Citation: Chen Guanghai, Bai Ying, Gao Yongsheng, Wu Feng, Wu Chuan. Chalcogenide Electrolytes for All-Solid-State Sodium Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2020, 36(5): 190500. doi: 10.3866/PKU.WHXB201905009 shu

Chalcogenide Electrolytes for All-Solid-State Sodium Ion Batteries

Beijing Key Laboratory of Environmental Science and Engineering, School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, P. R. China

Corresponding author: Wu Chuan, chuanwu@bit.edu.cn
Received Date: 2 May 2019
Revised Date: 4 June 2019
Accepted Date: 17 June 2019
Available Online: 24 May 2019
Fund Project: the Beijing Natural Science Foundation-Haidian Original Innovation Collaborative Fund, China L182056The project was supported by the National Basic Research Program of China (2015CB251100) and the Beijing Natural Science Foundation-Haidian Original Innovation Collaborative Fund, China (L182056)the National Basic Research Program of China 2015CB251100

All-solid-state sodium ion batteries (ASIBs) are important for future large-scale energy storage applications. ASIBs have come to occupy an important position in research on advanced secondary batteries in recent years owing to their advantages of abundance in resources, low cost, long lifetime, and high safety. As the key to the success of ASIBs, solid-state electrolytes such as polymers, oxide ceramics, and sulfide glass-ceramics have always attracted immense interest. Chalcogenide electrolytes for ASIBs have high room-temperature conductivity, high elastic modulus, and can be easily pressed into a mold at room temperature; hence, they are the research focus in ASIBs. This paper summarized recent studies on the structure and properties of chalcogenide electrolytes for ASIBs. These studies demonstrate the relationship between the phase structure and ionic conductivity of sulfide-based electrolytes and selenide-based electrolytes. Besides, arguments that the sodium vacancy in the crystal structure dominates ionic conduction, and creating a sodium vacancy via cation substitution is the principal strategy to increasing ionic conduction, are discussed. Further, the intrinsic chemical stability and interface stability between the electrode and electrolyte are highlighted. Based on the soft and hard acid and base theory, some studies adopted various anion/cation ion substitution strategies to improve the chemical stability of chalcogenide electrolytes in humid air. Particularly, the inconsistency in the electrochemical stability window of a representative chalcogenide electrode, Na₃PS₄, as measured by a semi-blocking electrode and calculated by first-principles, is compared. Additionally, to develop all-solid-state Na-S and Na-O₂ batteries with high capacity, the nonnegligible interface instability of the sulfide electrode against the sodium metal anode and feasible solutions are summarized. Next, the research progress on ASIBs using chalcogenide electrolytes is reviewed. Chalcogenide electrolytes are restricted by the electrochemical stability window and chemical compatibility with electrode materials; hence, they are expected to only be applicable to ASIBs using sulfur, sulfide, and organic matter as the cathode and Na-Sn alloy as the anode. However, these ASIBs have long cycling life (> 500 cycles), illustrating their potential applications in large-scale energy storage power stations. Finally, we comprehensively evaluate the ionic conductivity, stability against humid air, stability of the interface, electrochemical stability window, and ease of preparation of typical chalcogenide electrolytes, including Na₃PS₄, Na₃PSe₄, Na₃SbS₄, Na₃SbSe₄, Na₁₀SnPS₁₂, and Na₁₁Sn₂PS₁₂. Moreover, we highlight the challenges and propose possible solutions toward the development of chalcogenide electrolytes in future. Advanced technologies in fine synthesis, in situ characterization, and surface/interface modification are essential to overcome existing challenges and promote the development of chalcogenide-electrolyte-based ASIBs.
- All-solid-state sodium ion battery,
- Chalcogenide electrolyte,
- Conductivity,
- Chemical stability,
- Interface
1. [1]
  Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741 doi: 10.1126/science.1212741
2. [2]
  Pan, H.; Hu, Y. S.; Chen, L. Q. Energy Environ Sci. 2013, 6, 2338. doi: 10.1039/c3ee40847g doi: 10.1039/c3ee40847g
3. [3]
  Yang, Z.; Zhang, W.; Shen, Y.; Yuan, L. X.; Huang, Y. H. Acta Phys. -Chim. Sin. 2016, 32 (5), 1062. doi: 10.3866/PKU.WHXB201603231
4. [4]
  Zuo, X.; Cai, F.; Liu, X. M.; Yang, H.; Shen, X. D. Acta Phys. -Chim. Sin. 2013, 29 (1), 64. doi: 10.3866/PKU.WHXB201211023
5. [5]
  Ma, Q.; Hu, Y. S.; Li, H.; Chen, L. Q.; Huang, X. J.; Zhou, Z. B. Acta Phys. -Chim. Sin. 2018, 34 (2), 213. doi: 10.3866/PKU.WHXB201707172
6. [6]
  Tel'nova, G. B.; Solntsev, K. A. Inorg. Mater. 2015, 51, 305. doi: 10.1134/S0020168515030176 doi: 10.1134/S0020168515030176
7. [7]
  Noguchi, Y.; Kobayashi, E.; Plashnitsa, L. S.; Okada, S.; Yamaki, J. I. Electrochim Acta 2013, 101, 59. doi: 10.1016/j.electacta.2012.11.038 doi: 10.1016/j.electacta.2012.11.038
8. [8]
  Santhanagopalan, D.; Qian, D.; McGilvray, T.; Wang, Z.; Wang, F.; Camino, F.; Graetz, J.; Dudney, N.; Meng, Y. S. J. Phys. Chem. Lett. 2014, 5, 298. doi: 10.1021/jz402467x doi: 10.1021/jz402467x
9. [9]
  Wang, Y.; Zhong, W. H. ChemElectroChem 2015, 2, 22. doi: 10.1002/celc.201402277 doi: 10.1002/celc.201402277
10. [10]
  Nam, Y. J.; Cho, S. J.; Oh, D. Y.; Lim, J. M.; Kim, S. Y.; Song, J. H.; Lee, Y. G.; Lee, S. Y.; Jung, Y. S. Nano Lett. 2015, 15, 3317. doi: 10.1021/acs.nanolett.5b00538 doi: 10.1021/acs.nanolett.5b00538
11. [11]
  Park, K. H.; Oh, D. Y.; Choi, Y. E.; Nam, Y. J.; Han, L.; Kim, J. Y.; Xin, H. Lin, F.; Oh, S. M.; Jung, Y. S. Adv Mater. 2016, 28, 1874. doi: 10.1002/adma.201505008 doi: 10.1002/adma.201505008
12. [12]
  Seino, Y.; Ota, T.; Takada, K.; Hayashi, A.; Tatsumisago, M. Energy Environ. Sci. 2014, 7, 627. doi: 10.1039/c3ee41655k doi: 10.1039/c3ee41655k
13. [13]
  Kamaya, N.; Homma, K.; Yamakawa, Y.; Hirayama, M.; Kanno, R.; Yonemura, M.; Kamiyama, T.; Kato, Y.; Hama, S.; Kawamoto, K.; et al. Nat. Mater. 2011, 10, 682. doi: 10.1038/NMAT3066 doi: 10.1038/NMAT3066
14. [14]
  Jansen, M.; Henseler, U. J. Solid State Chem. 1992, 99, 110. doi: 10.1016/0022-4596(92)90295-7 doi: 10.1016/0022-4596(92)90295-7
15. [15]
  Hayashi, A.; Noi, K.; Sakuda, A.; Tatsumisago, M. Nat. Commun. 2012, 3, 1. doi: 10.1038/ncomms1843 doi: 10.1038/ncomms1843
16. [16]
  Zhu, Z.Y.; Chu, I. H.; Deng, Z.; Ong, S. P. Chem. Mater. 2015, 27, 8318. doi: 10.1021/acs.chemmater.5b03656 doi: 10.1021/acs.chemmater.5b03656
17. [17]
  Chu, I. H.; Kompella, C. S.; Nguyen, H.; Zhu, Z.; Hy, S.; Deng, Z.; Meng, Y. S.; Ong, S. P. Sci. Rep. 2016, 6, 33733. doi: 10.1038/srep33733 doi: 10.1038/srep33733
18. [18]
  de Klerk N. J. J.; Wagemaker, M. Chem. Mater. 2016, 28, 3122. doi: 10.1021/acs.chemmater.6b00698 doi: 10.1021/acs.chemmater.6b00698
19. [19]
  Noi, K.; Hayashi, A.; Tatsumisago, M. J. Power Sources 2014, 269, 260. doi: 0.1016/j.jpowsour.2014.06.158 doi: 10.1016/j.jpowsour.2014.06.158
20. [20]
  Yu, C.; Ganapathy, S.; de Klerk, N. J. J.; van Eck, E. R. H.; Wagemaker, M. J. Mater. Chem. A 2016, 4, 15095. doi: 10.1039/c6ta05896e doi: 10.1039/c6ta05896e
21. [21]
  Hayashi, A.; Noi, K.; Tanibata, N.; Nagao, M.; Tatsumisago, M. J. Power Sources 2014, 258, 420. doi: 10.1016/j.jpowsour.2014.02.054 doi: 10.1016/j.jpowsour.2014.02.054
22. [22]
  Takeuchi, S.; Suzuki, K.; Hirayama, M.; Kanno, R. J. Solid State Chem. 2018, 265, 353. doi: 10.1016/j.jssc.2018.06.023 doi: 10.1016/j.jssc.2018.06.023
23. [23]
  Rao, R. P.; Chen, H.; Wong, L. L.; Adams, S. J. Mater. Chem. A 2017, 5, 3377. doi: 10.1039/c6ta09809f doi: 10.1039/c6ta09809f
24. [24]
  Ponrouch, A.; Marchante, E.; Courty, M.; Tarascon, J. M.; Palacín, M. R. Energy Environ. Sci. 2012, 5, 8572. doi: 10.1039/c2ee22258b doi: 10.1039/c2ee22258b
25. [25]
  Yu, Z. X.; Shang, S. L.; Seo, J. H.; Wang, D.; Luo, X.; Huang, Q.; Chen, S.; Lu, J.; Li, X.; Liu, Z. K.; et al. Adv Mater. 2017, 29, 16. doi: 10.1002/adma.201605561 doi: 10.1002/adma.201605561
26. [26]
  Krebs, B. Angew. Chem. Int. Ed. Engl.1983, 22, 113. doi: 10.1002/anie.198301131| doi: 10.1002/anie.198301131|
27. [27]
  Kanno, R.; Murayama, M. J. Electrochem. Soc. 2001, 148, A742. doi: 10.1149/1.1379028 doi: 10.1149/1.1379028
28. [28]
  Tanibata, N.; Noi, K.; Hayashi, A; Tatsumisago, M. RSC Adv. 2014, 4, 17120. doi: 10.1039/c4ra00996g doi: 10.1039/c4ra00996g
29. [29]
  Tanibata, N.; Noi, K.; Hayashi, A; Kitamura, N.; Idemoto, Y.; Tatsumisago, M. ChemElectroChem 2014, 1, 1130. doi: 10.1002/celc.201402016 doi: 10.1002/celc.201402016
30. [30]
  Zhang, L.; Zhang, D.; Yang, K.; Yan, X.; Wang, L.; Mi, J.; Xu, B.; Li, Y. Adv. Sci. 2016, 1600089. doi: 10.1002/advs.201600089 doi: 10.1002/advs.201600089
31. [31]
  Graf, V. H. A.; Schafer, H.; Z. Anorg. Allg. Chem. 1976, 425, 67. doi: 10.1002/zaac.19764250109
32. [32]
  Wang, Y.; Richards, W. D.; Ong, S. P.; Miara, L. J.; Kim, J. C.; Mo, Y. F.; Ceder, G. Nat. Mater. 2015, 14, 1026. doi: 10.1038/NMAT4369 doi: 10.1038/NMAT4369
33. [33]
  Zhang, D.; Cao, X.; Xu, D.; Wang, N.; Yu, C.; Hu, W.; Yan, X.; Mi, J.; Wen, B.; Wang, L.; et al. Electrochim. Acta 2018, 259, 100. doi: 10.1016/j.electacta.2017.10.173 doi: 10.1016/j.electacta.2017.10.173
34. [34]
  Mikenda, A. Preisinger. W. Spectrochim. Acta Part A: Mol. Spectroscopy 1980, 36, 365. doi: 10.1016/0584-8539(80)80145-0 doi: 10.1016/0584-8539(80)80145-0
35. [35]
  Wang, H.; Chen, Y.; Hood, Z. D.; Sahu, G.; Pandian, A. S.; Keum, J. K.; An, K.; Liang, C. D. Angew Chem. Int. Ed. 2016, 55, 1. doi: 10.1002/anie.201601546 doi: 10.1002/anie.201601546
36. [36]
  Zhang, D. C.; Cao, X. T.; Xu, D.; Wang, N.; Yu, C.; Hu, W. T.; Yan, X. L.; Mi, J. L.; Wen, B.; Wang, L. M.; et al. Electrochim. Acta 2018, 259, 100. doi: 10.1016/j.electacta.2017.10.173 doi: 10.1016/j.electacta.2017.10.173
37. [37]
  Heo, J. W.; Banerjee, A.; Park, K. H.; Jung, Y. S.; Hong, S. T. Adv. Energy Mater. 2018, 8, 1702716. doi: 10.1002/aenm.201702716 doi: 10.1002/aenm.201702716
38. [38]
  Maier, J. Nat. Mater. 2005, 4, 805. doi: 10.1038/nmat1513 doi: 10.1038/nmat1513
39. [39]
  Jia, H. H.; Sun, Y. L.; Zhang, Z. R.; Peng, L. F.; An, T.; Xie, J. Energy Storage Mater. 2019, in press, doi: 10.1016/j.ensm.2019.04.011 doi: 10.1016/j.ensm.2019.04.011
40. [40]
  Ong, S. P.; Mo, Y. F.; Richards, W. D.; Miara, L.; Lee, H. S.; Ceder, G. Energy Environ. Sci. 2013, 6, 148. doi: 10.1039/c2ee23355j doi: 10.1039/c2ee23355j
41. [41]
  Zhang, L.; Yang, K.; Mi, J.; Lu, L.; Zhao, L.; Wang, L.; Li, Y.; Zeng, H. Adv. Energy Mater. 2015, 5, 1501294. doi: 10.1002/aenm.201501294 doi: 10.1002/aenm.201501294
42. [42]
  Bo, S. H.; Wang, Y.; Kim, J. C.; Richards, W. D.; Ceder, G. Chem. Mat. 2016, 28, 252. doi: 10.1021/acs.chemmater.5b04013 doi: 10.1021/acs.chemmater.5b04013
43. [43]
  Bo, S. H.; Wang, Y.; Ceder, G. J. Mater. Chem. A 2016, 4, 9044. doi: 10.1039/c6ta03027k doi: 10.1039/c6ta03027k
44. [44]
  Wang, N.; Yang, K.; Zhang, L.; Yan, X.; Wang, L.; Xu, B. J. Mater. Sci. 2017, 53, 1987. doi: 10.1007/s10853-017-1618-0 doi: 10.1007/s10853-017-1618-0
45. [45]
  Kato, Y.; Hori, S.; Saito, T.; Suzuki, K.; Hirayama, M.; Mitsui, A.; Yonemura, M.; Iba, H.; Kanno, R. Nat. Energy, 2016, 1, 16030. doi: 10.1038/nenergy.2016.30 doi: 10.1038/nenergy.2016.30
46. [46]
  Kandagal, V. S.; Bharadwaj, M. D.; Waghmare, U. V. J. Mater. Chem. A 2015, 3, 12992. doi: 10.1039/c5ta01616a doi: 10.1039/c5ta01616a
47. [47]
  Richards, W. D.; Tsujimura, T.; Miara, L. J.; Wang, Y.; Kim, J. C.; Ong, S. P.; Uechi, I.; Suzuki, N.; Ceder, G. Nat. Commun. 2016, 7, 11009. doi: 10.1038/ncomms11009 doi: 10.1038/ncomms11009
48. [48]
  Kandagal, V. S.; Bharadwaj, M. D.; Waghmare, U. V. J. Mater. Chem. A 2015, 3, 12992. doi: 10.1039/c5ta01616a doi: 10.1039/c5ta01616a
49. [49]
  Tsuji, F.; Tanibata, N.; Sakuda, A.; Hayashi, A.; Tasumisago, M. Chem. Lett. 2018, 47, 13. doi: 10.1246/cl.170836 doi: 10.1246/cl.170836
50. [50]
  Zhang, Z.; Ramos, E.; Lalère, F.; Assoud, A.; Kaup, K.; Hartman, P.; Nazar, L. F. Energy Environ. Sci. 2018, 11, 87. doi: 10.1039/c7ee03083e doi: 10.1039/c7ee03083e
51. [51]
  Kuhn, A.; Kohler, J.; Lotsch, B. V. Phys. Chem. Chem. Phys. 2013, 15, 11620. doi: 10.1039/c3cp51985f doi: 10.1039/c3cp51985f
52. [52]
  Kuhn, A.; Gerbig, O.; Zhu, C.; Falkenberg, F.; Maier, J.; Lotsch, B. V. Phys. Chem. Chem. Phys. 2014, 16, 14669. doi: 10.1039/c4cp02046d doi: 10.1039/c4cp02046d
53. [53]
  Duchardt, M.; Ruschewitz, U.; Adams, S.; Dehnen, S.; Roling, B. Angew. Chem. Int. Ed. 2018, 57, 1351. doi: 10.1002/ange.201712769 doi: 10.1002/ange.201712769
54. [54]
  Ramos, E. P.; Zhang, Z. Z.; Assoud, A.; Kaup, K.; Lalere, F.; Nazar, L. F. Chem. Mater. 2018, 30, 7413. doi: 10.1021/acs.chemmater.8b02077 doi: 10.1021/acs.chemmater.8b02077
55. [55]
  Yu, Z.; Shang, S. L.; Gao, Y.; Wang, D.; Li, X.; Liu, Z. K.; Wang, D. H. Nano Energy 2018, 47, 325. doi: 10.1016/j.nanoen.2018.01.046 doi: 10.1016/j.nanoen.2018.01.046
56. [56]
  Yu, Z. X.; Shang, S. L.; Wang, D. W.; Li, Y. C.; Yennawar, H. P.; Li, G. X.; Huang, H.; Gao, Y.; Mallouk, T. E.; Liu, Z. K.; et al. Energy Storage Mater. 2019, 17, 70. doi: 10.1016/j.ensm.2018.11.027 doi: 10.1016/j.ensm.2018.11.027
57. [57]
  Wang, Y.; Richards, W. D.; Bo, S. H.; Miara, L. J.; Ceder, G. Chem. Mat. 2017, 29, 7475. doi: 10.1021/acs.chemmater.7b02476 doi: 10.1021/acs.chemmater.7b02476
58. [58]
  Han, F. D.; Westover, A. S.; Yue, J.; Fan, X. L.; Wang, F.; Chi, M. F.; Leonard, D. N.; Dudney, N. J.; Wang, H.; Wang, C. S. Nat. Energy 2019, 4, 187. doi: 10.1038/s41560-018-0312-z doi: 10.1038/s41560-018-0312-z
59. [59]
  Banerjee, A.; Park, K. H.; Heo, J. W.; Nam, Y. J.; Moon, C. K.; Oh, S. M.; Hong, S. T.; Jung, Y. S. Angew. Chem. Int. Ed. 2016, 55, 9634. doi: 10.1002/anie.201604158 doi: 10.1002/anie.201604158
60. [60]
  Kim, T. W.; Park, K. H.; Choi, Y. E.; Lee, J. Y.; Jung, Y. S. J. Mater. Chem. A 2018, 6, 840. doi: 10.1039/C7TA09242C doi: 10.1039/C7TA09242C
61. [61]
  Moon, C. K.; Lee, H. J.; Park, K. H.; Kwak, H.; Heo, J. W.; Choi, K.; Yang, H.; Kim, M. S.; Hong, S. T.; Lee, J. H.; et al. ACS Energy Lett. 2018, 3, 2504. doi: 10.1021/acsenergylett.8b01479 doi: 10.1021/acsenergylett.8b01479
62. [62]
  Hibi, Y.; Tanibata, N.; Hayashi, A.; Tatsumisago, M. Solid State Ion. 2015, 270, 6. doi: 10.1016/j.ssi.2014.11.024 doi: 10.1016/j.ssi.2014.11.024
63. [63]
  Takada, K. Acta Mater. 2013, 61, 759. doi: 10.1016/j.actamat.2012.10.034 doi: 10.1016/j.actamat.2012.10.034
64. [64]
  Sahu, G.; Lin, Z.; Li, J.; Liu, Z.; Dudney, N.; Liang, C. D. Energy Environ. Sci. 2014, 7, 1053. doi: 10.1039/c3ee43357a doi: 10.1039/c3ee43357a
65. [65]
  Shang, S. L.; Yu, Z.; Wang, Y.; Wang, D.; Liu, Z. K. ACS Appl. Mater. Interfaces 2017, 9, 16261. doi: 10.1021/acsami.7b03606 doi: 10.1021/acsami.7b03606
66. [66]
  Han, F.; Gao, T.; Zhu, Y.; Gaskell, K. J.; Wang, C.S. Adv Mater. 2015, 27, 3473. doi: 10.1002/adma.201500180 doi: 10.1002/adma.201500180
67. [67]
  Tian, Y. S.; Shi, T.; Richards, W. D.; Li, J.; Kim, J. C.; Bo, S. H.; Ceder, G. Energy Environ. Sci. 2017, 10, 1150. doi: 10.1039/c7ee00534b doi: 10.1039/c7ee00534b
68. [68]
  Han, F.; Zhu, Y.; He, X.; Mo, Y. F.; Wang, C. S. Adv. Energy Mater. 2016, 6, 1501590. doi: 10.1002/aenm.201501590 doi: 10.1002/aenm.201501590
69. [69]
  Takada, K.; Ohta, N.; Zhang, L.; Xu, X.; Hang, B. T.; Ohnishi, T.; Osada, M.; Sasaki, T. Solid State Ion. 2012, 225, 594. doi: 10.1016/j.ssi.2012.01.009 doi: 10.1016/j.ssi.2012.01.009
70. [70]
  Hartmann, P.; Bender, C. L.; Vracar, M.; Durr, A. K.; Garsuch, A.; Janek, J.; Adelhelm, P. Nat. Mater. 2013, 12, 228. doi: 10.1038/NMAT3486 doi: 10.1038/NMAT3486
71. [71]
  Das, S. K.; Lau, S.; Archer, L. A. J. Mater. Chem. A 2014, 2, 12623. doi: 10.1039/c4ta02176b doi: 10.1039/c4ta02176b
72. [72]
  Manthiram, A.; Yu, X. W. Small 2015, 11, 2108. doi: 10.1002/smll.201403257 doi: 10.1002/smll.201403257
73. [73]
  Yu, X. W.; Manthiram, A. Adv. Energy Mater. 2015, 5, 1500350. doi: 10.1002/aenm.201500350 doi: 10.1002/aenm.201500350
74. [74]
  Wei, S.; Xu, S.; Agrawral, A.; Choudhury, S.; Lu, Y.; Tu, Z.; Ma, L.; Archer, L. A. Nat. Commun. 2016, 7, 11722. doi: 10.1038/ncomms11722 doi: 10.1038/ncomms11722
75. [75]
  Wu, F.; Liu, L.; Yuan, Y. F.; Li, Y.; Bai, Y.; Lu, J.; Wu, C. ACS Appl. Mater. Interfaces 2018, 10, 32, 27030. doi: 10.1021/acsami.8b08380 doi: 10.1021/acsami.8b08380
76. [76]
  Li, Y.; Yuan, Y. F.; Bai, Y.; Liu, Y. C.; Wang, Z. H.; Li, L. M.; Wu, F.; Khalil, A.; Wu, C.; Lu, J. Adv. Energy Mater. 2018, 25, 1702781. doi: 10.1002/aenm.201702781 doi: 10.1002/aenm.201702781
77. [77]
  Chen, G. H.; Bai, Y.; Li, H.; Li, Y.; Wang, Z. H.; Ni, Q.; Liu, L.; Wu, F.; Yao, Y. G.; Wu, C. ACS Appl. Mater. Interfaces 2017, 9, 8, 6666. doi: 10.1021/acsami.6b16186 doi: 10.1021/acsami.6b16186
78. [78]
  Luo, W.; Hu, L. B. ACS Cent. Sci. 2015, 1, 420. doi: 10.1021/acscentsci.5b00357 doi: 10.1021/acscentsci.5b00357
79. [79]
  Seh, Z. W.; Sun, J.; Sun, Y.; Cui, Y. ACS Cent. Sci. 2015, 1, 449. doi: 10.1021/acscentsci.5b00328 doi: 10.1021/acscentsci.5b00328
80. [80]
  Luo, W.; Lin, C. F.; Zhao, O.; Noked, M.; Zhang, Y.; Rubloff, G. W.; Hu, L. B. Adv. Energy Mater. 2016, 6, 1601526. doi: 10.1002/aenm.201601526 doi: 10.1002/aenm.201601526
81. [81]
  Bertheville, B.; LowH.Bill, D.F.; Kubel, F. J. Phys. Chem. Solids 1997, 58, 1569. doi: 10.1016/S0022-3697(97)00101-7 doi: 10.1016/S0022-3697(97)00101-7
82. [82]
  Yu, X. F.; Giorgi, G.; Ushiyama, H.; Yamashita, K. Chem. Phys. Lett. 2014, 612, 129. doi: 10.1016/j.cplett.2014.08.010 doi: 10.1016/j.cplett.2014.08.010
83. [83]
  Wenzel, S.; Leichtweiss, T.; Krüger, D.; Sann, J.; Janek, J. Solid State Ion. 2015, 278, 98. doi: 10.1016/j.ssi.2015.06.001 doi: 10.1016/j.ssi.2015.06.001
84. [84]
  Wu, E. A.; Kompella, C. S.; Zhu, Z.; Lee, J. Z.; Lee, S. C.; Chu, I. H.; Nguyen, H.; Ong, S. P.; Banerjee, A.; Meng, Y. S. ACS Appl. Mater. Interfaces 2018, 10, 12. doi: 10.1021/acsami.7b19037 doi: 10.1021/acsami.7b19037
85. [85]
  Hartmann, P.; Leichtweiss, T.; Busche, M. R.; Schneider, M.; Reich, M.; Sann, J.; Adelhelm, P.; Janek, J. J. Phys. Chem. C 2013, 117, 21064. doi: 10.1021/jp4051275 doi: 10.1021/jp4051275
86. [86]
  Hu, P.; Zhang, Y.; Chi, X.; Kumar Rao, K.; Hao, F.; Dong, H.; Guo, F.; Ren, Y.; Grabow, L. C.; Yao, Y. ACS Appl. Mater. Interfaces 2019, 11, 9672. doi: 10.1021/acsami.8b19984 doi: 10.1021/acsami.8b19984
87. [87]
  Tian, Y.; Sun, Y.; Hannah, D. C.; Xiao, Y.; Liu, H.; Chapman, K. W.; Bo, S. H.; Ceder, G. Joule 2019, 3, 1. doi: 10.1016/j.joule.2018.12.019 doi: 10.1016/j.joule.2018.12.019
88. [88]
  Kim, J. K.; Lim, Y. J.; Kim, H. J.; Cho, G. B.; Kim, Y. Energy Environ. Sci. 2015, 8, 3589. doi: 10.1016/j.joule.2018.12.019 doi: 10.1016/j.joule.2018.12.019
89. [89]
  Li, H.; Bai, Y.; Wu, F.; Li, Y.; Wu, C. J. Power Sources 2015, 273, 784. doi: 10.1016/j.jpowsour.2014.09.153 doi: 10.1016/j.jpowsour.2014.09.153
90. [90]
  Li, H.; Yu, X.; Bai, Y.; Wu, F.; Wu, C.; Liu, L. Y.; Yang, X. Q. J. Mater. Chem. A 2015, 3, 9578. doi: 10.1039/c5ta00277j doi: 10.1039/c5ta00277j
91. [91]
  Li, H.; Wu, C.; Bai, Y.; Wu, F.; Wang, M. Z. J. Power Sources 2016, 326, 14. doi: 10.1016/j.jpowsour.2016.06.096 doi: 10.1016/j.jpowsour.2016.06.096
92. [92]
  Zhang, Z.; Zhang, Q.; Shi, J.; Chu, Y. S.; Yu, X.; Xu, K.; Ge, M.; Yan, H.; Li, W.; Gu, L.; et al. Adv. Energy Mater. 2017, 7, 1601196. doi: 10.1002/aenm.201601196 doi: 10.1002/aenm.201601196
93. [93]
  Ni, Q.; Bai, Y.; Li, Y.; Ling, L. M.; Li, L.; Chen, G. H.; Wang, Z. H.; Ren, H. X.; Wu, F.; Wu, C. Small 2018, 14, 1702864. doi: 10.1002/smll.201702864 doi: 10.1002/smll.201702864
94. [94]
  Ni'mah, Y. L.; Cheng, M. Y.; Cheng, J. H.; Rick, J.; Hwang, B. J. J. Power Sources. 2015, 278, 375. doi: 10.1016/j.jpowsour.2014.11.047 doi: 10.1016/j.jpowsour.2014.11.047
95. [95]
  Tatsumisago, M.; Hayashi, A. Int. J. Appl. Glass Sci. 2014, 5, 226. doi: 10.1111/ijag.12084 doi: 10.1111/ijag.12084
96. [96]
  Wan, H.; Mwizerwa, J. P.; Qi, X.; Liu, X.; Xu, X.; Li, H.; Hu, Y. S.; Yao, X. Y. ACS Nano 2018, 12, 2809. doi: 10.1021/acsnano.8b00073 doi: 10.1021/acsnano.8b00073
97. [97]
  Tanibata, N.; Deguchi, M.; Hayashi, A.; Tatsumisago, M. Chem. Mat. 2017, 29, 5232. doi: 10.1021/acs.chemmater.7b01116 doi: 10.1021/acs.chemmater.7b01116
98. [98]
  Tanibata, N.; Tsukasaki, H.; Deguchi, M.; Mori, S.; Hayashi, A.; Tatsumisago, M. Solid State Ion. 2017, 311, 6. doi: 10.1016/j.ssi.2017.08.022 doi: 10.1016/j.ssi.2017.08.022
99. [99]
  Yue, J.; Han, F. D.; Fan, X. L.; Zhu, X. Y.; Ma, Z. H.; Yang, J.; Wang, C. S. ACS Nano 2017, 11, 4885. doi: 10.1021/acsnano.7b01445 doi: 10.1021/acsnano.7b01445
100. [100]
  Chi, X. W.; Liang, Y. L.; Hao, F.; Zhang, Y.; Whiteley, J.; Dong, H.; Hu, P.; Lee, S.; Yao, Y. Angew Chem. Int. Ed. 2018, 57, 2630. doi: 10.1002/anie.201712895 doi: 10.1002/anie.201712895
101. [101]
  Sakuda, A.; Hayashi, A.; Tatsumisago, M. Sci. Rep. 2013, 3, 2261. doi: 10.1038/srep02261 doi: 10.1038/srep02261
102. [102]
  Minami, T.; Hayashi, A.; Tatsumisago, M. Solid State Ion. 2006, 177, 2715. doi: 10.1016/j.ssi.2006.07.017 doi: 10.1016/j.ssi.2006.07.017
103. [103]
  Nagao, M.; Hayashi, A.; Tatsumisago, M. Electrochimica Acta 2011, 56, 6055. doi: 10.1016/j.electacta.2011.04.084 doi: 10.1016/j.electacta.2011.04.084
104. [104]
  Noi, K.; Nagata, Y.; Hakari, T.; Suzuki, K.; Yubuchi, S.; Ito, Y.; Sakuda, A.; Hayashi, A.; Tatsumisago, M. ACS Appl. Mater. Interfaces 2018, 10, 19605. doi: 10.1021/acsami.8b02427 doi: 10.1021/acsami.8b02427
105. [105]
  Yue, J.; Zhu, X. Y.; Han, F. D.; Fan, X. L.; Wang, L. N.; Yang, J.; Wang, C. S. ACS Appl. Mater. Interfaces 2018, 10, 39645. doi: 10.1021/acsami.8b12610 doi: 10.1021/acsami.8b12610
106. [106]
  Wu, F.; Fitzhugh, W.; Ye, L. H.; Ning, J. X.; Li, X. Nat. Commun. 2018, 9, 4037. doi: 10.1038/s41467-018-06123-2 doi: 10.1038/s41467-018-06123-2
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