 10.3866/PKU.WHXB202404030
11. [11]
  Xuejiao Wang , Suiying Dong , Kezhen Qi , Vadim Popkov , Xianglin Xiang . Photocatalytic CO₂ Reduction by Modified g-C₃N₄. Acta Physico-Chimica Sinica, 2024, 40(12): 2408005-. doi: 10.3866/PKU.WHXB202408005
12. [12]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
13. [13]
  Chenye An , Abiduweili Sikandaier , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . 红磷纳米颗粒嵌入花状CeO₂分级S型异质结高效光催化产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-. doi: 10.3866/PKU.WHXB202405019
14. [14]
  Guoqiang Chen , Zixuan Zheng , Wei Zhong , Guohong Wang , Xinhe Wu . 熔融中间体运输导向合成富氨基g-C₃N₄纳米片用于高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406021-. doi: 10.3866/PKU.WHXB202406021
15. [15]
  Qin Hu , Liuyun Chen , Xinling Xie , Zuzeng Qin , Hongbing Ji , Tongming Su . Ni掺杂构建电子桥及激活MoS₂惰性基面增强光催化分解水产氢. Acta Physico-Chimica Sinica, 2024, 40(11): 2406024-. doi: 10.3866/PKU.WHXB202406024
16. [16]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
17. [17]
  Shijie Li , Ke Rong , Xiaoqin Wang , Chuqi Shen , Fang Yang , Qinghong Zhang . Design of Carbon Quantum Dots/CdS/Ta₃N₅ S-Scheme Heterojunction Nanofibers for Efficient Photocatalytic Antibiotic Removal. Acta Physico-Chimica Sinica, 2024, 40(12): 2403005-. doi: 10.3866/PKU.WHXB202403005
18. [18]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
19. [19]
  Heng Chen , Longhui Nie , Kai Xu , Yiqiong Yang , Caihong Fang . 两步焙烧法制备大比表面积和结晶性增强超薄g-C₃N₄纳米片及其高效光催化产H₂O₂. Acta Physico-Chimica Sinica, 2024, 40(11): 2406019-. doi: 10.3866/PKU.WHXB202406019
20. [20]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(624)
HTML views(89)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142