Citation: Li Chao, Shen Ming, Hu Bingwen. Solid-State NMR and EPR Methods for Metal Ion Battery Research[J]. Acta Physico-Chimica Sinica, ;2020, 36(4): 190201. doi: 10.3866/PKU.WHXB201902019 shu

Solid-State NMR and EPR Methods for Metal Ion Battery Research

Li Chao ^† ,
Shen Ming ^† ,
Hu Bingwen ^,

Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Materials Science, East China Normal University, Shanghai 200062, P. R. China

Corresponding author: Hu Bingwen, bwhu@phy.ecnu.edu.cn
Received Date: 22 February 2019
Revised Date: 27 March 2019
Accepted Date: 1 April 2019
Available Online: 11 April 2019
Fund Project: the National Natural Science Foundation of China 21522303the National Natural Science Foundation of China 21703068the National Natural Science Foundation of China 21872055The project was supported by the National Natural Science Foundation of China (21872055, 21703068, 21522303)

The rapid development of batteries, especially lithium-ion batteries, has dramatically changed our daily lives. From portable electronics to electric vehicles and smart grids, batteries are extensively used in many fields and are difficult to be replaced in terms of their excellent energy and power densities. The advancement of battery technology requires the thorough understanding of electrochemical reaction mechanisms, which strongly depends on the collaboration of researchers from different fields. Magnetic resonance spectroscopy includes the important techniques of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR), and the former is suitable for studying light elements commonly found in batteries including Li, Na, P and O, while the latter is suitable for studying heavier transition metals such as Co, Mn, Fe and V. In addition, NMR and EPR are capable of quantitatively analysis in a nondestructive manner regardless of sample crystallinity. Hence, NMR and EPR spectroscopies have allowed for significant research progress and have become increasingly important for battery research over the past three decades. Herein, we will provide our perspective of magnetic resonance methods and first summarize the main interactions and the Hamiltonian forms of solid-state NMR and EPR (dipole-dipole interaction, electric quadrupole interaction, chemical shift, and hyperfine interaction). Subsequently, we summarize the important and frequently-used methods of solid-state NMR and EPR spectroscopies and introduce their representative applications in metal ion battery research (mainly lithium- and sodium-ion batteries). Specifically, we introduce the basic principles and representative applications of (ⅰ) MQMAS (multiple-quantum magic angle spinning), (ⅱ) pjMATPASS (MAT = magic-angle turning, PASS = phase-adjusted sideband separation, and pj = projection), (ⅲ) WURST-CPMG (WURST = wide band uniform rate smooth truncation, CPMG = Carr-Purcell Meiboom-Gil), (ⅳ) 2D homonuclear correlation and exchange (2D EXSY), (ⅴ) 2D homonuclear correlation based on dipole coupling (i.e. RFDR), (ⅵ) perpendicular mode EPR, (ⅶ) parallel mode EPR, (ⅷ) in situ NMR, and (ⅸ) in situ EPR. In addition, we briefly introduce representative applications of 2D heteronuclear correlation (i.e. CP-HETCOR), pulsed field gradient NMR, spin-lattice relaxation (SLR), spin alignment echo (SAE), DFT calculations, and dynamic nuclear polarization (DNP). Previous reviews regarding the application of magnetic resonance technology in battery research are almost all reported in terms of the classification of battery materials. In other words, they are written from the perspective of applications in cathode, anode, and electrolyte research. Herein, we summarize from the perspective of solid-state NMR and EPR methods, which may be beneficial for the readers to fully understand the value of these important technologies. We believe this review can serve as a guide to solve challenges related to using solid-state NMR and EPR spectroscopies in battery research.
- Solid-state NMR,
- Electron paramagnetic resonance,
- Lithium-ion battery,
- Sodium-ion battery,
- Charge-discharge mechanism,
- Structure-function ralationship,
- Local structure
1. [1]
  Li, M.; Lu, J.; Chen, Z.; Amine, K. Adv. Mater. 2018, 30, 1800561. doi: 10.1002/adma.201800561 doi: 10.1002/adma.201800561
2. [2]
  Larcher, D.; Tarascon, J. M. Nat. Chem. 2015, 7, 19. doi: 10.1038/nchem.2085 doi: 10.1038/nchem.2085
3. [3]
  Goodenough, J. B.; Park, K. S. J. Am. Chem. Soc. 2013, 135, 1167. doi: 10.1021/ja3091438 doi: 10.1021/ja3091438
4. [4]
  Yang, Z.; Zhang, W.; Shen, Y.; Yuan, L. X.; Huang, Y. H. Acta Phys. -Chim. Sin. 2016, 32, 1062. doi: 10.3866/PKU.WHXB201603231
5. [5]
  Goodenough, J. B. Energy Storage Mater. 2015, 1, 158. doi: 10.1016/j.ensm.2015.07.001 doi: 10.1016/j.ensm.2015.07.001
6. [6]
  Tarascon, J. M. Nat. Chem. 2010, 2, 510. doi: 10.1038/nchem.680 doi: 10.1038/nchem.680
7. [7]
  Choi, J. W.; Aurbach, D. Nat. Rev. Mater. 2016, 1, 16013. doi: 10.1038/natrevmats.2016.13 doi: 10.1038/natrevmats.2016.13
8. [8]
  Slater, M. D.; Kim, D.; Lee, E.; Johnson, C. S. Adv. Funct. Mater. 2013, 23, 947. doi: 10.1002/adfm.201200691 doi: 10.1002/adfm.201200691
9. [9]
  Fang, C.; Huang, Y.; Zhang, W.; Han, J.; Deng, Z.; Cao, Y.; Yang, H. Adv. Energy Mater. 2016, 6, 1501727. doi: 10.1002/aenm.201501727 doi: 10.1002/aenm.201501727
10. [10]
  Wang, P. F.; You, Y.; Yin, Y. X.; Guo, Y. G. Adv. Energy Mater. 2018, 8, 1701912. doi: 10.1002/aenm.201701912 doi: 10.1002/aenm.201701912
11. [11]
  Fang, Y. J.; Chen, Z. X.; Ai, X. P.; Yang, H. X.; Cao, Y. L. Acta Phys. -Chim. Sin. 2017, 33, 211. doi: 10.3866/PKU.WHXB201610111
12. [12]
  Wu, X.; Leonard, D. P.; Ji, X. Chem. Mater. 2017, 29, 5031. doi: 10.1021/acs.chemmater.7b01764 doi: 10.1021/acs.chemmater.7b01764
13. [13]
  Li, C.; Hu, X.; Hu, B. Electrochim. Acta 2017, 253, 439. doi: 10.1016/j.electacta.2017.09.090 doi: 10.1016/j.electacta.2017.09.090
14. [14]
  Zhang, Z.; Dong, S.; Cui, Z.; Du, A.; Li, G.; Cui, G. Small Methods 2018, 2, 1800020. doi: 10.1002/smtd.201800020 doi: 10.1002/smtd.201800020
15. [15]
  Wang, M.; Jiang, C.; Zhang, S.; Song, X.; Tang, Y.; Cheng, H. M. Nat. Chem. 2018, 10, 667. doi: 10.1038/s41557-018-0045-4 doi: 10.1038/s41557-018-0045-4
16. [16]
  Lin, M. C.; Gong, M.; Lu, B.; Wu, W.; Wang, D. Y.; Guan. M.; Angell, M.; Chen, C.; Yang. J.; Hwang, B. J.; et al. Nature 2015, 520, 324. doi: 10.1038/nature14340 doi: 10.1038/nature14340
17. [17]
  Kim, D. J.; Yoo, D. J.; Otley, M. T.; Prokofjevs, A.; Pezzato, C.; Owczarek, M.; Lee, S. J.; Choi, J. W.; Stoddart, J. F. Nat. Energy 2018, 4, 51. doi: 10.1038/s41560-018-0291-0 doi: 10.1038/s41560-018-0291-0
18. [18]
  Grey, C. P.; Tarascon, J. M. Nat. Mater. 2017, 16, 45. doi: 10.1038/nmat4777 doi: 10.1038/nmat4777
19. [19]
  Lu, J.; Wu, T.; Amine, K. Nat. Energy 2017, 2, 17011. doi: 10.1038/nenergy.2017.11 doi: 10.1038/nenergy.2017.11
20. [20]
  Pecher, O.; Carretero-González, J.; Griffith, K. J.; Grey, C. P. Chem. Mater. 2017, 29, 213. doi: 10.1021/acs.chemmater.6b03183 doi: 10.1021/acs.chemmater.6b03183
21. [21]
  Grey, C. P.; Dupre, N. Chem. Rev. 2004, 104, 4493. doi: 10.1021/cr020734p doi: 10.1021/cr020734p
22. [22]
  Zhong, G.; Liu, Z.; Wang, D.; Li, Q.; Fu, R.; Yang. Y. J. Electrochem. 2016, 22, 231. doi: 10.13208/j.electrochem.151246
23. [23]
  Duer, M. J. Solid-State Nmr Spectroscopy: Principles and Applications; Blackwell Sci., London, 2002.
24. [24]
  Pigliapochi, R.; Pell, A. J.; Seymour, I. D.; Grey, C. P.; Ceresoli, D.; Kaupp, M. Phys. Rev. B 2017, 95, 054412. doi: 10.1103/PhysRevB.95.054412 doi: 10.1103/PhysRevB.95.054412
25. [25]
  Frydman, L.; Harwood, J. S. J. Am. Chem. Soc. 1995, 117, 5367. doi: 10.1021/ja00124a023 doi: 10.1021/ja00124a023
26. [26]
  Hrobárik, P.; Reviakine, R.; Arbuznikov, A. V.; Malkina, O. L.; Malkin, V. G.; Köhler, F. H.; Kaupp, M. J. Chem. Phys. 2007, 126, 024107. doi: 10.1063/1.2423003 doi: 10.1063/1.2423003
27. [27]
  Amoureux, J. P.; Fernandez, C.; Steuernagel, S. J. Magn. Reson. A 1996, 123, 116. doi: 10.1006/jmra.1996.0221 doi: 10.1006/jmra.1996.0221
28. [28]
  Gan, Z.; Kwak, H. T. J. Magn. Reson. 2004, 168, 346. doi: 10.1016/j.jmr.2004.03.021 doi: 10.1016/j.jmr.2004.03.021
29. [29]
  Gan, Z. J. Am. Chem. Soc. 2000, 122, 3242. doi: 10.1021/ja9939791 doi: 10.1021/ja9939791
30. [30]
  Morita, R.; Gotoh, K.; Fukunishi, M.; Kubota, K.; Komaba, S.; Nishimura, N.; Yumura, T.; Deguchi, K; Ohki, S.; Shimizu, T.; et al. J. Mater. Chem. A 2016, 4, 13183. doi: 10.1039/C6TA04273B doi: 10.1039/C6TA04273B
31. [31]
  Li, C.; Shen, M.; Hu, B.; Lou, X.; Zhang, X.; Tong, W.; Hu, B. J. Mater. Chem. A 2018, 6, 8340. doi: 10.1039/C8TA00568K doi: 10.1039/C8TA00568K
32. [32]
  Li, C.; Shen, M.; Lou, X.; Hu, B. J. Phys. Chem. C 2018, 122, 27224. doi: 10.1021/acs.jpcc.8b09151 doi: 10.1021/acs.jpcc.8b09151
33. [33]
  Reeve, Z. E. M.; Franko, C. J.; Harris, K. J.; Yadegari, H.; Sun, X.; Goward, G. R. J. Am. Chem. Soc. 2017, 139, 595. doi: 10.1021/jacs.6b11333 doi: 10.1021/jacs.6b11333
34. [34]
  Hung, I.; Zhou, L.; Pourpoint, F.; Grey, C. P.; Gan, Z. J. Am. Chem. Soc. 2012, 134, 1898. doi: 10.1021/ja209600m doi: 10.1021/ja209600m
35. [35]
  Clement, R. J.; Pell, A. J.; Middlemiss, D. S.; Strobridge, F. C.; Miller, J. K.; Whittingham, M. S.; Emsley, L.; Grey, C. P.; Pintacuda, G. J. Am. Chem. Soc. 2012, 134, 17178. doi: 10.1021/ja306876u doi: 10.1021/ja306876u
36. [36]
  Li, X.; Tang, M.; Feng, X.; Hung, I.; Rose, A.; Chien, P. H.; Gan, Z.; Hu, Y. Y. Chem. Mater. 2017, 29, 8282. doi: 10.1021/acs.chemmater.7b02589 doi: 10.1021/acs.chemmater.7b02589
37. [37]
  Xu, J.; Lee, D. H.; Clément, R. J.; Yu, X.; Leskes, M.; Pell, A. J.; Pintacuda, G.; Yang, X. Q.; Grey, C. P.; Meng, Y. S. Chem. Mater. 2014, 26, 1260. doi: 10.1021/cm403855t doi: 10.1021/cm403855t
38. [38]
  Clément, R. J.; Xu, J.; Middlemiss, D. S.; Alvarado, J.; Ma, C.; Meng, Y. S.; Grey, C. P. J. Mater. Chem. A 2017, 5, 4129. doi: 10.1039/c6ta09601h doi: 10.1039/c6ta09601h
39. [39]
  Hung, I.; Gan, Z. J. Magn. Reson. 2010, 204, 150. doi: 10.1016/j.jmr.2010.02.004 doi: 10.1016/j.jmr.2010.02.004
40. [40]
  Gan, Z. J. Am. Chem. Soc. 1992, 114, 8307. doi: 10.1021/ja00047a062 doi: 10.1021/ja00047a062
41. [41]
  Antzutkin, O. N.; Shekar, S. C.; Levitt, M. H. J. Magn. Reson., Series A 1995, 115, 7. doi: 10.1006/jmra.1995.1142 doi: 10.1006/jmra.1995.1142
42. [42]
  Lee, J.; Kitchaev, D. A.; Kwon, D. H.; Lee, C. W.; Papp, J. K.; Liu, Y. S.; Lun, Z.; Clément, R.; Shi, T.; McCloskey, B. D.; et al. Nature 2018, 556, 185. doi: 10.1038/s41586-018-0015-4 doi: 10.1038/s41586-018-0015-4
43. [43]
  Lee, J.; Urban, A.; Li, X.; Su, D.; Hautier, G.; Ceder, G. Science 2014, 343, 519. doi: 10.1126/science.1246432 doi: 10.1126/science.1246432
44. [44]
  Xu, S.; Wang, G.; Biswal, B. P.; Addicoat, M.; Paasch, S.; Sheng, W.; Zhuang, X.; Brunner, E.; Heine, T.; Berger, R.; et al. Angew. Chem. Int. Ed. 2019, 58, 849. doi: 10.1002/anie.201812685 doi: 10.1002/anie.201812685
45. [45]
  O'Dell, L. A.; Schurko, R. W. Chem. Phys. Lett. 2008, 464, 97. doi: 10.1016/j.cplett.2008.08.095 doi: 10.1016/j.cplett.2008.08.095
46. [46]
  MacGregor, A. W.; O'Dell, L. A.; Schurko, R. W. J. Magn. Reson. 2011, 208, 103. doi: 10.1016/j.jmr.2010.10.011 doi: 10.1016/j.jmr.2010.10.011
47. [47]
  Hung, I.; Gan, Z. J. Magn. Reson. 2010, 204, 256. doi: 10.1016/j.jmr.2010.03.001 doi: 10.1016/j.jmr.2010.03.001
48. [48]
  Harris, K. J.; Reeve, Z. E. M.; Wang, D.; Li, X.; Sun, X.; Goward, G. R. Chem. Mater. 2015, 27, 3299. doi: 10.1021/acs.chemmater.5b00323 doi: 10.1021/acs.chemmater.5b00323
49. [49]
  Peng, B.; Shen, M.; Amoureux, J. P.; Hu, B. Solid State Nucl. Magn. Reson. 2016, 78, 1. doi: 10.1016/j.ssnmr.2016.05.002 doi: 10.1016/j.ssnmr.2016.05.002
50. [50]
  Takegoshi, K.; Nakamura, S.; Terao, T. J. Chem. Phys. 2003, 118, 2325. doi: 10.1063/1.1534105 doi: 10.1063/1.1534105
51. [51]
  Takegoshi, K.; Nakamura, S.; Terao, T. Chem. Phys. Lett. 2001, 344, 631. doi: 10.1016/S0009-2614(01)00791-6 doi: 10.1016/S0009-2614(01)00791-6
52. [52]
  Hu, B.; Lafon, O.; Trébosc, J.; Chen, Q.; Amoureux, J. P. J. Magn. Reson. 2011, 212, 320. doi: 10.1016/j.jmr.2011.07.011 doi: 10.1016/j.jmr.2011.07.011
53. [53]
  Hu, B.; Trébosc, J.; Lafon, O.; Chen, Q.; Masuda, Y.; Takegoshi, K.; Amoureux, J. P. ChemPhysChem 2012, 13, 3585. doi: 10.1002/cphc.201200548 doi: 10.1002/cphc.201200548
54. [54]
  Cahill, L. S.; Chapman, R. P.; Britten, J. F.; Goward, G. R. J. Phys. Chem. B 2006, 110, 7171-7177. doi: 10.1021/jp057015+ doi: 10.1021/jp057015+
55. [55]
  Langer, J.; Smiley, D. L.; Bain, A. D.; Goward, G. R.; Wilkening, M. J. Phys. Chem. C 2016, 120, 3130. doi: 10.1021/acs.jpcc.5b09894 doi: 10.1021/acs.jpcc.5b09894
56. [56]
  Bain, A. D. Prog. Nucl. Magn. Reson. Spectrosc. 2003, 43, 63. doi: 10.1016/j.pnmrs.2003.08.001 doi: 10.1016/j.pnmrs.2003.08.001
57. [57]
  Davis, L. J. M.; He, X. J.; Bain, A. D.; Goward, G. R. Solid State Nuclear Magnetic Resonance 2012, 42, 26. doi: 10.1016/j.ssnmr.2012.01.002 doi: 10.1016/j.ssnmr.2012.01.002
58. [58]
  Davis, L. J. M.; Heinmaa, I.; Goward, G. R. Chem. Mater. 2010, 22, 769. doi: 10.1021/cm901402u doi: 10.1021/cm901402u
59. [59]
  Smiley, D. L.; Davis, L. J. M.; Goward, G. R. J. Phys. Chem. C 2013, 117, 24181. doi: 10.1021/jp407510h doi: 10.1021/jp407510h
60. [60]
  Hu, Y. Y.; Liu, Z.; Nam, K. W.; Borkiewicz O. J.; Cheng, J.; Hua, X.; Dunstan, M. T.; Yu, , X.; Wiaderek, K. M.; Du, L. S.; et al. Nat. Mater. 2013, 12, 1130. doi: 10.1038/nmat3784 doi: 10.1038/nmat3784
61. [61]
  Kuhn, A.; Dupke, S.; Kunze, M.; Puravankara, S.; Langer, T.; Pöttgen, R.; Winter, M.; Wiemhöfer, H. D.; Eckert, H.; Heitjans, P. J. Phys. Chem. C 2014, 118, 28350. doi: 10.1021/jp505386u doi: 10.1021/jp505386u
62. [62]
  Smiley, D. L.; Goward, G. R. Chem. Mater. 2016, 28, 7645. doi: 10.1021/acs.chemmater.6b02539 doi: 10.1021/acs.chemmater.6b02539
63. [63]
  Zheng, J.; Tang, M.; Hu, Y. Y. Angew. Chem. Int. Ed. 2016, 55, 12538. doi: 10.1002/anie.201607539 doi: 10.1002/anie.201607539
64. [64]
  van Wullen, L.; Echelmeyer, T.; Meyer, H. W.; Wilmer, D. Phys. Chem. Chem. Phys. 2007, 9, 3298. doi: 10.1039/b703179c doi: 10.1039/b703179c
65. [65]
  Wang, D.; Zhong, G.; Pang, W. K.; Guo, Z.; Li, Y.; McDonald, M. J.; Fu, R.; Mi, J. X.; Yang, Y. Chem. Mater. 2015, 27, 6650. doi: 10.1021/acs.chemmater.5b02429 doi: 10.1021/acs.chemmater.5b02429
66. [66]
  Liu, Q.; Li, C.; Wei, L.; Shen, M.; Yao, Y.; Hu, B.; Chen, Q. Polymer 2014, 55, 5454. doi: 10.1016/j.polymer.2014.08.055 doi: 10.1016/j.polymer.2014.08.055
67. [67]
  Cadars, S.; Sein, J.; Duma, L.; Lesage, A.; Pham, T. N.; Baltisberger, J. H.; Brown, S. P.; Emsley, L. J. Magn. Reson. 2007, 188, 24. doi: 10.1016/j.jmr.2007.05.016 doi: 10.1016/j.jmr.2007.05.016
68. [68]
  Fayon, F.; Le Saout, G.; Emsley, L.; Massiot, D. Chem. Commun. 2002, 1702. doi: 10.1039/B205037B doi: 10.1039/B205037B
69. [69]
  Feike, M.; Demco, D. E.; Graf, R.; Gottwald, J.; Hafner, S.; Spiess, H. W. J. Magn. Reson., Series A 1996, 122, 214. doi: 10.1006/jmra.1996.0197 doi: 10.1006/jmra.1996.0197
70. [70]
  Bennett, A. E.; Griffin, R. G.; Ok, J. H.; Vega, S. J. Chem. Phys. 1992, 96, 8624. doi: 10.1063/1.462267 doi: 10.1063/1.462267
71. [71]
  Shen, M.; Hu, B.; Lafon, O.; Trébosc, J.; Chen, Q.; Amoureux, J. P. J. Magn. Reson. 2012, 223, 107. doi: 10.1016/j.jmr.2012.07.013 doi: 10.1016/j.jmr.2012.07.013
72. [72]
  Nishiyama, Y.; Zhang, R.; Ramamoorthy, A. J. Magn. Reson. 2014, 243, 25. doi: 10.1016/j.jmr.2014.03.004 doi: 10.1016/j.jmr.2014.03.004
73. [73]
  Wang, Q.; Hu, B.; Lafon, O.; Trébosc, J.; Deng, F.; Amoureux, J. P. J. Magn. Reson. 2009, 200, 251. doi: 10.1016/j.jmr.2009.07.009 doi: 10.1016/j.jmr.2009.07.009
74. [74]
  Hu, B.; Wang, Q.; Lafon, O.; Trébosc, J.; Deng, F.; Amoureux, J. P. J. Magn. Reson. 2009, 198, 41. doi: 10.1016/j.jmr.2009.01.002 doi: 10.1016/j.jmr.2009.01.002
75. [75]
  Wang, Q.; Hu, B.; Fayon, F.; Trébosc, J.; Legein, C.; Lafon, O.; Deng, F.; Amoureux, J. P. Phys. Chem. Chem. Phys. 2009, 11, 10391. doi: 10.1039/B914468D doi: 10.1039/B914468D
76. [76]
  Messinger, R. J.; Ménétrier, M.; Salager, E.; Boulineau, A.; Duttine, M.; Carlier, D.; Mba, J. M. A.; Croguennec, L.; Masquelier, C.; Massiot, D.; et al. Chem. Mater. 2015, 27, 5212. doi: 10.1021/acs.chemmater.5b01234 doi: 10.1021/acs.chemmater.5b01234
77. [77]
  Michan, A. L.; Divitini, G.; Pell, A. J.; Leskes, M.; Ducati, C.; Grey, C. P. J. Am. Chem. Soc. 2016, 138, 7918. doi: 10.1021/jacs.6b02882 doi: 10.1021/jacs.6b02882
78. [78]
  Michan, A. L.; Leskes, M.; Grey, C. P. Chem. Mater. 2016, 28, 385. doi: 10.1021/acs.chemmater.5b04408 doi: 10.1021/acs.chemmater.5b04408
79. [79]
  Neuberger, S.; Culver, S. P.; Eckert, H.; Zeier, W. G.; Auf der Gunne, J. S. Dalton Trans. 2018, 47, 11691. doi: 10.1039/c8dt02619j doi: 10.1039/c8dt02619j
80. [80]
  Pecquenard, B.; Gourier, D.; Baffier, N. Solid State Ionics 1995, 78, 287. doi: 10.1016/0167-2738(95)00099-R doi: 10.1016/0167-2738(95)00099-R
81. [81]
  Massarotti, V.; Capsoni, D.; Bini, M.; Azzoni, C. B.; Paleari, A. J. Solid State Chem. 1997, 128, 80. doi: 10.1006/jssc.1996.7158 doi: 10.1006/jssc.1996.7158
82. [82]
  Stoyanova, R.; Gorova, M.; Zhecheva, E. J. Phys. Chem. Solids 2000, 61, 609. doi: 10.1016/S0022-3697(99)00244-9 doi: 10.1016/S0022-3697(99)00244-9
83. [83]
  Sathiya, M.; Rousse. G.; Ramesha, K.; Laisa, C. P.; Vezin, H.; Sougrati, M. T.; Doublet, M. L.; Foix, D.; Gonbeau, D.; Walker, W.; et al. Nat. Mater. 2013, 12, 827. doi: 10.1038/nmat3699 doi: 10.1038/nmat3699
84. [84]
  Liao, Y.; Li, C.; Lou, X.; Hu, X.; Ning, Y.; Yuan, F.; Chen, B.; Shen, M.; Hu, B. Electrochimica Acta 2018, 271, 608. doi: 10.1016/j.electacta.2018.03.100 doi: 10.1016/j.electacta.2018.03.100
85. [85]
  Li, C.; Lou, X.; Shen, M.; Hu, X.; Yan, W.; Zou, Y.; Tong, W.; Hu, B. Energy Storage Materials 2017, 7, 195. doi: 10.1016/j.ensm.2017.02.002 doi: 10.1016/j.ensm.2017.02.002
86. [86]
  Li, C.; Lou, X.; Yang, Q.; Zou, Y.; Hu, B. Chem. Eng. J. 2017, 326, 10008. doi: 10.1016/j.cej.2017.06.048 doi: 10.1016/j.cej.2017.06.048
87. [87]
  Ning, Y.; Lou, X.; Li, C.; Hu, X.; Hu, B. Chem. -Euro. J. 2017, 23, 15984. doi: 10.1002/chem.201703077 doi: 10.1002/chem.201703077
88. [88]
  Hendrich, M. P.; Debrunner, P. G. Biophys. J. 1989, 56, 489. doi: 10.1016/S0006-3495(89)82696-7 doi: 10.1016/S0006-3495(89)82696-7
89. [89]
  Petasis, D. T.; Hendrich, M. P. Methods in Enzymology 2015, 563, 171. doi: 10.1016/bs.mie.2015.06.025 doi: 10.1016/bs.mie.2015.06.025
90. [90]
  Chevallier, F.; Letellier, M.; Morcrette, M.; Tarascon, J. M.; Frackowiak, E.; Rouzaud, J. N.; Bexguin, F. Electrochem. Solid-State Lett. 2003, 6, A225. doi: 10.1149/1.1612011 doi: 10.1149/1.1612011
91. [91]
  Poli, F.; Wong, A.; Kshetrimayum, J. S.; Monconduit, L.; Letellier, M. Chem. Mater. 2016, 28, 1787. doi: 10.1021/acs.chemmater.5b04802 doi: 10.1021/acs.chemmater.5b04802
92. [92]
  Shimoda, K.; Murakami, M.; Komatsu, H.; Arai, H.; Uchimoto, Y.; Ogumi, Z. J. Phys. Chem. C 2015, 119, 13472. doi: 10.1021/acs.jpcc.5b03273 doi: 10.1021/acs.jpcc.5b03273
93. [93]
  Jung, H.; Allan, P. K.; Hu, Y. Y.; Borkiewicz, O. J.; Wang, X. L.; Han, W. Q.; Du, L. S.; Pickard, C. J.; Chupas, P. J.; Chapman, K. W.; et al. Chem. Mater. 2015, 27, 1031. doi: 10.1021/cm504312x doi: 10.1021/cm504312x
94. [94]
  Bayley, P. M.; Trease, N. M.; Grey, C. P. J. Am. Chem. Soc. 2016, 138, 1955. doi: 10.1021/jacs.5b12423 doi: 10.1021/jacs.5b12423
95. [95]
  Feng, X.; Tang, M.; O'Neill, S.; Hu, Y. Y. J. Mater. Chem. A 2018, 6, 22240. doi: 10.1039/c8ta05433a doi: 10.1039/c8ta05433a
96. [96]
  Letellier, M.; Chevallier, F.; Béguin, F. J. Phys. Chem. Solids 2006, 67, 1228. doi: 10.1016/j.jpcs.2006.01.088 doi: 10.1016/j.jpcs.2006.01.088
97. [97]
  Liu, Z.; Hu, Y. Y.; Dunstan, M. T.; Huo, H.; Hao, X.; Zou, H.; Zhong, G.; Yang, Y.; Grey, C. P. Chem. Mater. 2014, 26, 2513. doi: 10.1021/cm403728w doi: 10.1021/cm403728w
98. [98]
  Salager, E.; Kanian, V. S.; Sathiya, M.; Tang, M.; Leiche, J. B.; Melin, P.; Wang, Z.; Vezin, H.; Bessada, C.; Deschamps, M.; et al. Chem. Mater. 2014, 26, 7009. doi: 10.1021/cm503280s doi: 10.1021/cm503280s
99. [99]
  Shimoda, K.; Murakami, M.; Takamatsu, D.; Arai, H.; Uchimoto, Y.; Ogumi, Z. Electrochim. Acta 2013, 108, 343. doi: 10.1016/j.electacta.2013.06.120 doi: 10.1016/j.electacta.2013.06.120
100. [100]
  Stratford, J. M.; Allan, P. K.; Pecher, O.; Chater, P. A.; Grey, C. P. Chem Commun 2016, 52, 12430. doi: 10.1039/c6cc06990h doi: 10.1039/c6cc06990h
101. [101]
  Key, B.; Bhattacharyya, R.; Morcrette, M.; Seznéc, V.; Tarascon, J. M.; Grey, C. P. J. Am. Chem. Soc. 2009, 131, 9239. doi: 10.1021/ja8086278 doi: 10.1021/ja8086278
102. [102]
  Zhou, L.; Leskes, M.; Liu, T.; Grey, C. P. Angew. Chem. Int. Ed. 2015, 54, 14782. doi: 10.1002/anie.201507632 doi: 10.1002/anie.201507632
103. [103]
  Poli, F.; Kshetrimayum, J. S.; Monconduit, L.; Letellier, M. Electrochem. Commun. 2011, 13, 1293. doi: 10.1016/j.elecom.2011.07.019 doi: 10.1016/j.elecom.2011.07.019
104. [104]
  Sathiya, M.; Leriche, J. B.; Salager, E.; Gourier, D.; Tarascon, J. M.; Vezin, H. Nat. Commun. 2015, 6, 6276. doi: 10.1038/ncomms7276 doi: 10.1038/ncomms7276
105. [105]
  Tang, M.; Dalzini, A.; Li, X.; Feng, X.; Chien, P. H.; Song, L.; Hu, Y. Y. J. Phys. Chem. Lett. 2017, 8, 4009. doi: 10.1021/acs.jpclett.7b01425 doi: 10.1021/acs.jpclett.7b01425
106. [106]
  Wandt, J.; Marino, C.; Gasteiger, H. A.; Jakes, P.; Eichel, R. A.; Granwehr, J. Energy Environ. Sci. 2015, 8, 1358. doi: 10.1039/c4ee02730b doi: 10.1039/c4ee02730b
107. [107]
  Wandt, J.; Jakes, P.; Granwehr, J.; Eichel, R. A.; Gasteiger, H. A. Mater. Today 2018, 21, 231. doi: 10.1016/j.mattod.2017.11.001 doi: 10.1016/j.mattod.2017.11.001
108. [108]
  Pines, A.; Gibby, M. G.; Waugh, J. S. J. Chem. Phys. 1973, 59, 569. doi: 10.1063/1.1680061 doi: 10.1063/1.1680061
109. [109]
  Hartmann, S. R.; Hahn, E. L. Phys. Rev. 1962, 128, 2042. doi: 10.1103/PhysRev.128.2042 doi: 10.1103/PhysRev.128.2042
110. [110]
  Lesage, A.; Emsley, L. J. Magn. Reson. 2001, 148, 449. doi: 10.1006/jmre.2000.2249 doi: 10.1006/jmre.2000.2249
111. [111]
  Wang, Q.; Trébosc, J.; Li, Y.; Xu, J.; Hu, B.; Feng, N.; Chen, Q.; Lafon, O.; Amoureux, J. P.; Deng, F. Chem. Commun. 2013, 49, 6653. doi: 10.1039/C3CC42961J doi: 10.1039/C3CC42961J
112. [112]
  Trebosc, J.; Hu, B.; Amoureux, J. P.; Gan, Z. J. Magn. Reson. 2007, 186, 220. doi: 10.1016/j.jmr.2007.02.015 doi: 10.1016/j.jmr.2007.02.015
113. [113]
  Gan, Z. J. Magn. Reson. 2007, 184, 39. doi: 10.1016/j.jmr.2006.09.016 doi: 10.1016/j.jmr.2006.09.016
114. [114]
  Hu, B.; Trébosc, J.; Amoureux, J. P. J. Magn. Reson. 2008, 192, 112. doi: 10.1016/j.jmr.2008.02.004 doi: 10.1016/j.jmr.2008.02.004
115. [115]
  Cavadini, S.; Lupulescu, A.; Antonijevic, S.; Bodenhausen, G. J. Am. Chem. Soc. 2006, 128, 7706. doi: 10.1021/ja0618898 doi: 10.1021/ja0618898
116. [116]
  Peng, B.; Yao, Y.; Chen, Q.; Hu, B. Annual Rep. NMR Spectros. 2014, 85, 1. doi: 10.1016/bs.arnmr.2014.12.002 doi: 10.1016/bs.arnmr.2014.12.002
117. [117]
  Lee, H. H.; Park, Y.; Shin, K. H.; Lee, K. T.; Hong, S. Y. ACS Appl. Mater. Interfaces 2014, 6, 19118. doi: 10.1021/am505090p doi: 10.1021/am505090p
118. [118]
  Peng, C.; Ning, G. H.; Su, J.; Zhong, G.; Tang, W.; Tian, B.; Su, C.; Yu, D.; Zu, L.; Yang, J.; et al. Nat. Energy 2017, 2, 17074. doi: 10.1038/nenergy.2017.74 doi: 10.1038/nenergy.2017.74
119. [119]
  Griffith, K. J.; Wiaderek, K. M.; Cibin, G.; Marbella, L. E.; Grey, C. P. Nature 2018, 559, 556. doi: 10.1038/s41586-018-0347-0 doi: 10.1038/s41586-018-0347-0
120. [120]
  Xiang, Y. X.; Zheng, G.; Zhong, G.; Wang, D.; Fu, R.; Yang, Y. Solid State Ionics 2018, 318, 19. doi: 10.1016/j.ssi.2017.11.025 doi: 10.1016/j.ssi.2017.11.025
121. [121]
  Engelke, S.; Marbella, L. E.; Trease, N. M.; De Volder, M.; Grey, C. P. Phys. Chem. Chem. Phys. 2019, 21, 4538. doi: 10.1039/c8cp07776b doi: 10.1039/c8cp07776b
122. [122]
  Prutsch, D.; Gadermaier, B.; Brandstätter, H.; Pregartner, V.; Stanje, B.; Wohlmuth, D.; Epp, V.; Rettenwander, D.; Hanzu, I.; Wilkening, H. M. R. Chem. Mater. 2018, 30, 7575. doi: 10.1021/acs.chemmater.8b02753 doi: 10.1021/acs.chemmater.8b02753
123. [123]
  Liang, X.; Wang, L.; Jiang, Y.; Wang, J.; Luo, H.; Liu, C.; Feng, J. Chem. Mater. 2015, 27, 5503. doi: 10.1021/acs.chemmater.5b01384 doi: 10.1021/acs.chemmater.5b01384
124. [124]
  Kuhn, A.; Sreeraj, P.; Pottgen, R.; Wiemhofer, H. D.; Wilkening, M.; Heitjans, P. J. Am. Chem. Soc. 2011, 133, 11018. doi: 10.1021/ja2020108 doi: 10.1021/ja2020108
125. [125]
  Wilkening, M.; Heitjans, P. ChemPhysChem 2012, 13, 53. doi: 10.1002/cphc.201100580 doi: 10.1002/cphc.201100580
126. [126]
  Pigliapochi, R.; Seymour, I. D.; Merlet, C.; Pell, A. J.; Murphy, D. T.; Schmid, S.; Grey, C. P. Chem. Mater. 2018, 30, 817. doi: 10.1021/acs.chemmater.7b04314 doi: 10.1021/acs.chemmater.7b04314
127. [127]
  Middlemiss, D. S.; Ilott, A. J.; Clément, R. l. J.; Strobridge, F. C.; Grey, C. P. Chem. Mater. 2013, 25, 1723. doi: 10.1021/cm400201t doi: 10.1021/cm400201t
128. [128]
  Castets, A.; Carlier, D.; Zhang, Y.; Boucher, F.; Ménétrier, M. J. Phys. Chem. C 2012, 116, 18002. doi: 10.1021/jp302549s doi: 10.1021/jp302549s
129. [129]
  Liu, Y.; Zeng, L.; Xu, C.; Geng, F.; Shen, M.; Yuan, Q.; Hu, B. Chem. Phys. Lett. 2019, 736, 136779. doi: 10.1016/j.cplett.2019.136779 doi: 10.1016/j.cplett.2019.136779
130. [130]
  Liu, Z.; Lee, J.; Xiang, G.; Glass, H. F. J.; Keyzer, E. N.; Dutton, S. E.; Grey, C. P. Chem. Commun. 2017, 53, 743. doi: 10.1039/C6CC08430C doi: 10.1039/C6CC08430C
131. [131]
  Lee, J.; Seymour, I. D.; Pell, A. J.; Dutton, S. E.; Grey, C. P. Phys. Chem. Chem. Phys. 2017, 19, 613. doi: 10.1039/C6CP06338A doi: 10.1039/C6CP06338A
132. [132]
  Canepa, P.; Bo, S. H.; Sai Gautam, G.; Key, B.; Richards, W. D.; Shi, T.; Tian, Y.; Wang, Y.; Li, J.; Ceder, G. Nat. Commun. 2017, 8, 1759. doi: 10.1038/s41467-017-01772-1 doi: 10.1038/s41467-017-01772-1
133. [133]
  Leroy, C.; Bryce, D. L. Prog. Nucl. Magn. Reson. Spectrosc. 2018, 109, 160. doi: 10.1016/j.pnmrs.2018.08.002 doi: 10.1016/j.pnmrs.2018.08.002
134. [134]
  Leskes, M.; Kim, G.; Liu, T.; Michan, A. L.; Aussenac, F.; Dorffer, P.; Paul, S.; Grey, C. P. J. Phys. Chem. Lett. 2017, 8, 1078. doi: 10.1021/acs.jpclett.6b02590 doi: 10.1021/acs.jpclett.6b02590
135. [135]
  Chakrabarty, T.; Goldin, N.; Feintuch, A.; Houben, L.; Leskes, M. ChemPhysChem 2018, 19, 2139. doi: 10.1002/cphc.201800462 doi: 10.1002/cphc.201800462
136. [136]
  Wolf, T.; Kumar, S.; Singh, H.; Chakrabarty, T.; Aussenac, F.; Frenkel, A. I.; Major, D. T.; Leskes, M. J. Am. Chem. Soc. 2018, 141, 451. doi: 10.1021/jacs.8b11015 doi: 10.1021/jacs.8b11015
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