Citation: Pan Wenli, Guan Wenhao, Jiang Yinzhu. Research Advances in Polyanion-Type Cathodes for Sodium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2020, 36(5): 190501. doi: 10.3866/PKU.WHXB201905017 shu

Research Advances in Polyanion-Type Cathodes for Sodium-Ion Batteries

State Key Laboratory of Silicon Materials, School of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, P. R. China

Corresponding author: Jiang Yinzhu, yzjiang@zju.edu.cn

Received Date: 2 May 2019
Revised Date: 5 June 2019
Accepted Date: 18 June 2019
Available Online: 24 May 2019
Fund Project: the Zhejiang Provincial Natural Science Foundation, China LR18B030001the Fundamental Research Funds for the Central Universities, China 2018XZZX002-08the National Natural Science Foundation of China 51722105The project was supported by the National Natural Science Foundation of China (51722105), the Zhejiang Provincial Natural Science Foundation, China (LR18B030001), and the Fundamental Research Funds for the Central Universities, China (2018XZZX002-08)

Because of their high energy density and long cycle life, lithium-ion batteries (LIBs) have dominated the portable electronics market for over 20 years. However, with the increasing demand for large-scale energy storage systems for grid applications, the price of Li resources has increased owing to the low abundance of Li in Earth's crust and non-uniform distribution on the planet. Because Na has similar physical and chemical properties as Li and is an abundant natural resource, room-temperature sodium-ion batteries (SIBs) are expected to be among the most promising next-generation large grid energy storage devices. It is known that the cathode, anode, separator and electrolyte materials are the main components of batteries. Among these, Na-containing cathode materials are of critical importance. As a cathode material for SIBs, polyanion-type compounds have become a hot research topic owing to their versatile structural frameworks, high thermal stabilities, high ambient stabilities even in the charging state, small volume changes, tunable operating voltage by tuning the chemical environment of the polyanions, and high operating voltages owing to the inductive effects of the polyanionic groups (PO₄³⁻, SO₄²⁻, SiO₄⁴⁻, etc.). In particular, for Earth's abundant resources and inherent stability, polyanion-based compounds are suitable for large-scale stationary energy storage. Taking grid balancing into account, batteries with fast charge rates are in demand, which requires cathodes having high rate capability. However, despite the presence of ion diffusion channels in polyanion compounds, the electronic transport channels are blocked owing to the separation of the metal polyhedral and the strong electronegativity of the anions, leading to poor electron conductivity, which largely limits the rate capability of polyanion compounds. Therefore, it is crucial to understand the inherent limitation of the kinetics in terms of the structural aspects and to determine strategies for improving the rate capability. This review discusses the intrinsic reasons for the factors impacting ion diffusion based on the different structures of polyanion-type cathodes. From the perspectives of surface modification and morphology, strategies for enhancing the transport of sodium ions and electrons at the surface and interface are summarized and discussed. Then, from the standpoint of the hierarchical structures of materials to the design of a structural framework, which have been rarely reported, this review proposes schemes that intrinsically enhance the rate capability of polyanion compounds and provides a perspective on developments that can further improve the rate capability of cathode materials. This review provides suggestions for designing and optimizing high-rate polyanion-type and other kinds of cathodes from both academic and practical viewpoints.
- Sodium-ion battery,
- Polyanion-type cathode,
- High rate capability,
- Ion diffusion,
- Electron transport
1. [1]
  Evans, A.; Strezov, V.; Evans, T. J. Renew. Sust. Energ. Rev. 2012, 16, 4141. doi: 10.1016/j.rser.2012.03.048 doi: 10.1016/j.rser.2012.03.048
2. [2]
  Liu, J.; Zhang, J. G.; Yang, Z.; Lemmon, J. P.; Imhoff, C.; Graff, G. L.; Li, L.; Hu, J.; Wang, C.; Xiao, J. Adv. Funct. Mater. 2013, 23, 929. doi: 10.1002/adfm.201200690 doi: 10.1002/adfm.201200690
3. [3]
  Ellis, B. L.; Nazar, L. F. Curr. Opin. Solid State Mat. Sci. 2012, 16, 168. doi: 10.1016/j.cossms.2012.04.002 doi: 10.1016/j.cossms.2012.04.002
4. [4]
  Xiang, X.; Zhang, K.; Chen, J. Adv. Mater. 2015, 27, 5343. doi: 10.1002/adma.201501527 doi: 10.1002/adma.201501527
5. [5]
  Guo, S. P.; Li, J. C.; Xu, Q. T.; Ma, Z.; Xue, H. G. J. Power Sources 2017, 361, 285. doi: 10.1016/j.jpowsour.2017.07.002 doi: 10.1016/j.jpowsour.2017.07.002
6. [6]
  Wang, P. F.; You, Y.; Yin, Y. X.; Guo, Y. G. Adv. Energy Mater. 2018, 8. doi: 10.1002/aenm.201701912 doi: 10.1002/aenm.201701912
7. [7]
  Jiang, Y.; Yu, S.; Wang, B.; Li, Y.; Sun, W.; Lu, Y.; Yan, M.; Song, B.; Dou, S. Adv. Funct. Mater. 2016, 26, 5315. doi: 10.1002/adfm.201600747 doi: 10.1002/adfm.201600747
8. [8]
  Wang, B.; Han, Y.; Wang, X.; Bahlawane, N.; Pan, H.; Yan, M.; Jiang, Y. iScience 2018, 3, 110. doi: 10.1016/j.isci.2018.04.008 doi: 10.1016/j.isci.2018.04.008
9. [9]
  Barpanda, P.; Lander, L.; Nishimura, S. I.; Yamada, A. Adv. Energy Mater. 2018, 8, 1703055. doi: 10.1002/aenm.201703055 doi: 10.1002/aenm.201703055
10. [10]
  Masquelier, C.; Croguennec, L. Chem. Rev. 2013, 113, 6552. doi: 10.1021/cr3001862 doi: 10.1021/cr3001862
11. [11]
  Yabuuchi, N.; Kubota, K.; Dahbi, M.; Komaba, S. Chem. Rev. 2014, 114, 11636. doi: 10.1021/cr500192f doi: 10.1021/cr500192f
12. [12]
  Ouyang, X.; Lei, M.; Shi, S.; Luo, C.; Liu, D.; Jiang, D.; Ye, Z.; Lei, M. J. Alloy. Compd. 2009, 476, 462. doi: 10.1016/j.jallcom.2008.09.028 doi: 10.1016/j.jallcom.2008.09.028
13. [13]
  Balke, N.; Jesse, S.; Morozovska, A.; Eliseev, E.; Chung, D.; Kim, Y.; Adamczyk, L.; Garcia, R.; Dudney, N.; Kalinin, S. Nat. Nanotechnol. 2010, 5, 749. doi: 10.1038/nnano.2010.174 doi: 10.1038/nnano.2010.174
14. [14]
  Padhi, A. K.; Nanjundaswamy, K. S.; Goodenough, J. B. J. Electrochem. Soc. 1997, 144, 1188. doi: 10.1149/1.1837571 doi: 10.1149/1.1837571
15. [15]
  Yamada, A.; Chung, S. C.; Hinokuma, K. J. Electrochem. Soc. 2001, 148, A224. doi: 10.1149/1.1348257 doi: 10.1149/1.1348257
16. [16]
  Huang, H.; Yin, S. C.; Nazar, L. S. Electrochem. Solid State Lett. 2001, 4, A170. doi: 10.1149/1.1396695 doi: 10.1149/1.1396695
17. [17]
  Oh, S. M.; Myung, S. T.; Hassoun, J.; Scrosati, B.; Sun, Y. K. Electrochem. Commun. 2012, 22, 149. doi: 10.1016/j.elecom.2012.06.014 doi: 10.1016/j.elecom.2012.06.014
18. [18]
  Zhu, Y.; Xu, Y.; Liu, Y.; Luo, C.; Wang, C. Nanoscale 2013, 5, 780. doi: 10.1039/C2NR32758A doi: 10.1039/C2NR32758A
19. [19]
  Casas-Cabanas, M.; Roddatis, V. V.; Saurel, D.; Kubiak, P.; Carretero-González, J.; Palomares, V.; Serras, P.; Rojo, T. J. Mater. Chem. 2012, 22, 17421. doi: 10.1039/C2JM33639A doi: 10.1039/C2JM33639A
20. [20]
  Kim, J.; Seo, D. H.; Kim, H.; Park, I.; Yoo, J. K.; Jung, S. K.; Park, Y. U.; Goddard III, W. A.; Kang, K. Energy Environ. Sci. 2015, 8, 540. doi: 10.1039/C4EE03215B doi: 10.1039/C4EE03215B
21. [21]
  Barpanda, P.; Ye, T.; Lu, J.; Yamada, Y.; Chung, S. C.; Nishimura, S.; Okubo, M.; Zhou, H.; Yamada, A. ECS Trans. 2013, 50, 71. doi: 10.1149/05024.0071ecst doi: 10.1149/05024.0071ecst
22. [22]
  Barpanda, P.; Liu, G.; Ling, C. D.; Tamaru, M.; Avdeev, M.; Chung, S. C.; Yamada, Y.; Yamada, A. Chem. Mat. 2013, 25, 3480. doi: 10.1021/cm401657c doi: 10.1021/cm401657c
23. [23]
  Kim, H.; Park, C. S.; Choi, J. W.; Jung, Y. Angew. Chem. Int. Edit. 2016, 55, 6662. doi: 10.1002/anie.201601022 doi: 10.1002/anie.201601022
24. [24]
  Gopalakrishnan, J.; Rangan, K. K. Chem. Mat. 1992, 4, 745. doi: 10.1021/cm00022a001 doi: 10.1021/cm00022a001
25. [25]
  Lim, S. Y.; Kim, H.; Shakoor, R.; Jung, Y.; Choi, J. W. J. Electrochem. Soc. 2012, 159, A1393. doi: 10.1149/2.015209jes doi: 10.1149/2.015209jes
26. [26]
  Jian, Z.; Yuan, C.; Han, W.; Lu, X.; Gu, L.; Xi, X.; Hu, Y. S.; Li, H.; Chen, W.; Chen, D. Adv. Funct. Mater. 2014, 24, 4265. doi: 10.1002/adfm.201400173 doi: 10.1002/adfm.201400173
27. [27]
  Zhu, C.; Song, K.; van Aken, P. A.; Maier, J.; Yu, Y. Nano Lett. 2014, 14, 2175. doi: 10.1021/nl500548a doi: 10.1021/nl500548a
28. [28]
  Zhou, W.; Xue, L.; Lü, X.; Gao, H.; Li, Y.; Xin, S.; Fu, G.; Cui, Z.; Zhu, Y.; Goodenough, J. B. Nano Lett. 2016, 16, 7836. doi: 10.1021/acs.nanolett.6b04044 doi: 10.1021/acs.nanolett.6b04044
29. [29]
  Gao, H.; Seymour, I. D.; Xin, S.; Xue, L.; Henkelman, G.; Goodenough, J. B. J. Am. Chem. Soc. 2018, 140, 18192. doi: 10.1021/jacs.8b11388 doi: 10.1021/jacs.8b11388
30. [30]
  Gover, R.; Bryan, A.; Burns, P.; Barker, J. Solid State Ion. 2006, 177, 1495. doi: 10.1016/j.ssi.2006.07.028 doi: 10.1016/j.ssi.2006.07.028
31. [31]
  Serras, P.; Palomares, V.; Goñi, A.; de Muro, I. G.; Kubiak, P.; Lezama, L.; Rojo, T. J. Mater. Chem. 2012, 22, 22301. doi: 10.1039/c2jm35293a doi: 10.1039/c2jm35293a
32. [32]
  Chen, M.; Hua, W.; Xiao, J.; Cortie, D.; Chen, W.; Wang, E.; Hu, Z.; Gu, Q.; Wang, X.; Indris, S. Nat. Commun. 2019, 10, 1480. doi: 10.1038/s41467-019-09170-5 doi: 10.1038/s41467-019-09170-5
33. [33]
  Kee, Y.; Dimov, N.; Staykov, A.; Okada, S. Mater. Chem. Phys. 2016, 171, 45. doi: 10.1016/j.matchemphys.2016.01.033 doi: 10.1016/j.matchemphys.2016.01.033
34. [34]
  Li, S.; Guo, J.; Ye, Z.; Zhao, X.; Wu, S.; Mi, J. X.; Wang, C. Z.; Gong, Z.; McDonald, M. J.; Zhu, Z. ACS Appl. Mater. Interfaces 2016, 8, 17233. doi: 10.1021/acsami.6b03969 doi: 10.1021/acsami.6b03969
35. [35]
  Guan, W.; Pan, B.; Zhou, P.; Mi, J.; Zhang, D.; Xu, J.; Jiang, Y. ACS Appl. Mater. Interfaces 2017, 9, 22369. doi: 10.1021/acsami.7b02385 doi: 10.1021/acsami.7b02385
36. [36]
  Chen, C. Y.; Matsumoto, K.; Nohira, T.; Hagiwara, R. Electrochem. Commun. 2014, 45, 63. doi: 10.1016/j.elecom.2014.05.017 doi: 10.1016/j.elecom.2014.05.017
37. [37]
  Law, M.; Ramar, V.; Balaya, P. J. Power Sources 2017, 359, 277. doi: 10.1016/j.jpowsour.2017.05.069 doi: 10.1016/j.jpowsour.2017.05.069
38. [38]
  Zhang, D.; Ding, Z.; Yang, Y.; Zhao, S.; Huang, Q.; Chen, C.; Chen, L.; Wei, W. Electrochim. Acta 2018, 269, 694. doi: 10.1016/j.electacta.2018.03.045 doi: 10.1016/j.electacta.2018.03.045
39. [39]
  Treacher, J. C.; Wood, S. M.; Islam, M. S.; Kendrick, E. Phys. Chem. Chem. Phys. 2016, 18, 32744. doi: 10.1039/c6cp06777h doi: 10.1039/c6cp06777h
40. [40]
  Rangasamy, V. S.; Thayumanasundaram, S.; Locquet, J. P. Electrochim. Acta 2018, 276, 102. doi: 10.1016/j.electacta.2018.04.166 doi: 10.1016/j.electacta.2018.04.166
41. [41]
  Reynaud, M.; Ati, M.; Boulineau, S.; Sougrati, M. T.; Melot, B. C.; Rousse, G.; Chotard, J. N.; Tarascon, J. M. ECS Trans. 2013, 50, 11. doi: 10.1149/05024.0011ecst doi: 10.1149/05024.0011ecst
42. [42]
  Barpanda, P.; Oyama, G.; Ling, C. D.; Yamada, A. Chem. Mat. 2014, 26, 1297. doi: 10.1021/cm4033226 doi: 10.1021/cm4033226
43. [43]
  Meng, Y.; Zhang, S.; Deng, C. J. Mater. Chem. A 2015, 3, 4484. doi: 10.1039/c4ta06711h doi: 10.1039/c4ta06711h
44. [44]
  Meng, Y.; Li, Q.; Yu, T.; Zhang, S.; Deng, C. CrystEngComm 2016, 18, 1645. doi: 10.1039/c5ce02046h doi: 10.1039/c5ce02046h
45. [45]
  Reynaud, M.; Rousse, G.; Abakumov, A. M.; Sougrati, M. T.; Van Tendeloo, G.; Chotard, J. N.; Tarascon, J. M. J. Mater. Chem. A 2014, 2, 2671. doi: 10.1039/c3ta13648e doi: 10.1039/c3ta13648e
46. [46]
  Singh, P.; Shiva, K.; Celio, H.; Goodenough, J. B. Energy Environ. Sci. 2015, 8, 3000. doi: 10.1039/c5ee02274f doi: 10.1039/c5ee02274f
47. [47]
  Yu, C. J.; Choe, S. H.; Ri, G. C.; Kim, S. C.; Ryo, H. S.; Kim, Y. J. Phys. Rev. Appl. 2017, 8, 024029. doi: 10.1103/PhysRevApplied.8.024029 doi: 10.1103/PhysRevApplied.8.024029
48. [48]
  Chong, X. Y.; Jiang, Y.; Feng, J. J. Micromech. Mol. Phys. 2017, 2, 1750002. doi: 10.1142/S2424913017500023 doi: 10.1142/S2424913017500023
49. [49]
  Barpanda, P.; Oyama, G.; Nishimura, S. I.; Chung, S. C.; Yamada, A. Nat. Commun. 2014, 5, 4358. doi: 10.1038/ncomms5358 doi: 10.1038/ncomms5358
50. [50]
  Oyama, G.; Nishimura, S. I.; Suzuki, Y.; Okubo, M.; Yamada, A. ChemElectroChem 2015, 2, 1019. doi: 10.1002/celc.201500036 doi: 10.1002/celc.201500036
51. [51]
  Meng, Y.; Yu, T.; Zhang, S.; Deng, C. J. Mater. Chem. A 2016, 4, 1624. doi: 10.1039/c5ta07696j doi: 10.1039/c5ta07696j
52. [52]
  Dwibedi, D.; Ling, C. D.; Araujo, R. B.; Chakraborty, S.; Duraisamy, S.; Munichandraiah, N.; Ahuja, R.; Barpanda, P. ACS Appl. Mater. Interfaces 2016, 8, 6982. doi: 10.1021/acsami.5b11302 doi: 10.1021/acsami.5b11302
53. [53]
  Prosini, P. P.; Lisi, M.; Zane, D.; Pasquali, M. Solid State Ion. 2002, 148, 45. doi:10.1016/S0167-2738(02)00134-0 doi: 10.1016/S0167-2738(02)00134-0
54. [54]
  Deiss, E. Electrochim. Acta 2005, 50, 2927. doi: 10.1016/j.electacta.2004.11.042 doi: 10.1016/j.electacta.2004.11.042
55. [55]
  Yang, Z.; Feng, Y.; Li, Z.; Sang, S.; Zhou, Y.; Zeng, L. J. Electroanal. Chem. 2005, 580, 340. doi: 10.1016/j.jelechem.2005.04.004 doi: 10.1016/j.jelechem.2005.04.004
56. [56]
  Das, S.; Majumder, S.; Katiyar, R. J. Power Sources 2005, 139, 261. doi: 10.1016/j.jpowsour.2004.06.056 doi: 10.1016/j.jpowsour.2004.06.056
57. [57]
  Longoni, G.; Wang, J. E.; Jung, Y. H.; Kim, D. K.; Mari, C. M.; Ruffo, R. J. Power Sources 2016, 302, 61. doi: 10.1016/j.jpowsour.2015.10.033 doi: 10.1016/j.jpowsour.2015.10.033
58. [58]
  Li, G.; Jiang, D.; Wang, H.; Lan, X.; Zhong, H.; Jiang, Y. J. Power Sources 2014, 265, 325. doi: 10.1016/j.jpowsour.2014.04.054 doi: 10.1016/j.jpowsour.2014.04.054
59. [59]
  Song, W.; Ji, X.; Wu, Z.; Yang, Y.; Zhou, Z.; Li, F.; Chen, Q.; Banks, C. E. J. Power Sources 2014, 256, 258. doi: 10.1016/j.jpowsour.2014.01.025 doi: 10.1016/j.jpowsour.2014.01.025
60. [60]
  Deng, G.; Chao, D.; Guo, Y.; Chen, Z.; Wang, H.; Savilov, S. V.; Lin, J.; Shen, Z. X. Energy Storage Mater. 2016, 5, 198. doi: 10.1016/j.ensm.2016.07.007 doi: 10.1016/j.ensm.2016.07.007
61. [61]
  Lu, J.; Yamada, A. ChemElectroChem 2016, 3, 902. doi: 10.1002/celc.201500535 doi: 10.1002/celc.201500535
62. [62]
  Rahman, M. M.; Sultana, I.; Mateti, S.; Liu, J.; Sharma, N.; Chen, Y. J. Mater. Chem. A 2017, 5, 16616. doi: 10.1039/C7TA04946C doi: 10.1039/C7TA04946C
63. [63]
  Liu, Y.; Zhang, N.; Wang, F.; Liu, X.; Jiao, L.; Fan, L. Z. Adv. Funct. Mater. 2018, 28, 1801917. doi: 10.1002/adfm.201801917 doi: 10.1002/adfm.201801917
64. [64]
  Ali, G.; Lee, J. H.; Susanto, D.; Choi, S. W.; Cho, B. W.; Nam, K. W.; Chung, K. Y. ACS Appl. Mater. Interfaces 2016, 8, 15422. doi: 10.1016/j.elecom.2012.06.014 doi: 10.1016/j.elecom.2012.06.014
65. [65]
  Barpanda, P.; Ye, T.; Nishimura, S. I.; Chung, S. C.; Yamada, Y.; Okubo, M.; Zhou, H.; Yamada, A. Electrochem. Commun. 2012, 24, 116. doi: 10.1021/acsami.6b04014 doi: 10.1021/acsami.6b04014
66. [66]
  Jian, Z.; Zhao, L.; Pan, H.; Hu, Y. S.; Li, H.; Chen, W.; Chen, L. Electrochem. Commun. 2012, 14, 86. doi: 10.1016/j.elecom.2011.11.009 doi: 10.1016/j.elecom.2011.11.009
67. [67]
  Rui, X.; Sun, W.; Wu, C.; Yu, Y.; Yan, Q. Adv. Mater. 2015, 27, 6670. doi: 10.1002/adma.201502864 doi: 10.1002/adma.201502864
68. [68]
  Liu, Q.; Meng, X.; Wei, Z.; Wang, D.; Gao, Y.; Wei, Y.; Du, F.; Chen, G. ACS Appl. Mater. Interfaces 2016, 8, 31709. doi: 10.1021/acsami.6b11372 doi: 10.1021/acsami.6b11372
69. [69]
  Serras, P.; Palomares, V.; Kubiak, P.; Lezama, L.; Rojo, T. Electrochem. Commun. 2013, 34, 344. doi: 10.1016/j.elecom.2013.07.010 doi: 10.1016/j.elecom.2013.07.010
70. [70]
  Ali, B.; Ghafoor, F.; Shahzad, M. I.; Shah, S. K.; Abbas, S. M. J. Power Sources 2018, 396, 467. doi: 10.1016/j.jpowsour.2018.06.049 doi: 10.1016/j.jpowsour.2018.06.049
71. [71]
  Pan, W.; Guan, W.; Liu, S.; Xu, B. B.; Liang, C.; Pan, H.; Yan, M.; Jiang, Y. J. Mater. Chem. A 2019, 7, 13197. doi: 10.1039/C9TA02188D doi: 10.1039/C9TA02188D
72. [72]
  Zhang, Y.; Xia, X.; Liu, B.; Deng, S.; Xie, D.; Liu, Q.; Wang, Y.; Wu, J.; Wang, X.; Tu, J. Adv. Energy Mater. 2019, 9, 1803342. doi: 10.1002/aenm.201803342 doi: 10.1002/aenm.201803342
73. [73]
  Jung, Y. H.; Lim, C. H.; Kim, D. K. J. Mater. Chem. A 2013, 1, 11350. doi: 10.1039/c3ta12116j doi: 10.1039/c3ta12116j
74. [74]
  Zhang, J.; Yuan, T.; Wan, H.; Qian, J.; Ai, X.; Yang, H.; Cao, Y. Sci. China Chem. 2017, 60, 1546. doi: 10.1007/s11426-017-9125-y doi: 10.1007/s11426-017-9125-y
75. [75]
  Li, S.; Dong, Y.; Xu, L.; Xu, X.; He, L.; Mai, L. Adv. Mater. 2014, 26, 3545. doi: 10.1002/adma.201305522 doi: 10.1002/adma.201305522
76. [76]
  Xu, Y.; Wei, Q.; Xu, C.; Li, Q.; An, Q.; Zhang, P.; Sheng, J.; Zhou, L.; Mai, L. Adv. Energy Mater. 2016, 6, 1600389. doi: 10.1002/aenm.201600389 doi: 10.1002/aenm.201600389
77. [77]
  An, Q.; Xiong, F.; Wei, Q.; Sheng, J.; He, L.; Ma, D.; Yao, Y.; Mai, L. Adv. Energy Mater. 2015, 5, 1401963. doi: 10.1002/aenm.201401963 doi: 10.1002/aenm.201401963
78. [78]
  Fang, Y.; Xiao, L.; Ai, X.; Cao, Y.; Yang, H. Adv. Mater. 2015, 27, 5895. doi: 10.1002/adma.201502018 doi: 10.1002/adma.201502018
79. [79]
  Jiang, T.; Wei, Y.; Pan, W.; Li, Z.; Ming, X.; Chen, G.; Wang, C. J. Alloy. Compd. 2009, 488, L26. doi: 10.1016/j.jallcom.2009.08.134 doi: 10.1016/j.jallcom.2009.08.134
80. [80]
  Ni, J.; Zhang, L.; Fu, S.; Savilov, S.; Aldoshin, S.; Lu, L. Carbon 2015, 92, 15. doi: 10.1016/j.carbon.2015.02.047 doi: 10.1016/j.carbon.2015.02.047
81. [81]
  Li, Y. D.; Deng, Y. F.; Pan, Z. Y.; Wei, Y. P.; Zhao, S. X.; Gan, L. Acta Phys. -Chim. Sin. 2017, 33, 2293. doi: 10.3866/PKU.WHXB201705294
82. [82]
  Zhang, S.; Gu, H.; Pan, H.; Yang, S.; Du, W.; Li, X.; Gao, M.; Liu, Y.; Zhu, M.; Ouyang, L. Adv. Energy Mater. 2017, 7, 1601066. doi: 10.1002/aenm.201601066 doi: 10.1002/aenm.201601066
83. [83]
  Zhang, S.; Chen, J.; Tang, T.; Jiang, Y.; Chen, G.; Shao, Q.; Yan, C.; Zhu, T.; Gao, M.; Liu, Y. J. Mater. Chem. A 2018, 6, 3610. doi: 10.1039/C7TA10887G doi: 10.1039/C7TA10887G
1. [1]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
2. [2]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
3. [3]
  Siyu Zhang , Kunhong Gu , Bing'an Lu , Junwei Han , Jiang Zhou . Hydrometallurgical Processes on Recycling of Spent Lithium-lon Battery Cathode: Advances and Applications in Sustainable Technologies. Acta Physico-Chimica Sinica, 2024, 40(10): 2309028-. doi: 10.3866/PKU.WHXB202309028
4. [4]
  Qingtang ZHANG , Xiaoyu WU , Zheng WANG , Xiaomei WANG . Performance of nano Li₂FeSiO₄/C cathode material co-doped by potassium and chlorine ions. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1689-1696. doi: 10.11862/CJIC.20240115
5. [5]
  Zhenming Xu , Mingbo Zheng , Zhenhui Liu , Duo Chen , Qingsheng Liu . Experimental Design of Project-Driven Teaching in Computational Materials Science: First-Principles Calculations of the LiFePO₄ Cathode Material for Lithium-Ion Batteries. University Chemistry, 2024, 39(4): 140-148. doi: 10.3866/PKU.DXHX202307022
6. [6]
  Yifeng Xu , Jiquan Liu , Bin Cui , Yan Li , Gang Xie , Ying Yang . “Xiao Li’s School Adventures: The Working Principles and Safety Risks of Lithium-ion Batteries”. University Chemistry, 2024, 39(9): 259-265. doi: 10.12461/PKU.DXHX202404009
7. [7]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
8. [8]
  Qi Li , Pingan Li , Zetong Liu , Jiahui Zhang , Hao Zhang , Weilai Yu , Xianluo Hu . Fabricating Micro/Nanostructured Separators and Electrode Materials by Coaxial Electrospinning for Lithium-Ion Batteries: From Fundamentals to Applications. Acta Physico-Chimica Sinica, 2024, 40(10): 2311030-. doi: 10.3866/PKU.WHXB202311030
9. [9]
  Wendian XIE , Yuehua LONG , Jianyang XIE , Liqun XING , Shixiong SHE , Yan YANG , Zhihao HUANG . Preparation and ion separation performance of oligoether chains enriched covalent organic framework membrane. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1528-1536. doi: 10.11862/CJIC.20240050
10. [10]
  Wenjun Zheng . Application in Inorganic Synthesis of Ionic Liquids. University Chemistry, 2024, 39(8): 163-168. doi: 10.3866/PKU.DXHX202401020
11. [11]
  Hong LI , Xiaoying DING , Cihang LIU , Jinghan ZHANG , Yanying RAO . Detection of iron and copper ions based on gold nanorod etching colorimetry. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 953-962. doi: 10.11862/CJIC.20230370
12. [12]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
13. [13]
  Rui Li , Huan Liu , Yinan Jiao , Shengjian Qin , Jie Meng , Jiayu Song , Rongrong Yan , Hang Su , Hengbin Chen , Zixuan Shang , Jinjin Zhao . 卤化物钙钛矿的单双向离子迁移. Acta Physico-Chimica Sinica, 2024, 40(11): 2311011-. doi: 10.3866/PKU.WHXB202311011
14. [14]
  Feiya Cao , Qixin Wang , Pu Li , Zhirong Xing , Ziyu Song , Heng Zhang , Zhibin Zhou , Wenfang Feng . Magnesium-Ion Conducting Electrolyte Based on Grignard Reaction: Synthesis and Properties. University Chemistry, 2024, 39(3): 359-368. doi: 10.3866/PKU.DXHX202308094
15. [15]
  Xuyang Wang , Jiapei Zhang , Lirui Zhao , Xiaowen Xu , Guizheng Zou , Bin Zhang . Theoretical Study on the Structure and Stability of Copper-Ammonia Coordination Ions. University Chemistry, 2024, 39(3): 384-389. doi: 10.3866/PKU.DXHX202309065
16. [16]
  Dongqi Cai , Fuping Tian , Zerui Zhao , Yanjuan Zhang , Yue Dai , Feifei Huang , Yu Wang . Exploration of Factors Influencing the Determination of Ion Migration Number by Hittorf Method. University Chemistry, 2024, 39(4): 94-99. doi: 10.3866/PKU.DXHX202310031
17. [17]
  Jiayu Tang , Jichuan Pang , Shaohua Xiao , Xinhua Xu , Meifen Wu . Improvement for Measuring Transference Numbers of Ions by Moving-Boundary Method. University Chemistry, 2024, 39(5): 193-200. doi: 10.3866/PKU.DXHX202311021
18. [18]
  Kexin Dong , Chuqi Shen , Ruyu Yan , Yanping Liu , Chunqiang Zhuang , Shijie Li . Integration of Plasmonic Effect and S-Scheme Heterojunction into Ag/Ag₃PO₄/C₃N₅ Photocatalyst for Boosted Photocatalytic Levofloxacin Degradation. Acta Physico-Chimica Sinica, 2024, 40(10): 2310013-. doi: 10.3866/PKU.WHXB202310013
19. [19]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
20. [20]
  Guang Huang , Lei Li , Dingyi Zhang , Xingze Wang , Yugai Huang , Wenhui Liang , Zhifen Guo , Wenmei Jiao . Cobalt’s Valor, Nickel’s Foe: A Comprehensive Chemical Experiment Utilizing a Cobalt-based Imidazolate Framework for Nickel Ion Removal. University Chemistry, 2024, 39(8): 174-183. doi: 10.3866/PKU.DXHX202311051

Get Citation

PDF

XML

Metrics

PDF Downloads(66)
Abstract views(1614)
HTML views(545)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142