Citation: Zhao Pan, Yang Bingjun, Chen Jiangtao, Lang Junwei, Zhang Tianyun, Yan Xingbin. A Safe, High-Performance, and Long-Cycle Life Zinc-Ion Hybrid Capacitor Based on Three-Dimensional Porous Activated Carbon[J]. Acta Physico-Chimica Sinica, ;2020, 36(2): 190405. doi: 10.3866/PKU.WHXB201904050 shu

A Safe, High-Performance, and Long-Cycle Life Zinc-Ion Hybrid Capacitor Based on Three-Dimensional Porous Activated Carbon

Zhao Pan ^1,2 ,
Yang Bingjun ^1,2,, ,
Chen Jiangtao ¹ ,
Lang Junwei ¹ ,
Zhang Tianyun ^1,3 ,
Yan Xingbin ^1,2,,

1.
Laboratory of Clean Energy Chemistry and Materials, State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
2.
Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100080, P. R. China
3.
School of Mechanical and Electronical Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China

Corresponding author: Yang Bingjun, xbyan@licp.cas.cn Yan Xingbin, yangbj@licp.cas.cn
Received Date: 11 April 2019
Revised Date: 6 May 2019
Accepted Date: 15 May 2019
Available Online: 27 February 2019
Fund Project: the National Natural Science Foundation of China 21573265The project was supported by the National Natural Science Foundation of China (21573265, 21673263, 21805291)the National Natural Science Foundation of China 21805291the National Natural Science Foundation of China 21673263

The rapid development of electronic products has increased the demand for safe, low-cost, and high-performance energy storage devices. Lithium-ion batteries have been commercialized owing to their high energy density. However, the limited lithium resources and their uneven distribution have triggered the search for alternative energy storage systems. In this context, rechargeable aqueous zinc-ion batteries have gained immense attention owing to their low cost and environmental friendliness. Nevertheless, it is highly challenging to develop zinc-ion battery cathode materials with both high capacity and long cycle life. Hence, in this study, we prepared three-dimensional porous activated carbon (3DAC) with high specific surface area by using ethylenediaminetetraacetic acid (EDTA) tetrasodium salt hydrate as the raw material. We developed a zinc-ion hybrid capacitor (ZIHC) in 1 mol∙L⁻¹ ZnSO₄ using 3DAC as the cathode and a zinc foil as the anode. The ZIHC stored charge by the reversible deposition/dissolution of Zn²⁺ on the zinc anode and rapid reversible adsorption/desorption of ions on the 3DAC cathode. Owing to the large specific surface area and highly porous structure of the 3DAC cathode, the assembled ZIHC exhibited excellent electrochemical performance. It worked well over the voltage range of 0.1–1.7 V, providing a high specific capacitance of 213 mAh·g⁻¹ at the current density of 0.5 A·g⁻¹ (the highest value reported till date). The ZIHC showed specific capacities of 182, 160, 139, 130, 127, 122, and 116 mAh·g⁻¹ at the current densities of 1, 2, 4, 6, 8, 10, and 20 A·g⁻¹, respectively. Meanwhile, it exhibited the highest energy density of 164 Wh·kg⁻¹ (at a power density of 390 W·kg⁻¹) and still delivered the highest power density of 9.3 kW·kg⁻¹ with a high energy density of 74 Wh·kg⁻¹. In addition, our ZIHC also exhibited excellent cycling stability. After 20000 cycles at 10 A·g⁻¹, it retained 90% of its initial capacity and exhibited high Coulombic efficiency (≈100%). In order to investigate the causes of capacity decay, we examined the cycled zinc foil by scanning electron microscopy and X-ray diffraction. The results showed that a large number of Zn₄SO₄(OH)₆⋅3H₂O disordered dendrites were formed on the surface of the zinc foil. These dendrites inhibited the reversible deposition/dissolution of zinc ions, resulting in the capacity decay of the ZIHC during the cycling process. This study will be helpful for developing next-generation high-performance energy storage devices.
- Zinc ion hybrid capacitor,
- Three-dimensional porous activated carbon,
- Energy density,
- Power density,
- Long cycle life
1. [1]
  Liu, B.; Sun, Y. L.; Liu, L. Y.; Chen, J. T.; Yang, B. J.; Xu, S.; Yan, X. B. Energy Environ. Sci. 2019, 12, 887. doi: 10.1039/C8EE03417F doi: 10.1039/C8EE03417F
2. [2]
  Armand, M.; Tarascon, J. M. Nature 2008, 451, 652. doi: 10.1038/451652a doi: 10.1038/451652a
3. [3]
  Dunn, B.; Kamath, H.; Tarascon, J. M. Science 2011, 334, 928. doi: 10.1126/science.1212741 doi: 10.1126/science.1212741
4. [4]
  Tang, Y. P.; Yuan, S.; Guo, Y. Z.; Huang, R. A.; Wang, J. H.; Yang, B.; Dai, Y. N. Acta Phys. -Chim. Sin. 2016, 32, 2280. doi: 10.3866/PKU.WHXB201605124
5. [5]
  Liu, L.; Su, L.; Lang, J. W.; Hu, B.; Xu, S.; Yan, X. B. J. Mater. Chem. A 2017, 5, 5523. doi: 10.1039/c7ta00744b doi: 10.1039/c7ta00744b
6. [6]
  Li, Y. Y.; Li, Z. S.; Shen, P. K.Adv. Mater. 2013, 25, 2474. doi: 10.1002/adma.201205332 doi: 10.1002/adma.201205332
7. [7]
  Liu, J.; Zhang, L.; Wu, H. B.; Lin, J.; Shen, Z.; Lou, X. W. Energy Environ. Sci. 2014, 7, 3709. doi: 10.1039/C4EE01475H doi: 10.1039/C4EE01475H
8. [8]
  Wang, P. Y.; Wang, R. T.; Lang, J. W.; Zhang, X.; Chen, Z. T.; Yan, X. B. J. Mater. Chem. A 2016, 4, 9760. doi: 10.1039/c6ta03633c doi: 10.1039/c6ta03633c
9. [9]
  Wang, H.; Zhu, C.; Chao, D.; Yan, Q.; Fan, H. J. Adv. Mater. 2017, 29, 1702093. doi: 10.1002/adma.201702093 doi: 10.1002/adma.201702093
10. [10]
  Jia, Z. Y.; Liu, M. N.; Zhao, X. L.; Wang, X. S.; Pan, Z. H.; Zhang, Y. G. Acta Phys. -Chim. Sin.2017, 33, 2510. doi: 10.3866/PKU.WHXB201705311
11. [11]
  Li, H. X.; Lang, J. W.; Lei, S. L.; Chen, J. T.; Wang, K. J.; Liu, L. Y.; Zhang, T. Y.; Liu, W. S.; Yan, X. B. Adv. Funct. Mater. 2018, 28, 1800757. doi: 10.1002/adfm.201800757 doi: 10.1002/adfm.201800757
12. [12]
  Li, Y. Z.; Wang, H. W.; Wang, L. B.; Mao, Z. F.; Wang, R.; He, B. B.; Gong, Y. S.; Hu, X. L. Small2019, 15, 1804539. doi: 10.1002/smll.201804539 doi: 10.1002/smll.201804539
13. [13]
  Zhang, Z. Y.; Li, M. L.; Gao, Y.; Wei, Z. X.; Zhang, M. N.; Wang, C. Z.; Zeng, Y.; Zou, B.; Chen, G.; Du, F. Adv. Funct. Mater. 2018, 28, 1802684. doi: 10.1002/adfm.201802684 doi: 10.1002/adfm.201802684
14. [14]
  Fan, L.; Lin, K. Y.; Wang, J.; Ma, R. F.; Lu, B. G. Adv. Mater. 2018, 30, 1800804. doi: 10.1002/adma.201800804 doi: 10.1002/adma.201800804
15. [15]
  Sun, G. Q.; Yang, H. S.; Zhang, G. F.; Gao, J.; Jin, X. T.; Zhao, Y.; Jiang, L.; Qu, L. T. Energy Environ. Sci. 2018, 11, 3367. doi: 10.1039/c8ee02567c doi: 10.1039/c8ee02567c
16. [16]
  Wu, N. Z.; Yao, W. J.; Song, X. H.; Zhang, G.; Chen, B. J.; Yang, J. H.; Tang, Y. B. Adv. Energy Mater. 2019, 1803865. doi: 10.1002/aenm.201803865 doi: 10.1002/aenm.201803865
17. [17]
  Yang, B. J.; Chen, J. T.; Lei, S. L.; Guo, R. S.; Yan, X. B. Adv. Energy Mater. 2017, 8, 1702409. doi: 10.1002/aenm.201702409 doi: 10.1002/aenm.201702409
18. [18]
  Chen, J. T.; Yang, B. J.; Hou, H. J.; Li, H. X.; Liu, L.; Zhang, L.; Yan, X. B. Adv. Energy Mater. 2019, 1803894. doi: 10.1016/j.carbon.2017.01.005 doi: 10.1016/j.carbon.2017.01.005
19. [19]
  Chen, J. T.; Yang, B. J.; Li, H. X.; Ma, P. J.; Lang, J. W.; Yan, X. B. J. Mater. Chem. A 2019. doi: 10.1039/c9ta01653h doi: 10.1039/c9ta01653h
20. [20]
  Yamada, Y.; Usui, K.; Sodeyama, K.; Ko, S.; Tateyama, Y.; Yamada, A. Nat. Energy 2016, 1, 16129. doi: 10.1038/nenergy.2016.129 doi: 10.1038/nenergy.2016.129
21. [21]
  Haegyeom, K.; Jihyun, H.; Kyu-Young, P.; Hyungsub, K.; Sung-Wook, K.; Kisuk, K. Chem. Rev.2014, 114, 11788. doi: 10.1021/cr500232y doi: 10.1021/cr500232y
22. [22]
  Chao, D.; Zhu, C. R.; Song, M.; Liang, P.; Zhang, X.; Tiep, N. H.; Zhao, H.; Wang, J.; Wang, R.; Zhang, H.; et al. Adv. Mater. 2018, 30, e1803181. doi: 10.1002/adma.201803181 doi: 10.1002/adma.201803181
23. [23]
  Shi, H. Y.; Ye, Y. J.; Liu, K.; Song, Y.; Sun, X. Angew. Chem. Int. Ed. 2018, 57, 16359. doi: 10.1002/anie.201808886 doi: 10.1002/anie.201808886
24. [24]
  Huang, J.; Wang, Z.; Hou, M.; Dong, X.; Liu, Y.; Wang, Y.; Xia, Y. Nat. Commun. 2018, 9, 2906. doi: 10.1038/s41467-018-04949-4 doi: 10.1038/s41467-018-04949-4
25. [25]
  Yang, Y.; Tang, Y.; Fang, G.; Shan, L.; Guo, J.; Zhang, W.; Wang, C.; Wang, L.; Zhou, J.; Liang, S. Energy Environ. Sci. 2018, 11, 3157. doi: 10.1039/C8EE01651H doi: 10.1039/C8EE01651H
26. [26]
  Wan, F.; Zhang, L.; Dai, X.; Wang, X.; Niu, Z.; Chen, J. Nat. Commun. 2018, 9, 1656. doi: 10.1038/s41467-018-04060-8 doi: 10.1038/s41467-018-04060-8
27. [27]
  Dong, L. B.; Ma, X. P.; Li, Y.; Zhao, L.; Liu, W. B.; Cheng, J. Y.; Xu, C. J.; Li, B. H.; Yang, Q. H.; Kang, F. Y. Energy Storage Mater. 2018, 13, 96. doi: 10.1016/j.ensm.2018.01.003 doi: 10.1016/j.ensm.2018.01.003
28. [28]
  Wang, H.; Wang, M.; Tang, Y. B. Energy Storage Mater. 2018, 13, 1. doi: 10.1016/j.ensm.2017.12.022 doi: 10.1016/j.ensm.2017.12.022
29. [29]
  Chen, J.; Yang, B.; Hou, H.; Li, H.; Liu, L.; Zhang, L.; Yan, X. Adv. Energy Mater. 2019, 1803894. doi: 10.1002/aenm.201803894 doi: 10.1002/aenm.201803894
30. [30]
  Yang, B. J.; Chen, J. T.; Liu, L.; Ma, P. J.; Liu, B.; Lang, J. W.; Tang, Y.; Yan, X. B. Energy Storage Mater. 2019. doi: 10.1016/j.ensm.2019.04.008 doi: 10.1016/j.ensm.2019.04.008
31. [31]
  Sevilla, M.; Mokaya, R. Energy Environ. Sci. 2014, 7, 1250. doi: 10.1039/C3EE43525C. doi: 10.1039/C3EE43525C
32. [32]
  Wang, H. L.; Mitlin, D.; Ding, J.; Li, Z.; Cui, K. J. Mater. Chem. A 2016, 4, 5149. doi: 10.1039/C6TA01392A doi: 10.1039/C6TA01392A
33. [33]
  Li, H. S.; Peng, L. L.; Zhu, Y.; Zhang, X. G.; Yu, G. H. Nano Lett. 2016, 16, 5938. doi: 10.1021/acs.nanolett.6b02932 doi: 10.1021/acs.nanolett.6b02932
34. [34]
  Dong, S.; Li, Z.; Xing, Z.; Wu, X.; Ji, X.; Zhang, X. ACS Appl. Mater. Interfaces 2018, 10, 15542. doi: 10.1021/acsami.7b15314 doi: 10.1021/acsami.7b15314
1. [1]
  Yanhui XUE , Shaofei CHAO , Man XU , Qiong WU , Fufa WU , Sufyan Javed Muhammad . Construction of high energy density hexagonal hole MXene aqueous supercapacitor by vacancy defect control strategy. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1640-1652. doi: 10.11862/CJIC.20240183
2. [2]
  Ning DING , Siyu WANG , Shihua YU , Pengcheng XU , Dandan HAN , Dexin SHI , Chao ZHANG . Crystalline and amorphous metal sulfide composite electrode materials with long cycle life: Preparation and performance of hybrid capacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1784-1794. doi: 10.11862/CJIC.20240146
3. [3]
  Lu XU , Chengyu ZHANG , Wenjuan JI , Haiying YANG , Yunlong FU . Zinc metal-organic framework with high-density free carboxyl oxygen functionalized pore walls for targeted electrochemical sensing of paracetamol. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 907-918. doi: 10.11862/CJIC.20230431
4. [4]
  Ruiqing LIU , Wenxiu LIU , Kun XIE , Yiran LIU , Hui CHENG , Xiaoyu WANG , Chenxu TIAN , Xiujing LIN , Xiaomiao FENG . Three-dimensional porous titanium nitride as a highly efficient sulfur host. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 867-876. doi: 10.11862/CJIC.20230441
5. [5]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
6. [6]
  Jin CHANG . Supercapacitor performance and first-principles calculation study of Co-doping Ni(OH)₂. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1697-1707. doi: 10.11862/CJIC.20240108
7. [7]
  Jianjun LI , Mingjie REN , Lili ZHANG , Lingling ZENG , Huiling WANG , Xiangwu MENG . UV-assisted degradation of tetracycline hydrochloride by MnFe₂O₄@activated carbon activated persulfate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1869-1880. doi: 10.11862/CJIC.20240187
8. [8]
  Zhaomei LIU , Wenshi ZHONG , Jiaxin LI , Gengshen HU . Preparation of nitrogen-doped porous carbons with ultra-high surface areas for high-performance supercapacitors. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 677-685. doi: 10.11862/CJIC.20230404
9. [9]
  Xiaochen Zhang , Fei Yu , Jie Ma . 多角度数理模拟在电容去离子中的前沿应用. Acta Physico-Chimica Sinica, 2024, 40(11): 2311026-. doi: 10.3866/PKU.WHXB202311026
10. [10]
  Shanying Chen , Kangning Huo , Ke Qi , Jingyi Li , Shuxin Li , Yunchao Li . A Novel Colloid Electrophoresis Experiment with the Characteristics of Resource Recycling and Inquiry-Driven Experimental Design. University Chemistry, 2024, 39(5): 274-286. doi: 10.3866/PKU.DXHX202311067
11. [11]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-. doi: 10.3866/PKU.WHXB202310034
12. [12]
  Yujia Luo , Yunpeng Qi , Huiping Xing , Yuhu Li . The Use of Viscosity Method for Predicting the Life Expectancy of Xuan Paper-based Heritage Objects. University Chemistry, 2024, 39(8): 290-294. doi: 10.3866/PKU.DXHX202401037
13. [13]
  Xiaoning TANG , Shu XIA , Jie LEI , Xingfu YANG , Qiuyang LUO , Junnan LIU , An XUE . Fluorine-doped MnO₂ with oxygen vacancy for stabilizing Zn-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1671-1678. doi: 10.11862/CJIC.20240149
14. [14]
  Peiran ZHAO , Yuqian LIU , Cheng HE , Chunying DUAN . A functionalized Eu³⁺ metal-organic framework for selective fluorescent detection of pyrene. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 713-724. doi: 10.11862/CJIC.20230355
15. [15]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
16. [16]
  Zhening Lou , Quanxing Mao , Xiaogeng Feng , Lei Zhang , Xu Xu , Yuyang Zhang , Xueyan Liu , Hongling Kang , Dongyang Feng , Yongku Li . Practice of Implementing Blended Teaching in Shared Analytical Chemistry Course. University Chemistry, 2024, 39(2): 263-269. doi: 10.3866/PKU.DXHX202308089
17. [17]
  Xiaosong PU , Hangkai WU , Taohong LI , Huijuan LI , Shouqing LIU , Yuanbo HUANG , Xuemei LI . Adsorption performance and removal mechanism of Cd(Ⅱ) in water by magnesium modified carbon foam. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1537-1548. doi: 10.11862/CJIC.20240030
18. [18]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
19. [19]
  Huan Zhang , Linyu Pu , Wei Wang , Yatang Dai , Xu Huang . Curriculum Development and Blended Teaching Practice in the Graduate Course on Elemental Inorganic Chemistry. University Chemistry, 2024, 39(6): 166-173. doi: 10.3866/PKU.DXHX202402010
20. [20]
  Zhiguang Xu , Xuan Xu , Qiong Luo , Ganquan Wang , Bin Peng . Reform and Practice of Online and Offline Blended Teaching in Structural Chemistry Course. University Chemistry, 2024, 39(6): 195-200. doi: 10.3866/PKU.DXHX202310112

Get Citation

PDF

XML

Metrics

PDF Downloads(10)
Abstract views(870)
HTML views(53)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142