Citation: CHENG Long, LIU Gongping, JIN Wanqin. Recent Progress in Two-dimensional-material Membranes for Gas Separation[J]. Acta Physico-Chimica Sinica, ;2019, 35(10): 1090-1098. doi: 10.3866/PKU.WHXB201810059 shu

Recent Progress in Two-dimensional-material Membranes for Gas Separation

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China

Author Bio:

JIN Wanqin is a professor of chemical engineering at Nanjing Tech University. He received his PhD degree from Nanjing University of Technology in 1999. He was a research associate at the Institute of Materials Research & Engineering of Singapore (2001), an Alexander von Humboldt Research Fellow (2001-2013), and visiting professors at Arizona State University (2007) and Hiroshima University (2011, JSPS invitation fellowship). His current research focuses on membrane materials and processes
Corresponding author: JIN Wanqin, wqjin@njtech.edu.cn
Received Date: 26 October 2018
Revised Date: 23 November 2018
Accepted Date: 26 November 2018
Available Online: 28 October 2018
Fund Project: the National Natural Science Foundation of China 21476107the National Natural Science Foundation of China 21776125the Innovative Research Team Program of the Ministry of Education of China IRT17R54the National Natural Science Foundation of China 21490585the National Natural Science Foundation of China 51861135203The project was supported by the National Natural Science Foundation of China (21490585, 21476107, 21776125, 51861135203) and the Innovative Research Team Program of the Ministry of Education of China (IRT17R54)

Two-dimensional (2D) materials, led by graphene, have emerged as nano-building blocks to develop high-performance membranes. The atom-level thickness of nanosheets makes a membrane as thin as possible, thereby minimizing the transport resistance and maximizing the permeation flux. Meanwhile, the sieving channels can be precisely manipulated within sub-nanometer size for molecular separation, such as gas separation. For instance, graphene oxide (GO) channels with an interlayer height of about 0.4 nm assembled by external forces exhibited excellent H₂/CO₂ sieving performance compared to commercial membranes. Cross-linking was also employed to fabricate ultrathin (< 20 nm) GO-facilitated transport membranes for efficient CO₂ capture. A borate-crosslinked membrane exhibited a high CO₂ permeance of 650 GPU (gas permeation unit), and a CO₂/CH₄ selectivity of 75, which is currently the best performance reported for GO-based composite membranes. The CO₂-facilitated transport membrane with piperazine as the carrier also exhibited excellent separation performance under simulated flue gas conditions with CO₂ permeance of 1020 GPU and CO₂/N₂ selectivity as high as 680. In addition, metal-organic frameworks (MOFs) with layered structures, if successfully exfoliated, can serve as diverse sources for MOF nanosheets that can be fabricated into high-performance membranes. It is challenging to maintain the structural and morphological integrity of nanosheets. Poly[Zn₂(benzimidazole)₄] (Zn₂(bim)₄) was firstly exfoliated into 1-nm-thick nanosheets and assembled into ultrathin membranes possessing both high permeance and excellent molecular sieving properties for H₂/CO₂ separation. Interestingly, reversed thermo-switchable molecular sieving was also demonstrated in membranes composed of 2D MOF nanosheets. Besides, researchers employed layered double hydroxides (LDHs) to prepare molecular-sieving membranes via in situ growth, and the as-prepared membranes showed a remarkable selectivity of ~80 for H₂-CH₄ mixture. They concluded that the amount of CO₂ in the precursor solution contributed to LDH membranes with various preferred orientations and thicknesses. Apart from these 2D materials, MXenes also show great potential in selective gas permeation. Lamellar stacked MXene membranes with aligned and regular sub-nanometer channels exhibited excellent gas separation performance. Moreover, our ultrathin (20 nm) MXene nanofilms showed outstanding molecular sieving property for the preferential transport of H₂, with H₂ permeance as high as 1584 GPU and H₂/CO₂ selectivity of 27. The originally H₂-selective MXene membranes could be transformed into membranes selectively permeating CO₂ by chemical tuning of the MXene nanochannels. This paper briefly reviews the latest groundbreaking studies in 2D-material membranes for gas separation, with a focus on sub-nanometer 2D channels, exfoliation of 2D nanosheets with structural integrity, and tunable gas transport property. Challenges, in terms of the mass production of 2D nanosheets, scale-up of lab-level membranes and a thorough understanding of the transport mechanism, and the potential of 2D-material membranes for wide implementation are briefly discussed.
- Two-dimensional material,
- Gas separation membrane,
- Sub-nanometer channel,
- Ultrathin membrane,
- Tunable gas transport
1. [1]
2. [2]
  Liu, G. P.; Jin, W. Q.; Xu, N. P. Angew. Chem. Int. Ed. 2016, 55, 13384. doi: 10.1002/anie.201600438 doi: 10.1002/anie.201600438
3. [3]
  Bunch, J. S.; Verbridge, S. S.; Alden, J. S.; van der Zande, A. M.; Parpia, J. M.; Craighead, H. G.; McEuen, P. L. Nano Lett. 2008, 8, 2458. doi: 10.1021/nl801457b doi: 10.1021/nl801457b
4. [4]
  Jiang, D. E.; Cooper, V. R.; Dai, S. Nano Lett. 2009, 9, 4019. doi: 10.1021/nl9021946 doi: 10.1021/nl9021946
5. [5]
6. [6]
  Koenig, S. P.; Wang, L.; Pellegrino, J.; Bunch, J. S. Nature Nanotech. 2012, 7, 728. doi: 10.1038/nnano.2012.162 doi: 10.1038/nnano.2012.162
7. [7]
  Celebi, K.; Buchheim, J.; Wyss, R. M.; Droudian, A.; Gasser, P.; Shorubalko, I.; Kye, J. I.; Lee, C.; Park, H. G. Science 2014, 344, 289. doi: 10.1126/science.1249097 doi: 10.1126/science.1249097
8. [8]
  (a) Kim, H. W.; Yoon, H. W.; Yoon, S. M.; Yoo, B. M.; Ahn, B. K.; Cho, Y. H.; Shin, H. J.; Yang, H.; Paik, U.; Kwon, S.; et al. Science 2013, 342, 91. 10.1126/science.1236098
  (b) Li, H.; Song, Z.; Zhang, X.; Huang, Y.; Li, S.; Mao, Y.; Ploehn, H. J.; Bao, Y.; Yu, M. Science 2013, 342, 95. doi: 10.1126/science.1236686
9. [9]
  Shen, J.; Liu, G.; Huang, K.; Chu, Z.; Jin, W.; Xu, N. ACS Nano 2016, 10, 3398. doi: 10.1021/acsnano.5b07304 doi: 10.1021/acsnano.5b07304
10. [10]
  Chen, L.; Shi, G. S.; Shen, J.; Peng, B. Q.; Zhang, B. W.; Wang, Y. Z.; Bian, F. G.; Wang, J. J.; Li, D. Y.; Qian, Z.; et al. Nature 2017, 550, 415. doi: 10.1038/nature24044 doi: 10.1038/nature24044
11. [11]
  Hu, M.; Mi, B. Environ. Sci. Technol. 2013, 47, 3715. doi: 10.1021/es400571g doi: 10.1021/es400571g
12. [12]
  Hung, W. S.; Tsou, C. H.; De Guzman, M.; An, Q. F.; Liu, Y. L.; Zhang, Y. M.; Hu, C. C.; Lee, K. R.; Lai, J. Y. Chem. Mater. 2014, 26, 2983. doi: 10.1021/cm5007873 doi: 10.1021/cm5007873
13. [13]
  Wang, S.; Wu, Y.; Zhang, N.; He, G.; Xin, Q.; Wu, X.; Wu, H.; Cao, X.; Guiver, M. D.; Jiang, Z. Energ. Environ. Sci. 2016, 9, 3107. doi: 10.1039/c6ee01984f doi: 10.1039/c6ee01984f
14. [14]
  Zhou, F.; Tien, H. N.; Xu, W. L.; Chen, J. T.; Liu, Q.; Hicks, E.; Fathizadeh, M.; Li, S.; Yu, M. Nat. Commun. 2017, 8, 2107. doi: 10.1038/s41467-017-02318-1 doi: 10.1038/s41467-017-02318-1
15. [15]
  Peng, Y.; Li, Y.; Ban, Y.; Jin, H.; Jiao, W.; Liu, X.; Yang, W. Science 2014, 346, 1356. doi: 10.1126/science.1254227 doi: 10.1126/science.1254227
16. [16]
  Wang, X.; Chi, C.; Zhang, K.; Qian, Y.; Gupta, K. M.; Kang, Z.; Jiang, J.; Zhao, D. Nat. Commun. 2017, 8, 14460. doi: 10.1038/ncomms14460 doi: 10.1038/ncomms14460
17. [17]
  Wang, Q.; O'Hare, D. Chem. Rev. 2012, 112, 4124. doi: 10.1021/cr200434v doi: 10.1021/cr200434v
18. [18]
  Liu, Y.; Wang, N.; Cao, Z.; Caro, J. J. Mater. Chem. A 2014, 2, 1235. doi: 10.1039/c3ta13792a doi: 10.1039/c3ta13792a
19. [19]
  Liu, Y.; Wang, N.; Caro, J. J. Mater. Chem. A 2014, 2, 5716. doi: 10.1039/c4ta00108g doi: 10.1039/c4ta00108g
20. [20]
  Naguib, M.; Kurtoglu, M.; Presser, V.; Lu, J.; Niu, J.; Heon, M.; Hultman, L.; Gogotsi, Y.; Barsoum, M. W. Adv. Mater. 2011, 23, 4248. doi: 10.1002/adma.201102306 doi: 10.1002/adma.201102306
21. [21]
  Ding, L.; Wei, Y.; Li, L.; Zhang, T.; Wang, H.; Xue, J.; Ding, L. X.; Wang, S.; Caro, J.; Gogotsi, Y. Nat. Commun. 2018, 9, 155. doi: 10.1038/s41467-017-02529-6 doi: 10.1038/s41467-017-02529-6
22. [22]
  Shen, J.; Liu, G.; Ji, Y.; Liu, Q.; Cheng, L.; Guan, K.; Zhang, M.; Liu, G.; Xiong, J.; Yang, J.; et al. Adv. Funct. Mater. 2018, 28, 1801511. doi: 10.1002/adfm.201801511 doi: 10.1002/adfm.201801511
23. [23]
  Zhang, P.; Li, J.; Lv, L.; Zhao, Y.; Qu, L. ACS Nano 2017, 11, 5087. doi: 10.1021/acsnano.7b01965 doi: 10.1021/acsnano.7b01965
1. [1]
  Xin-Tong Zhao , Jin-Zhi Guo , Wen-Liang Li , Jing-Ping Zhang , Xing-Long Wu . Two-dimensional conjugated coordination polymer monolayer as anode material for lithium-ion batteries: A DFT study. Chinese Chemical Letters, 2024, 35(6): 108715-. doi: 10.1016/j.cclet.2023.108715
2. [2]
  Yan Zou , Yin-Shuang Hu , Deng-Hui Tian , Hong Wu , Xiaoshu Lv , Guangming Jiang , Yu-Xi Huang . Tuning the membrane rejection behavior by surface wettability engineering for an effective water-in-oil emulsion separation. Chinese Chemical Letters, 2024, 35(6): 109090-. doi: 10.1016/j.cclet.2023.109090
3. [3]
  Changle Liu , Mingyuzhi Sun , Haoran Zhang , Xiqian Cao , Yuqing Li , Yingtang Zhou . All in one doubly pillared MXene membrane for excellent oil/water separation, pollutant removal, and anti-fouling performance. Chinese Journal of Structural Chemistry, 2024, 43(8): 100355-100355. doi: 10.1016/j.cjsc.2024.100355
4. [4]
  Si-Hua Liu , Jun-Hao Zhou , Jian-Ke Sun . Interconnecting zero-dimensional porous organic cages into sub-8 nm nanofilm for bio-inspired separation. Chinese Journal of Structural Chemistry, 2024, 43(7): 100312-100312. doi: 10.1016/j.cjsc.2024.100312
5. [5]
  Ningning Gao , Yue Zhang , Zhenhao Yang , Lijing Xu , Kongyin Zhao , Qingping Xin , Junkui Gao , Junjun Shi , Jin Zhong , Huiguo Wang . Ba²⁺/Ca²⁺ co-crosslinked alginate hydrogel filtration membrane with high strength, high flux and stability for dye/salt separation. Chinese Chemical Letters, 2024, 35(5): 108820-. doi: 10.1016/j.cclet.2023.108820
6. [6]
  Yixin Zhang , Ting Wang , Jixiang Zhang , Pengyu Lu , Neng Shi , Liqiang Zhang , Weiran Zhu , Nongyue He . Formation mechanism for stable system of nanoparticle/protein corona and phospholipid membrane. Chinese Chemical Letters, 2024, 35(4): 108619-. doi: 10.1016/j.cclet.2023.108619
7. [7]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
8. [8]
  Tian Yang , Yi Liu , Lina Hua , Yaoyao Chen , Wuqian Guo , Haojie Xu , Xi Zeng , Changhao Gao , Wenjing Li , Junhua Luo , Zhihua Sun . Lead-free hybrid two-dimensional double perovskite with switchable dielectric phase transition. Chinese Chemical Letters, 2024, 35(6): 108707-. doi: 10.1016/j.cclet.2023.108707
9. [9]
  Zhuoer Cai , Yinan Zhang , Xiu-Ni Hua , Baiwang Sun . Phase transition arising from order-disorder motion in stable layered two-dimensional perovskite. Chinese Journal of Structural Chemistry, 2024, 43(11): 100426-100426. doi: 10.1016/j.cjsc.2024.100426
10. [10]
  Xiaoyan Peng , Xuanhao Wu , Fan Yang , Yefei Tian , Mingming Zhang , Hongye Yuan . Gas sensors based on metal-organic frameworks: challenges and opportunities. Chinese Journal of Structural Chemistry, 2024, 43(3): 100251-100251. doi: 10.1016/j.cjsc.2024.100251
11. [11]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
12. [12]
  Kexin Yuan , Yulei Liu , Haoran Feng , Yi Liu , Jun Cheng , Beiyang Luo , Qinglian Wu , Xinyu Zhang , Ying Wang , Xian Bao , Wanqian Guo , Jun Ma . Unlocking the potential of thin-film composite reverse osmosis membrane performance: Insights from mass transfer modeling. Chinese Chemical Letters, 2024, 35(5): 109022-. doi: 10.1016/j.cclet.2023.109022
13. [13]
  Xubin Qian , Lei Xu , Xu Ge , Zhun Liu , Cheng Fang , Jianbing Wang , Junfeng Niu . Can perfluorooctanoic acid be effectively degraded using β-PbO₂ reactive electrochemical membrane?. Chinese Chemical Letters, 2024, 35(7): 109218-. doi: 10.1016/j.cclet.2023.109218
14. [14]
  Lingna Wang , Chenxin Tian , Ruobin Dai , Zhiwei Wang . Eco-friendly regeneration of end-of-life PVDF membrane with triethyl phosphate: Efficiency and mechanism. Chinese Chemical Letters, 2024, 35(9): 109356-. doi: 10.1016/j.cclet.2023.109356
15. [15]
  Ying Gao , Rong Zhou , Qiwen Wang , Shaolong Qi , Yuanyuan Lv , Shuang Liu , Jie Shen , Guocan Yu . Natural killer cell membrane doped supramolecular nanoplatform with immuno-modulatory functions for immuno-enhanced tumor phototherapy. Chinese Chemical Letters, 2024, 35(10): 109521-. doi: 10.1016/j.cclet.2024.109521
16. [16]
  Zhihong LUO , Yan SHI , Jinyu AN , Deyi ZHENG , Long LI , Quansheng OUYANG , Bin SHI , Jiaojing SHAO . Two-dimensional silica-modified polyethylene oxide solid polymer electrolyte to enhance the performance of lithium-ion batteries. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 1005-1014. doi: 10.11862/CJIC.20230444
17. [17]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
18. [18]
  Xuan Zhu , Lin Zhou , Xiao-Yun Huang , Yan-Ling Luo , Xin Deng , Xin Yan , Yan-Juan Wang , Yan Qin , Yuan-Yuan Tang . (Benzimidazolium)2GeI4: A layered two-dimensional perovskite with dielectric switching and broadband near-infrared photoluminescence. Chinese Journal of Structural Chemistry, 2024, 43(6): 100272-100272. doi: 10.1016/j.cjsc.2024.100272
19. [19]
  Yuting Wu , Haifeng Lv , Xiaojun Wu . Design of two-dimensional porous covalent organic framework semiconductors for visible-light-driven overall water splitting: A theoretical perspective. Chinese Journal of Structural Chemistry, 2024, 43(11): 100375-100375. doi: 10.1016/j.cjsc.2024.100375
20. [20]
  Chenlu Huang , Xinyu Yang , Qingyu Yu , Linhua Zhang , Dunwan Zhu . Gas-generating polymersomes-based amplified photoimmunotherapy for abscopal effect and tumor metastasis inhibition. Chinese Chemical Letters, 2024, 35(6): 109680-. doi: 10.1016/j.cclet.2024.109680

Get Citation

PDF

XML

Metrics

PDF Downloads(8)
Abstract views(640)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142